Research Progress on Comprehensive Utilization and Upgrading Technologies of Fly Ash
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摘要:
粉煤灰是我国堆积量最大的固体废弃物之一,粉煤灰的堆积和外排不仅占用了大量土地资源,而且容易造成环境污染。粉煤灰中含有一定量的残碳、磁珠和微珠等有用组分和有价元素,根据粉煤灰的特性对其进行提质或综合利用对减少环境污染、提高粉煤灰经济效益具有重要意义。论文阐述了粉煤灰在建材制备、陶瓷生产、土壤改良和多孔材料制造等领域的综合利用现状及研究进展,介绍了分选脱碳、有价元素提取、有用组分分离等粉煤灰提质方法的研究现状,探讨了粉煤灰综合利用与提质方法存在的问题及发展趋势。建议根据不同粉煤灰的特性,进一步开展粉煤灰材料制备的研究,同时强化对粉煤灰中微量元素、稀有元素和其它高附加值组分的回收。
Abstract:As one of the largest solid waste in China, the stockpiling and discharge of fly ash occupied a large amount of land sources and caused environmental problems. There are a certain amount of valuable components such as residual carbon, magnetic beads, microbeads and valuable elements. It is of great significance to improve the economic benefits by comprehensive utilization according to the characteristics of fly ash after upgrading. The comprehensive utilization and research progress in building materials, ceramic products, soil improvement and porous materials was stated. And the research progress of fly ash upgrading methods such as decarbonization by separation, valuable elements extraction and valuable components separation were also introduced; and the problems and development trends of fly ash comprehensive utilization and upgrading were discussed. Further research on materials and valuable element and components extraction should conducted based on the characteristics of the fly ash.
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Key words:
- fly ash /
- solid waste /
- upgrading /
- comprehensive utilization
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[1] 中华人民共和国生态环境部.2018年全国大、中城市固体废物污染环境防治年报[R].北京, 2018.
[2] 王建新, 李晶, 赵仕宝, 等.中国粉煤灰的资源化利用研究进展与前景[J].硅酸盐通报, 2018, 37(12):3833-3841. http://d.old.wanfangdata.com.cn/Periodical/gsytb201812020
[3] 李辰晨.燃煤固体废物制备介孔硅基材料[D].上海: 华东理工大学, 2016.
http://cdmd.cnki.com.cn/Article/CDMD-10251-1017040382.htm [4] 牛季收, 王保君.粉煤灰在混凝土中的效应及应用[J].铁道建筑, 2004(2):74-77. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=tdjz200402028
[5] 杨星, 呼文奎, 贾飞云, 等.粉煤灰的综合利用技术研究进展[J].能源与环境, 2018(4):55-57. doi: 10.3969/j.issn.1672-9064.2018.04.025
[6] Yao ZT, Ji XS, Sarker PK, et al. A comprehensive review on the applications of coal fly ash[J]. Earth-science reviews, 2015, 141:105-121. doi: 10.1016/j.earscirev.2014.11.016
[7] Dilmore Robert M, Neufeld Ronald D. Autoclaved aerated concrete produced with low NOx burner selective catalytic reduction fly ash[J]. Journal of energy engineering, 2001, 127(2):37-50. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=f1b9cfdbbad55db5da8dac2824621dd1
[8] 李阳, 王瑞骏, 闫菲, 等.粉煤灰对混凝土抗冻及抗硫酸盐性能的影响[J].西北农林科技大学学报(自然科学版), 2017, 45(2):219-226. http://d.old.wanfangdata.com.cn/Periodical/xbnydxxb201702030
[9] Zhang Henian, Shen Chen, Xi Peisheng, et al. Study on flexural properties of active magnesia carbonation concrete with fly ash content[J].Construction and building materials, 2018, 187:884-891. doi: 10.1016/j.conbuildmat.2018.08.017
[10] Rashad Alaa M. A brief on high-volume Class F fly ash as cement replacement-a guide for civil engineer[J]. International journal of sustainable built environment, 2015, 4(2):278-306. doi: 10.1016/j.ijsbe.2015.10.002
[11] 盛昌栋, 张军.粉煤灰中残碳的特性和利用[J].粉煤灰综合利用, 2005(1):3-5. doi: 10.3969/j.issn.1005-8249.2005.01.001
[12] Habert G, D Espinose De Lacaillerie JB, Roussel N. An environmental evaluation of geopolymer based concrete production:reviewing current research trends[J]. Journal of cleaner production, 2011, 19(11):1229-1238. doi: 10.1016/j.jclepro.2011.03.012
[13] Martinez Rivera Francisco Javier. Strength and durability of fly ash-based fiber-reinforced geopolymer concrete in a simulated marine environment[D].Florida: Florida Atlantic University, 2013.
[14] Zhuang Xiao Yu, Chen Liang, Komarneni Sridhar, et al. Fly ash-based geopolymer:clean production, properties and applications[J]. Journal of cleaner production, 2016, 125:253-267. doi: 10.1016/j.jclepro.2016.03.019
[15] 贾屹海.Na-粉煤灰地质聚合物制备与性能研究[D].北京: 中国矿业大学(北京), 2009.
http://cdmd.cnki.com.cn/Article/CDMD-11413-2009263145.htm [16] 杨久俊, 王文娟, 吴宏江, 等.不同燃煤电厂粉煤灰的特性及影响因素分析[J].粉煤灰综合利用, 2008(06):6-9. doi: 10.3969/j.issn.1005-8249.2008.06.002
[17] 侯芹芹, 张创, 赵亚娟, 等.粉煤灰综合利用研究进展[J].应用化工, 2018, 47(6):1281-1284. doi: 10.3969/j.issn.1671-3206.2018.06.049
[18] 赵吉, 康振中, 韩勤勤, 等.粉煤灰在土壤改良及修复中的应用与展望[J].江苏农业科学, 2017, 45(2):1-6. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=jsnykx201702001
[19] 严彩霞, 董健苗.粉煤灰在农业方面的利用[J].粉煤灰综合利用, 2001(5):41-44. doi: 10.3969/j.issn.1005-8249.2001.05.019
[20] 赵亮, 唐泽军, 刘芳.粉煤灰改良沙质土壤水分物理性质的室内试验[J].环境科学学报, 2009, 29(9):1951-1957. doi: 10.3321/j.issn:0253-2468.2009.09.024
[21] 李九玉, 王宁, 徐仁扣.工业副产品对红壤酸度改良的研究[J].土壤, 2009, 41(6):932-939. doi: 10.3321/j.issn:0253-9829.2009.06.015
[22] 杨海儒, 宫伟光.不同土壤改良剂对松嫩平原盐碱土理化性质的影响[J].安徽农业科学, 2008(20):8715-8716. doi: 10.3969/j.issn.0517-6611.2008.20.137
[23] 王娟, 熊又升, 张志毅, 等.粉煤灰在土壤改良和污染治理中研究进展[J].安徽农业科学, 2012, 40(30):14811-14813. doi: 10.3969/j.issn.0517-6611.2012.30.073
[24] Jambhulkar Hemlata P, Shaikh Siratun Montaha S, Kumar M. Suresh. Fly ash toxicity, emerging issues and possible implications for its exploitation in agriculture; Indian scenario:A review[J]. Chemosphere, 2018, 213:333-344. doi: 10.1016/j.chemosphere.2018.09.045
[25] 宗燕兵, 张学东, 李飞.粉煤灰陶瓷的制备及致密化过程讨论[J].环境工程, 2018:1-7.DOI:10.13205/j.hjgc.201904028.
[26] Kniess CT, De Lima JC, Prates PB, et al. Dilithium dialuminium trisilicate phase obtained using coal bottom ash[J]. Journal of non-crystalline solids, 2007, 353(52-54):4819-4822. doi: 10.1016/j.jnoncrysol.2007.06.047
[27] Luo Yang, Zheng Shili, Ma Shuhua, et al. Ceramic tiles derived from coal fly ash:Preparation and mechanical characterization[J]. Ceramics international, 2017, 43(15):11953-11966. doi: 10.1016/j.ceramint.2017.06.045
[28] Lee Yuri, Soe June Thet, Zhang Siqian, et al. Synthesis of nanoporous materials via recycling coal fly ash and other solid wastes:A mini review[J]. Chemical engineering journal, 2017, 317:821-843. doi: 10.1016/j.cej.2017.02.124
[29] Zhou Chunyu, Gao Qiang, Luo Wenjun, et al. Preparation, characterization and adsorption evaluation of spherical mesoporous Al-MCM-41 from coal fly ash[J]. Journal of the Taiwan institute of chemical engineers, 2015, 52:147-157. doi: 10.1016/j.jtice.2015.02.014
[30] Bukhari Syed Salman, Behin Jamshid, Kazemian Hossein, et al. Conversion of coal fly ash to zeolite utilizing microwave and ultrasound energies:A review[J]. Fuel, 2015, 140:250-266. doi: 10.1016/j.fuel.2014.09.077
[31] 邓庆德, 姬海宏, 胡鑫, 等.燃煤电厂飞灰脱碳技术研究进展[J].华电技术, 2018, 40(10):56-58. doi: 10.3969/j.issn.1674-1951.2018.10.019
[32] Hower James C, Groppo John G, Graham Uschi M, et al. Coal-derived unburned carbons in fly ash:A review[J]. International journal of coal geology, 2017, 179:11-27. doi: 10.1016/j.coal.2017.05.007
[33] 任琳珠, 王永田, 李国胜.某粉煤灰浮选脱炭试验研究[J].矿山机械, 2013, 41(1):80-83. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=ksjx201301021
[34] 范桂侠, 曹亦俊, 刘炯天, 等.钢厂粉煤灰浮选提碳试验研究[J].中国煤炭, 2011, 37(8):85-88. http://d.old.wanfangdata.com.cn/Periodical/zgmt201108023
[35] 翟雪, 曹亦俊, 周强, 等.某电厂粉煤灰浮选脱碳试验研究[J].金属矿山, 2011(3):162-164. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=jsks201103046
[36] Zhang Wencai, Honaker Rick. Studies on carbon flotation from fly ash[J]. Fuel processing technology, 2015, 139:236-241. doi: 10.1016/j.fuproc.2015.06.045
[37] 程芳琴, 王波, 成怀刚.粉煤灰提取高附加值有价元素的技术现状及进展[J].无机盐工业, 2017, 49(2):1-4. http://d.old.wanfangdata.com.cn/Periodical/wjygy201702001
[38] Dai Shifeng, Zhao Lei, Peng Suping, et al. Abundances and distribution of minerals and elements in high-alumina coal fly ash from the jungar power plant, inner mongolia, China[J]. International journal of coal geology, 2010, 81(4):320-332. doi: 10.1016/j.coal.2009.03.005
[39] 杨丹, 郭庆丰, 赵成龙, 等.鄂尔多斯某电厂粉煤灰中主要元素的赋存状态研究[C]//第六届尾矿与冶金渣综合利用技术研讨会暨衢州市项目招商对接会.衢州, 2015.
[40] Ding Jian, Ma Shuhua, Shen Shirley, et al. Research and industrialization progress of recovering alumina from fly ash:A concise review[J]. Waste Management, 2017, 60:375-387. doi: 10.1016/j.wasman.2016.06.009
[41] Valeev D, Kunilova I, Alpatov A, et al. Complex utilisation of ekibastuz brown coal fly ash:Iron & carbon separation and aluminum extraction[J]. Journal of cleaner production, 2019, 218:192-201. doi: 10.1016/j.jclepro.2019.01.342
[42] Sangita Seoul, Nayak Niva, Panda Chitta Ranjan. Extraction of aluminium as aluminium sulphate from thermal power plant fly ashes[J]. Transactions of nonferrous metals society of China, 2017, 27(9):2082-2089. doi: 10.1016/S1003-6326(17)60231-0
[43] Gong Bengen, Tian Chong, Xiong Zhuo, et al. Mineral changes and trace element releases during extraction of alumina from high aluminum fly ash in Inner Mongolia, China[J]. International journal of coal geology, 2016, 166:96-107. doi: 10.1016/j.coal.2016.07.001
[44] 刘丽霞, 李文挺, 彭军, 等.粉煤灰中锗的赋存状态研究[J].稀有金属与硬质合金, 2017, 45(5):27-30. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=xyjsyyzhj201705006
[45] Kamran Haghighi Hossein, Irannajad Mehdi, Fortuny Agustin, et al. Recovery of germanium from leach solutions of fly ash using solvent extraction with various extractants[J]. Hydrometallurgy, 2018, 175:164-169. doi: 10.1016/j.hydromet.2017.11.006
[46] King Jack F., Taggart Ross K., Smith Ryan C., et al. Aqueous acid and alkaline extraction of rare earth elements from coal combustion ash[J]. International journal of coal geology, 2018, 195:75-83. doi: 10.1016/j.coal.2018.05.009
[47] Das Saptarshi, Gaustad Gabrielle, Sekar Ashok, et al. Techno-economic analysis of supercritical extraction of rare earth elements from coal ash[J]. Journal of cleaner production, 2018, 189:539-551. doi: 10.1016/j.jclepro.2018.03.252
[48] 吴先锋, 李建军, 朱金波, 等.粉煤灰磁珠资源化利用研究进展[J].材料导报, 2015, 29(23):103-107. http://d.old.wanfangdata.com.cn/Periodical/cldb201523019
[49] 李辉, 商博明, 徐德龙, 等.粉煤灰中磁珠的微观结构及化学组成[J].矿业研究与开发, 2006(6):65-68. doi: 10.3969/j.issn.1005-2763.2006.06.020
[50] 王龙贵.回收粉煤灰磁珠在污水处理中的应用[J].环境污染治理技术与设备, 2004(3):88-89. http://d.old.wanfangdata.com.cn/Periodical/hjwrzljsysb200403020
[51] Hanif Asad, Lu Zeyu, Li Zongjin. Utilization of fly ash cenosphere as lightweight filler in cement-based composites-A review[J]. Construction and building materials, 2017, 144:373-384. doi: 10.1016/j.conbuildmat.2017.03.188
[52] Singh LP, Karade SR, Bhattacharyya SK, et al. Beneficial role of nanosilica in cement based materials-A review[J]. Construction and building materials, 2013, 47:1069-1077. doi: 10.1016/j.conbuildmat.2013.05.052
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