Geochemical Characteristics of Synthetic Hydrocarbon Inclusions in Rock Salt-Crude Oil and Their Implication for Oil Source Comparison
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摘要: 油气包裹体广泛应用于油气成藏研究，但油气包裹体能否继承母油荧光及地球化学特征等，尚缺乏直接的实验证据。本文在开放体系下用NaCl挥发结晶法对一轻质原油进行合成烃类包裹体实验，通过镜下观察和激光剥蚀色谱-质谱技术分析合成的烃包裹体和母油的荧光特征、成分特征及地化特征，研究两者的异同点。结果表明，在NaCl合成烃类包裹体中共发现三种相态的包裹体：纯液相烃包裹体、气液两相烃包裹体和气油水三相包裹体；共有绿黄色荧光、蓝色荧光两种不同颜色的荧光特征。相对于母油，合成包裹体的饱和烃和芳烃类化合物中的轻质组分含量较低，可以推测在母油被捕获成为包裹体的过程中，不同的化学成分存在差异性捕获。但合成包裹体的Pr/Ph等地化参数和不同系列化合物相对含量与母油相差不大，能很好地反映母油的沉积环境等地化特征。因此，包裹体成分信息可以应用于油源对比分析。
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关键词:
- 合成烃包裹体 /
- 母油 /
- 激光剥蚀色谱-质谱分析 /
- 地化参数 /
- 油源对比
Abstract: Petroleum inclusions are widely used in hydrocarbon accumulation, but the lack of direct experimental evidence means that proof cannot be determined as to whether petroleum inclusions inherit the fluorescence and geochemical characteristics from crude oil. The petroleum inclusion in NaCl crystal is synthesized using the NaCl evaporation crystallization method under the open system and is reported in this paper. The fluorescence, composition and geochemical characteristics of synthesized petroleum inclusion and crude oil were studied by Microscope and Laser Ablation GC-MS. Three kinds of petroleum-bearing inclusions are identified at room temperature, such as liquid single-phase hydrocarbon inclusion, gas and liquid two-phase hydrocarbon inclusion, and gas, petroleum and water three-phase inclusion. These petroleum-bearing inclusions show yellow-green and blue-green fluorescence. The synthesized petroleum inclusions have lower content of light fractions in saturated hydrocarbons and aromatics than the crude oil. It can be inferred that the selective-capture of different compounds occur during the trapping process of synthesized petroleum inclusion. However, both the crude oil and synthesized petroleum inclusion show similar Pr/Ph ratios and the relative content of different types of compounds, which can be used to discriminate the sedimentary environment and other geochemical characteristics. Therefore, the geochemical composition of petroleum inclusion is still a powerful and reliable tool to trace the source rock of the crude oil, using the method described here. -
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[1] 卢焕章,欧光习,范宏瑞等编著.流体包裹体[M].北京:科学出版社,2004:374-377.
Lu H Z,O G X,Fan H R,et al.Fluid Inclusion[M].Beijing:Science Press,2004:374-377.
[2] 刘德汉,卢焕章,肖贤明编著.油气包裹体及其在石油勘探和开发中的应用[M].广州:广东科技出版社,2007:173-178.
Liu D H,Lu H Z,Xiao X M.Petroleum Inclusion and Its Application in Petroleum Exploration and Development[M].Guangzhou:Guangdong Science and Technology Press,2007:173-178.
[3] 时保宏,张艳,张雷,等.鄂尔多斯盆地延长组长7致密储层流体包裹体特征与成藏期次[J].石油实验地质,2012,34(6):599-603. http://www.cnki.com.cn/Article/CJFDTOTAL-SYSD201206009.htm
Shi B H,Zhang Y,Zhang L,et al.Hydrocoabon Accumulation Dating by Fluid Inclusion Characteristics in Chang7 Tight Sandstone Reservoirs of Yanchang Formation in Ordos Basin[J].Petroleum Geology & Experiment,2012,34(6):599-603. http://www.cnki.com.cn/Article/CJFDTOTAL-SYSD201206009.htm
[4] 罗枭,姜振学,李卓,等.英买力地区中生界-新生界油气藏石油包裹体特征及成藏期次[J].石油学报,2015,36(1):60-66.
Luo X,Jiang Z X,Li Z,et al.The Properties of Petroleum Inclusions and Stages of Hydrocarbon Accumulation in Mesozoic-Cenozoic Reservoirs in Yingmaili Area of Tabei Uplift,Tarim Basin[J].Acta Petrolei Sinica,2015,36(1):60-66.
[5] Kihle J,Hurum H J,Liebe L.Preliminary Results on Liquid Petroleum Occurring as Fluid Inclusions in Intracellular Mineral Precipitates in the Vertebrae of Pliosaurus Funkei[J].Norwegian Journal of Geology,2012,92(2-3):341-352. https://www.researchgate.net/profile/Lene_Delsett/publication/272999113_Preliminary_results_on_Iiquid_petroleum_occurring_as_fluid_inclusions_in_intracellular_mineral_precipitates_in_the_vertebrae_of_Pliosaurus_funkei/links/54f4744d0cf2f9e34f0a47d5.pdf?inViewer=true&pdfJsDownload=true&disableCoverPage=true&origin=publication_detail
[6] Guo X W,Liu K Y,He S,et al.Petroleum Generation and Charge History of the Northern Dongying Depression,Bohai Bay Basin,China:Insight from Integrated Fluid Inclusion Analysis and Basin Modeling[J].Marine and Petroleum Geology,2012,32(1):21-35. doi: 10.1016/j.marpetgeo.2011.12.007
[7] 刘文汇,王杰,陶成,等.中国海相层系油气成藏年代学[J].天然气地球科学,2013,24(2):199-209. http://www.cnki.com.cn/Article/CJFDTOTAL-TDKX201302002.htm
Liu W H,Wang J,Tao C,et al.The Geochronology of Petroleum Accumulation of China Marine Sequence[J].Natural Gas Geoscience,2013,24(2):199-209. http://www.cnki.com.cn/Article/CJFDTOTAL-TDKX201302002.htm
[8] 胡雄,梁为,李洋冰,等.黄河口凹陷流体包裹体成藏年代和充注期次研究[J].矿物岩石地球化学通报,2014,33(6):868-873. http://www.cnki.com.cn/Article/CJFDTOTAL-KYDH201406019.htm
Hu X,Liang W,Li Y B,et al.Research on the Age of Hydrocarbon Accumulation and Filling History of Fluid Inclusions in Huanghekou Depression[J].Bulletin of Mineralogy,Petrology and Geochemistry,20l4,33 (6):868-873. http://www.cnki.com.cn/Article/CJFDTOTAL-KYDH201406019.htm
[9] 陈红汉,吴悠,丰勇,等.塔河油田奥陶系油气成藏期次及年代学[J].石油与天然气地质,2014,35(6):806-819. http://www.cnki.com.cn/Article/CJFDTOTAL-SYYT201406010.htm
Chen H H,Wu Y,Feng Y,et al.Timing and Chronology of Hydrocarbon Charging in the Ordovician of Tahe oilfield,Tarim Basin,NW China[J].Oil ＆ Gas Geology,2014,35(6):806-819. http://www.cnki.com.cn/Article/CJFDTOTAL-SYYT201406010.htm
[10] Liu K,Eadington P J,Middleton H,et al.Applying Quantitative Fluorescence Techniques to Investigate Petroleum Charge History of Sedimentary Basins in Australia and Papuan New Guinea[J].Journal of Petroleum Science and Engineering,2007,57:139-151. doi: 10.1016/j.petrol.2005.11.019
[11] Cao J,Jin Z J,Hu W X,et al.Improved Understanding of Petroleum Migration History in the Hongche Fault Zone,Northwestern Junggar Basin (Northwest China):Constrained by Vein-calcite Fluid Inclusions and Trace Elements[J].Marine and Petroleum Geology,2010,27(1):61-68. doi: 10.1016/j.marpetgeo.2009.08.014
[12] Zhuo Q G,Meng F W,Song Y,et al.Hydrocarbon Migration through Salt:Evidence from Kelasu Tectonic Zone of Kuqa Foreland Basin in China[J].Carbonates and Evaporites,2014,29(3):291-297. doi: 10.1007/s13146-013-0177-y
[13] 马剑,黄志龙,范彩伟,等.应用定量颗粒荧光技术研究宝岛13-1气田油气成藏特征[J].天然气地球科学,2014,25(8):1188-1196.
Ma J,Huang Z L,Fan C W,et al.The Application of Quantitative Grain Fluorescence Technique to Study Hydrocarbon Accumulation Characteristics of BD13-1,Qiongdongnan Basin[J].Natural Gas Geoscience,2014,25(8):1188-1196.
[14] 米敬奎,张水昌,何坤,等.群体包裹体地球化学特征及在油气源对比中的应用[J].石油实验地质,2011,33(2):188-192.
Mi J K,Zhang S C,He K.Application of Colonial Inclusions Geochemistry in Oil- and Gas-origin Study[J]. Petroleum Geology ＆ Experiment,2011,33(2):188-192.
[15] 席伟军,乔明全,张枝焕,等.包裹体技术在春风油田稠油油源对比中的应用[J].石油天然气学报,2013,35(4):27-30.
Xi W J,Qiao M Q,Zhang Z H,et al.Application of Inclusions Technology in Heavy Oil Source Correlation in Spring Oilfield[J].Journal of Oil and Gas Technology,2013,35(4):27-30.
[16] 陈红汉.单个油包裹体显微荧光特性与热成熟度评价[J].石油学报,2014,35(3):584-590. http://www.cnki.com.cn/Article/CJFDTOTAL-SYXB201403026.htm
Chen H H.Mircrospectro Fluorimetric Characterization and Thermal Maturity Assessment of Individual Oil Inclusion[J].Acta Petrolei Sinica,2014,35(3):584-590. http://www.cnki.com.cn/Article/CJFDTOTAL-SYXB201403026.htm
[17] 许锦,郑伦举,贾存善,等.群体包裹体成分分析法及在沙雅隆起的应用探索[J].石油实验地质,2011,33(2):197-201. http://www.cnki.com.cn/Article/CJFDTOTAL-SYSD201102019.htm
Xu J,Zheng L J,Jia C S,et al.Grouped Fluid Inclusion Composition Analysis and Application in Shaya Uplift[J].Petroleum Geology ＆ Experiment,2011,33(2):197-201. http://www.cnki.com.cn/Article/CJFDTOTAL-SYSD201102019.htm
[18] Zhang Z R,Greenwood P,Zhang Q,et al.Laser Ablation GC-MS Analysis of Oil-bearing Fluid Inclusions in Petroleum Reservoir Rocks[J].Organic Geochemistry,2012,43:20-25. doi: 10.1016/j.orggeochem.2011.11.005
[19] 饶丹,秦建中,许锦,等.塔河油田奥陶系油藏成藏期次研究[J].石油实验地质,2014,36(1):65-71. http://www.cqvip.com/QK/95265X/201401/48730827.html
Rao D,Qin J Z,Xu J,et al.Accumulation Periods of Ordovician Reservoirs in Tahe Oil Field[J].Petroleum Geology ＆ Experiment,2014,36(1):65-71. http://www.cqvip.com/QK/95265X/201401/48730827.html
[20] 倪培,孟凡巍.碳酸盐岩中烃类包裹体的人工合成实验研究[J].岩石学报,2008,24(1):161-165. http://www.cqvip.com/QK/94579X/200801/27198194.html
Ni P,Meng F W.Experimental Study on Synthetic Oil (Hydrocarbon)-bearing Inclusions in Carbonate[J].Acta Petrologica Sinica,2008,24(1):161-165. http://www.cqvip.com/QK/94579X/200801/27198194.html
[21] 孟凡巍,倪培,丁俊英,等.人工合成烃类流体包裹体测温数据对石油地质的指示[J].岩石学报,2008,24(9):1975-1980. http://www.cnki.com.cn/Article/CJFDTOTAL-YSXB200809005.htm
Meng F W,Ni P,Ding J Y,et al.Homogenization Temperatures from Synthetic Fluid Inclusions:Implications for Oil and Gas Geology[J].Acta Petrologica Sinica,2008,24(9):1975-1980. http://www.cnki.com.cn/Article/CJFDTOTAL-YSXB200809005.htm
[22] 孟凡巍,倪培,葛晨东,等.实验室合成石盐包裹体的均一温度以及古气候意义[J].岩石学报,2011,27(5):1543-1547. http://www.cnki.com.cn/Article/CJFDTOTAL-YSXB201105027.htm
Meng F W,Ni P,Ge C D,et al.Homogenization Temperature of Fluid Inclusions in Laboratory Grown Halite and Its Implication for Paleotem Peraturerecon Struction[J].Acta Petrlogica Sinica,2011,27(5):1543-1547. http://www.cnki.com.cn/Article/CJFDTOTAL-YSXB201105027.htm
[23] 葛云锦,陈勇,周瑶琪,等.实验模拟碳酸盐岩储层包裹体对油气充注的响应[J].地球科学进展,2011,26(10):1050-1056. http://www.cnki.com.cn/Article/CJFDTotal-DXJZ201110006.htm
Ge Y J,Chen Y,Zhou Y Q,et al.Experimental Simulation of Fluid Inclusion Response to Hydrocarbon Charge in Carbonate Reservoir[J].Advances in Earth Science,2011,26(10):1050-1056. http://www.cnki.com.cn/Article/CJFDTotal-DXJZ201110006.htm
[24] 陈勇,葛云锦,周振柱,等.矿物润湿性对储层烃类包裹体形成制约的实验研究[J].地质学报,2011,85(4):569-575. http://d.wanfangdata.com.cn/Periodical/dizhixb201104012
Chen Y,Ge Y J,Zhou Z Z,et al.Experimental Study of the Constraint of Minerals Wettability on Hydrocarbon-bearing Inclusion Forming in Reservoir[J].Acta Geologica Sinica,2011,85(4):569-575. http://d.wanfangdata.com.cn/Periodical/dizhixb201104012
[25] Guillaume D,Teinturier S,Dubessy J,et al.Calibration of Methane Analysis by Raman Spectroscopy in H2O-NaCl-CH4 Fluid Inclusions[J].Chemical Geology,2003,194(1-3):41-49. doi: 10.1016/S0009-2541(02)00270-X
[26] Liu D H,Xiao X M,Mi J K,et al.Determination of Trapping Pressure and Temperature of Petroleum Inclusions Using PVT Simulation Software-A Case Study of Lower Ordovician Carbonates from the Lunnan Low Uplift,Tarim Basin[J].Marine Petroleum Geology,2003,20(1):29-43. doi: 10.1016/S0264-8172(03)00047-3
[27] 张志荣,张渠,席斌斌,等.含油包裹体成在线激光剥蚀色谱-质谱分析[J].石油实验地质,2011,33(4):437-440. http://www.cnki.com.cn/Article/CJFDTotal-SYSD201104022.htm
Zhang Z R,Zhang Q,Xi B B,et al.On-line Analysis of Oil-bearing Fluid Inclusion with Laser Ablation GC-MS[J].Petroleum Geology ＆ Experiment,2011,33(4):437-440. http://www.cnki.com.cn/Article/CJFDTotal-SYSD201104022.htm
[28] Albrecht M,Derrey I T,Horn I,et al.Quantification of Trace Element Contents in Frozen Fluid Inclusions by μs-fs-LA-ICP-MS Analysis[J].Journal of Analytical Atomic Spectrometry,2014,29:1034-1041. doi: 10.1039/C4JA00015C
[29] Pironon J.Synthesis of Hydrocarbon Fluid Inclusion at Low Temperature[J].American Mineralogist,1990,75:226-229.
[30] Teinturier S,Elie M,Pironon J.Oil-cracking Processes Evidence from Synthetic Petroleum Inclusions[J].Journal of Geochemical Exploration,2003,78-79:421-425. doi: 10.1016/S0375-6742(03)00135-3
[31] Chou I M,Song Y C,Burruss R C.A New Method for Synthesizing Fluid Inclusions in Fused Silica Capillaries Containing Organic and Inorganic Material[J].Geochimica et Cosmochimica Acta,2008,72(21):5217-5231. doi: 10.1016/j.gca.2008.07.030
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