Characters and risk assessment of hydrocarbons in surface sediments of Sanniang Bay in Guangxi Province
-
摘要: 为研究广西三娘湾海域表层沉积物有机质中烃类化合物的分布特征及来源,于2019年10月在三娘湾海域采集了表层沉积物样品,利用加速溶剂萃取GC-MSD法对沉积物中的16种多环芳烃(PAHs)进行了分析。结果表明: 三娘湾海域表层沉积物样品中多环芳烃的含量为37~241.8 ng/g,总体处于含量较低的水平,但与往年相比研究区PAHs含量增加明显。通过组分分析等方法进行PAHs的来源分析,结果指示其主要来源为燃烧源,夹杂石油源的混合来源; 通过效应区间法对多环芳烃进行生态风险评价,认为其总体处于风险较低的水平。综合研究表明,三娘湾海域总体生态环境较好,但人类活动对多环芳烃含量及分布特征的影响较明显,需要持续关注。Abstract: In order to study the distribution characteristics and sources of hydrocarbons in the surface sediments of Sanniang Bay in Guangxi Province, the authors have collected five surface sediments samples in October 2019 and analyzed their polycyclic aromatic hydrocarbons (PAHs) using GC-MSD method. The results showed that the PAHs content was 37~241.8 ng/g, which was generally in a low level, but it markedly increased in recent years. The component analysis on PAHs source indicated that the main source is combustion source and mixed oil source. The ecological risk assessment of PAHs was carried out by the effect interval method, and it was found that the PAHs content was in low risk level. The comprehensive study shows that the overall ecological environment of Sanniang Bay is good, but the impact of human activities on PAHs is obvious and needs to be paid continuous attention.
-
Key words:
- Sanniang Bay /
- sediment /
- polycyclic aromatic hydrocarbons /
- risk assessment
-
-
[1] Sverdrup L E,Nielsen T,Krogh P H.Soil ecotoxicity of polycyclic aromatic hydrocarbons in relation to soil sorption,lipophilicity,and water solubility[J].Environ Sci Technol,2002,36(11):2429-2435.
[2] Baek S O,Field R A,Goldstone M E,et al.A review of atmospheric polycyclic aromatic hydrocarbons:sources,fate and behavior[J].Water Air Soil Pollut,1991,60(3/4):279-300.
[3] Khalili N R,Scheff P A,Holsen T M.PAH source fingerprints for coke ovens,diesel and,gasoline engines,highway tunnels,and wood combustion emissions[J].Atmos Environ,1995,29(4):533-542.
[4] 李斌,吴莹,张经.北黄海表层沉积物中多环芳烃的分布及其来源[J].中国环境科学,2002,22(5):429-432.
[5] Li B,Wu Y,Zhang J.Distribution and source of polycyclic aromatic hydrocarbons (PAHs) in surface sediment of the northern Yellow Sea[J].China Environ Sci,2002,22(5):429-432.
[5] 杨永亮,麦碧娴,潘静,等.胶州湾表层沉积物中多环芳烃的分布及来源[J].海洋环境科学,2003,22(4):38-43.
[7] Yang Y L,Mai B X,Pan J,et al.Distribution and sources of polycyclic aromatic hydrocarbon in sediments of Jiaozhou Bay[J].Mar Environ Sci,2003,22(4):38-43.
[6] 罗孝俊,陈社军,麦碧娴,等.珠江及南海北部海域表层沉积物中多环芳烃分布及来源[J].环境科学,2005,26(4):129-134.
[9] Luo X J,Chen S J,Mai B X,et al.Distribution and sources of po-lycyclic aromatic hydrocarbons in sediments from rivers of Pearl River delta and its nearby South China Sea[J].Environ Sci,2005,26(4):129-134.
[7] 李泽利. 锦州湾沉积物典型有机物组成及来源研究[D].青岛:中国海洋大学,2011.
[11] Li Z L.Composition and Source of Typical Organics in Jinzhou Bay Sediments[D].Qingdao:Ocean University of China,2011.
[8] 中华人民共和国环境保护部.HJ 805—2016土壤和沉积物多环芳烃的测定气相色谱-质谱法[S].北京:中国环境科学出版社,2016.
[13] Ministry of Environmental Protection of the People's Republic of China.HJ 805-2016 Soil and Sediment-determination of Polycyclic Aromatic Hydrocarbon by Gas Chromatography-mass Spectrometry[S].Beijing:China Environmental Science Press,2016.
[9] Yan W,Chi J S,Wang Z Y,et al.Spatial and temporal distribution of polycyclic aromatic hydrocarbons (PAHs) in sediments from Daya Bay,South China[J].Environ Pollut,2009,157(6):1823-1830.
[10] Hong H,Xu L,Zhang L,et al.Environmental Fate and Chemistry of Organic Pollutants in the Sediment of Xiamen and Victoria Harbours[J].Mar Pollut Bull,1995,31(4/12):229-236.
[11] 崔振昂,黄向青.广西钦州湾近岸表层沉积物多环芳烃分布特征及生态风险评价[J].安徽农业科学,2014,42(33):11824-11826,11933.
[17] Cui Z A,Huang X Q.Distributions and risk assessment of polycyclic aromatic hydrocarbons (PAHs) in surface sediments from Qinzhou Bay,Guangxi[J].J Anhui Agric Sci,2014,42(33):11824-11826,11933.
[12] Krauss M,Wilcke W.Predicting soil-water partitioning of polycyclic aromatic hydrocarbons and polychlorinated biphenyls by desorption with methanol-water mixtures at different tempera-tures[J].Environ Sci Technol,2001,35(11):2319-2325.
[13] 余顺. 东京湾及河口区表层沉积物中污染物行为的研究:Ⅱ.多环芳烃的行为及其来源[J].海洋环境科学,1988,7(4):10-16.
[20] Yu S.Study on the behavior of pollutants in the surface sediments of the Tokyo Bay and its estuary:Ⅱ.The behavior and source of polycyclic aromatic hydrocarbons[J].Mar Environ Sci,1988,7(4):10-16.
[14] Sicre M A,Marty J C,Saliot A,et al.Aliphatic and aromatic hydrocarbons in the Mediterranean aerosol[J].Int J Environ Anal Chem,1987,29(1/2):73-94.
[15] 朱先磊,刘维立,卢妍妍,等.燃煤烟尘多环芳烃成分谱特征的研究[J].环境科学研究,2001,14(5):4-8.
[23] Zhu X L,Liu W L,Lu Y Y,et al.Study on the characteristics of PAHs source profile of coal combustion[J].Res Environ Sci,2001,14(5):4-8.
[16] Butler J D,Crossley P.Reactivity of polycyclic aromatic hydrocarbons adsorbed on soot particles[J].Atmos Environ,1981,15(1):91-94.
[17] 邓伟. 南黄海、东海表层沉积物中脂肪烃与多环芳烃的分布特征及来源初步研究[D].青岛:中国海洋大学,2013.
[26] Deng W.A Preliminary Study on the Composition,Distribution and Source Apportionment of Aliphatic and Polycyclic Aromatic Hydrocarbons in Surface Sediments from the South Yellow Sea and East China Sea[D].Qingdao:Ocean University of China,2013.
[18] 杨敏,倪余文,苏凡,等.辽河沉积物中多环芳烃的污染水平与特征[J].环境化学,2007,26(2):217-220.
[28] Yang M,Ni Y W,Su F,et al.Distribution and sources of polycyclic aromatic hydrocarbons (PAHs) in sediments of Liaohe Ri-ver,China[J].Environ Chem,2007,26(2):217-220.
[19] Maliszewska-Kordybach B.Polycyclic aromatic hydrocarbons in agricultural soils in Poland:Preliminary proposals for criteria to evaluate the level of soil contamination[J].Appl Geochem,1996,11(1/2):121-127.
[20] CCME(Canadian Council of Ministers of the Environment).A Protocol for the Derivation of Environmental and Human Health Soil Quality Guidelines[M].Winnipeg:Canadian Council of Ministers of the Environment,1996.
[21] 朱文锋. 广东省沿海表层沉积物中多环芳烃研究[D].广州:中国科学院研究生院(广州地球化学研究所),2007.
[32] Zhu W F.Occurrence of Polycyclic Aromatic Hydrocarbons in Coastal Sediments off Guangdong Province[D].Guangzhou:Graduate School of Chinese Academy of Sciences (Guangzhou Institute of Geochemistry),2007.
[22] 徐绍箐,马启敏,李泽利,等.锦州湾表层沉积物中多环芳烃测定与生态风险评价[J].环境化学,2011,30(11):1900-1905.
[34] Xu S Q,Ma Q M,Li Z L,et al.Determination and risk assessment of polycyclic aromatic hydrocarbons in surface sediment from Jinzhou Bay,China[J].Environ Chem,2011,30(11):1900-1905.
-
计量
- 文章访问数: 589
- PDF下载数: 76
- 施引文献: 0