ZIRCON U-Pb AGE AND Hf ISOTOPIC CHARACTERISTICS OF THE GNEISSIC GRANITES IN LAOZUOSHAN GOLDFIELD OF HEILONGJIANG PROVINCE: Geological Implication
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摘要:
黑龙江老柞山金矿床是佳木斯地块中北部的大型热液叠加夕卡岩型矿床.对矿区东矿带赋矿片麻状花岗岩进行了LA-ICP-MS的U-Pb定年和Hf同位素分析,共获得3组年龄,分别为697.1±8.0、703.0±8.8和484.7±2.7 Ma.其中前2组为捕获的锆石年龄,暗示佳木斯地块南缘可能存在新元古代的结晶基底.第三组锆石年龄代表片麻状花岗岩结晶年龄.锆石原位Hf同位素测试显示,片麻状花岗岩的εHf(t)值为-2.4~+3.6,TDM2为1620~1390 Ma,指示片麻状花岗岩原岩可能是中元古代陆壳物质重熔.结合区域构造演化,认为片麻状花岗岩可能形成于晚泛非-早加里东期的碰撞造山作用,是麻山群深熔岩浆结晶作用的产物.
Abstract:The Laozuoshan gold deposit in Heilongjiang Province is a large hydrothermal superimposed skarn deposit in the north-central of Jiamusi block. Three groups of age, 697.1±8.0, 703.0±8.8, and 484.7±2.7 Ma respectively, are acquired through the LA-ICP-MS U-Pb dating and Hf isotope analysis of gneissic granites in the east ore belt of orefield, among which the former two are the age of captured zircons, suggesting that there might be Neoproterozoic crystalline basement in the south margin of Jiamusi block, and the latter represents the crystallization ages of gneissic granites. The zircon Hf isotope tests show that the εHf(t) ranges from -2.4 to +3.6, with TDM2 of 1620-1390 Ma, indicating that the protolith of gneissic granite may be the derived from the remelting of Mesoproterozoic continental crust material. Combined with the regional tectonic evolution, it is believed that the gneissic granite was possibly formed by the late Pan-African-early Caledonian collision-orogeny as the product of anatectic magma crystallization of Mashan Group.
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Key words:
- zircon U-Pb dating /
- Hf isotope /
- gneissic granite /
- Laozuoshan gold deposit /
- Heilongjiang Province
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图 1 老柞山金矿床矿区地质图(据文献[4]修编)
Figure 1.
表 1 老柞山金矿片麻状花岗岩的主量元素测试结果
Table 1. Contents of major elements in the gneissic granites of Laozuoshan gold deposit
样品号 Na2O MgO Al2O3 SiO2 P2O5 K2O CaO TiO2 MnO TFe2O3 FeO LOI LZS-1 3.80 4.60 11.94 56.32 0.39 2.82 5.07 0.84 0.037 5.94 5.12 2.58 LZS-2 0.52 0.45 12.27 54.11 0.06 10.52 10.18 0.30 0.093 3.15 2.43 8.37 LZS-3 2.54 1.70 14.19 63.74 0.24 3.83 5.40 0.60 0.035 3.89 3.50 3.25 LZS-4 3.42 1.95 17.16 61.38 0.30 3.94 4.52 0.92 0.054 5.19 4.40 1.42 LZS-5 1.70 0.82 13.30 68.50 0.19 7.22 2.43 0.56 0.047 3.89 3.39 1.47 含量单位:%. 表 2 老柞山金矿片麻状花岗岩LA-MC-ICP-MS锆石U-Pb同位素分析结果
Table 2. LA-MC-ICP-MS zircon U-Pb isotopic compositions of the gneissic granites in Laozuoshan gold deposit
样品号 Th/10-6 U/10-6 Th/U 同位素比值 表面年龄/Ma 207Pb/206Pb 1σ 207Pb/235U 1σ 206Pb/238U 1σ 208Pb/232Th 1σ 207Pb/206Pb 1σ 207Pb/235U 1σ 206Pb/238U 1σ LZS-2-1 109.01 415.97 0.26 0.07826 0.0009 0.62851 0.01264 0.02409 0.0004 0.07826 0.0009 539 43.84 495.2 7.88 485.7 5.37 LZS-2-2 270.96 720.67 0.38 0.07821 0.00086 0.63095 0.00901 0.02452 0.00024 0.07821 0.00086 549.4 29.92 496.7 5.61 485.4 5.12 LZS-2-3. 109.14 540.61 0.20 0.07839 0.00087 0.62773 0.01003 0.02418 0.00033 0.07839 0.00087 532.7 34.4 494.7 6.26 486.5 5.19 LZS-2-4 83.32 751.19 0.11 0.07812 0.00091 0.59695 0.01288 0.02508 0.00064 0.07812 0.00091 429.3 46.88 475.3 8.19 484.9 5.43 LZS-2-5 84.62 881.61 0.10 0.07806 0.00087 0.6257 0.00995 0.02998 0.00051 0.07806 0.00087 534.8 34.28 493.4 6.22 484.5 5.17 LZS-2-6 114.4 213.34 0.54 0.0783 0.00093 0.64509 0.01557 0.02681 0.00039 0.0783 0.00093 594.6 51.92 505.5 9.61 486 5.57 LZS-2-7 157.76 505.57 0.31 0.11523 0.00152 1.18829 0.03381 0.04235 0.001 0.11523 0.00152 1063.3 56.91 795.2 15.69 703 8.76 LZS-2-8 59.59 987.83 0.06 0.07759 0.00089 0.59325 0.01229 0.02991 0.0009 0.07759 0.00089 430.8 44.91 472.9 7.83 481.7 5.35 LZS-2-9 58.32 1593 0.04 0.07736 0.00093 0.58852 0.01465 0.03057 0.00145 0.07736 0.00093 419.5 54.31 469.9 9.36 480.4 5.56 LZS-2-10 255.56 478.25 0.53 0.07839 0.00087 0.64108 0.01044 0.02838 0.00028 0.07839 0.00087 579 34.3 503 6.46 486.5 5.2 LZS-2-11 158.91 549.01 0.29 0.07828 0.00088 0.61534 0.01111 0.03126 0.0004 0.07828 0.00088 491.8 39 486.9 6.98 485.8 5.27 LZS-2-12 70.01 924.55 0.08 0.07784 0.00085 0.63181 0.00924 0.03165 0.00051 0.07784 0.00085 562.6 30.86 497.2 5.75 483.2 5.11 LZS-2-13 95.74 532.81 0.18 0.07776 0.00099 0.60816 0.01842 0.03003 0.00085 0.07776 0.00099 480.5 66.89 482.4 11.63 482.7 5.92 LZS-2-14 79.67 496.06 0.16 0.07824 0.00092 0.62616 0.01451 0.03377 0.00072 0.07824 0.00092 531.3 50.45 493.7 9.06 485.6 5.52 LZS-2-15 48.59 702.78 0.07 0.0785 0.00087 0.62085 0.01033 0.03211 0.00069 0.0785 0.00087 505.3 35.29 490.4 6.47 487.2 5.22 LZS-2-16 142.49 317.16 0.45 0.1142 0.00139 1.09545 0.02643 0.05153 0.0008 0.1142 0.00139 916 49.06 751.1 12.81 697.1 8.04 LZS-2-17 43.81 721.84 0.06 0.07781 0.00096 0.63374 0.01729 0.03733 0.00154 0.07781 0.00096 570.2 58.71 498.4 10.75 483 5.75 表 3 老柞山金矿片麻状花岗岩LA-MC-ICP-MS锆石Hf同位素分析结果
Table 3. LA-MC-ICP-MS zircon Hf isotopic compositions of the gneissic granites in Laozuoshan gold deposit
样品号 t/Ma 176Yb/177Hf 2σ 176Lu/177Hf 2σ 176Hf/177Hf 2σ εHf(0) εHf(t) 2σ TDM1/Ma TDM2/Ma fLu/Hf TDM2 (镁铁质) TDM2 (长英质) LZS-2-1 485.7 0.017895 0.001385 0.000471 0.000039 0.282438 0.000011 -11.8 -1.3 0.4 1135 1536 -0.99 1973 1331 LZS-2-2 485.4 0.017814 0.000334 0.000469 0.000009 0.282468 0.000013 -10.8 -0.2 0.5 1093 1469 -0.99 1878 1277 LZS-2-3 486.5 0.028564 0.002643 0.000776 0.000073 0.282413 0.000013 -12.7 -2.2 0.5 1179 1597 -0.98 2060 1380 LZS-2-4 484.9 0.007256 0.000166 0.000182 0.000004 0.282455 0.000012 -11.2 -0.6 0.4 1103 1492 -0.99 1912 1295 LZS-2-5 484.5 0.029353 0.001744 0.000778 0.000049 0.282482 0.000013 -10.3 0.2 0.5 1082 1444 -0.98 1844 1257 LZS-2-6 486.0 0.041257 0.00338 0.00112 0.000091 0.28249 0.000015 -10.0 0.4 0.5 1081 1432 -0.97 1826 1247 LZS-2-7 481.7 0.011692 0.000101 0.000304 0.000003 0.282451 0.000011 -11.4 -0.8 0.4 1112 1506 -0.99 1932 1306 LZS-2-8 480.4 0.004508 0.000017 0.000114 0.000001 0.282418 0.000012 -12.5 -2.0 0.4 1151 1577 -1.00 2033 1362 LZS-2-9 486.5 0.004923 0.00025 0.000126 0.000007 0.28242 0.000013 -12.4 -1.8 0.5 1149 1569 -1.00 2019 1357 LZS-2-10 485.8 0.032692 0.000503 0.000886 0.00001 0.282501 0.000015 -9.6 0.8 0.5 1059 1403 -0.97 1785 1224 LZS-2-11 483.2 0.026504 0.000698 0.000698 0.000015 0.282473 0.000012 -10.6 -0.2 0.4 1093 1464 -0.98 1871 1272 LZS-2-12 482.7 0.009875 0.000151 0.000255 0.000005 0.282407 0.000011 -12.9 -2.4 0.4 1171 1603 -0.99 2069 1384 LZS-2-13 485.6 0.00573 0.000288 0.000123 0.000008 0.282431 0.000015 -12.1 -1.4 0.5 1134 1544 -1.00 1985 1338 LZS-2-14 487.2 0.024292 0.000951 0.000649 0.000026 0.282498 0.000014 -9.7 0.8 0.5 1056 1404 -0.98 1786 1225 LZS-2-15 505.0 0.021344 0.000134 0.000578 0.000004 0.282396 0.000013 -13.3 -2.4 0.5 1196 1620 -0.98 2084 1402 LZS-2-16 697.0 0.012193 0.000611 0.000325 0.000017 0.282443 0.000012 -11.6 3.6 0.4 1123 1390 -0.99 1678 1254 LZS-2-17 483.0 0.016992 0.000152 0.00045 0.000004 0.282502 0.000012 -9.5 0.9 0.4 1045 1394 -0.99 1773 1216 -
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