超临界流体的地质意义

王传远, 杜建国, 刘巍, 周晓成, 郑朝阳. 超临界流体的地质意义[J]. 西北地质, 2005, 38(2): 49-53.
引用本文: 王传远, 杜建国, 刘巍, 周晓成, 郑朝阳. 超临界流体的地质意义[J]. 西北地质, 2005, 38(2): 49-53.
WANG Chuan-yuan, DU Jian-guo, LIU Wei, ZHOU Xiao-cheng, ZHENG Chao-yang. Geological applications of supercritical fluids[J]. Northwestern Geology, 2005, 38(2): 49-53.
Citation: WANG Chuan-yuan, DU Jian-guo, LIU Wei, ZHOU Xiao-cheng, ZHENG Chao-yang. Geological applications of supercritical fluids[J]. Northwestern Geology, 2005, 38(2): 49-53.

超临界流体的地质意义

  • 基金项目: 国家自然科学基金(批准号12099040);中科院兰州地质所知识创新基金项目(2003-19-DJG)

Geological applications of supercritical fluids

  • 超临界流体具有一系列特殊性质,如,临界发散性、“临界乳光”、强氧化性、可变的介电常数、较强的溶解性等。地球深部超临界流体的存在不仅影响岩石的性质,而且对地质构造演化有重要的意义;超临界流体为油气的形成提供物质和能量,同时又是热液成矿过程中元素迁移、聚集和矿石矿物赋存空间形成的重要因素;地质构造演化与超临界流体密不可分;超临界流体对地震孕育及岩浆的产生和喷发有重要影响;超临界流体技术(超临界萃取、超临界水氧化等)不但能最大限度地回收有价值的矿物,而且能有效处理“三废”。
  • 加载中
  • 胡英.近代化工热力学[M].上海:上海科技文献出版社,1993.

    谢洪森.地球深部物质科学导论[M].北京:科学出版社,1997.

    Matyn Poliakoff,Peter King,Phenomenal fluids[J].Nature,2001,412:125.

    Mauro Boero,Kiyoyuki Terakura,Tamio Ikeshoji,et al.Hydrogen Bonding and dipolar moment of water at supercritical conditions: A first-principles molecular dynamics study [J].Physical review letters,2000,85(15): 3245-3248.

    葛良胜,郭晓东,邹依林.试论地球内部流体与地质作用——现代地质科学思考[J].地球科学进展,1998,(2):129-140.

    苏根利,谢鸿森,丁东业,等.超临界水的物理化学性质及意义[J].地质地球化学,1998,26(2):83-89.

    朱自强.超临界流体技术原理和应用[M].北京:化学工业出版社,2001.

    戴航,黄卫红,钱晓良,等.超临界水氧化法水处理技术进展[J].化工环保,2001,21(20):79-82.

    陈维木丑.超临界流体的萃取原理和应用[M].北京:化学工业出版社,1998.

    Zhang Xiaogang,Gao Liang,Liu Zhimin,et al.Effect of size and polarity of solutes on partial molar volumes and intermolecular interaction in supercritical fluids[J].Journal of Supercritical Fluids,2002,23:233-241.

    Jonson J W,Norton D.Critical phenomena in hydrothermal system: state,thermodynamic,electrostatic and transport properties of H2O in the critical region[J].Am J Sci,1991,291: 541-648.

    Alfons Balker.Supercritical Fluids in Heterogeneous Catalysis[J].Chem.Rev.1999,99:453-473.

    谭凯旋,戴塔根.非线性地球化学动力学[J].地球科学进展,1998,13(2):145-150.

    Philip G,Jessop,Takao Lkariya,Ryoji Noyori.Homogeneous catalysis in super-critical fluids [J].Chem.Rev.,1999,99:475-493.

    Randolph T W,Brein J A,Ganapathy S.Does critical clustering affect reaction rate constants? Molecular dynamics study in pure supercritical fluids[J].J.Phys.Chem.,1994,98:4173-4179.

    Kalinichev A G,Bass J D.Hydrogen bonding in supercritical water[J].J.Phys.Chem.A,1997,101:9720-9727.

    赵志丹,高山,驼庭川,等.秦岭和华北地区地壳低速层的成因探讨——岩石高温高压实验证据[J].地球物理学报,1996,39(5):637-652.

    毕思文.地球内部流体系统科学统一理论[J].地学前缘,1996,3,(3-4):4-8.

    Ito K.Effects of H2O on elastics in ultrabasic rocks at 900℃ under 1Gpa [J].Physics Earth Planet Inter,1990,61:260-268.

    Karato S.The role of hydrogen in the electrical conductivity of the upper mantle [J].Nature,1990,347:272-273.

    Li X Y,Mao H K.Solid carbon at high pressure: Electrical resitivity and phase transition[J].Phys.Chem.Minerals,1994,12:1-5.

    Glover P W,Vine F J.Electrical conductivity of carbon-bearing granulite at raised temperatures and pressure [J].Nature,1992,360:723-726.

    田宜灵,冯季军,秦颖,等.超临界水的性质及其在化学反应的应用[J].化学通报,2002,6:396-402.

    Mian Z U,Tozer D C.No water,no plate tectonics: Convective heat transfer and the planetary surface of Venus and Earth[J].Terra Nova,1990,2:455-459.

    杜乐天.上地幔软流层(体)的成因[J].地球物理学会年刊,1999,321.

    李曙光,侯振辉.大陆俯冲过程中的流体[J].地学前缘,2001,8(3):123-129.

    Frank P,Lucien,Neil R.et al.Solubilities of solid mixtures in supercritical carbon dioxide:a review [J].Journal of Supercritical Fluids,2000,17:111-134.

    Ballhaus C,Frost B R.The Generation of oxidized CO2-bearing melts from reduced CH4-bearing upper mantle sources[J].Geochim.Acta,1995,59:683-689.

    Brenan J M.Partitioning of fluorine and chlorine between apatite and aqueous fluids at high pressure and temperature: implications for high pressure and temperature fluids[J].Earth Planet Sci Lett.1993,117:251-263.

    高波,陶明信,王万春.深部热流体对油气成藏的影响[J].矿物岩石地球化学通报,2001,2091):30-34.

    谢洪森,侯渭,张月明,等.中国东南海陆岩石圈结构与演化研究[M],北京:中国科学技术出版社,1992.

    杜建国,康春丽.地震地下流体发展概述[J].地震,2000,20(增刊):107-113.

    Yong T E,Green H W.Infrared spectroscopic investigation of hydroxyl in (Mg Fe)2SiO4 and coexisting olivine and dynamics[J].Phys.Chem.Minerals,1993,19:409-422.

    刘巍,杜建国,白利平.浅谈超临界流体在地震孕育中的作用[J].地震地质.2000,22(4):439-444.

    Gaetani G A,Grove T L.The influence of water on melting of mantle peridotite[J].Contrib Mineral Petrol.,1998,131:323-346.

  • 加载中
计量
  • 文章访问数:  2448
  • PDF下载数:  3883
  • 施引文献:  0
出版历程
收稿日期:  2004-02-11
修回日期:  2005-03-29
刊出日期:  2005-06-15

目录