Regional metallogenic geological background of granite-type Nb-Ta deposits in Southeast China
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摘要:
为探究华东南地区花岗岩型铌-钽矿床区域成矿地质背景，给华东南地区花岗岩型铌-钽矿区域成矿规律总结和资源潜力评价提供地质构造依据，收集整理15个典型花岗岩型铌-钽矿床的资料，结合其矿床特征、成矿时代、成矿岩体及岩石地球化学研究，认为矿床形成时代集中于124~185 Ma，属燕山期。地球化学特征显示，P2O5含量在不同成矿花岗岩中富集程度不同，既有高P，也有低P，A/CNK=0.97~1.99（绝大部分大于1.1），具有过铝质特征；微量元素富集Rb和Nb、Ta、Th、Zr、Hf等，亏损Sr、Ti、Ba，稀土元素含量总体呈现出较低的趋势，具有明显的负Eu异常；Zr/Hf=3.13~23.31，Nb/Ta=0.28~7.67，结合其矿物特征，认为含矿岩体均为高分异花岗岩。成矿岩体底部到顶部，除部分隐伏岩体显示出顶上带的特征外，其余成矿岩体都显示出明显的相带特征，且特征矿物云母的变化较明显，向浅色云母及富锂方向演化；成矿岩体为黑云母花岗岩、二云母花岗岩和白云母花岗岩的共生或过渡组合，成矿花岗岩既有S型高分异的花岗岩，也有黄玉A型花岗岩，黄玉A型花岗岩与S型花岗岩共生且由S型花岗岩熔融作用形成。结合区域研究资料，认为矿床形成于洋-陆汇聚背景下的俯冲增生造山过程，即古太平洋板块向西俯冲，诱导扬子陆块东南缘发生陆内俯冲，导致东南沿海侵入（岩）弧的西北缘推覆至扬子陆块东南缘上方，形成众多碰撞型花岗岩型铌-钽矿床。
Abstract:In order to explore the regional metallogenic geological background of granite-type Nb-Ta deposits in southeast China and to provide geological tectonic basis for the regional mineralization regularity and resource potential evaluation of granite-type Nb-Ta deposits in southeast China, the authors collected and collated data from 15 typical granite type Nb-Ta deposits and, in combination with the deposit characteristics, metallogenic age, metallogenic rock mass and rock geochemical research analysis, concluded that the formation ages of the deposits are concentrated at 124 ~ 185 Ma, suggesting Yanshanian period.Geochemical characteristics show that the concentration of P2O5 is different in different ore-forming granites, with both high P and low P, A/CNK equal to 0.97~1.99, mostly greater than 1.1, and peraluminous characteristics; trace elements show enrichment of Rb and Nb, Ta, Th, Zr, Hf and other elements but loss of Sr, Ti, Ba; the content of rare earth elements generally shows a low trend, and Eu has a significantly negative anomaly; Zr/Hf=3.13~23.31, and Nb/Ta=0.28~7.67.In combination with the mineral characteristics, it is believed that the ore-bearing rock masses are all highly differentiated granites.From the bottom to the top of the ore-forming rock mass, except for some hidden rock masses that show the characteristics of the top zone, the ore-forming rock masses all show obvious facies belt characteristics, and the characteristic mineral mica changes more obviously, towards light-colored mica and evolution in lithium-richer direction; the ore-forming rocks are the associated or transitional combination of biotite granite, two-mica granite and muscovite granite.The mineralizing granite includes both S-type highly differentiated granite and topaz A-type granite, and topaz A-type granite.Granite and S-type granite are symbiotic and were formed by melting of the S-type granite.Combined with regional research data, the authors hold that the deposits were formed in the subduction accretive orogenic process under the background of ocean-continent convergence:westward subduction of the Paleo-Pacific plate led to the occurrence of intracontinental subduction on the southeast margin of the Yangtze Block, which resulted in the northwest margin of the intrusive (rock) arc of the southeast coast pushing over the southeast margin of the Yangtze Block, forming many "collision type" granite Nb-Ta deposits.
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表 1 华东南地区花岗岩型铌-钽矿床成矿时代
Table 1. Metallogenic age of granite-type Nb-Ta deposits in Southeast China
矿床名称 地区 矿产组合 测试样品 成矿年龄(时代)/Ma 测试方法 资料来源 松树岗 江西 Nb, Ta, Sn, W 花岗岩 124~131 [34] 海罗岭 江西 Nb, Ta, Sn 花岗岩 127.7 Rb-Sr ① 黄山 江西 Nb, Ta, W 花岗岩 130 铌钽铁矿U-Pb [21] 姜坑里 江西 Nb, Ta, Sn, REE 花岗岩 140.6 Rb-Sr ② 金竹垄 湖南 Nb, Ta, Sn 花岗岩 148.3±1.1 Ar-Ar [35] 癞子岭 湖南 Nb, Ta, Sn, W 花岗岩 155 锆石U-Pb [13] 尖峰岭 湖南 Be, Nb, Ta, Sn 花岗岩 160 锆石U-Pb [36] 雅山(414) 江西 Ta, Nb, Li, W 花岗岩 160 铌钽铁矿U-Pb [37] 鱼菜 广西 Nb, Ta, W, Sn 花岗岩 160 [38] 三个黄牛 广西 Nb, Ta, W, Sn 花岗岩 160 [39] 大吉山 江西 Ta, Nb, W 花岗岩 161 Rb-Sr [40] 牛岭坳 江西 Nb, Ta, Sn, 花岗岩 燕山中期 [41] 水溪庙 广西 Nb, Ta, W, Sn 花岗岩 185 锂云母K-Ar [42] 会仙峰 江西 Nb, Ta, Sn, Au 花岗岩 燕山早期 [43] 博罗525 广东 Nb, Ta, W, Hf 花岗岩 燕山期 [44] 
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表 2 华东南地区花岗岩型铌-钽矿成矿岩体形成时代与岩石组合
Table 2. Metallogenetic rock bodies' formation age and rock assemblage of granite-type Nb-Ta deposits in Southeast China
矿床 地区 形成时代 岩石组合 尖峰岭 湖南 燕山期 黑云母花岗岩-二云母花岗岩-白云母花岗岩 癞子岭 湖南 燕山期 黑云母花岗岩-二云母花岗岩-白云母花岗岩 大吉山 江西 燕山期 黑云母花岗岩-二云母花岗岩-白云母花岗岩 牛岭坳 江西 燕山期 黑云母花岗岩-白云母花岗岩-花岗斑岩 雅山(414) 江西 燕山期 二云母花岗岩-白云母花岗岩 黄山 江西 燕山期 黑云母花岗岩-花岗斑岩 海罗岭 江西 燕山期 黑云母花岗岩-似斑状花岗 会仙峰 江西 燕山期 黑云母花岗-二云母花岗岩 松树岗 江西 燕山期 黑云母花岗岩-花岗斑岩 姜坑里 江西 燕山期 黑云母花岗岩-似斑状花岗 博罗525 广东 无资料 无资料 水溪庙 广西 黑云母花岗岩形成于印支期，二云母、白云母花岗岩形成于燕山期 黑云母花岗岩-二云母花岗岩-白云母花岗岩 鱼菜 广西 三个黄牛 广西 黑云母花岗岩形成于印支期，二云母、白云母花岗岩形成于燕山期 黑云母花岗岩-二云母花岗岩-白云母花岗岩 金竹垄 湖南
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表 3 华东南地区燕山早期花岗岩型铌-钽矿床全岩主量、微量和稀土元素含量[6-7, 10-13, 43, 48-50]
Table 3. Major, trace elements and REE of the EarlyYanshanian granite-type Nb-Ta deposits in Southeast China
元素 水溪庙 会仙峰 博罗525 ZK301-18 ZK301-30 ZK701-13 ZK701-52 1 2 1 2 3 白云母花岗岩(上部)，二云母花岗岩(深部) 中粗粒黑云母花岗岩 中粗粒黑云母花岗岩 含矿花岗岩 SiO2 76.74 75.93 75.86 75.92 76.76 76.57 77.39 76.86 76.28 TiO2 0.01 0.01 0.02 0.01 0.01 0.05 0.07 0.03 0.02 Al2O3 14.62 15.17 14.86 14.83 13.18 12.94 14.88 13.70 13.51 Fe2O3 0.04 0.07 0.06 0.09 0.75 1.32* 0.25 0.08 0.07 FeO 0.56 0.56 0.89 0.68 0.61 0.00 0.45 0.94 0.75 MnO 0.19 0.16 0.22 0.19 0.04 0.07 0.04 0.06 0.02 MgO 0.03 0.01 0.01 0.01 0.02 0.09 0.20 0.13 0.09 CaO 0.18 0.20 0.46 0.61 0.09 0.34 0.27 0.35 0.25 Na2O 4.34 4.98 4.26 3.96 4.00 4.49 1.03 2.59 4.46 K2O 3.04 2.71 3.10 3.36 4.51 4.08 5.40 5.24 4.52 P2O5 0.26 0.21 0.27 0.34 0.02 0.05 0.01 0.01 0.02 总计 100.00 100.00 100.00 100.00 100.00 100.00 100.00 100.00 100.00 La 0.43 0.36 0.39 0.53 Ce 0.83 0.81 0.71 1.13 Pr 0.10 0.10 0.09 0.15 Nd 0.30 0.25 0.25 0.43 Sm 0.15 0.15 0.12 0.23 Eu 0.01 0.00 0.03 0.01 Gd 0.11 0.10 0.08 0.17 Tb 0.04 0.04 0.03 0.07 Dy 0.24 0.26 0.18 0.37 Ho 0.04 0.04 0.03 0.05 Er 0.10 0.10 0.08 0.15 Tm 0.03 0.03 0.02 0.04 Yb 0.21 0.24 0.16 0.31 Lu 0.03 0.03 0.02 0.04 Y 1.58 1.77 1.22 2.25 Rb 1530 1440 1390 1500 Ba 12.5 12.5 14.2 10.4 K 24986.91 22330.497 25401.98 27643.329 Ta 45.86 19.65 55.69 30.3 Nb 139.9 29.36 31.46 45.44 La 0.43 0.36 0.39 0.53 Ce 0.83 0.81 0.71 1.13 Sr 4.38 1 36.8 11.9 Nd 0.3 0.25 0.25 0.43 P 1117.338 916.566 1143.525 1466.5056 Sm 0.15 0.15 0.12 0.23 Ti 29.975 29.975 101.915 35.97 Y 1.58 1.77 1.22 2.25 Yb 0.21 0.24 0.16 0.31 Lu 0.033 0.034 0.023 0.038 注：带*数据代表TFe2O3，主量元素为通过剔除水和烧失量后重新换算为100%所获得的实际含量，主量元素含量单位为%，微量和稀土元素含量为10-6
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表 4 华东南地区燕山中期花岗岩型铌-钽矿床全岩主量、微量和稀土元素含量[6-7, 10-13, 43, 48-50]
Table 4. Major, trace elements and REE of the Middle Yanshanian granite-type Nb-Ta deposits in Southeast China
元素 松树岗 海罗岭 黄山 姜坑里 1 2 1 2 3 4 1 2 3 1 2 3 中粗粒黑云母花岗岩 钠长石化黑云母花岗岩 花岗岩 黄玉花岗岩 弱钠化花岗岩 中钠化花岗岩 强钠化花岗岩 花岗岩 SiO2 73.84 74.52 71.91 75.86 73.72 72.26 73.23 71.51 70.60 70.25 74.45 TiO2 0.21 0.13 0.03 0.05 0.05 0.03 0.03 0.02 0.05 0.05 0.05 Al2O3 13.94 14.23 16.49 13.08 15.93 16.18 16.51 16.96 16.95 17.01 14.69 Fe2O3 0.59 0.79 0.11 0.01 0.16 0.50 0.32 0.54 0.83 0.44 0.17 FeO 1.87 1.38 0.97 1.55 1.25 1.05 0.45 0.58 4.51 3.50 1.05 MnO 0.00 0.03 0.03 0.06 0.04 0.08 0.03 0.02 0.48 0.30 0.16 MgO 0.32 0.21 0.00 0.27 0.04 0.13 0.04 0.05 0.05 0.03 0.04 CaO 0.38 0.35 0.33 0.24 0.36 0.10 0.16 0.09 0.05 0.92 0.90 Na2O 3.88 4.43 5.80 3.03 7.26 5.75 5.48 6.78 3.56 4.96 4.39 K2O 4.96 3.92 4.29 5.79 1.20 3.91 3.74 3.45 2.89 2.53 4.08 P2O5 0.00 0.00 0.03 0.05 0.00 0.00 0.00 0.00 0.02 0.01 0.01 总计 100.00 100.00 100.00 100.00 100.00 100.00 100.00 100.00 100.00 100.00 100.00 Ta 16 Nb 74 Zr 115 Hf 3.9 元素 金竹垄 癞子岭 HXC69 HXC70 LZ07 XH22 S77 LZ23 XH420 XH29 LZ28 XH14 LZ02 LZ05 LZ05-2 燕山期花岗岩Ⅱ2 钠长石花岗岩 浅色花岗岩 黑磷云母花岗岩 SiO2 75.41 76.06 75.65 76.66 74.48 71.18 75.56 75.16 75.32 74.19 72.56 75.12 76.22 TiO2 0.02 0.02 0.07 0.02 0.01 0.03 0.02 0.01 0.04 0.04 0.08 0.09 0.08 Al2O3 14.65 13.94 13.80 13.95 14.14 15.84 14.77 14.08 13.69 13.97 17.07 13.97 13.57 Fe2O3 0.23 0.32 0.31* 0.81* 1.38* 1.43* 2.05* 0.84* 2.02* 1.37* 4.15* 1.53* 1.43* FeO 1.16 1.09 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 MnO 0.12 0.15 0.02 0.09 0.02 0.10 0.11 0.08 0.09 0.11 0.18 0.09 0.10 MgO 0.06 0.04 0.01 0.14 0.06 0.06 0.08 0.14 0.15 0.08 0.02 0.09 0.02 CaO 0.31 0.31 1.51 0.58 0.50 0.51 0.58 0.20 1.23 0.57 0.58 1.37 0.62 Na2O 3.46 3.73 3.70 4.23 5.71 5.90 3.42 3.72 3.04 4.84 3.09 3.12 3.55 K2O 4.35 4.09 4.92 3.50 3.68 4.92 3.40 5.73 4.40 4.84 2.24 4.59 4.38 P2O5 0.21 0.25 0.02 0.01 0.01 0.04 0.00 0.04 0.02 0.00 0.02 0.02 0.02 总计 100.00 100.00 100.00 100.00 100.00 100.00 100.00 100.00 100.00 100.00 100.00 100.00 100.00 La 0.39 0.22 46.61 58.32 10.86 56.80 41.54 32.53 55.76 53.59 40.72 34.40 32.62 Ce 0.80 0.43 113.00 110.20 30.90 144.50 84.90 78.40 138.70 114.30 104.30 88.90 83.50 Pr 0.08 0.04 13.30 11.83 3.04 14.70 10.80 9.10 16.11 15.02 11.04 10.08 9.30 Nd 0.27 0.12 43.53 31.90 7.18 39.87 34.67 26.05 54.78 53.13 35.81 36.02 30.90 Sm 0.07 0.04 11.16 7.49 1.47 7.43 9.52 6.56 14.72 15.62 9.21 10.67 9.23 Eu 0.01 0.00 0.03 0.01 0.00 0.03 0.03 0.01 0.03 0.05 0.02 0.04 0.02 Gd 0.07 0.04 10.35 5.80 0.88 5.71 8.24 4.92 15.02 15.59 9.36 11.79 9.40 Tb 0.01 0.01 1.97 1.11 0.16 1.19 1.68 1.00 3.27 3.04 1.63 2.20 1.80 Dy 0.07 0.04 16.00 8.46 1.24 8.39 13.36 7.45 21.72 23.86 11.78 16.58 13.99 Ho 0.01 0.01 3.62 1.75 0.25 1.78 2.89 1.63 4.60 5.28 2.50 3.93 3.14 Er 0.03 0.02 13.14 6.05 0.89 5.92 9.49 5.66 14.73 17.70 7.86 12.82 10.13 Tm 0.01 0.00 2.54 1.22 0.20 1.21 1.74 1.14 2.63 3.12 1.31 2.11 1.84 Yb 0.04 0.02 18.12 9.41 1.79 8.95 12.70 9.16 17.98 21.02 8.54 14.47 13.25 Lu 0.01 0.00 2.72 1.46 0.28 1.32 1.94 1.47 2.75 3.19 1.21 2.13 1.97 Y 86.20 24.60 2.60 27.30 49.00 24.10 116.20 137.80 54.50 103.60 68.80 Rb 973 1166 1069 1616 1924 1979 1620 1865 1902 1267 1269 Ba 16 18.8 10.9 2.8 10.2 10.6 8.4 14.9 7.2 23.7 6.1 Th 32 25.8 12.5 34 25.2 26.1 42.8 44.1 29.3 26.8 23.3 U 23.1 39.5 15.1 21.5 23.7 13.9 50.6 35.2 31.6 27.8 26.4 K 40012.27 28556.5 30548.78 40344 27394.3 47151 35696 39680 18346 37273 35779 Ta 28.2 28.9 43.8 26.4 30.3 39 28 20.6 7.7 19.7 21.7 Nb 54 74.6 59.1 83.8 67.4 70.6 82 79.7 59.1 56.2 56.1 La 46.61 58.32 10.86 56.8 41.54 32.53 55.76 53.59 40.72 34.4 32.62 Ce 113 110.2 30.9 144.5 84.9 78.4 138.7 114.3 104.3 88.9 83.5 Sr 61.6 10.7 25.1 9.4 7.4 12.4 10.5 5.8 4.3 19 4.6 Nd 43.53 31.9 7.18 39.87 34.67 26.05 54.78 53.13 35.81 36.02 30.9 P 87.292 43.646 43.646 174.58 0 174.58 87.29 0 87.292 87.29 87.292 Zr 118.7 73.6 52.5 71.4 68.5 70.4 84.7 89.8 99.9 101.5 93 Hf 8.2 7 8.6 6.7 5.4 8.5 6.8 5.1 6.4 5.7 7.4 Sm 11.16 7.49 1.47 7.43 9.52 6.56 14.72 15.62 9.21 10.67 9.23 Ti 419.65 119.9 59.95 179.85 119.9 59.95 239.8 239.8 479.6 539.6 479.6 Y 86.2 24.6 2.6 27.3 49 24.1 116.2 137.8 54.5 103.6 68.8 Yb 18.12 9.41 1.79 8.95 12.7 9.16 17.98 21.02 8.54 14.47 13.25 Lu 2.72 1.46 0.28 1.32 1.94 1.47 2.75 3.19 1.21 2.13 1.97 元素 尖峰岭 雅山 JFL-1-2 JFL-1-8 JFL-2-6 JFL-2-11 YC-27 YC-29 YC-30 YC-31 YC-36-1 YC-38 YC42 YC43 黑云母花岗岩 钠长石花岗岩 锂云母花岗岩(雅山铌钽矿主体) 钠长石花岗岩 白云母花岗岩 SiO2 75.52 75.98 72.29 73.86 71.58 73.40 72.45 72.06 73.75 74.86 73.93 73.85 TiO2 0.03 0.04 0.01 0.02 0.06 0.08 0.07 0.05 0.12 0.09 0.04 0.06 Al2O3 13.76 13.86 16.69 15.92 18.89 16.53 18.54 18.49 17.10 14.84 15.18 14.78 Fe2O3 0.55 0.52 0.03 0.05 0.09 0.11 0.08 0.06 0.13 0.24 0.46 0.63 FeO 1.08 0.97 0.23 0.16 0.12 0.08 0.06 0.11 0.53 0.84 0.61 0.64 MnO 0.09 0.09 0.01 0.01 0.11 0.09 0.06 0.11 0.23 0.32 0.33 0.40 MgO 0.06 0.14 0.03 0.04 0.03 0.03 0.03 0.02 0.03 0.05 0.12 0.12 CaO 0.89 0.93 3.52 2.27 0.21 0.22 0.13 0.13 0.25 0.12 0.15 0.14 Na2O 2.92 1.57 3.53 3.77 5.77 6.53 6.18 5.80 4.28 4.81 4.23 4.20 K2O 5.09 5.88 3.65 3.89 2.57 2.71 1.74 2.69 3.17 3.60 4.69 4.95 P2O5 0.01 0.01 0.01 0.01 0.56 0.22 0.65 0.48 0.40 0.22 0.27 0.22 总计 100.00 100.00 100.00 100.00 100.00 100.00 100.00 100.00 100.00 100.00 100.00 100.00 La 42.50 43.50 30.40 21.70 0.38 0.03 0.02 0.03 0.77 0.04 0.23 0.13 Ce 95.60 104.00 76.60 44.90 0.77 0.07 0.06 0.04 2.56 0.18 0.91 0.69 Pr 12.50 12.60 8.81 6.81 0.08 0.02 0.05 0.03 0.19 0.05 0.07 0.05 Nd 44.70 43.70 23.50 19.90 0.82 0.04 0.03 0.04 0.70 0.03 0.31 0.17 Sm 13.40 13.50 5.71 5.49 0.03 0.02 0.02 0.03 0.20 0.04 0.11 0.09 Eu 0.05 0.05 0.05 0.05 0.01 0.00 0.00 0.00 0.05 0.01 0.01 0.01 Gd 14.00 14.40 4.04 4.42 0.14 0.05 0.06 0.05 0.19 0.05 0.14 0.10 Tb 2.83 3.21 1.06 1.12 0.02 0.01 0.00 0.00 0.07 0.02 0.05 0.04 Dy 18.60 22.50 7.44 8.15 0.12 0.05 0.04 0.05 0.14 0.07 0.13 0.08 Ho 3.75 4.94 1.46 1.66 0.01 0.01 0.00 0.01 0.01 0.01 0.02 0.01 Er 12.90 17.30 5.50 6.45 0.01 0.01 0.01 0.01 0.05 0.01 0.05 0.04 Tm 2.06 2.80 1.12 1.22 0.01 0.00 0.00 0.01 0.01 0.01 0.02 0.01 Yb 14.80 20.10 9.57 10.60 0.00 0.00 0.01 0.01 0.06 0.02 0.05 0.15 Lu 2.18 2.99 1.39 1.62 0.00 0.00 0.00 0.00 0.00 0.02 0.01 0.06 Y 114.00 159.00 22.50 31.70 0.27 0.15 0.02 0.03 0.63 0.07 0.65 0.29 Rb 1687 1760 1492 1541 3605 3662 3068 3997 2010 2024 1648 1434 Ba 8.45 12 10 10.7 3.81 1.36 0.8 2.42 17.2 1.85 2.27 11 Th 37.9 43.4 23 23 1.58 0.95 0.47 0.96 2.02 1.01 1.6 1.41 U 35 44.1 19.6 10.4 8.16 8.19 6.57 11.8 20.8 7.28 19.4 14.6 K 41589.51 47898.50 29552.62 31710.96 20919 22247.5 14278.2 21915 25983.07 29884.7 38518 40842 Ta 22.2 21.5 50.4 61.4 21.1 20.3 15 12.5 13.9 23.9 13.6 12.9 Nb 69.5 69.8 79.8 92.8 34.8 47.9 44.4 34.4 68.7 35.3 69.4 56.9 La 42.5 43.5 30.4 21.7 0.38 0.03 0.02 0.03 0.77 0.04 0.23 0.13 Ce 95.6 104 76.6 44.9 0.77 0.07 0.06 0.04 2.56 0.18 0.91 0.69 Sr 7.7 14.7 8.52 5.85 2.8 0.31 0.62 1.5 8.03 1.68 6.94 6.94 Nd 44.7 43.7 23.5 19.9 0.82 0.04 0.03 0.04 0.7 0.03 0.31 0.17 P 43.646 43.646 43.646 43.646 2404.9 955.847 2806.44 2042.6 1719.652 973.306 1147.9 934.02 Zr 93.9 91.7 34.2 57.7 16 15.7 13.2 12.3 15.5 15.3 11.7 12.8 Hf 6.73 6.47 4.76 6.62 3.94 3.8 3.4 3.23 1.74 2.8 1.49 1.16 Sm 13.4 13.5 5.71 5.49 0.03 0.02 0.02 0.03 0.2 0.04 0.11 0.09 Ti 179.85 239.8 59.95 119.9 359.7 479.6 419.65 299.75 719.4 539.55 239.8 359.7 Y 114 159 22.5 31.7 0.27 0.15 0.02 0.03 0.63 0.07 0.65 0.29 Yb 14.8 20.1 9.57 10.6 0.001 0.001 0.009 0.01 0.06 0.02 0.05 0.15 Lu 2.18 2.99 1.39 1.62 0.001 0.001 0.002 0.003 0.003 0.02 0.012 0.06 元素 雅山 鱼菜 三个黄牛 YC-45 YC-46 YC-47 ZK4002-08 ZK4003-04 ZK4003-22 ZK4003-60 ZK713-03 ZK713-22 ZK713-33 ZK713-56 二云母花岗岩 白云母花岗岩(上部)，二云母花岗岩(深部) 白云母花岗岩(上部)，二云母花岗岩(深部) SiO2 74.87 74.97 74.02 70.27 76.95 75.70 76.07 74.84 75.81 76.53 75.61 TiO2 0.26 0.21 0.19 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.02 Al2O3 15.07 14.54 15.73 19.19 13.78 15.23 14.91 15.78 15.18 14.53 15.07 Fe2O3 1.06 1.03 1.24 0.28 0.16 0.03 0.04 0.07 0.06 0.06 0.11 FeO 0.53 0.49 0.57 0.64 0.34 0.38 0.57 0.55 0.49 0.41 0.65 MnO 0.24 0.22 0.29 0.19 0.38 0.12 0.15 0.13 0.20 0.16 0.11 MgO 0.18 0.19 0.19 0.03 0.05 0.01 0.01 0.01 0.01 0.01 0.02 CaO 0.23 0.22 0.22 0.49 0.30 0.32 0.24 0.43 0.21 0.20 0.37 Na2O 3.29 3.19 3.18 4.71 3.87 4.76 3.98 4.28 4.66 4.91 4.08 K2O 4.25 4.91 4.34 3.93 4.00 3.23 3.84 3.64 3.19 2.98 3.71 P2O5 0.02 0.02 0.02 0.27 0.17 0.20 0.18 0.26 0.19 0.19 0.27 总计 100.00 100.00 100.00 100.00 100.00 100.00 100.00 100.00 100.00 100.00 100.00 La 3.74 3.23 11.50 0.65 0.45 0.57 1.81 1.14 0.50 0.55 2.33 Ce 10.00 7.38 28.60 1.62 0.76 1.38 4.51 3.22 1.18 1.21 5.73 Pr 1.03 0.80 3.11 0.22 0.09 0.19 0.60 0.44 0.15 0.16 0.73 Nd 4.07 3.02 12.10 0.65 0.24 0.53 1.86 1.39 0.40 0.43 2.31 Sm 0.74 0.53 2.20 0.40 0.12 0.33 0.99 0.89 0.23 0.24 1.04 Eu 0.11 0.09 0.13 0.01 0.02 0.00 0.01 0.00 0.00 0.01 0.02 Gd 0.53 0.39 1.86 0.26 0.08 0.21 0.66 0.60 0.17 0.16 0.75 Tb 0.09 0.07 0.32 0.10 0.03 0.09 0.24 0.25 0.07 0.06 0.26 Dy 0.43 0.36 1.78 0.57 0.21 0.52 1.42 1.45 0.38 0.36 1.45 Ho 0.07 0.06 0.33 0.08 0.03 0.07 0.21 0.20 0.05 0.05 0.21 Er 0.23 0.20 1.03 0.20 0.09 0.18 0.53 0.49 0.15 0.14 0.55 Tm 0.11 0.09 0.17 0.05 0.02 0.05 0.12 0.12 0.04 0.03 0.12 Yb 0.28 0.25 1.15 0.40 0.22 0.39 0.92 0.91 0.29 0.30 0.87 Lu 0.11 0.09 0.16 0.06 0.03 0.05 0.12 0.12 0.04 0.04 0.11 Y 2.05 2.05 10.40 3.32 1.20 3.01 7.84 7.94 2.35 2.24 7.76 Rb 1327 1758 754 1700 1550 1670 1490 1880 1520 1350 1700 Ba 34.2 41.3 58.7 14.4 13.3 14 10.8 10.5 11.7 17.5 18.1 Th 5.58 4.35 12.6 U 19.6 5.17 20 K 34450 39929 35530 32873 32541 26564 31628 29885 26232 24572 30465.8 Ta 10.5 13.6 6.73 44.22 32.76 18.84 15.56 9.01 21.29 16.38 15.56 Nb 41.7 41.8 25.4 55.22 50.33 44.74 30.06 60.12 34.95 25.17 65.01 La 3.74 3.23 11.5 0.65 0.45 0.57 1.81 1.14 0.5 0.55 2.33 Ce 10 7.38 28.6 1.62 0.76 1.38 4.51 3.22 1.18 1.21 5.73 Sr 11 2.85 26.8 34.6 12.1 21.3 18 17.9 6.9 0.4 10.6 Nd 4.07 3.02 12.1 0.65 0.24 0.53 1.86 1.39 0.4 0.43 2.31 P 100.39 96.021 91.657 1169.7 707.1 881.65 789.993 1143.5 829.27 820.54 1156.62 Zr 29.3 25.9 45.7 Hf 1.86 1.68 1.96 Sm 0.74 0.53 2.2 0.4 0.12 0.33 0.99 0.89 0.23 0.24 1.04 Ti 1498.8 1259 1139.1 65.945 29.98 41.965 41.965 35.97 35.97 29.975 101.915 Y 2.05 2.05 10.4 3.32 1.2 3.01 7.84 7.94 2.35 2.24 7.76 Yb 0.28 0.25 1.15 0.4 0.22 0.39 0.92 0.91 0.29 0.3 0.87 Lu 0.11 0.09 0.16 0.057 0.029 0.054 0.12 0.12 0.042 0.04 0.11 元素 大吉山 牛岭坳 DJS-14 DJS-13 DJS-12 DJS-11 DJS-6 DJS-5 DJS-4 DJS-3 DJS-1 1 白云母碱长花岗岩417中段 白云母碱长花岗岩317中段 白云母碱长花岗岩267中段 少钠长石白云母花岗岩 SiO2 75.83 77.26 76.89 77.14 76.42 75.26 74.99 74.29 75.45 75.68 TiO2 0.01 0.01 0.01 0.01 0.01 0.01 0.02 0.01 0.01 0.00 Al2O3 14.58 14.10 13.83 13.96 13.92 13.98 13.75 14.15 13.39 13.76 Fe2O3 0.20 0.44 0.24 0.26 0.12 0.59 0.98 0.96 0.83 0.80 FeO 0.08 0.11 0.18 0.21 0.17 0.42 0.69 0.78 0.57 0.40 MnO 0.13 0.03 0.11 0.16 0.07 0.24 0.36 0.55 0.58 0.00 MgO 0.13 0.15 0.14 0.06 0.06 0.08 0.15 0.18 0.12 0.33 CaO 0.33 0.42 0.66 0.71 0.45 0.32 0.23 0.32 0.28 0.16 Na2O 5.05 4.22 4.11 3.55 4.17 4.66 4.05 4.46 4.53 3.97 K2O 3.64 3.25 3.80 3.93 4.58 4.43 4.76 4.28 4.21 4.89 P2O5 0.02 0.01 0.02 0.01 0.02 0.02 0.02 0.02 0.02 0.00 总计 100.00 100.00 100.00 100.00 100.00 100.00 100.00 100.00 100.00 100.00 La 2.74 2.23 3.05 4.95 2.46 2.13 3.26 3.66 2.07 Ce 7.82 6.69 7.98 12.40 7.24 6.70 13.10 13.00 6.50 Pr 1.45 1.22 1.34 1.93 1.27 1.14 2.03 2.12 1.72 Nd 5.62 4.97 4.95 8.14 4.15 5.10 8.23 9.60 4.79 Sm 6.75 4.69 3.40 5.42 3.24 4.19 7.79 7.21 4.22 Eu 0.09 0.05 0.07 0.09 0.09 0.12 0.10 0.04 0.04 Gd 9.06 7.19 4.28 6.15 3.29 4.96 6.43 8.27 7.58 Tb 1.54 1.69 0.89 1.11 0.99 0.97 2.04 1.73 1.13 Dy 4.20 6.38 3.79 4.14 3.80 4.32 6.26 5.93 3.83 Ho 0.18 0.34 0.26 0.34 0.21 0.18 0.27 0.31 0.20 Er 0.13 0.29 0.32 0.51 0.26 0.13 0.28 0.22 0.15 Tm 0.03 0.05 0.05 0.06 0.02 0.02 0.02 0.02 0.02 Yb 0.15 0.19 0.24 0.45 0.17 0.13 0.21 0.16 0.12 Lu 0.05 0.05 0.05 0.08 0.03 0.02 0.04 0.02 0.02 Y 17.70 18.90 23.10 15.80 13.70 17.20 16.70 22.40 20.40 Rb 734 647 705 745 902.3 735.57 992.62 831.8 962.37 Ba 37.9 35.7 86.1 105 76.61 21.74 64.39 37.32 36 Th 1.99 0.86 0.73 1.53 1.03 1.61 1.32 1.15 0.88 U 13 2.32 2.37 17.7 7.32 8.03 6.23 11.61 5.68 K 30217 26979 31545 32790 38020 36775 38933 35613 34782.4 Ta 29.7 17.1 7.36 42 53.48 8.55 46.46 31.53 28.75 Nb 30.4 19.8 15.2 56.5 56.79 2.38 21.79 41.9 39.59 La 2.74 2.23 3.05 4.95 2.46 2.13 3.26 3.66 2.07 Ce 7.82 6.69 7.98 12.4 7.24 6.7 13.1 13 6.5 Sr 17.6 12.7 32.8 24.5 27.67 25.12 22.57 25.29 32.14 Nd 5.62 4.97 4.95 8.14 4.15 5.1 8.23 9.6 4.79 P 87.292 43.646 87.29 43.65 87.292 87.292 87.292 87.29 87.292 Zr 27.3 21.7 25.5 27.1 30.69 24.89 17.49 26.86 66.09 Hf 7.42 6.93 7.41 6.27 6.72 7.67 3.01 4.36 7.64 Sm 6.75 4.69 3.4 5.42 3.24 4.19 7.79 7.21 4.22 Ti 59.95 59.95 59.95 59.95 59.95 59.95 119.9 59.95 59.95 Y 17.7 18.9 23.1 15.8 13.7 17.2 16.7 22.4 20.4 Yb 0.15 0.19 0.24 0.45 0.17 0.13 0.21 0.16 0.12 Lu 0.05 0.05 0.05 0.08 0.03 0.02 0.04 0.02 0.02 注：带*数据代表TFe2O3，主量元素为通过剔除水和烧失量后重新换算为100%所获得的实际含量，主量元素含量单位为%，微量和稀土元素含量为10-6
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[1] Ĉerný P.Rare-element granitic pegmatites Part Ⅱ:regional to global environments and petrogenesis[J].Geoscience Canada, 1991, 18(2):68-81. https://www.researchgate.net/publication/285711507_Rare-element_granitic_pegmatites_Part_II_regional_to_global_environments_and_petrogenesis
[2] Ĉerný P.Regional zoning of pegmatite populations and its interpretation[J].Mitteilungen der Österreichischen Mineralogischen Gesellschaft, 1992, 137:99-108.
[3] Lafleur M P J, Eng P, Ayad M A B, et al.NI 43-101 Technical Report to present the mineral resources of the rare earth elements zone Niobec Mine-IAMGOLD Corporation[J].Ste-Therese, QC, CA, 2012:1-145.
[4] Soloviev S G, Kryazhev S, Dvurechenskaya S.Geology, igneous geochemistry, mineralization, and fluid inclusion characteristics of the Kougarok tin-tantalum-lithium prospect, Seward Peninsula, Alaska, USA[J].Mineralium Deposita, 2020, 55(1):79-106. https://link.springer.com/article/10.1007/s00126-019-00883-7
[5] Küster D.Granitoid-hosted Ta mineralization in the Arabian-Nubian Shield:Ore deposit types, tectono-metallogenetic setting and petrogenetic framework[J].Ore Geology Reviews, 2008, 35(1):68-86. https://www.researchgate.net/publication/222415411_Granitoid-hosted_Ta_mineralization_in_the_Arabian-Nubian_Shield_Ore_deposit_types_tectono-metallogenetic_setting_and_petrogenetic_framework
[6] 左梦璐.江西雅山与大吉山两类稀有金属花岗岩成矿差异性研究[D].中国地质大学(北京)硕士学位论文, 2016.
[7] 邵力军.南岭及邻区花岗岩型稀有金属矿床地质成矿特征[M].北京:地质出版社, 2011.
[8] 林德松.华南富钽花岗岩矿床[M].北京:地质出版社, 1996.
[9] 李文辉, 钟晓清, 张苑平, 等.广东省博罗县横河钠长石矿构造岩浆演化及成矿机理[J].大地构造与成矿学, 2010, 34(1):71-77. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=ddgzyckx201001008
[10] 文春华, 邵拥军, 黄革非, 等.湖南尖峰岭稀有金属花岗岩地球化学特征及成矿作用[J].矿床地质, 2017, 36(4):879-892. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=kcdz201704006
[11] 董业才, 丁汝福.广西栗木矿田花岗岩体地球化学特征制约因素及其动力学背景[J].矿产与地质, 2016, 30(6):998-1005. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=kcydz201606022
[12] 蔡报元, 靳鑫, 张云蛟.葛源松树岗铌钽矿分布规律及与灵山岩体的关系[J].西部探矿工程, 2017, 29(09):171-175. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=xbtkgc201709055
[13] 朱金初, 王汝成, 陆建军, 等.湘南癞子岭花岗岩体分异演化和成岩成矿[J].高校地质学报, 2011, 17(3):381-392. http://www.cnki.com.cn/Article/CJFDTotal-GXDX201103005.htm
[14] Li H, Sun H S, Algeo T J, et al.Mesozoic multi-stage W-Sn polymetallic mineralization in the Nanling Range, South China:An example from the Dengfuxian-Xitian ore field[J].Geological Journal, 2019, 54(6):3755-3785. https://www.researchgate.net/publication/329211046_Mesozoic_multi-stage_W-Sn_polymetallic_mineralization_in_the_Nanling_Range_South_China_An_example_from_the_Dengfuxian-Xitian_ore_field
[15] Ĉerný P.Extreme fractionation in rare element granitic pegmatites selected examples of data and mechanism[J].Canadian Mineralogist, 1985, 23:381-421. https://rruff.info/doclib/cm/vol23/CM23_381.pdf
[16] Yin L, Pollard P J, Shouxi H, et al.Geologic and geochemical characteristics of the Yichun Ta-Nb-Li deposit, Jiangxi Province, South China[J].Economic Geology, 1995, 90(3):577-585. https://www.researchgate.net/publication/247863929_Geologic_and_geochemical_characteristics_of_the_Yichun_Ta-Nb-Li_deposit_Jiangxi_Province_South_China
[17] Pollard P J.Geochemistry of Granites Associated with Tantalum and Niobium Mineralization[C]//Lanthanides, Tantalum and Niobium.Springer Berlin Heidelberg, 1989.
[18] Cuney M, Raimbault L.Variscan rare metal granites and associated mineralizations from the North French Massif Central[C]//Field Trip Guidebook, SGA 25.Anniversary Meeting, Nancy, 1991: 30.
[19] Cuney M, Marignac C, Weisbrod A.The Beauvoir topaz-lepidolite albitic granite (Massif Central France).A highly specialized granite with disseminated Sn-Li-Ta-Nb-Be mineralization of magmatic origin[J].Econ.Geol., 1992, 87:1766-1794. https://www.researchgate.net/publication/247863613_The_Beauvoir_topaz-lepidolite_albite_granite_Massif_Central_France_the_disseminated_magmatic_Sn-Li-Ta-Nb-Be_mineralization
[20] Johan V, Johan Z.Accessory minerals of the Cínovec (Zinnwald) granite cupola, Czech Republic Part 1:Nb-, Ta-and Ti-bearing oxides[J].Mineralogy and Petrology, 1994, 51(2/4):323-343. https://link.springer.com/article/10.1007/BF01159735
[21] Che X D, Wu F Y, Wang R C, et al.Corrigendum to "In situ U-Pb isotopic dating of columbite-tantalite by LA-ICP-MS" (Ore Geol.Rev.65(2015) 979-989)[J].Ore Geology Reviews, 2015, 65(4):979-989. https://www.sciencedirect.com/science/article/pii/S0169136814003461
[22] Linnen R L, I M Samson, A E Williams-Jones, et al.Treatise on Geochemistry||Geochemistry of the Rare-Earth Element, Nb, Ta, Hf, and Zr Deposits[J].Earth Systems and Environmental Sciences, 2014, 13:543-568 https://www.sciencedirect.com/science/article/pii/B9780080959757011244
[23] Dill, Harald G.Pegmatites and aplites:Their genetic and applied ore geology[J].Ore Geology Reviews, 2015, 69:417-561. https://www.researchgate.net/publication/276166100_Pegmatites_and_aplites_Their_genetic_and_applied_ore_geology
[24] Jahn B M, Chen P Y, Yen T P.Rb-Sr ages of granitic rocks in southeastern China and their tectonic significance[J].Geological Society of America Bulletin, 1976, 87(5):763-776. https://pubs.geoscienceworld.org/gsa/gsabulletin/article-abstract/87/5/763/202047/Rb-Sr-ages-of-granitic-rocks-in-southeastern-China?redirectedFrom=fulltext
[25] 吴利仁.华东及邻区中新生代火山岩[M].北京:科学出版社, 19984:1-287.
[26] Sun W D, Yang X Y, Fan W M, et al.Mesozoic large scale magmatism and mineralization in South China:Preface[J].Lithos, 2012, 150:1-5. https://www.sciencedirect.com/science/article/abs/pii/S0024493712002678
[27] 冯艳芳, 姚晓峰, 魏友卿, 等.长乐-南澳构造带燕山期(J-K)TTG岩石组合及其地质意义[J].岩石学报, 2014, 30(11):3315-3333. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=ysxb98201411016
[28] 李兆鼐.中国东部中、新生代火成岩及其深部过程[J].地球学报, 2004, (4):436. https://www.ixueshu.com/document/131f2cf8ce8a3377.html
[29] Wang B, Shu L, Yang Z.Study of the early-middle Jurassic tectono-stratigraphy in the Jiangxi-Fujian-Guangdong region, SE China[J].Journal of Stratigraphy, 2006, 30(1):42-49. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=dcxzz200601006
[30] 张旗, 李承东.花岗岩:地球动力学意义[M].北京:海洋出版社, 2012:1-276.
[31] 张国伟, 郭安林, 王岳军, 等.中国华南大陆构造与问题[J].中国科学:地球科学, 2013, 43(10):1553-1582. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=zgkx-cd201310003
[32] 杨明桂, 王光辉.华南陆区板块活动与构造体系的形成演化——纪念李四光先生诞辰130周年[J].地质学报, 2019, 93(3):22-38. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=dizhixb201903003
[33] 邓晋福, 冯艳芳, 狄永军, 等.华南地区侵入岩时空演化框架[J].地质论评, 2016, 62(1):3-16. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=dzlp201601002
[34] 黄定堂.江西横峰松树岗钨锡铌钽多金属矿床成因探讨[J].有色金属矿产与勘查, 1999, (4):40-45. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=QK199901110141
[35] 孙颖超, 陈郑辉, 赵国春, 等.湖南邓阜仙钨铌钽矿花岗细晶岩接触带白云母40Ar/39Ar年龄及其地质意义[J].地质通报, 2017, 36(2/3):466-476. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=zgqydz201702028
[36] 轩一撒, 袁顺达, 原垭斌, 等.湘南尖峰岭岩体锆石U-Pb年龄、地球化学特征及成因[J].矿床地质, 2014, 33(6):1379-1390. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=kcdz201406015
[37] Ying Y C, Chen W, Lu J, et al.In situ U-Th-Pb ages of the Miaoya carbonatite complex in the South Qinling orogenic belt, central China[J].Lithos, 2017, 290:159-171. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=419cb3598c095d3a5c772686274ba850
[38] 覃宗光, 邓贵安, 董业才, 等.栗木矿田鱼菜花岗岩型锡钨矿床的发现及其找矿标志[J].云南冶金, 2011, 40(S2):76-79, 84. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=7722155
[39] 邓贵安, 吴继炜, 汪恕生, 等.栗木矿田三个黄牛花岗岩型钨锡矿床地质特征[J].矿产与地质, 2012, 26(1):1-6. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=kcydz201201001
[40] 张思明, 陈郑辉, 施光海, 等.江西省大吉山钨矿床辉钼矿铼-锇同位素定年[J].矿床地质, 2011, 30(6):1113-1121. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=kcdz201106011
[41] 何维基.江西省钽铌矿床类型及时空分布规律[J].矿产与地质, 2001, (S1):450-456. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=kcydz2001z1014
[42] 甘晓春, 朱金初, 沈渭洲.广西栗木水溪庙稀有金属花岗岩成因[J].地质找矿论丛, 1992, (2):35-45. http://www.cnki.com.cn/Article/CJFDTotal-DZZK199202003.htm
[43] 曾晓建, 陈正钱.武夷山成矿带会仙峰花岗岩体及稀有金属成矿特征[J].矿产与地质, 2002, (3):174-178. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=kcydz200203009
[44] 李文辉, 钟晓清, 张苑平, 等.广东省博罗县横河钠长石矿构造岩浆演化及成矿机理[J].大地构造与成矿学, 2010, 34(1):71-77. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=ddgzyckx201001008
[45] 刘家远.复式岩体和杂岩体——花岗岩类岩体组合的两种基本形式及其意义[J].地质找矿论丛, 2003, (3):143-148. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=dzzklc200303001
[46] Middlemost E A K.Naming materials in the magma/igneous rock system[J].Annual Review of Earth & Planetary ences, 1994, 37(3/4):215-224. https://www.researchgate.net/publication/223901164_Naming_materials_in_the_magmaigneous_rock_system
[47] Maniar P D, Piccoli P M.Tectonic discrimination of granitoids[J].Geological Society of America Bulletin, 1989, 101(5):635-643. https://www.researchgate.net/publication/279908588_Tectonic_discrimination_of_granitoid
[48] 杨毅, 祝新友, 王艳丽, 等.湖南湘东钨矿区花岗岩地质地球化学特征及意义[J].矿产与地质, 2014, 28(2):202-208. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=kcydz201402013
[49] 刘昌实, 贺伯初, 周亮, 等.赣东南含黄玉花岗质岩石的成因探讨[J].大地构造与成矿学, 1993, (1):39-51. http://www.cnki.com.cn/Article/CJFDTotal-DGYK199301005.htm
[50] 周红升, 苏华, 马昌前.灵山岩体的形成时代、构造背景及其A型花岗岩的厘定[J].信阳师范学院学报(自然科学版), 2009(2):222-226. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=xysfxyxb-zrkx200902016
[51] Boynton W V.Cosmochemistry of the rare earth elements: meteorite studies[C]//Developments in geochemistry.Elsevier, 1984, 2: 63-114.
[52] Sun S S, McDonough W F.Chemical and isotopic systematics of oceanic basalts:implications for mantle composition and processes[J].Geological Society, London, Special Publications, 1989, 42(1):313-345. https://www.researchgate.net/publication/231575101_Chemical_and_isotopic_systematics_of_oceanic_basalts_Implications_for_mantle_composition_and_processes
[53] Aguilar C P, González C.Petrogenesis of highly fractionated I-type peraluminous granites:La Pedriza pluton (Spanish Central System)[J].Geologica Acta, 2010, 8(2):131-149. https://www.researchgate.net/publication/45842450_Petrogenesis_of_highly_fractionated_I-type_peraluminous_granites_La_Pedriza_pluton_Spanish_Central_System
[54] Ballouard C, Poujol M, Boulvais P, et al.Nb-Ta fractionation in peraluminous granites:A marker of the magmatic-hydrothermal transition[J].Geology, 2016, 44:231-234. https://www.researchgate.net/publication/293109912_Nb-Ta_fractionation_in_peraluminous_granites_A_marker_of_the_magmatic-hydrothermal_transition
[55] Bau M.Controls on the fractionation of isovalent trace elements in magmatic and aqueous systems:evidence from Y/Ho, Zr/Hf, and lanthanide tetrad effect[J].Contributions to Mineralogy & Petrology, 1996, 123(3):323-333.
[56] Green T H.Significance of Nb/Ta as an indicator of geochemical processes in the crust-mantle system[J].Chemical Geology, 1995, 120(3/4):347-359. https://www.sciencedirect.com/science/article/abs/pii/000925419400145X
[57] Dostal J, Chatterjee A K.Contrasting behaviour of Nb/Ta and Zr/Hf ratios in a peraluminous granitic pluton (Nova Scotia, Canada)[J].Chemical Geology, 2000, 163(1/4):207-218. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=7a86ecd7b7229cb687620d8d59cd9c61
[58] Claiborne L L, Miller C F, Walker B A, et al.Tracking magmatic processes through Zr/Hf ratios in rocks and Hf and Ti zoning in zircons:An example from the Spirit Mountain batholith, Nevada[J].Mineralogical Magazine, 2006, 70(5):517-543. https://www.researchgate.net/publication/249851104_Tracking_magmatic_processes_through_ZrHf_ratios_in_rocks_and_Hf_and_Ti_zoning_in_zircons_An_example_from_the_Spirit_Mountain_batholith_Nevada
[59] Dostal J, Kontak D J, Gerel O, et al.Cretaceous ongonites (topaz-bearing albite-rich microleucogranites) from Ongon Khairkhan, Central Mongolia:Products of extreme magmatic fractionation and pervasive metasomatic fluid:rock interaction[J].Lithos, 2015, 236/237:173-189. https://www.researchgate.net/publication/282218498_Cretaceous_ongonites_topaz-bearing_albite-rich_microleucogranites_from_Ongon_Khairkhan_Central_Mongolia_Products_of_extreme_magmatic_fractionation_and_pervasive_metasomatic_fluid_Rock_interaction
[60] 吴福元, 刘小驰, 纪伟强, 等.高分异花岗岩的识别与研究[J].中国科学:地球科学, 2017, 47(7):745-765. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=zgkx-cd201707001
[61] Whalen J B, Currie K L, Chappell B W.A-type granites:geochemical characteristics, discrimination and petrogenesis[J].Contributions to Mineralogy & Petrology, 1987, 95(4):407-419. https://link.springer.com/article/10.1007%2FBF00402202
[62] 黑慧欣, 牛耀龄, 赵志丹, 等.一代表性矿物中Nb, Ta, Zr, Hf的丰度与分配[C]//2009年全国岩石学与地球动力学研讨会.2009.
[63] Taylor R P.Petrological and geochemical characteristics of the Pleasant Ridge zinnwaldite-topaz granite, southern New Brunswick, and comparisons with other topaz-bearing felsic rocks[J].Canadian Mineralogist, 1992, 30(3):895-921. https://www.researchgate.net/publication/282445400_Petrological_and_geochemical_characteristics_of_the_Pleasant_Ridge_zinnwaldite-topaz_granite_southern_New_Brunswick_and_comparisons_with_other_topaz-bearing_felsic_rocks
[64] Kovalenko V I.Ongonites (topaz-bearing quartz keratophyre)-subvolcanic analogue of rare-metal Li-F granites[J].Nauka Moskva, 1976, 15:124-128.
[65] Eby G N.Chemical subdivision of the A-type granitoids:petrogenetic and tectonic implications[J].Geology, 1992, 20(7):641-644. https://ui.adsabs.harvard.edu/abs/1992Geo....20..641E/abstract
[66] 吴福元, 李献华, 杨进辉, 等.花岗岩成因研究的若干问题[J].岩石学报, 2007, (6):3-24. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=ysxb98200706001
[67] Pearce J A, Harris N B W, Tindle A G.Trace element discrimination diagrams for the tectonic interpretation of granitic rocks[J].Journal of petrology, 1984, 25(4):956-983. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=HighWire000005685327
[68] 马丽芳.中国地质图集[Z].北京: 地质出版社, 2002: 1-248.
[69] 张岳桥, 徐先兵, 贾东, 等.华南早中生代从印支期碰撞构造体系向燕山期俯冲构造体系转换的形变记录[J].地学前缘, 2016, (1):234-247. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=6866745
[70] 邓晋福, 冯艳芳, 狄永军, 等.中国侵入岩大地构造图(1:250万)[M].北京:地质出版社, 2016:522-528.
[71] Pitcher W S.The Nature and Origin of Granite[M].London:Chapman & Hall Press, 1997:215-225.
[72] Clemens J D, Holloway J R, White A J R.Origin of an A-type granite:experimental constraints[J].American Mineralogist, 1986, 71(3):317-324. https://www.researchgate.net/publication/279898234_Origin_of_an_A-type_granite_experimental_constraints?ev=auth_pub
[73] King P L, White A J R, Chappell B W, et al.Characterization and Origin of Aluminous A-type Granites from the Lachlan Fold Belt, Southeastern Australia[J].Journal of Petrology, 1997, (3):3. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=HighWire000001850479
[74] King P L, Chappell B W, Allen C M, et al.Are A-type granites the high-temperature felsic granites? Evidence from fractionated granites of the Wangrah Suite[J].Journal of the Geological Society of Australia, 2001, 48(4):501-514. https://www.tandfonline.com/doi/abs/10.1046/j.1440-0952.2001.00881.x
[75] Ballouard C, Massuyeau M, Elburg M A, et al.The magmatic and magmatic-hydrothermal evolution of felsic igneous rocks as seen through Nb-Ta geochemical fractionation, with implications for the origins of rare-metal mineralizations[J].Earth-Science Reviews, 2020, 203:103115. https://www.sciencedirect.com/science/article/abs/pii/S0012825219303460
[76] 邓晋福, 赵海玲, 莫宣学, 等.扬子大陆的陆内俯冲与大陆的缩小——由白云母(二云母)花岗岩推导[J].高校地质学报, 1995, (1):50-57. http://www.cnki.com.cn/Article/CJFDTotal-GXDX501.005.htm
[77] 唐梅华.华东南内陆地区早白垩世中期挤压构造事件及其地质意义[D].东华理工大学硕士学位论文, 2016.
[78] 顾连兴.A型花岗岩的特征、成因及成矿[J].地质科技情报, 1990, 9(1):27-33. http://www.cnki.com.cn/Article/CJFDTotal-DZKQ199001006.htm
[79] 陈璟元, 杨进辉.佛冈高分异Ⅰ型花岗岩的成因: 来自Nb-Ta-Zr-Hf等元素的制约[C]//中国科学院地质与地球物理研究所2015年度(第15届)学术年会.2016.
[80] 邓晋福.岩石成因、构造环境与成矿作用[M].北京:地质出版社, 2004.
① 邢光福，张允平.中国东部中新生代陆缘弧盆系大地构造图说明书.中国地质调查局发展中心，2013:1-149.
② 周亮，苟月明，王取义，等.赣南石城及寻乌锡多金属隐伏矿预测研究.江西省地质矿产局赣南地质调查大队南京大学，2008.
③ 许建详，王淑敏，梁景时，等.江西省石城县姜坑里矿区钒但矿详查地质报告.2008:5-36.
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