Application of deep eutectic solvent extraction in eco-geological sample analysis
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摘要: 新型绿色溶剂的开发和利用是当前的研究热点。将绿色溶剂替代传统溶剂用于生态地质样品前处理过程,可以减少对实验人员及环境的危害。深共晶溶剂因其具有可生物降解性、低环境影响、低成本和易于合成等优点,逐渐被应用于生态地质样品中分析物的提取和分离。文章在介绍深共晶溶剂的概念、制备方法和主要理化特性的基础上,综述了该技术在水、土壤和生物样品检测中的最新研究进展,并对其应用前景进行了展望,认为深共晶溶剂是一类有望替代传统有毒有害溶剂的新型绿色溶剂,但仍需要解决其高黏度的缺点,同时要加强提取机理研究和与多种检测方法联用技术的研究。Abstract: The development and utilization of innovative green solvents is currently a hot topic of research. Substituting conventional solvents with environment friendly alternatives in the pretreatment of ecological geological samples can effectively mitigate potential risks to both researchers and the environment. Deep eutectic solvents (DESs) have garnered increasing attention due to their biodegradability, minimal environmental impact, cost-effectiveness and facile synthesis, rendering them suitable for extraction and separation in eco-geological sample analysis. This paper comprehensively overviews the deep eutectic solvents (DESs) from the perspectives of its conceptual framework, preparation methodologies, and essential physicochemical properties. Additionally, it summarizes latest research advances on applying DES technology to water quality assessment, soil analysis, and biological sample characterization with the discussion of its prospects. As a new type of green solvent, DESs offers a promising alternative to replace conventional toxic solvents; however, it is crucial to address challenges related to high viscosity along with further investigation in extraction mechanisms and integration with various detection techniques.
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[1] POLLET P, DAVEY E A, UREÑA-BENAVIDES E E, et al. Solvents for sustainable chemical proce-sses[J]. Green Chemistry, 2014, 16(3):1034-1055.
[2] 陶春军,李明辉,马明海,等.皖南某典型富硒区土壤-水稻重金属生态风险评估[J].华东地质,2023,44(2):160-171.
TAO C J,LI M H,MA M H,et al.Ecological risk assessment of heavy metals in soil-rice in a typical selenium-rich area of southern Anhui Province[J].East China Geology,2023,44(2):160-171.
[3] CHEN T L, KIM H, PAN S Y, et al. Implementation of green chemistry principles in circular economy system towards sustainable development goals:challenges and perspectives[J]. Science of The Total Environment, 2020, 716:136998.
[4] HALDER A K, CORDEIRO M N D S. Probing the environmental toxicity of deep eutectic solvents and their components:an in silico modeling approach[J]. ACS Sustainable Chemistry&Engineering, 2019, 7(12):10649-10660.
[5] ABBOTT A P, BOOTHBY D, CAPPER G, et al. Deep eutectic solvents formed between choline chloride and carboxylic acids:versatile alternatives to ionic liquids[J]. Journal of the American Chemical Society, 2004, 126(29):9142-9147.
[6] GÓMEZ E, COJOCARU P, MAGAGNIN L, et al. Electrodeposition of Co, Sm and SmCo from a deep eutectic solvent[J]. Journal of Electroanalytical Chemistry, 2011, 658(1):18-24.
[7] KHANDELWAL S, TAILOR Y K, KUMAR M. Deep eutectic solvents (DESs) as eco-friendly and sustainable solvent/catalyst systems in organic transformations[J]. Journal of Molecular Liquids 2016, 215:345-386.
[8] DI MARINO D, SHALABY M, KRIESCHER S, et al. Corrosion of metal electrodes in deep eutectic solvents[J]. Electrochemistry Communications, 2018, 90:101-105.
[9] XU P, ZHENG G W, ZONG M H, et al. Recent progress on deep eutectic solvents in biocatalysis[J]. Bioresources and Bioprocessing, 2017, 4(1):34.
[10] ZHUANG B, DOU L L, LI P, et al. Deep eutectic solvents as green media for extraction of flavonoid glycosides and aglycones from Platycladi Cacumen[J]. Journal of Pharmaceutical and Biomedical Analysis, 2017, 134:214-219.
[11] ZHAO W, XU L, WANG, H, et al. Deep eutectic solvent-based ultrasound-assisted extraction in soil samples preparation and elemental determination by ICP-OES[J]. Analytical Sciences, 2023, 40(2):263-270.
[12] ZHAO W, SUN Y, WEI X, et al. Determination of major and trace elements in plant samples by inductively coupled plasma optical emission spectrometry with deep eutectic solvent extraction based on choline chloride and carboxylic acids[J]. Analytical Methods, 2023, 15(34):4275-4281.
[13] SANTANA A P R, ANDRADE D F, GUIMARÃES T G S, et al. Synthesis of natural deep eutectic solvents using a mixture design for extraction of animal and plant samples prior to ICP-MS analy-sis[J]. Talanta, 2020, 216:120956.
[14] TANG B, ROW K H. Recent developments in deep eutectic solvents in chemical sciences[J]. Monatshefte für Chemie-Chemical Monthly, 2013, 144(10):1427-1454.
[15] HUANG J, GUO X, XU T, et al. Ionic deep eutectic solvents for the extraction and separation of natural products[J]. Journal of Chromatography A, 2019, 1598:1-19.
[16] WAGLE D V, ADHIKARI L, BAKER G A. Computational perspectives on structure, dynamics, gas sorption, and bio-interactions in deep eutectic solvents[J]. Fluid Phase Equilibria, 2017, 448:50-58.
[17] VAN OSCH D J G P, DIETZ C H J T, VAN SPRONSEN J, et al. Search for natural hydrophobic deep eutectic solvents based on natural components[J]. ACS Sustainable Chemistry&Engineering, 2019, 7(3):2933-2942.
[18] MARTINS M A R, PINHO S P, COUTINHO J A P. Insights into the nature of eutectic and deep eutectic mixtures[J]. Journal of Solution Chemistry, 2019, 48(7):962-982.
[19] FRANCISCO M, VAN DEN BRUINHORST A, KROON M C. Low-transition-temperature mixtures (LTTMs):a new generation of designer solvents[J]. Angewandte Chemie International Edition, 2013, 52(11):3074-3085.
[20] MJALLI F S, NASER J. Viscosity model for choline chloride-based deep eutectic solvents[J]. Asia-Pacific Journal of Chemical Engineering, 2015, 10(2):273-281.
[21] ALKHATIB I I I, BAHAMON D, LLOVELL F, et al. Perspectives and guidelines on thermodynamic modelling of deep eutectic solvents[J]. Journal of Molecular Liquids, 2020, 298:112183.
[22] HANSEN B B, SPITTLE S, CHEN B, et al. Deep eutectic solvents:a review of fundamentals and applications[J]. Chemical Reviews, 2021, 121(3):1232-1285.
[23] AYDIN F, YILMAZ E, SOYLAK M. A simple and novel deep eutectic solvent based ultrasound-assisted emulsification liquid phase microextraction method for malachite green in farmed and ornamental aquarium fish water samples[J]. Microchemical Journal, 2017, 132:280-285.
[24] ZOUNR R A, TUZEN M, KHUHAWAR M Y. A simple and green deep eutectic solvent based air assisted liquid phase microextraction for separation, preconcentration and determination of lead in water and food samples by graphite furnace atomic absorption spectrometry[J]. Journal of Molecular Liquids, 2018, 259:220-226.
[25] EL-DEEN A K, SHIMIZU K. Deep eutectic solvent as a novel disperser in dispersive liquid-liquid microextraction based on solidification of floating organic droplet (DLLME-SFOD) for preconcentration of steroids in water samples:Assessment of the method deleterious impact on the environment using Analytical Eco-Scale and Green Analytical Procedure Index[J]. Microchemical Journal, 2019, 149:10415.
[26] ARAIN M B, YILMAZ E, SOYLAK M. Deep eutectic solvent based ultrasonic assisted liquid phase microextraction for the FAAS determination of co-balt[J]. Journal of Molecular Liquids, 2016, 224:538-543.
[27] YOUSEFI S M, SHEMIRANI F, GHORBANIAN S A. Enhanced headspace single drop microextraction method using deep eutectic solvent based magnetic bucky gels:application to the determination of volatile aromatic hydrocarbons in water and urine samples[J]. Journal of Separation Science, 2017, 41(4):966-974.
[28] YOUSEFI S M, SHEMIRANI F, GHORBANIAN S A. Deep eutectic solvent magnetic bucky gels in developing dispersive solid phase extraction:Application for ultra trace analysis of organochlorine pesticides by GC-micro ECD using a large-volume injection tech-nique[J]. Talanta, 2017, 168:73-81.
[29] LIU Q, HUANG X, LIANG P. Preconcentration of copper and lead using deep eutectic solvent modified magnetic nanoparticles and determination by inductively coupled plasma optical emission spectrometry[J]. Atomic Spectroscopy-Norwalk Connecticut, 2020, 41:36-42.
[30] FLORINDO C, BRANCO L C, MARRUCHO I M. Development of hydrophobic deep eutectic solvents for extraction of pesticides from aqueous environ-ments[J]. Fluid Phase Equilibria, 2017, 448:135-142.
[31] MATONG J M, NYABA L, NOMNGONGO P N. Determination of As, Cr, Mo, Sb, Se and V in agricultural soil samples by inductively coupled plasma optical emission spectrometry after simple and rapid solvent extraction using choline chloride-oxalic acid deep eutectic solvent[J]. Ecotoxicology and Environmental Safety, 2017, 135:152-157.
[32] ZAREI A R, NEDAEI M, GHORBANIAN S A. Ferrofluid of magnetic clay and menthol based deep eutectic solvent:application in directly suspended droplet microextraction for enrichment of some emerging contaminant explosives in water and soil samples[J]. Journal of Chromatography A, 2018, 1553:32-42.
[33] HABIBOLLAHI M H, KARIMYAN K, ARFAEINIA H, et al. Extraction and determination of heavy metals in soil and vegetables irrigated with treated municipal wastewater using new mode of dispersive liquid-liquid microextraction based on the solidified deep eutectic solvent followed by GFAAS[J]. Journal of the Science of Food and Agriculture, 2019, 99(2):656-665.
[34] NEDAEI M, ZAREI A R, GHORBANIAN S A, et al. Miniaturized matrix solid-phase dispersion based on deep eutectic solvent and carbon nitride associated with high-performance liquid chromatography:a new feasibility for extraction and determination of trace nitrotoluene pollutants in soil samples[J]. Journal of Chromatography A, 2019, 1601:35-44.
[35] KACHANGOON R, VICHAPONG J, SANTALADCHAIYAKIT Y, et al. Cloud-point extraction coupled to in-situ metathesis reaction of deep eutectic solvents for preconcentration and liquid chromatographic analysis of neonicotinoid insecticide residues in water, soil and urine samples[J]. Microchemical Journal, 2020, 152:104377
[36] KARIMI M, SHABANI A M H, DADFARNIA S. Deep eutectic solvent-mediated extraction for ligand-less preconcentration of lead and cadmium from environmental samples using magnetic nanoparticles[J]. Microchimica Acta, 2015, 183(2):563-571.
[37] ZOUNR R A, TUZEN M, KHUHAWAR M Y. Ultrasound assisted deep eutectic solvent based on dispersive liquid liquid microextraction of arsenic speciation in water and environmental samples by electrothermal atomic absorption spectrometry[J]. Journal of Molecular Liquids, 2017, 242:441-446.
[38] SANTANA A P R, ANDRADE D F, MORA-VARGAS J A, et al. Natural deep eutectic solvents for sample preparation prior to elemental analysis by plasma-based techniques[J]. Talanta, 2019, 199:361-369.
[39] TANG B, BI W, ZHANG H, et al. Deep eutectic solvent-based HS-SME coupled with GC for the analysis of bioactive terpenoids in chamaecyparis obtusa Leaves[J]. Chromatographia, 2013, 77(3-4):373-377.
[40] SHISHOV A, GERASIMOV A, BULATOV A. Deep eutectic solvents based on carboxylic acids for metals separation from plant samples:elemental analysis by ICP-OES[J]. Food Chemistry, 2022, 366:130634.
[41] 陈佳楠,李丹,周一冉,等.基于深共晶溶剂的液-液微萃取法结合液相色谱-串联质谱法检测枸杞中的10种农药残留[J].食品安全质量检测学报, 2021, 12(12):4793-4800.
CHEN J N, LI D, ZHOU Y R, et al. Determination of 10 pesticide residues in Lycium barbarum by liquid-liquid microextraction combined with liquid chromatography-tandem mass spectrometry based on deep eutectic solvent[J]. Journal of Food Safety and Quality Inspection, 2021, 12(12):4773-4800.
[42] HABIBI E, GHANEMI K, FALLAH-MEHRJARDI M, et al. A novel digestion method based on a choline chloride-oxalic acid deep eutectic solvent for determining Cu, Fe, and Zn in fish samples[J]. Anal Chim Acta, 2013, 762:61-67.
[43] GHANEMI K, NAVIDI M A, FALLAH-MEHRJARDI M, et al. Ultra-fast microwave-assisted digestion in choline chloride-oxalic acid deep eutectic solvent for determining Cu, Fe, Ni and Zn in marine biological samples[J]. Analytical Methods, 2014, 6(6):1774-1781.
[44] PANHWAR A H, TUZEN M, KAZI T G. Choline chloride-oxalic acid as a deep eutectic solvent-based innovative digestion method for the determination of selenium and arsenic in fish samples[J]. Journal of AOAC International, 2018, 101(4):1183-1189.
[45] HELALAT-NEZHAD Z, GHANEMI K, FALLAH-MEHRJARDI M. Dissolution of biological samples in deep eutectic solvents:an approach for extraction of polycyclic aromatic hydrocarbons followed by liquid chromatography-fluorescence detection[J]. Journal of Chromatography A, 2015, 1394:46-53.
[46] ZHANG W, LIANG X. Headspace gas chromatography-mass spectrometry for volatile components analysis in Ipomoea cairica (L.) Sweet leaves:natural deep eutectic solvents as green extraction and dilution matrix[J]. Foods, 2019, 8(6):205.
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