铂铼重整催化剂的开发应用现状与发展趋势

王雷; 张雷; 蔺慧杰; 冀成庆; 熊文良; 黄焜

doi:10.3969/j.issn.1000-6532.2023.06.014

铂铼重整催化剂的开发应用现状与发展趋势

1.
中国石油天然气股份有限公司，辽河油田分公司新能源事业部，辽宁　盘锦　124099

2.
中国地质科学院矿产综合利用研究所，中国地质调查局稀土资源应用技术创新中心，四川　成都　610041

3.
北京科技大学冶金与生态工程学院，北京　100083

基金项目: 松辽盆地海坨子等靶区深部成矿潜力分析与勘查示范（2018YFC0604205）；中石油科技管理部超前储备技术项目（2021KJ-07-02）

详细信息

作者简介: 王雷（1985-），男，工程师，主要从事石油冶炼，催化剂材料等研究工作

通讯作者: 张雷（1984-），男，工程师，主要从事石油开采，石油精加工等研究工作

中图分类号: TD986

收稿日期: 2022-09-05

刊出日期: 2023-12-25

Development and Application of the Current Situation and Development Trend of Platinum-Rhenium Reforming Catalyst

1.
New Energy Department of Liaohe Oilfield Company, China National Petroleum Corporation, Panjin, Liaoning, China

2.
Institute of Multipurpose Utilization of Mineral Resources, China Geological Survey, China Geological Survey Rare Earth Resource Application Technology Innovation Center, Chengdu, Sichuan, China

3.
College of Metallurgy and Ecological Engineering, Beijing University of Science and Technology, Beijing, China

More Information

Corresponding author: Zhang Lei, lh_wwzl@petrochina.com.cn

Received Date: 05 September 2022

Publish Date: 25 December 2023

摘要

摘要:
这是一篇陶瓷及复合材料领域的论文。我国铂铼催化剂行业随着原油加工技术需求不断提升发展，催化剂是石油冶炼的核心，其中浸渍法是重整催化剂主要制取方法。催化重整催化剂一般为铂-铼催化剂，未来研究趋势主要是提高催化剂的铼含量降低铂用量。铂铼催化剂的特点是稳定性好，选择性稍差，可以长周期稳定运转，再生周期可以达到3~5年，在半再生重整工艺大规模生产中得到了广泛应用。从20世纪后半叶以来，我国炼油催化剂市场现已形成了以中国石化和中国石油旗下催化剂公司为主，以民营催化剂公司为辅的市场格局，催化剂需求量稳定在10 t/a 以上。
- 陶瓷及复合材料 /
- 铂铼催化剂 /
- 催化重整 /
- 浸渍法 /
- 生产应用
Abstract:
This is an essay in the field of ceramics and composites.With the increasing demand for crude oil processing technology, China′s platinum rhenium catalyst industry is also developing. Catalyst is the core material of petroleum smelting, and impregnation method is the most important preparation method of reforming catalyst. Catalytic reforming catalysts generally refer to trace rhenium catalysts. The main research direction in the future is to increase the rhenium content of the catalyst and reduce the amount of platinum in the catalyst. The characteristics of platinum-rhenium catalysts are good stability, slightly poor selectivity, long-term stable operation, and regeneration cycle that can reach 3~5 years, which have been widely used in large-scale production of semi-regenerative reforming processes. Since the late 20th century, China′s refining catalyst market has formed a′Sinopec and PetroChina′s catalyst companies, supplemented by private catalyst companies′ market structure, catalyst demand is stable at more than 10 tons per year.
- Ceramics and composites /
- Platinum rhenium catalyst /
- Catalytic reforming /
- Impregnation method /
- Production application

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表 1 国外主要铂-铼催化剂产品^[25-28]

Table 1. Main platinum-rhenium catalyst products abroad

国家	公司	牌号	金属组分/%			载体	形状	应用年份
国家	公司	牌号	铂	铼	其他	载体	形状	应用年份
美国	雪弗龙	A	0.60	Re	/	改进载体		1967
		B	0.30	0.44	/			1969
		D	Pt	Re	/			1972
		E	0.30	0.30	/	γ-Al₂O₃	圆柱	1975
		F	0.30	0.60	/	γ-Al₂O₃	条形	1978
	恩格哈德（Englhard Co）	E-601	0.35	0.35	/	γ-Al₂O₃	条形	/
		E-611	0.275	0.275	/	γ-Al₂O₃	条形	/
		E-802	0.26	0.50	/	γ-Al₂O₃	条形	/
		E-803	0.22	0.42	/	γ-Al₂O₃	条形	/
		E-804	0.22	0.22	/	γ-Al₂O₃	条形	/
	环球油品公司（UOP）	R-16G	0.375	0.375	/	γ-小球		1968
		R-62	0.22	0.44	/	γ-小球		1982
		R-56	0.25	0.40	/	γ-挤条		1992
		R-72	0.30	/	Ge	γ-小球		1994
		R-86	0.25	0.4	/	γ-挤条		2001
	埃克森美孚（ExxonMobil）	KX-120	0.30	/	Ir：0.30	圆柱条		1971
		KX-130	0.30	/	Ir：0.30			1971
		KX-160	Pt	Re	/			1971
		KX-170	Pt	Re	/			1971
法国	法国石油研究院(IFP)	RG-451	0.30	/	Ir：0.04Ti：0.24	η-挤条		1973
		RG-482	0.30	0.30	/	γ-挤条		1982
		RG-492	0.30	0.60	/	γ-挤条		/
		RG-582A	0.275	0.275	X	γ-挤条		1994
		RG-582	0.30	0.20	X	γ-挤条		1994
		RG-682A	0.275	0.40	X	γ-挤条		/
		RG-682	0.30	0.40	X	γ-挤条		/
荷兰	阿克苏国际化学公司(AKZO Chemicals intern BV)	CK-433	0.3	0.3	/	γ-Al₂O₃	条形	/

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表 2 中国石油化工科学研究院铂-铼重整催化剂产品

Table 2. Chinese platinum-rhenium reforming catalyst products

产品编号		金属组分/%			载体	球形直径 (形状)d/mm	应用年份
石科院	工业	铂	铼	其他元素	载体	球形直径 (形状)d/mm	应用年份
/	7341	0.5	0.45	/	η- Al₂O₃	1.7-2.3	1974
/	CB-5	0.5	0.35	/	η- Al₂O₃	1.5-2.25	1982
/	3741-2	0.5	0.45	/	η- Al₂O₃	1.7-2.3	1984
PR-A	CB-6	0.5	0.27	/	η- Al₂O₃	1.5-2.5	1985
PR-B	CB-7	0.21	0.42	/	η- Al₂O₃	1.5-2.2	1989
/	CB-8	0.15	0.30	/	η- Al₂O₃	1.5-2.2	1991
PR-C	CB-60	0.25	0.26	无	SB	条	1995
PR-D	CB-70	0.21	0.46	无	SB	条	1995
PR-D	3923	/	/	/	/	/	/
PRT-C	PRT-C	0.25	0.26	含有	SB	条	2002
PRT-D	PRT-D	0.21	0.46	含有	SB	条	2002
/	R-最新	0.25	0.40	无	不详	/	/

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表 3 铂铼重整催化剂制备相关专利^[31-35]

Table 3. Patents on preparation of platinum-rhenium reforming catalyst

专利授权号	专利名称	专利权人
CN105413714B	一种铂铼重整催化剂的制备方法和铂铼重整催化剂	中国石油化工股份有限公司；中国石化催化剂有限公司
CN105709784B	一种硫化型铂铼重整催化剂的制备方法	中国石油化工股份有限公司；中国石油化工股份有限公司抚顺石油化工研究院
CN102140366B	一种铂铼重整催化剂的初始反应方法	中国石油化工股份有限公司；中国石油化工股份有限公司石油化工科学研究院
CN1191121C	一种铂-铼重整催化剂及制备方法	中国石油化工股份有限公司；中国石油化工股份有限公司石油化工科学研究院
CN109954505A	一种还原态铂铼重整催化剂	中国石油化工股份有限公司；中国石油化工股份有限公司大连石油化工研究院

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铂铼重整催化剂的开发应用现状与发展趋势

作者简介: 王雷（1985-），男，工程师，主要从事石油冶炼，催化剂材料等研究工作

通讯作者: 张雷（1984-），男，工程师，主要从事石油开采，石油精加工等研究工作

Development and Application of the Current Situation and Development Trend of Platinum-Rhenium Reforming Catalyst

Corresponding author: Zhang Lei, lh_wwzl@petrochina.com.cn

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