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摘要:
在矿物浮选过程中,矿浆中的金属离子对矿物浮选行为有重要影响。分析和总结相关文献,综述了金属离子对硅酸盐矿物抑制作用、活化作用、分散行为的影响规律及机理。在不同浮选体系中,金属离子以络合物或沉淀吸附于矿物表面,通过消耗浮选药剂,改变矿物表面电性等方式,来影响矿物浮选行为。金属离子改变矿物表面电性,影响硅酸盐分散行为,金属氢氧化物沉淀通过桥连作用促使矿物聚沉。金属离子的干扰作用一般采用沉淀、络合或屏蔽法消除。
Abstract:Metal ions existed in the pulp tend to have a significant impact on the flotation behavior of minerals in the flotation process. Based on the summary and analysis of related literatures, the influence law and underlying mechanism of metal ions on depression, activation and decentralization of silicate were reviewed in this work. Metal ions adsorb on minerals in the form of complexes or precipitates in different flotation system, and affect the mineral flotation by consuming reagents, changing surface electricity of minerals. The change of surface electrical properties of minerals by metal ions will affect the dispersion behavior of silicates. The bridging role of metal hydroxide precipitation promotes the coagulation of minerals. The interference of metal ions can be eliminated by precipitation interaction, complexing reaction and shielding effect.
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Key words:
- metal ion /
- depression /
- activation /
- dispersion /
- flotation
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[1] Fuerstenau M C, Miller J D, Pray R E, et al. Metal ion activation in xanthate flotation of quartz[J]. Transaction of American Institute of Mining, Metallurical and Petroleum Engineering, 1965, 232:359-365. http://content.lib.utah.edu/u?/uspace,49
[2] 邓久帅. 黄铜矿流体包裹体组分释放及其与弛豫表面的相互作用[D]. 昆明: 昆明理工大学, 2013.
http://cdmd.cnki.com.cn/Article/CDMD-10674-1016036891.htm [3] 刘谷山, 冯其明, 欧乐明, 等.铜离子和镍离子对滑石浮选的影响及作用机理[J].硅酸盐学报, 2005(8):1018-1022. http://www.cqvip.com/QK/90326X/2005008/20003431.html
[4] 卢佳, 高惠民, 金俊勋, 等.钙离子对红柱石浮选的影响及作用机理[J].中国有色金属学报, 2016(6):1311-1315. http://www.ysxbcn.com/down/down_2046411.html
[5] 何小民, 邓海波, 朱海玲, 等.金属离子对红柱石与绢云母可浮性的影响[J].矿冶工程, 2012(2):55-57, 61. http://www.cqvip.com/QK/93291X/201202/41820792.html
[6] Jin S, Shi Q, Feng Q, et al. The role of calcium and carbonate ions in the separation of pyrite and talc[J]. Minerals Engineering, 2018, 119:205-211. doi: 10.1016/j.mineng.2018.01.016
[7] Jin S, Shi Q, Li Q, et al. Effect of calcium ionic concentrations on the adsorption of carboxymethyl cellulose onto talc surface:flotation, adsorption and AFM imaging study[J]. Powder Technology, 2018, 331:155-161. doi: 10.1016/j.powtec.2018.03.014
[8] Burdukova E, Leerdam G C V, Prins F E, et al. Effect of calcium ions on the adsorption of CMC onto the basal planes of New York talc-A ToF-SIMS study[J]. Minerals Engineering, 2008, 21(12):1020-1025.
[9] Feng Q M, Feng B, Lu Y P. Influence of copper ions and calcium ions on adsorption of CMC on chlorite[J]. Transactions of Nonferrous Metals Society of China, 2013, 23(1):237-242. doi: 10.1016/S1003-6326(13)62451-6
[10] 冯其明, 刘谷山, 喻正军, 等.铁离子和亚铁离子对滑石浮选的影响及作用机理[J].中南大学学报(自然科学版), 2006(3):476-480. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=zngydxxb200603012
[11] 冯博, 汪惠惠, 王鹏程.铜离子和镍离子对绿泥石的抑制作用及机理[J].硅酸盐通报, 2015(5):1237-1240, 1245. http://www.cnki.com.cn/Article/CJFDTOTAL-ZYSY201301032.htm
[12] 刘星, 张晋霞, 徐亮, 等.金属离子对赤铁矿、石英、绿泥石可浮性的影响[J].西部探矿工程, 2016(7):93-96. http://industry.wanfangdata.com.cn/yj/Detail/Thesis?id=Thesis_Y2359748
[13] Lelis D F, Leão V A, Lima R M F. Effect of EDTA on quartz and hematite flotation with starch/amine in an aqueous solution containing Mn2+ ions[J]. REM:Int. Eng. J., Ouro Preto, 2016, 69(4):479-485. doi: 10.1590/0370-44672016690014
[14] 李晔, 雷东升, 许时.矿浆中金属离子对硅线石与石英浮选分离的影响[J].硅酸盐学报, 2002(3):362-365. http://www.cnki.com.cn/Article/CJFDTOTAL-JSKS508.009.htm
[15] 张琪, 方和平.Fe3+对Al3+活化微斜长石产生屏蔽的机理[J].中国有色金属学报, 1999(3):606-609. http://kns.cnki.net/KCMS/detail/detail.aspx?filename=zyxz199903030&dbname=CJFD&dbcode=CJFQ
[16] 张晋霞, 冯雅丽, 牛福生.矿浆中金属离子对蓝晶石矿物浮选行为的影响[J].东北大学学报(自然科学版), 2014, 35(12):1787-1791. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=dbdxxb201412026
[17] 孙传尧, 印万忠.硅酸盐矿物浮选原理[M].科学出版社, 2001.
[18] Ruan Y, Zhang Z, Luo H, et al. Effects of metal ions on the flotation of apatite, dolomite and quartz[J]. Minerals, 2018, 8(4):141. doi: 10.3390/min8040141
[19] 谢兴中.褐铁矿与石英正浮选分离及其机理研究[J].矿产保护与利用, 2017(5):38-43. http://kcbh.cbpt.cnki.net/WKD/WebPublication/paperDigest.aspx?paperID=dacdbb16-cfe8-41f7-b05b-dfdba6139b59
[20] 吴卫国, 孙传尧, 朱永楷.有机螯合剂对活化石英的抑制及其作用机理[J].金属矿山, 2007(2):33-37. http://mall.cnki.net/magazine/Article/JSKS200702010.htm
[21] Kou J, Xu S, Sun T, et al. A study of sodium oleate adsorption on Ca2+ activated quartz surface using quartz crystal microbalance with dissipation[J]. International Journal of Mineral Processing, 2016, 154:24-34. doi: 10.1016/j.minpro.2016.06.008
[22] Feng Q, Wen S, Zhao W, et al. Effect of calcium ions on adsorption of sodium oleate onto cassiterite and quartz surfaces and implications for their flotation separation[J]. Separation and Purification Technology, 2018, 200:300-306. doi: 10.1016/j.seppur.2018.02.048
[23] Hao H, Li L, Yuan Z, et al. Molecular arrangement of starch, Ca2+ and oleate ions in the siderite-hematite-quartz flotation system[J]. Journal of Molecular Liquids, 2018, 254:349-356. doi: 10.1016/j.molliq.2018.01.117
[24] 张国范, 鄢代翠, 朱阳戈, 等.Ca2+对钛铁矿与钛辉石浮选行为的影响[J].中南大学学报(自然科学版), 2011(3):561-567. http://kns.cnki.net/KCMS/detail/detail.aspx?filename=zngd201103000&dbname=CJFD&dbcode=CJFQ
[25] Wang X, Liu W, Duan H, et al. The adsorption mechanism of calcium ion on quartz(101) surface:A DFT study[J]. Powder Technology, 2018, 329:158-166. doi: 10.1016/j.powtec.2018.01.086
[26] Wang YH, Yu FS. Effects of metallic ions on the flotation of spodumene and beryl[J]. Journal of China University of Mining and Technology, 2007, 17(1):35-39. doi: 10.1016/S1006-1266(07)60008-X
[27] Zhang J, Wang W, Liu J, et al. Fe(Ⅲ) as an activator for the flotation of spodumene, albite and quartz minerals[J]. Minerals Engineering, 2014, 61:16-22. doi: 10.1016/j.mineng.2014.03.004
[28] Liu W, Zhang S, Wang W, et al. The effects of Ca(Ⅱ) and Mg(Ⅱ) ions on the flotation of spodumene using NaOL[J]. Minerals Engineering, 2015, 79:40-46. doi: 10.1016/j.mineng.2015.05.008
[29] 曹钊, 张亚辉, 孙传尧, 等.铜镍硫化矿浮选中Cu(Ⅱ)和Ni(Ⅱ)离子对蛇纹石的活化机理[J].中国有色金属学报, 2014(2):506-510. http://cdmd.cnki.com.cn/Article/CDMD-10533-2006173328.htm
[30] 曹钊, 孙传尧, 张亚辉, 等. Cu(Ⅱ)、Ni(Ⅱ)离子对绿泥石的活化作用机理研究[C]. 南宁: 全国矿产资源综合利用学术会议, 2013.
[31] Fornasiero D, Ralston J. Cu(Ⅱ) and Ni(Ⅱ) activation in the flotation of quartz, lizardite and chlorite[J]. International Journal of Mineral Processing, 2005, 76(1-2):75-81. doi: 10.1016/j.minpro.2004.12.002
[32] 周瑜林, 王毓华, 胡岳华, 等.金属离子对一水硬铝石和高岭石浮选行为的影响[J].中南大学学报(自然科学版), 2009(2):268-274. http://mall.cnki.net/magazine/article/ZNGD200902005.htm
[33] 董宏军, 陈荩, 毛钜凡.金属离子对红柱石的吸附与活化[J].有色金属, 1996(2):35-39, 24. http://www.cnki.com.cn/Article/CJFDTOTAL-JSKS200412008.htm
[34] 张琪, 方和平.金属离子对硅线石和微斜长石可浮性的影响[J].矿产保护与利用, 1999(1):34-37. http://kcbh.cbpt.cnki.net/WKD/WebPublication/paperDigest.aspx?paperID=8967c766-8b59-442f-abd8-42d2dae3e8da
[35] Tang J, Zhang Y, Bao S. The effect of Ca2+ and Mg2+ on the dispersion and focculation behaviors of muscovite particles[J]. Minerals, 2016, 6(3):93. doi: 10.3390/min6030093
[36] Zhou Y L, Hu Y H, Wang Y H. Effect of metallic ions on dispersibility of fine diaspore[J]. Transactions of Nonferrous Metals Society of China, 2011, 21(5):1166-1171. doi: 10.1016/S1003-6326(11)60838-8
[37] 孙大翔, 王毓华, 周瑜林.钙离子对铝土矿选择性絮凝的影响及消除的试验研究[J].矿冶工程, 2010(5):34-39. http://doi.wanfangdata.com.cn/10.3969/j.issn.0253-6099.2010.05.009
[38] 王毓华, 陈兴华, 周瑜林.金属离子对细粒铝硅酸盐矿物分散行为的影响[J].金属矿山, 2007(5):38-43. http://mall.cnki.net/magazine/Article/ZNGD200702010.htm
[39] 方启学.钙镁对微细矿粒分散稳定性的影响及其机理研究[J].国外金属矿选矿, 1998(6):42-45. http://www.cqvip.com/QK/93727X/199806/3065984.html
[40] 崔萌萌. 菱锌矿与石英浮选分离中难免离子的影响及消除[D]. 长沙: 中南大学, 2012.
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