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高岭土的功能化改性及其战略性应用

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文章导航 > 矿产保护与利用 > 2019 > 39(6): 69-76

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孟宇航, 尚玺, 张乾, 杨华明. 高岭土的功能化改性及其战略性应用[J]. 矿产保护与利用, 2019, 39(6): 69-76. doi: 10.13779/j.cnki.issn1001-0076.2019.06.011
引用本文: 孟宇航, 尚玺, 张乾, 杨华明. 高岭土的功能化改性及其战略性应用[J]. 矿产保护与利用, 2019, 39(6): 69-76. doi: 10.13779/j.cnki.issn1001-0076.2019.06.011
shu
MENG Yuhang, SHANG Xi, ZHANG Qian, YANG Huaming. Functional Modification of Kaolin and Its Strategic Application[J]. Conservation and Utilization of Mineral Resources, 2019, 39(6): 69-76. doi: 10.13779/j.cnki.issn1001-0076.2019.06.011
Citation: MENG Yuhang, SHANG Xi, ZHANG Qian, YANG Huaming. Functional Modification of Kaolin and Its Strategic Application[J]. Conservation and Utilization of Mineral Resources, 2019, 39(6): 69-76. doi: 10.13779/j.cnki.issn1001-0076.2019.06.011
shu

高岭土的功能化改性及其战略性应用

  • 1.

    中南大学 资源生物学院，湖南 长沙 410083

  • 2.

    中南大学矿物材料及其应用湖南省重点实验室，湖南 长沙 410083

  • 3.

    中南大学建筑材料行业黏土矿物功能材料重点实验室，湖南 长沙 410083

  • 基金项目:
    国家重点研发计划课题（2017YFB0310903）；湖南省科技创新计划项目（2018WK4023）
详细信息
    作者简介: 孟宇航(1997-), 男, 山西吕梁人, 硕士研究生, 主要从事矿物材料研究, E-mail:Myhzsy@csu.edu.cn
    通讯作者: 杨华明(1968-), 男, 浙江绍兴人, 博士, 教授, 博士生导师, 主要从事矿物材料研究, E-mail:hmyang@csu.edu.cn

  • 中图分类号: TD973+.2;TB34

Functional Modification of Kaolin and Its Strategic Application

  • 1.

    School of Minerals Processing and Bioengineering, Central South University, Changsha 410083, China

  • 2.

    Hunan Key Laboratory of Mineral Materials and Application, Central South University, Changsha 410083, China

  • 3.

    Key Laboratory of Clay Mineral Functional Materials in China Building Materials Industry, Central South University, Changsha 410083, China

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    摘要

  • 高岭土是一种天然的黏土矿物，具有典型的1：1层状硅酸盐晶体结构。首先介绍了高岭土资源背景、结构组成和物化特性，着重介绍了高岭土在节能环保、生物医药和新材料三个战略性新兴产业的研究现状。天然的层状结构、丰富的表面羟基、较大的比表面积以及良好的生物相容性为高岭土的功能化应用提供了多种选择。随着科学技术的发展和国家社会的进步，对高岭土的研究更加深入。未来高岭土将作为一种战略性非金属矿物，在更多的领域有更好的应用前景。

    Kaolin is a natural clay mineral with a typical 1:1 layered silicate crystal structure. This paper firstly introduces the background, composition and physicochemical characteristics of kaolinite resources, and emphatically introduces the research status of kaolinite in three strategic emerging industries of energy conservation and environmental protection, biomedicine and new materials. The natural layered structure, abundant surface hydroxyl groups, large specific surface area and good biocompatibility provide a variety of options for the functional application of kaolin. With the development of science and technology and the progress of national society, the research on kaolinite will be more in-depth.Kaolin will be a strategic non-metallic mineral in the future and will have better application prospects in more fields.

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  • 图 1  高岭石的晶体结构示意图(左图为多面体模型，右图为球棍模型)[50]

    Figure 1. 

    下载: 全尺寸图片 幻灯片

    图 2  三维介孔生物玻璃-高岭石支架(MBG-XK)制备示意图[59]

    Figure 2. 

    下载: 全尺寸图片 幻灯片

    表 1  一些复合相变材料在文献中的热性能[33]

    Table 1.  Thermal characteristics of some composite PCMs in the literature[32]

    Composite PCM Phase change
    temperature/℃    		 Latent heat phase
    chang/(J·g-1)
    Lauric acid (60%)/expanded perlite 44.1 93.4
    Lauric-capric acid+fire retardant/gypsum 17 28
    Lauric-stearic acid(38%)/gypsum 34.0 50.4
    Capric-myristic acid(20%)/VMT 19.8 27
    Capric-myristic acid/expanded perlite 21.7 85.1
    LA-LAL/kaolin 25.1 45.24
    下载: 导出CSV

    表 2  几种相变储热材料的热性能[38]

    Table 2.  Thermal properties of several phase change material[38]

    Sample Melting temperature/℃ Condensing temperature/℃ Latent heat of fusion/(J·g-1) Latent heat of condensation/(J·g-1)
    Sodium stearate/Kaolin 252.86 256.91 109.25 109.01
    laurinol/Kaolin 19.10 17.10 48.08 46.65
    Paraffin/kaolin 56.90 56.90 70.30 75.20
    Al-Si metal/kaolin 573.80 588.70 102.50 102.50
    下载: 导出CSV
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收稿日期:  2019-11-05
刊出日期:  2019-12-25

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