Geological Characteristics, Genetic Types and Utilization Value of Yonghong Fluorite Deposit in Mabian Area, Southwest Sichuan and Its Enlightenment to Regional Prospecting
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摘要:
四川地区属于缺乏萤石矿和无萤石成矿区带分布的地区,本次在马边地区发现中型萤石矿床,具有重大的意义。通过野外地质调查和收集分析地质资料,探讨了马边地区永红萤石矿床的矿床成因以及对区域找矿的启示。结果表明,矿体产出于寒武系纽芬兰统筇竹寺组粉砂岩中,严格受断层控制,成矿要素为白云岩、灰岩、含氟磷块岩和断裂,无火山岩和侵入岩,而前人总结的热液充填型萤石矿床中的5种亚类型均有火山岩或侵入岩,因此本次总结为另一种热液充填型萤石矿床亚类型——永红式热液充填型萤石矿(断裂+碳酸盐岩+含氟磷酸盐);马边地区永红萤石矿查明资源量45.0万 t,CaF2平均品位34.61%,为中型萤石矿床;经选矿实验研究,经一次粗选和七次精选,可获得产率为26.17 %,品位为91.35 %,回收率61.34 %的萤石精矿,可选性较好,属于易选矿石;通过成矿要素对比分析,峨边-金阳大断裂带上的马边、雷波、金阳地区具有较好的萤石找矿前景,以上成果对填补四川无萤石成矿带的空白和指导峨边-金阳大断裂带的区域找矿及推动乌蒙山区经济发展都具有重要意义。
Abstract:Sichuan is an area where there are no fluorite deposits and no fluorite metallogenic belts. The discovery of medium-sized fluorite deposit in Mabian area is of great significance. Through field geological investigation and collection and analysis of geological data, the genesis of Yonghong Fluorite deposit in Mabian area and its enlightenment to regional prospecting are discussed. The results showed that the ore body occurs in the siltstone of Qiongzhusi Formation of Cambrian Terreneuvian, which is strictly controlled by fault. The metallogenic factors are dolomite, limestone, fluorine-containing phosphorites and fault, and there are no volcanic rock and intrusive rock. The five subtypes of hydrothermal filling type fluorite deposits summarized by predecessors have volcanic rock or intrusive rock. Therefore, it is summarized as a new subtype of hydrothermal filling fluorite type deposit-Yonghong subtype of hydrothermal filling type fluorite deposit (fault+carbonate rock+fluorophosphate); Yonghong fluorite deposit in Mabian area is a medium-sized fluorite deposit with an identified resource of 450000 t and its average content of CaF2 was 34.61%; Through the comparative analysis of metallogenic factors, Mabian-Leibo-Jinyang areas on Ebian-Jinyang fault zone have good fluorite prospecting prospects. The above results are of great significance to fill the gap of fluorite without metallogenic belt in Sichuan, guide the regional prospecting of Ebian-Jinyang fault zone and promote the economic development of Wumeng Mountains region.
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表 1 马边地区永红矿区萤石精矿多元素分析结果/%
Table 1. Multi element analysis results of fluorite concentrate in Yonghong ore district of Mabian area
CaF2 BaSO4 CaCO3 Al2O3 Fe2O3 SiO2 SrSO4 97.05 0.97 1.01 0.06 0.03 0.75 0.05 -
[1] 陈军元, 刘艳飞, 颜玲亚, 等. 石墨、萤石等战略非金属矿产发展趋势研究[J]. 地球学报, 2021, 42(2):287-296. CHEN J Y, LIU Y F, YAN L Y, et al. Research on development trend of strategic nonmetallic minerals such as graphite and fluorite[J]. Acta Geoscientica Sinica, 2021, 42(2):287-296. doi: 10.3975/cagsb.2020.102606
[2] 李敬, 高永璋, 张浩. 中国萤石资源现状及可持续发展对策[J]. 中国矿业, 2017, 26(10):7-14. LI J, GAO Y Z, ZHANG H. Fluorite resource status and its sustainable development countermeasures in China[J]. China Mining Magazine, 2017, 26(10):7-14.
[3] 曾小波, 印万忠. 共伴生型萤石矿浮选研究进展与展望[J]. 矿产综合利用, 2021(1):1-7. ZENG X B, YIN W Z. Resesrch progress and prospect of flotation of assou ciated fluorite minerals[J]. Multipurpose Utilization of Mineral Resources, 2021(1):1-7. doi: 10.3969/j.issn.1000-6532.2021.01.001
[4] 刘忠义, 马子龙, 刘杰, 等. 含云母方解石型萤石矿的浮选柱分选实验研究[J]. 矿产综合利用, 2019(2):60-64. LIU Z Y, MA Z L, LIU J, et al. Experimental research on flotation column separation of micaceous calcite-type fluorite[J]. Multipurpose Utilization of Mineral Resources, 2019(2):60-64. doi: 10.3969/j.issn.1000-6532.2019.02.012
[5] 崔瑞, 王旭, 魏骞, 等. 湖北某重晶石-萤石型矿综合利用研究[J]. 矿产综合利用, 2019(2):70-74. CUI R, WANG X, WEI Q, et al. Study on comprehensive utilization of a barite-fluorite ore in Hubei Province[J]. Multipurpose Utilization of Mineral Resources, 2019(2):70-74. doi: 10.3969/j.issn.1000-6532.2019.02.014
[6] HAN B B, SHANG P Q, GAO Y Z, et al. Fluorite deposits in China: geological features, metallogenic regularity, and research progress[J]. China Geology, 2020(3):473-489. doi: 10.31035/cg2020054
[7] 王吉平, 商朋强, 熊先孝, 等. 中国萤石矿床分类[J]. 中国地质, 2014, 41(2):315-325. WANG J P, SHANG P Q, XIONG X X, et al. The classification of Fluorite deposits in China[J]. Geology in China, 2014, 41(2):315-325. doi: 10.3969/j.issn.1000-3657.2014.02.001
[8] 文俊, 张航飞, 竹合林, 等. 四川马边地区找矿新发现: 磷-铅-萤石矿三位一体找矿新模型[J]. 地质论评, 2021, 67(6):1802-1803. WEN J, ZHANG H F, ZHU H L, et al. New discovery of prospecting in Mabian area, Sichuan: a new trinity prospecting model of phosphorus-lead-fluorite deposit[J]. Geological Review, 2021, 67(6):1802-1803.
[9] 王吉平, 商朋强, 牛桂芝. 中国萤石矿主要矿集区及其资源潜力探讨[J]. 化工矿产地质, 2010, 32(2):87-94. WANG J P, SHANG P Q, NIU G Z. Discussion on China fluorite-concentrating area and the resource potentialhina[J]. Geology of Chemical Minerals, 2010, 32(2):87-94. doi: 10.3969/j.issn.1006-5296.2010.02.003
[10] 刘宝珺, 许效松, 潘杏南, 等. 中国南方古大陆沉积地壳演化与成矿[M]. 北京: 科学出版社, 1993, 1-188.
LIU B J, XU X S, PAN X N, et al. Sedimentary crustal evolution and mineralization of ancient continents in Southern China [M]. Beijing : Science Press, 1993, 1-188 .
[11] 张芹贵, 彭向辉, 祝建华. 马边-雷波峨边-金阳大断裂构造特征及活动性[J]. 四川地质学报, 2019, 39(1):30-33. ZHANG Q G, PENG X H, ZHU J H. Characteristics and activity of the Mabian-Leibo-Ebian-Jinyang major Fault[J]. Acta Geologica Sichuan, 2019, 39(1):30-33. doi: 10.3969/j.issn.1006-0995.2019.01.007
[12] 刘建清, 何利, 江永富, 等. 四川雷波地区下寒武统麦地坪含磷地层研究及磷矿资源潜力分析[J]. 中国地质, 2020. https://kns.cnki.net/kcms/detail/11.1167.P.20200804.0937.004.html.
LIU J Q, HE L, JIANG Y F, et al . Phosphorus bearing strata in Maidiping formation of lower Cambrian in Leibo area of Sichuan Province and its potential analysis of phosphate resources[J]. Geology in China, 2020. https://kns.cnki.net/kcms/detail/11.1167.P.20200804.0937.004.html.
[13] 文俊, 刘治成, 赵俊兴, 等. 川南沐川地区宣威组底部铌-稀土多金属富集层富集规律、沉积环境与成矿模式[J]. 地质学报, 2021. WEN J, LIU Z C, ZHAO J X, et al. Enrichment regularity, sedimentary environment and metallogenic model of niobium-rare earth polymetallic enrichment layer in bottom of Xuanwei Formation in Muchuan Area, South Sichuan[J]. Acta Geologica Sinica, 2021. doi: 10.19762/j.cnki.dizhixuebao.2021281
[14] 马隆飞, 廖寅飞, 贺玉程, 等. 赣州某萤石尾矿浮选柱分选实验研究[J]. 矿产综合利用, 2019(2):89-93. MA L F, LIAO Y F, HE Y C, et al. Experimental study on flotation column separation of a fluorite tailings in Ganzhou[J]. Multipurpose Utilization of Mineral Resources, 2019(2):89-93. doi: 10.3969/j.issn.1000-6532.2019.02.018
[15] 宁江峰, 李茂林, 崔瑞, 等. ZnSO4•7H2O与水玻璃组合抑制剂对萤石、方解石浮选分离的影响[J]. 矿产综合利用, 2020(6):186-192. NING J F, LI M L, CUI R, et al. Effect of ZnSO4•7H2O and sodium silicate as combination inhibitors on flotation separation of fluorite and calcite[J]. Multipurpose Utilization of Mineral Resources, 2020(6):186-192. doi: 10.3969/j.issn.1000-6532.2020.06.031
[16] 秦建华, 廖震文, 朱斯豹, 等. 川滇黔相邻区碳酸盐岩容矿铅锌矿成矿特征[J]. 沉积与特提斯地质, 2016, 36(1):1-13. QIN J H, LIAO Z W, ZHU S B, et al. Mineralization of the carbonate-hosted Pb-Zn deposits in the Sichuan-Yunnan-Guizhou area, southwestern China[J]. Sedimentary Geology and Tethyan Geology, 2016, 36(1):1-13. doi: 10.3969/j.issn.1009-3850.2016.01.001
[17] 王健, 张均, 张晓军, 等. 四川天宝山矿床闪锌矿Rb-Sr 年代学、稳定同位素及地质意义[J]. 地球科学, 2019, 44(9):3026-3041. WANG J, ZHANG J, ZHANG X J, et al. Rb-Sr geochronology, stable isotopic analyses and geological significance of the Tianbaoshan Pb-Zn deposit in Sichuan Province, China[J]. Earth Science, 2019, 44(9):3026-3041.
[18] 王吉平, 商朋强, 熊先孝, 等. 中国萤石矿床成矿规律[J]. 中国地质, 2015, 42(1):18-32. WANG J P, SHANG P Q, XIONG X X, et al. Metallogenic regularities of fluorite deposits in China[J]. Geology in China, 2015, 42(1):18-32. doi: 10.3969/j.issn.1000-3657.2015.01.003
[19] 韦晨, 叶霖, 李珍立, 等. 四川乌斯河铅锌矿床成矿物质来源及矿床成因: 来自原位S-Pb 同位素证据[J]. 岩石学报, 2020, 36(12): 3783-3796.
WEI C, YE L, LI Z L, et al. Metal sources and ore genesis of the Wusihe Pb-Zn deposit in Sichuan, China: new evidence from in-situ S and Pb isotopes[J]. Acta Petrologica Sinica, 2020, 36(12): 3783-3796 .
[20] 蔡祖成. 磷矿伴生氟资源综合利用探讨[J]. 广州化工, 2016, 44(13):26-28. CAI Z C. Discussion on the comprehensive utilization of phosphate associated fluorine resource[J]. Guangzhou Chemical Industry, 2016, 44(13):26-28. doi: 10.3969/j.issn.1001-9677.2016.13.010
[21] 曹俊臣. 中国萤石矿床分类及其成矿规律[J]. 地质与勘探, 1987(3):12-17. CAO J C. The classification and metallogenic regularity of fluorite deposits in China[J]. Geology and Prospecting, 1987(3):12-17.
[22] 四川省地质矿产局. 四川省区域地质志[M]. 北京: 地质出版社, 1982, 1-621.
Sichuan provincial bureau of geology and mineral resources. Sichuan provincial regional geology [M]. Beijing : Geological Publishing House, 1982, 1-621.
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