Comparative Analysis on the Characteristic Changes of the Brine Reservoir System before and after Exploration of the Qarhan Salt Lake(Huobuxun Area)
-
摘要: 柴达木盆地察尔汗盐湖赋存储量可观的低品位固体钾盐矿, 其主要的开发方式为液化开采。本文对比分析了霍布逊区段盐湖资源大规模开采前(2004年)和开采后(2011年和2019年)典型钻孔岩芯孔隙度、固体钾矿含量、卤水组分变化特征, 评价了钾盐液化开采效率。结果表明: 由于大规模采卤使得大量高矿化度卤水被带出, 而低矿化度水体补给储卤层孔隙并溶解盐层中盐类矿物, 使得储卤层孔隙率有逐渐增大趋势; 卤水中主要组分KCl和NaCl浓度均出现降低现象, 而MgCl2则出现增加趋势, 这主要与补水工程及补给水体中兑卤有关。在这期间, 卤水矿中KCl品位下降幅度要小于固体矿床KCl品位下降幅度, 说明卤水溶解了石盐层中大量固体低品位钾矿, 提升了其KCl品位。本次研究对于优化霍布逊区段固体钾盐液化开采方案具有重要的指导意义。Abstract: Qarhan Salt Lake in Qaidam Basin has a considerable amount of low-grade solid potassium salt ore; developed mainly through water-replenishing dissolved liquefaction mining. This paper compares and analyzes the characteristics of typical drilling core porosity, solid potassium ore content, and halogen composition change before (2004) and after (2011 and 2019) large-scale exploitation of salt lake resources in Hobson District, and the efficiency of potassium salt liquefaction mining is evaluated. The results show that a large number of high-mineralized brines are brought out due to large-scale brine mining, while the low mineralization water recharge reservoir pores dissolve salt minerals in the salt layer, gradually increasing the porosity of the reservoir.During this period, the KCl grade drop in brine ore was less than the decrease in the KCl grade of solid deposit.This showed that the brine dissolved a large number of solid low-grade potassium ore in the stone salt layer, raising its KCl grade. This paper is of great significance for the optimization of solid potassium salt liquefaction mining scheme in the Qaidam Basin.
-
-
蔡克勤, 高建华. 1994. 察尔汗盐湖钾盐矿床的形成条件[J]. 地学前缘, 1(3-4): 231-233.
常政, 袁小龙, 刘万平, 李梦玲, 苗卫良, 程怀德, 卜迪, 张昊, 张西营. 2022. 察尔汗盐湖固体钾盐溶解对溶剂注入速率响应机制研究[J]. 地球学报, 43(3): 287-294.
郭新华, 王春男, 马明珠. 2006. 青海柴达木盆地察尔汗盐湖首采区钾镁盐矿床开发及老卤排放对液体钾矿的影响现状[J].西北地质, 39(1): 98-104.
焦鹏程, 刘成林.2020. 青海别勒滩低品位固体钾矿液化开发技术[M]. 北京: 科学出版社.
李瑞琴, 刘成林, 赵艳军, 刘万平, 王石军, 江雨彤. 2021. 青海别勒滩试验区低品位固体钾盐液化开采的野外实验研究[J].岩石矿物学杂志, 40(1): 76-88.
李文鹏. 1991. 察尔汗盐湖溶矿驱动开采模型及其软件开发[D].北京: 中国地质科学院.
刘喜业, 李勇刚, 张兴儒, 崔小琴, 张爱华. 2014. 察尔汗盐湖表层低品位钾矿溶矿实验及数值模拟分析[J]. 无机盐工业, 46(8): 18-20.
龙鹏宇, 赵艳军, 胡宇飞, 杜江民, 何继辉, 王朝旭. 2022. 马海盐湖北部矿段低品位固体钾矿中钾盐矿物的赋存特征及成因探讨[J]. 地球学报, 43(3): 338-346.
孙大鹏, 吕亚萍. 1995. 察尔汗盐湖首采区卤水溶解光卤石实验的初步研究[J]. 盐湖研究, 3(4): 40-43.
孙大鹏. 1974. 我国某盐湖现代钾盐沉积的形成[J]. 地球化学, (4): 19.
王石军. 2005. 察尔汗盐湖钾镁盐矿床可采储量特征及其开采探讨[J]. 化工矿物与加工, 34(1): 30-32.
王文祥, 李文鹏, 刘振英, 郝爱兵, 王石军, 焦鹏程. 2010. 察尔汗盐湖低品位固体钾矿液化开采的现场试验研究探讨[J].矿床地质, 29(4): 697-703.
王兴富, 王石军, 田红斌, 于雪峰, 朱金义, 刘万平. 2017. 青海盐湖提钾技术进展与我国钾肥工业的发展[J]. 化工矿物与加工, 46(11): 48-52.
王有德, 李正焕, 张兆广, 任金润, 马林, 高云, 覃功平, 李金献, 井忠民, 仪增寿. 2003. 青海省察尔汗盐湖霍布逊区段钾矿补充勘探报告[R]. 格尔木: 青海省柴达木综合地质矿产勘查院.
吴必豪, 段振豪, 关玉华, 连卫. 1986. 柴达木盆地察尔汗干盐湖钾镁盐的沉积[J]. 地质学报, 59(3): 286-296.
杨谦. 1992. 察尔汗盐湖盐层及钾矿层的分布规律[J]. 青海地质, 14(2): 66-80.
袁见齐, 霍承禹, 蔡克勤. 1985. 干盐湖阶段的沉积特征兼论钾盐矿层的形成[J]. 地球科学, 10(4): 1-9.
袁见齐, 霍承禹. 1981. 青海察尔汗盐湖钾盐矿床成因的若干问题[J]. 地球科学, 14(1): 207-213.
袁小龙, 盛金昌, 张西营, 李斌凯, 周同亮, 高东林. 2018. 昆特依盐湖浅部储卤层对卤水组成的影响[J]. 水文地质工程地质, 45(2): 13-20.
袁小龙, 张西营, 盛金昌, 高东林, 李斌凯, 都永生, 万维汉.2018. 环境温度对盐湖卤水化学组成及储卤层渗透性变化的制约[J]. 地质学报, 92(8): 1724-1732.
郑绵平, 侯献华. 2017. 青海盐湖资源综合利用与可持续发展战略[J]. 科技导报, 35(12): 11-13.
CAI Ke-qin, GAO Jian-hua. 1994. Formation conditions of potassium deposit in Qarhan salt lake[J]. Earth Science Frontiers, 1(3-4): 231-233(in Chinese).
CHANG Zheng, YUAN Xiao-long, LIU Wan-ping, LI Meng-ling, MIAO Wei-liang, CHENG Huai-de, BU Di, ZHANG Hao, ZHANG Xi-ying. 2022. A Study on the Mechanism of Influence of the Dissolution of Solid Potassium Salt in Qarhan Salt Lake to the Rate of Solvent Injection[J]. Acta Geoscientica Sinica, 43(3): 287-294(in Chinese with English abstract).
GUO Xin-hua, WANG Chun-nan, MA Ming-zhu. 2006. Influence on the ore of development of the potash ore and the Laolu disposing in the first mine area of Qarhan saline lake, Qinghai[J]. Northwestern Geology, 39(1): 98-104(in Chinese with English abstract).
HOMMEL J, COLTMAN E, CLASS H. 2018. Porosity-permeability relations for evolving pore space: A review with a focus on (bio-)geochemically altered porous media[J].Transport in Porous Media, 124: 589-629.
JIAO Peng-cheng, LIU Cheng-lin.2020. Low grade solid potash mining technology in Bieletan saline lake, Qinghai[M]. Beijing: Science Press(in Chinese).
LI Rui-qin, LIU Cheng-lin, ZHAO Yan-jun, LIU Wan-ping, WANG Shi-jun, JIANG Yu-tong. 2021. A study of the field experimental liquefaction and exploitation of low-grade solid potassium resource in the Bieletan experimental area, Qinghai Province[J]. Acta Petrologica et Mineralogica, 40(1): 76-88(in Chinese with English abstract).
LI Wen-peng. 1991. The model of dissolving and driving exploitation and the software development in Qarhan Salt Lake[D].Beijing: Chinese Academy of Geological Sciences(in Chinese with English abstract).
LIU Xi-ye, LI Yong-gang, ZHANG Xing-ru, CUI Xiao-qin, ZHANG Ai-hua. 2014. Dissolution experiment and numerical simulation on surface salt of Qarhan Salt Lake[J]. Inorganic Chemicals Industry, 46(8): 18-20(in Chinese with English abstract).
LONG Peng-yu, ZHAO Yan-jun, HU Yu-fei, DU Jiang-min, HE Ji-hui, WANG Zhao-xu. 2022. Occurrence Characteristics and Genetic Study of Potassium Salt Minerals in Low Grade Solid Potassium Ore in the North Section of Mahai Salt Lake[J].Acta Geoscientica Sinica, 43(3): 338-346(in Chinese with English abstract).
MOLINS S, TREBOTICH D, STEEFEL C I, SHEN C P. 2012. An investigation of the effect of pore scale flow on average geochemical reaction rates using direct numerical simulation[J].Water Resources Research, 48(3): W03527.
NOIRIEL C, STEEFEL C I, YANG L, BERNARD D. 2016. Effects of pore-scale precipitation on permeability and flow[J].Advances in Water Resources, 95: 125-137.
PEREIRA NUNES J P, BIJELJIC B, BLUNT M J. 2016.Pore–space structure and average dissolution rates: A simulation study[J]. Water Resources Research, 52(9): 7198-7212.
SUN Da-peng, LÜ Ya-ping. 1995. A preliminary investigation on carnallite-resolving experiment for intercrystal brines in the first exploitation area of Qarhan Salt Lake, Qinghai, China[J].Journal of Salt Lake Research, 3(4): 40-43(in Chinese with English abstract).
SUN Da-peng. 1974. The origin of recent potash deposits in a certain salt lake, China[J]. Geochimica, 4:230-248.
WANG Shi-jun. 2005. Discussion on characteristics of workable reserves of potassium and magnesium salt deposit in Chaerhan Salt Lake and its mining[J]. Industial Minerals and Processing, 34(1): 30-32(in Chinese with English abstract).
WANG Wen-xiang, LI Wen-peng, LIU Zhen-ying, HAO Ai-bing, WANG Shi-jun, JIAO Peng-cheng. 2010. A tentative discussion on in-situ experimental liquefaction and exploitation of low grade solid potassium resources in Qarhan Salt Lake[J].Mineral Deposits, 29(4): 697-703(in Chinese with English abstract).
WANG Xing-fu, WANG Shi-jun, TIAN Hong-bin, YU Xue-feng, ZHU Jin-yi, LIU Wan-ping. 2017. Potassium extraction technology progress in Qinghai Salt Lake and development of potash fertilizer industry in China[J]. Industrial Minerals & Processing, 46(11): 48-52(in Chinese with English abstract).
WANG You-de, LI Zheng-huan, ZHANG Zhao-guang, REN Jin-run, MA Lin, GAO Yun, QIN Gong-ping, LI Jin-xian, JING Zhong-min, YI Zeng-shou. 2003. Report on supplementary exploration of potassium deposits in the Hobson section of Qarhan salt lake, Qinghai province[R]. Golmud: Qaidam Comprehensive Geological and Mineral Exploration Institute of Qinghai Province(in Chinese).
WU Bi-hao, DUAN Zhen-hao, GUAN Yu-hua, LIAN Wei. 1986.Deposition of potash-magnesium salts in the Qarhan playa, Qaidam Basin[J]. Acta Geological Sinica, 59(3): 286-296(in Chinese with English abstract).
YANG Qian. 1992. Distribution regularity of saline beds and potash ore beds in Qarhan saline lake[J]. Qinghai Geology, 14(2):66-80(in Chinese with English abstract).
YUAN Jian-qi, HUO Cheng-yu, CAI Ke-qin. 1985. Characteristics of salt deposits in the dry salt lake and the formation of potash beds[J]. Earth Science, 10(4): 1-9(in Chinese with English abstract).
YUAN Jian-qi, HUO Cheng-yu. 1981. Genesis of the sylvinite deposits in the Charhan saline lake, Qinghai Province[J].Earth Science, 14(1): 207-213(in Chinese with English abstract).
YUAN Xiao-long, ZHANG Xi-ying, SHENG Jin-chang, GAO Dong-lin, LI Bin-kai, DU Yong-sheng, WAN Wei-han. 2018.Constraint of environmental temperature on chemical composition of brine and permeability of aquifer in the saline lake[J].Acta Geologica Sinica, 92(8): 1724-1732(in Chinese with English abstract).
YUAN Xiao-long, SHENG Jin-chang, ZHANG Xi-ying, LI Bin-kai, ZHOU Tong-liang, GAO Dong-lin. 2018. Influence of shallow reservoir upon the components of brines in the Kunteyi playa[J]. Hydrogeology & Engineering Geology, 45(2):13-20(in Chinese with English abstract).
ZHENG Mian-ping, HOU Xian-hua. 2017. Comprehensive utilization and sustainable development strategy of Qinghaisalt lake resources[J]. Science and Technology Review, 35(12):11-13(in Chinese).
-
计量
- 文章访问数: 50
- PDF下载数: 42
- 施引文献: 0