激光剥蚀电感耦合等离子体质谱元素微区分析标准物质研究进展

吴石头; 王亚平; 许春雪

doi:10.15898/j.cnki.11-2131/td.2015.05.002

激光剥蚀电感耦合等离子体质谱元素微区分析标准物质研究进展

1.
国家地质实验测试中心, 北京 100037

2.
中国地质大学(武汉)地球科学学院, 湖北武汉 430074

3.
Geoscience Center Göttingen, University of Göttingen, Goldschmidt Straβe.1, 37077, Göttingen, Germany

基金项目: 中国地质大调查项目(12120113021500)

详细信息

作者简介: 吴石头, 在读博士研究生, 主要研究方向为地球化学。E-mail: wushitou111@hotmail.com

通讯作者: 王亚平, 博士, 研究员, 从事标准物质研制和岩矿测试方面的研究工作。E-mail: wangyaping@cags.ac.cn

中图分类号: O657.63;TQ421.31

收稿日期: 2015-05-17

修回日期: 2015-08-28

录用日期: 2015-09-05

刊出日期: 2015-05-25

Research Progress on Reference Materials for in situ Elemental Analysis by Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry

1.
National Research Center for Geoanalysis, Beijing 10037, China

2.
School of Earth Sciences, China University of Geosciences (Wuhan), Wuhan 430074, China

3.
Geoscience Center Göttingen, University of Göttingen, Goldschmidt Straβe.1, 37077, Göttingen, Germany

More Information

Corresponding author: WANG Ya-ping, wangyaping@cags.ac.cn

Received Date: 17 May 2015

Revised Date: 28 August 2015

Accepted Date: 05 September 2015

Publish Date: 25 May 2015

摘要

摘要:
激光剥蚀电感耦合等离子体质谱(LA-ICP-MS)是目前地球科学分析领域的重要技术手段, 元素微区分析标准物质研制是该分析技术发展的重要方向。本文对当前LA-ICP-MS元素微区分析标准物质的种类、元素分布以及应用上的优缺点和标准物质的制备方法进行了评述。现有的有证标准物质数量不多、种类不齐全, 部分元素浓度较低, 定值不确定度较大, 应用上受到较大的局限性; 研制标准也不成熟, 均匀性检验方面尚未有统一的方法。本文参照岩石粉末标准物质均匀性检验方法提出了两步均匀性检验法, 同时指出在标准物质种类方面, 铂族元素及Au元素浓度适当、Pb-S等不同硫化物基体标准物质, 以及化学成分不同的碳酸岩和磷酸岩基体标准物质是当前的迫切需求; 在标准物质研制技术方面, 纳米岩石粉末压片技术的研发、原位微区分析标准物质(固体)均匀性检验判别标准研究是亟待解决的问题。
- LA-ICP-MS /
- 标准物质 /
- 熔融玻璃法 /
- 纳米粉末压片法 /
- 均匀性检验
Abstract:
Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry (LA-ICP-MS) is currently an important microanalysis technique in the geoscience field. Development of related reference materials is a key for this technique. In this paper, the types, elemental distribution, application limits and manufacture method of reference materials for LA-ICP-MS analysis were reviewed. Currently, there are limited accessible Certified Reference Materials (CRMs). Some of the CRMs have low elemental contents and large uncertainties, which has restricted their application. Meanwhile, manufacture methods are immature and the homogeneity test for microanalysis reference material did not reach an agreement. Based on the homogeneity test method for rock powder reference materials, a two-step homogeneity test method was proposed. PGEs and Au contents in reference materials should be appropriate. Reference materials for Pb-S sulfide matrix, carbonate and phosphate matrix with different chemical compositions are urgently needed. With respect the the manufacture method of reference materials, nano-powder tablet technology and homogeneity tests should be developed further.
- Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry (LA-ICP-MS) /
- reference materials /
- glass melting technique /
- nano-powder tablet technique /
- homogeneity test

HTML全文

表 1 现有主要的LA-ICP-MS元素微区分析标准物质

Table 1. Main elemental microanalysis reference materials for LA-ICP-MS

生产商	标准物质名称	参考文献
美国国家标准与技术研究所(NIST)	熔融玻璃NIST610、NIST612、 NIST614、NIST616等	^{[19, 23, 24, 25, 26]}
美国地质调查局 (USGS)	熔融玻璃BCR-2G、BHVO- 2G、BIR-1G、NKT-1G、TB- 1G、GSC-1G、GSD-1G、GSE -1G等；粉末压片MACS-3、 MASS-1等	^{[16, 17, 20, 26, 27, 28, 29, 30, 31]}
德国马普化学研究所 (MPI-DING)	熔融玻璃KL2-G、ML3B-G、 StHs6/80-G、GOR128-G、 GOR132-G、ATHO-G、T1- G、BM90/21-G等	^{[18, 20, 32]}
国家地质实验测试中心 (CGSG)	熔融玻璃CGSG-1、CGSG-2、 CGSG-4、CGSG-5等	^[33]
德国联邦材料与测试研究所(BAM)	熔融玻璃BAM-S005-A、BAM -S005-B等	^[34]

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激光剥蚀电感耦合等离子体质谱元素微区分析标准物质研究进展

1. 国家地质实验测试中心, 北京 100037 2. 中国地质大学(武汉)地球科学学院, 湖北 武汉 430074 3. Geoscience Center Göttingen, University of Göttingen, Goldschmidt Straβe.1, 37077, Göttingen, Germany

作者简介: 吴石头, 在读博士研究生, 主要研究方向为地球化学。E-mail: wushitou111@hotmail.com

通讯作者: 王亚平, 博士, 研究员, 从事标准物质研制和岩矿测试方面的研究工作。E-mail: wangyaping@cags.ac.cn

Research Progress on Reference Materials for in situ Elemental Analysis by Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry

1. National Research Center for Geoanalysis, Beijing 10037, China 2. School of Earth Sciences, China University of Geosciences (Wuhan), Wuhan 430074, China 3. Geoscience Center Göttingen, University of Göttingen, Goldschmidt Straβe.1, 37077, Göttingen, Germany

Corresponding author: WANG Ya-ping, wangyaping@cags.ac.cn

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目录

1.
国家地质实验测试中心, 北京 100037

2.
中国地质大学(武汉)地球科学学院, 湖北武汉 430074

3.
Geoscience Center Göttingen, University of Göttingen, Goldschmidt Straβe.1, 37077, Göttingen, Germany

1.
National Research Center for Geoanalysis, Beijing 10037, China

2.
School of Earth Sciences, China University of Geosciences (Wuhan), Wuhan 430074, China

3.
Geoscience Center Göttingen, University of Göttingen, Goldschmidt Straβe.1, 37077, Göttingen, Germany