Determination of mineralization age and ore-forming materials of the Dingjiashan Pb-Zn deposit in the Meixian ore concentration area, the central Fujian Province: evidence from the sphalerite Rb-Sr isotope
-
摘要:
丁家山铅锌矿床位于闽中梅仙矿集区西南部, 矿体多呈层状、似层状和透镜状, 产于中—新元古界马面山群龙北溪组的绿片岩和大理岩中。为查明该矿床的成矿时代, 对该矿床中的主要矿石矿物闪锌矿开展了Rb-Sr同位素测年。8件闪锌矿样品构成的等时线年龄为143.1±3.2Ma(MSWD=1.7), 表明该矿床形成于燕山中期晚侏罗世。闪锌矿的锶同位素(初始比值为0.71434±0.00036)及前人的硫、铅同位素研究成果共同指示, 丁家山矿床的成矿物质可能主要来源于下地壳的深源岩浆。综合分析认为, 丁家山矿床形成于古太平洋板块向欧亚大陆板块俯冲-消减后的伸展引张环境背景下, 是晚侏罗世到早白垩世期间的花岗岩体与中—新元古界的大理岩经接触交代后的矽卡岩型矿床。作为梅仙矿集区的典型铅锌矿床, 丁家山矿床的成矿时代对区内其他铅锌矿床的成矿时代具有一定约束意义。
Abstract:The Dingjiashan Pb -Zn deposit is located in the southwest of the Meixian ore concentration area in the central Fujian province. The Pb -Zn orebodies are predominantly hosted in the Meso-Neoproterozoic greenschist and marble of the Longbeixi Formation belonging to the Mamianshan Group in the layer, layer-like, and lenticular shape. In this contribution, the Rb-Sr dating for sphalerite was carried out in order to determine the mineralization age of the deposit. The isochron age of 8 sphalerite samples is 143.1 ±3.2 Ma (MSWD = 1.7), indicating that the deposit was formed in the Late Jurassic. The initial 87Sr/86Sr ratio of the sphalerite (0.71434 ±0.00036) and the previous S-Pb isotope studies indicate that the ore-forming materials at Dingjiashan may mainly source from deep-seated magma in the lower crust. Base on the above analyses, it is considered that the Dingjiashan deposit was formed under the condition of the extensional environment caused by the subduction of the ancient Pacific plate to the Eurasian continental plate, and was the product of contact metasomatism between the Late Jurassic to Early Cretaceous granite intrusions and the Meso -Neoproterozoic marble. The mineralization age of the Dingjiashan deposit has a constraint on that of the other Pb-Zn deposits from the Meixian ore concentration area.
-
-
图 1 闽中地区地质构造略图(据参考文献[23]修改)
Figure 1.
图 6 锶同位素在地壳和地幔中的演化(底图据参考文献[41])
Figure 6.
表 1 丁家山铅锌矿床闪锌矿Rb-Sr测试分析结果
Table 1. Rb-Sr isotopic analytical results of sphalerite from the Dingjiashan Pb-Zn deposit
样品编号 Rb/10-6 Sr/10-6 87Rb/86Sr 87Sr/86Sr 2σ DJS-30-2 15.55 0.09844 502.9 1.73354 0.00006 DJS-50 6.183 0.5019 35.78 0.78505 0.00003 DJS-17-1 5.246 5.462 2.773 0.72046 0.00004 DJS-17-2 1.07 0.3524 8.773 0.73287 0.00006 DJS-96 0.5741 8.908 0.1859 0.71422 0.00003 DJS-110 32.23 0.3281 298.5 1.31855 0.00007 DJS-165 184.9 1.86 304.2 1.32185 0.00008 DJS-170 3.498 0.9928 10.18 0.73522 0.00003 -
[1] 翟裕生, 王建平, 邓军, 等. 成矿系统时空演化及其找矿意义[J]. 现代地质, 2008, 2: 143-150. doi: 10.3969/j.issn.1000-8527.2008.02.001
[2] Stein H J, Markey R J, Morgan J W, et al. Highly precise and accurate Re-Os ages for molybdenite from the East Qinling molybdenum belt, Shaanxi Province, China[J]. Economic Geology, 1997, 92: 827-835. doi: 10.2113/gsecongeo.92.7-8.827
[3] 刘建明, 沈洁, 赵善仁, 等. 金属矿床同位素精确定年的方法和意义[J]. 有色金属矿产与勘查, 1998, 2: 44-50. https://www.cnki.com.cn/Article/CJFDTOTAL-YSJS802.007.htm
[4] Mao J W, Zhang Z C, Zhang Z H, et al. Re-Os isotopic dating of molybdenites in the Xiaoliugou W(Mo(deposit in the northern Qilian mountains and its geological significance[J]. Geochimica et Cosmochimica Acta, 1999, 63: 1815-1818. doi: 10.1016/S0016-7037(99)00165-9
[5] 毛景文, 谢桂青, 张作衡, 等. 中国北方中生代大规模成矿作用的期次及其地球动力学背景[J]. 岩石学报, 2005, 21(1): 169-188. https://www.cnki.com.cn/Article/CJFDTOTAL-YSXB200501018.htm
[6] 毛景文, 胡瑞忠, 陈毓川, 等. 大规模成矿作用与大型矿集区[M]. 北京: 地质出版社, 2006.
[7] Liu P, Mao J W, Pirajno F, et al. Ore genesis and geodynamic setting of the Lianhuashan porphyry tungsten deposit, eastern Guangdong Province, SE China: constraints from muscovite 40Ar-39Ar and zircon U-Pb dating and Hf isotopes[J]. Mineralium Deposita, 2017, 53: 797-814.
[8] 赵葵东, 蒋少涌. 金属矿床的同位素直接定年方法[J]. 地学前缘, 2004, 11(2): 425-434. doi: 10.3321/j.issn:1005-2321.2004.02.012
[9] Nakai S, Halliday A N, Kesler S E, et al. Rb-Sr dating of sphalerites from Tennessce and the genesis of Mississippi Vally type ore deposit[J]. Nature, 1990, 34: 354-357.
[10] Nakai S, Halliday A N, Kesler S E, et al. Rb-Sr dating of sphalerites from Mississippi Vally-type(MVT)ore deposit[J]. Geochemica et Cosmochimica Acta, 1993, 57: 417-427. doi: 10.1016/0016-7037(93)90440-8
[11] Christensen J N, Halliday A N, Vearncombe J R, et al. Testing models of large-scale crustal fluid flow using direct dating of sulfides; Rb-Sr evidence for early dewatering and formation of Mississippi valley-type deposits, Canning Basin, Australia[J]. Economic Geology, 1995, 90(4): 877-884. doi: 10.2113/gsecongeo.90.4.877
[12] Pettke T, Diamond L W. Rb-Sr dating of sphalerite based on fluid inclusion-host mineral isochrons; a clarification of why it works[J]. Economic Geology, 1996, 91(5): 951-956. doi: 10.2113/gsecongeo.91.5.951
[13] 石得凤. 福建尤溪丁家山铅锌矿矿床成因、成矿机理及成矿规律研究[D]. 中南大学博士学位论文, 2012.
[14] 龚银杰, 张遵遵, 陈立波, 等. 川东南褶皱带洞岩铅锌矿床闪锌矿Rb-Sr同位素测年及其构造变形时代[J]. 中国地质, 2020, 47(2): 485-496. https://www.cnki.com.cn/Article/CJFDTOTAL-DIZI202002016.htm
[15] 曹亮, 段其发, 周云. 湖北凹子岗锌矿床Rb-Sr同位素测年及其地质意义[J]. 中国地质, 2015, 42(1): 235-247. doi: 10.3969/j.issn.1000-3657.2015.01.019
[16] 毛景文, 谢桂青, 袁顺达, 等. 环太平洋成矿带斑岩-矽卡岩型铜矿和与花岗岩有关的锡多金属矿研究现状与展望(英文, [J]. 岩石学报, 2018, 34(9): 2501-2517. https://www.cnki.com.cn/Article/CJFDTOTAL-YSXB201809001.htm
[17] 周兵, 顾连兴. 论梅仙块状硫化物矿床的特征及成矿地质环境[J]. 矿床地质, 1999, 18(2): 99-109. doi: 10.3969/j.issn.0258-7106.1999.02.001
[18] 叶水泉, 倪大平, 吴志强. 福建省梅仙式块状硫化物矿床[J]. 火山地质与矿产, 1999, 20(3): 172-178. https://www.cnki.com.cn/Article/CJFDTOTAL-HSDZ199903001.htm
[19] 吴志强. 福建省梅仙铅锌银矿田成矿地质特征和成因模式[J]. 矿产与地质, 2003, (5): 606-609. doi: 10.3969/j.issn.1001-5663.2003.05.006
[20] 张生辉, 石建基, 狄永军, 等. 闽中裂谷块状硫化物型铅锌矿床的地质特征及找矿意义[J]. 现代地质, 2005, 19(3): 375-384. doi: 10.3969/j.issn.1000-8527.2005.03.009
[21] 黄仁生. 福建尤溪梅仙矿田铅锌银矿床特征及找矿方向[J]. 福建地质, 2006, 26(4): 211-221. https://www.cnki.com.cn/Article/CJFDTOTAL-FJDZ200704000.htm
[22] 陈振宁. 福建省尤溪县谢坑铅锌多金属矿区地质特征及成因研究[D]. 南京大学硕士学位论文, 2017.
[23] 袁莹. 福建尤溪丁家山铅锌矿区龙北溪组变质岩岩石学特征——原岩恢复及成因探讨[D]. 中南大学硕士学位论文, 2011.
[24] 孙洪涛, 雷如雄, 陈世忠, 等. 闽中裂谷带梅仙铅锌矿区花岗斑岩的LA-ICP-MS锆石U-Pb年龄、成因及成矿效应[J]. 吉林大学学报(地球科学版). 2014, 44(2): 527-539. https://www.cnki.com.cn/Article/CJFDTOTAL-CCDZ201402012.htm
[25] 丰成友, 丰耀东, 张德全, 等. 闽中梅仙式铅锌银矿床矿质来源的硫、铅同位素示踪及成矿时代[J]. 地质学报, 2007, 81(7): 906-916. doi: 10.3321/j.issn:0001-5717.2007.07.005
[26] 周兵, 顾连兴, 李玉荷. 福建两个块状硫化物矿床中磁黄铁矿结构的研究[J]. 岩石矿物学杂志, 1998, (1): 69-74. https://www.cnki.com.cn/Article/CJFDTOTAL-YSKW801.008.htm
[27] 张术根, 石得凤, 韩世礼, 等. 福建丁家山铅锌矿区磁黄铁矿成因矿物学特征研究[J]. 矿物岩石, 2011, 31(3): 11-17. doi: 10.3969/j.issn.1001-6872.2011.03.003
[28] 周兵, 顾连兴, 张文兰, 等. 福建尤溪梅仙矿床闪锌矿中黄铜矿交生体的交代成因[J]. 地质论评, 1999, 45(1): 15-19. https://www.cnki.com.cn/Article/CJFDTOTAL-DZLP199901002.htm
[29] 狄永军, 吴淦国, 张达, 等. 闽中地区铅锌矿床辉石成分特征及其成因意义[J]. 矿床地质, 2006, 25(2): 123-134. https://www.cnki.com.cn/Article/CJFDTOTAL-KCDZ200602001.htm
[30] 石得凤, 张术根, 韩世礼, 等. 福建梅仙丁家山铅锌矿成矿系统分析[J]. 中国有色金属学报, 2012, 22(3): 809-818. https://www.cnki.com.cn/Article/CJFDTOTAL-ZYXZ201203023.htm
[31] 毛建仁, 陶奎元, 陈三元, 等. 闽西南花岗质岩浆作用与成矿[J]. 火山地质与矿产, 1998, (4): 311-320. https://www.cnki.com.cn/Article/CJFDTOTAL-HSDZ199804007.htm
[32] 肖晓牛, 费利东, 余新明, 等. 闽中梅仙铅锌多金属矿区花岗岩锆石U-Pb年龄、Sr-Nd同位素组成特征及其地质意义[J]. 地质通报, 2019, 38(10): 1733-1739. http://dzhtb.cgs.cn/gbc/ch/reader/view_abstract.aspx?file_no=20191014&flag=1
[33] 肖晓牛, 肖娥, 陈振宁, 等. 闽中梅仙铅锌多金属矿区花岗岩锆石U-Pb年代学、地球化学特征及其地质意义[J]. 地学前缘, 2020, 27(4): 158-171. https://www.cnki.com.cn/Article/CJFDTOTAL-DXQY202004016.htm
[34] Ludwig K R. Users manual for Isoplot/EX(rev. 2.49. ): A geochronological toolkit for miscrosoft Excel[M]. Berkeley: Berkeley Geochronology Center Special Publication, 2001: 1-55.
[35] Brannon J C, Podosek F A, McLimans R K. A Permian Rb-Sr age for sphalerite from the Upper Mississippi Valley zinc-lead district, southwest Wisconsin[J]. Nature, 1992, 356: 509-511.
[36] 段其发, 曹亮, 曾健康, 等. 湘西花垣矿集区狮子山铅锌矿床闪锌矿Rb-Sr定年及地质意义[J]. 地球科学——中国地质大学学报, 2014, 39(8): 977-986, 999. https://www.cnki.com.cn/Article/CJFDTOTAL-DQKX201408004.htm
[37] 魏菊英, 王关玉. 同位素地球化学[M]. 北京: 地质出版社, 1987: 22-41.
[38] 姚海涛, 郑海飞. 流体包裹体Rb-Sr等时线定年的可靠性[J]. 地球化学, 2001, (6): 507-511. https://www.cnki.com.cn/Article/CJFDTOTAL-DQHX200106000.htm
[39] 李文博, 黄智龙, 许德如, 等. 铅锌矿床Rb-Sr定年研究综[J]. 大地构造与成矿学, 2002, (4): 436-441. https://www.cnki.com.cn/Article/CJFDTOTAL-DGYK200204014.htm
[40] 郑伟, 陈懋弘, 徐林刚, 等. 广东天堂铜铅锌多金属矿床Rb-Sr等时线年龄及其地质意义[J]. 矿床地质, 2013, 32(2): 259-272. https://www.cnki.com.cn/Article/CJFDTOTAL-KCDZ201302004.htm
[41] Faure G. Principles of Isotope Geology[M]. New York: John Wiley & Sons(2nd edition), 1986.
[42] Bell K, Anglin C D, Franklin J M. Sm-Nd and Rb-Sr isotope systematics of schieelites: possible implications for the age and genesis of vein-hosted gold deposits[J]. Geology, 1989, 17(6): 500-504.
[43] Dension R E, Koepnick R B, Burke W H, et al., Construction of the Cambrian and Ordovician Seawater 87Sr/86Sr Curve[J]. Chemical Geology, 1998, 152: 325-340.
[44] 毛景文, 华仁民, 李晓波. 浅议大规模成矿作用与大型矿集区[J]. 矿床地质, 1999, 18(4): 291-299. https://www.cnki.com.cn/Article/CJFDTOTAL-KCDZ199904000.htm
[45] 华仁民, 毛景文. 试论中国东部中生代成矿大爆发[J]. 矿床地质, 1999, 18(4): 300-308. https://www.cnki.com.cn/Article/CJFDTOTAL-KCDZ199904001.htm
[46] 南京大学地质系. 华南不同时代花岗岩类及其与成矿关系[M]. 北京: 科学出版社, 1981.
[47] 吴淦国, 张达, 陈柏林. 中国东南大陆中生代构造域的转换及其成矿的关系——以闽西南地区为例[J]. 地球科学, 2000, 25(4): 390-396. https://www.cnki.com.cn/Article/CJFDTOTAL-DQKX200004011.htm
[48] 张达, 吴淦国, 狄永军, 等. 闽中梅仙峰岩铅锌矿床地球化学特征及其古构造环境[J]. 地质力学学报, 2009, 15(1): 20-35. https://www.cnki.com.cn/Article/CJFDTOTAL-DZLX200901003.htm
① 华东有色地质矿产勘查开发院. 福建省尤溪县丁家山矿区3~29线铅锌矿2012年资源储量核实报告. 2012.
-