-
摘要: 随着能源消费持续升高,常规资源无法满足日常需求,进行深井钻探显得尤为重要。然而,井底深部高温带来的钻井液粘度增加、流变性变差等问题,致使降粘剂成为不可缺少的钻井液处理剂之一。降粘剂主要通过拆散或阻拦粘土颗粒间形成网架结构,从而达到降低钻井液粘度、改善流变性的目的。结合相关研究文献,综述近十年来国内钻井液降粘剂的研究现状,介绍了3大类降粘剂:合成聚合物类、改性天然材料类、利用工业废料制备降粘剂。针对目前存在的问题,指出未来应从分子结构设计层面研发低成本、环保、适用于高温高盐高密度钻井液的降粘剂,同时注重工业废料的利用,积极与现场应用相结合加快成果转化。近年来,合成聚合物类降粘剂研究量居多、发展最迅速,本文着重介绍了此类降粘剂的发展现状及应用前景。Abstract: As energy consumption continues to rise, and conventional resources cannot meet daily needs, deep well drilling is particularly important. However, problems such as increased viscosity of drilling fluid, deterioration of rheology caused by high temperature at the bottom of the well have made the high temperature resistant viscosity reducer one of the indispensable drilling fluid treatment agents. To reduce the viscosity of the drilling fluid and improve the rheology, viscosity reducers mainly disassemble or block the formation of the grid structure between clay particles. In reference to the relevant research literature, this paper summarizes the research status of domestic drilling fluid viscosity reducers in the past ten years with emphasis on three types of viscosity reducers: synthetic polymers, modified natural materials, and industrial waste-made viscosity reducers. In view of the current problems, it is pointed out that in the future, low-cost and environment-friendly viscosity reducers suitable for high-temperature, high-salt and high-density drilling fluids should be developed at the molecular structure design level. At the same time, it pays attention to the utilization of industrial waste and the speeding up of the technology transformation through field applications. In recent years, synthetic polymer viscosity reducers have been studied mostly and developed the fastest. This article focuses on the development status and prospects of this type of viscosity reducer.
-
-
[1] 李旭方,熊正强.抗高温环保水基钻井液研究进展[J].探矿工程(岩土钻掘工程),2019,46(9):32-39.
LI Xufang, XIONG Zhengqiang. Research progress on high temperature resistant and environment friendly water-based drilling fluid[J]. Exploration Engineering (Rock& Soil Drilling and Tunneling), 2019,46(9):32-39.
[2] [2] 刘畅,冉恒谦,许洁.干热岩耐高温钻井液的研究进展与发展趋势[J].钻探工程,2021,48(2):8-15.
LIU Chang, RAN Hengqian, XU Jie. Research progress and development trend of high-temperature drilling fluid in hor dry rock[J]. Drilling Engineering, 2021,48(2):8-15.
[3] [3] 苏光.探究钻井液用降粘剂的合成与评价[J].化工管理,2018(1):221.SU Guang. Explore the synthesis and evaluation of viscosity reducers for drilling fluids[J]. Chemical Enterprise Management, 2018(1):221.
[4] [4] 曹秀云.环保型稀释剂HBF-1的室内评价[J].化工管理,2020(9):65-66.
CAO Xiuyun. Indoor evaluation of environmentally friendly thinner HBF-1[J]. Chemical Enterprise Management, 2020(9): 65-66.
[5] [5] 陈娟娟.抗温耐盐钻井液降粘剂开发与机理研究[D].大庆:东北石油大学,2014.CHEN Juanjuan. Research on high-temperature resistance and salt-tolerance thinner for drilling fluid and mechanism of action[D]. Daqing: Northeast Petroleum University, 2014.
[6] [6] 刘立新,杜俊涛,刘顺平,等.耐高温钻井液降黏剂St/AMPS/AA的研制[J].钻井液与完井液,2012,29(2):18-20,90.
LIU Lixin, DU Juntao, LIU Shunping, et al. Research on high temperature drilling fluid thinner St/AMPS/AA[J]. Drilling Fluid & Completion Fluid, 2012,29(2):18-20,90.
[7] [7] 张龙军,彭波,彭商平,等.不同链转移剂制备丙烯酸/2-丙烯酰胺基-2-甲基丙磺酸共聚物及其降黏性能研究[J].精细石油化工,2013,30(6):4-7.
ZHANG Longjun, PENG Bo, PENG Shangping, et al. Synthesis of AA/AMPS copolymer with different chain-transfer agents and its properties as visocsity reducer[J]. Speciality Petrochemicals, 2013,30(6):4-7.
[8] [8] 黄维安,贾江鸿,李树皎,等.抗高温低聚物KGDP的研制及在深井钻井中的应用[J].西安石油大学学报(自然科学版),2015,30(3):72-76,10.
HUANG Weian, JIA Jianghong, LI Shujiao, et al. Development of low molecular polymer (KGDP) with high-temperature resistance and its application in drilling fluid for deep wells[J]. Journal of Xi’an Shiyou University (Natural Science Edition), 2015, 30(3):72-76,10.
[9] [9] 鲁家荣.抗高温抗高浓度盐水基钻井液降黏剂研制与效果评价[D].成都:西南石油大学,2015.LU Jiarong. Development and effect evaluation of viscosity reducer for high temperature and high concentration brine-based drilling fluid[D]. Chengdu: Journal of Southwest Petroleum University, 2015.
[10] [10] 贾敏,黄维安,邱正松,等.超高温(240℃)抗盐聚合物降粘剂的合成与评价[J].化学试剂,2015,37(12):1067-1072.
JIA Min, HUANG Weian, QIU Zhengsong, et al. Synthesis and evaluation of polymer viscosity reducer with ultra-high temperature (240℃) and salt tolerance[J]. Chemical Reagents, 2015,37(12):1067-1072.
[11] [11] 夏凯.抗高温共聚物降粘剂的合成及其性能研究[D].武汉:武汉理工大学,2016.XIA Kai. Study on the synthesis and properties of copolymer viscosity agent with high temperature resistance[D]. Wuhan: Journal of Wuhan University of Technology, 2016.
[12] [12] 张晶.抗高温钻井液降粘剂的研究及性能评价[J].中国石油和化工标准与质量,2014,34(11):48.ZHANG Jing. Research and performance evaluation of anti-high temperature drilling fluid viscosity reducer[J]. China Petroleum and Chemical Standard and Quality, 2014,34(11):48.
[13] [13] 张太亮,许诗雪,黄志宇.抗高温钻井液聚合物降粘剂研究[J].应用化工,2014,43(8):1473-1476,1488.
ZHANG Tailiang, XU Shixue, HUANG Zhiyu. Research on drilling fluid polymer viscosity reducer with high temperature resistance[J]. Applied Chemical Industry, 2014,43(8):1473-1476,1488.
[14] [14] 鲁家荣,王平全,王波,等.钻井液用高效降粘剂HRT的研制与评价[J].内蒙古石油化工,2015,41(17):10-13.
LU Jiarong, WANG Pingquan, WANG Bo, et al. Effective viscosity reducer HRT used in drilling fluid develop and evaluation[J]. Inner Mongolia Petrochemical Industry, 2015, 41(17): 10-13.
[15] [15] 王飞龙,杨泽星,刘泽,等.钻井液降黏剂SSMA的本体聚合制备与性能[J].钻井液与完井液,2017,34(6):8-12.
WANG Feilong, YANG Zexing, LIU Ze, et al. Study on the performance of SSMA—A thinner made through mass polymerization[J]. Drilling Fluid & Completion Fluid, 2017,34(6):8-12.
[16] [16] 杜俊涛,刘立新,陈娟娟,等.两种2-丙烯酸酰胺基-2-甲基丙磺酸类抗高温钻井液降黏剂的合成与评价[J].精细石油化工,2015,32(2):16-20.
DU Juntao, LIU Lixin, CHEN Juanjuan, et al. Sythesis and evaluation of high temperature resistance drilling fluid viscosity reducer[J]. Speciality Petrochemicals, 2015,32(2):16-20.
[17] [17] 曹书金,王雅新,卢景峰,等.耐温抗盐降黏剂的研制及评价[J].精细石油化工进展,2012,13(7):31-34.
CAO Shujin, WANG Yaxin, LU Jingfeng, et al. Development and evaluation of viscosity reducer with heat-resistance and salt-tolerance[J]. Advances in Fine Petrochemicals, 2012,13(7):31-34.
[18] [18] 赵晓非,陈娟娟,娄刚,等.MA/SAS/AMPS共聚物耐高温钻井液降粘剂的研制[J].化工科技,2014,22(2):38-41.
ZHAO Xiaofei, CHEN Juanjuan, LOU Gang, et al. Study on MA/SAS/AMPS copolymer high temperature thinner for drilling fluid[J]. Science & Technology in Chemical Industry, 2014,22(2):38-41.
[19] [19] 夏凯,吴仲岿,王松,等.高含盐量高密度钻井泥浆降粘剂的合成及其降粘性能研究[J].湖北大学学报(自然科学版),2016,38(5):465-470.
XIA Kai, WU Zhongkui, WANG Song, et al. Study on the synthesis and properties of viscosity reducer in high salinity and high density drilling mud[J]. Journal of Hubei University (Natural Science), 2016,38(5):465-470.
[20] [20] 肖沣峰.环保型抗高温抗盐聚合物降粘剂的合成及评价[J].科技传播,2016,8(10):151-152.
XIAO Fengfeng. Synthesis and evaluation of environment-friendly high-temperature and salt-resistant polymer viscosity reducer[J]. Public Communication of Science & Technology, 2016,8(10):151-152.
[21] [21] 明显森,彭新侠,李强,等.水基钻井液降粘剂JNG-1的合成与性能评价[J].应用化工,2014,43(1):124-127.
MING Xiansen, PENG Xinxia, LI Qiang, et al. Synthesis and performance evaluation of water-based drilling fluid viscosity reducer JNG-1[J]. Applied Chemical Industry, 2014,43(1):124-127.
[22] [22] 张龙军,彭波,林珍,等.抗高温降黏剂MHRT的制备及性能评价[J].油田化学,2014,31 (2):173-176.
ZHANG Longjun, PENG Bo, LIN Zhen, et al. Preparation and properties of high temperature water base drilling fluid thinner MHRT[J]. Oilfield Chemistry, 2014,31(2):173-176.
[23] [23] 郝彬彬,李文波.超高温耐盐型稀释剂HF-2的合成与性能评价[J].广东化工,2018,45(8):69-71.
HAO Binbin, LI Wenbo. Synthesis and performance evaluation of ultra high temperature salt-tolerant diluent HF-2[J]. Guangdong Chemical Industry, 2018,45(8):69-71.
[24] [24] 朱胜,何丹丹.木质素磺酸盐的接枝改性及其应用研究[J].长江大学学报(自然科学版),2012,9(8):16-18.
ZHU Sheng, HE Dandan. Study on graft modification of lignosulfonate and its application[J]. Journal of Yangtze University (Natural Science Edition), 2012,9(8):16-18.
[25] [25] 李骑伶,赵乾,代华,等.对苯乙烯磺酸钠/马来酸酐/木质素磺酸钙接枝共聚物钻井液降黏剂的合成及性能评价[J].高分子材料科学与工程,2014,30(2):72-76.
LI Qiling, ZHAO Qian, DAI Hua, et al. Synthesis and characterization of calcium lignosulfonate grafted with P-styrenesulfonate and maleic anhydride[J]. Polymer Materials Science and Engineering, 2014,30(2):72-76.
[26] [26] 陈珍喜,郑福尔,刘剑锋,等.复合型木质素基钻井液降黏剂的工艺条件研究[J].山东化工,2014,43(12):16-18,21.
CHEN Zhenxi, ZHENG Fuer, LIU Jianfeng, et al. Study on synthesis of a novel compound modified lignin-Based viscosity reducer for drilling fluids[J]. Shandong Chemical Industry, 2014,43(12):16-18,21.
[27] [27] 陈珍喜,刘明华.复合型改性木质素基钻井液用降粘剂的性能研究[J].广州化学,2012,37(4):7-11,17.
CHEN Zhenxi, LIU Minghua. Performance study on a novel compound modified lignin-based viscosity reducer for drilling fluids[J]. Guangzhou Chemistry, 2012,37(4):7-11,17.
[28] [28] 王光平,吴洋,刘大海,等.抗温耐盐型钻井液降粘剂合成与性能评价[J].应用化工,2015,44(10):1897-1900,1904.
WANG Guangping, WU Yang, LIU Dahai, et al. Synthesis and performance evaluation of thinner for drilling fluid used at high temperature and salt[J]. Applied Chemical Industry, 2015,44(10):1897-1900,1904.
[29] [29] 孟繁奇,薛伟,张志磊,等.水基钻井液用无铬降粘剂腐植酸接枝聚丙烯腈的制备及其降粘特性[J].工业技术创新,2015,2(3):359-365.
MENG Fanqi, XUE Wei, ZHANG Zhilei, et al. Preparation and properties of humic acid grafted polyacrylonitrile copolymer as a new chromium-free thinner for water-based drilling fluid[J]. Industrial Technology Innovation, 2015,2(3):359-365.
[30] [30] 郭南南,艾立玲,车亮,等.改性栲胶在油田应用研究进展[J].化学工程师,2016,30(1):55-57,30.
GUO Nannan, AI Liling, CHE Liang, et al. Research development of modified tannin extract in oilfield application[J]. Chemical Engineer, 2016,30(1):55-57,30.
[31] [31] 陆明富.一种钻井液用降黏剂的制备方法:
102676130A [P].2012-09-19 .LU Mingfu. Preparation method of viscosity reducer for drilling fluid:
102676130A [P].2012-09-19 .[32] [32] 陆明富.一种抗高温降黏剂的制备方法:
102675560A [P].2012-09-19 .LU Mingfu. Preparation method of anti-high temperature viscosity reducing agent:
102675560A [P].2012-09-19 .[33] [33] 强天佩,黄凯,李竞,等.钻井液用抗温抗盐稀释剂TX的研制与应用[J].石化技术,2016,23(2):154-157.
QIANG Tianpei, HUANG Kai, LI Jing, et al. Development and application of salt and temperature resistant diluent TX for drilling fluid[J]. Petrochemical Industry Technology, 2016,23(2):154-157.
[34] [34] 段宝荣,郭景颂,苏立清,等.板栗刺壳栲胶制备油田用降粘剂的初步研究[J].石化技术,2018,25(2):26-27.
DUAN Baorong, GUO Jingsong, SU Liqing, et al. A preliminary study on the chestnut shell extract prepared with oil viscosity reducer[J]. Petrochemical Industry Technology, 2018,25(2):26-27.
[35] [35] 付帆,陶士先,李晓东.绿色勘查高温环保冲洗液研究[J].探矿工程(岩土钻掘工程),2020,47(4):129-133.
FU Fan, TAO Shixian, LI Xiaodong. Research on environment-friendly high-temperature drilling for green exploration[J]. Exploration Engineering (Rock& Soil Drilling and Tunneling), 2020,47(4):129-133.
[36] [36] 刘玲榕.抗高温水泥浆体系研究及应用[J].探矿工程(岩土钻掘工程),2018,45(9):29-33.
LIU Lingrong. Research and application of thermostable cement slurry system[J]. Exploration Engineering (Rock& Soil Drilling and Tunneling), 2018,45(9):29-33.
-
计量
- 文章访问数: 1325
- PDF下载数: 375
- 施引文献: 0