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人工湿地净化污染物的应用及机制研究进展

A Review of Research Progress on the Application and Mechanism of Constructed Wetlands in Purifying Pollutants

  • 摘要: 人工湿地是一个复杂的生态处理系统,其污染物净化过程是物理、化学和生物过程的综合作用,但不同来源污水中污染物种类与浓度差异显著,导致人工湿地在污染物去除效果及机制上存在复杂性与差异性,制约了人工湿地技术的推广应用。本文总结了人工湿地处理工业污水、农业污水和生活污水等不同来源污水的研究成果,归纳了可处理的污染物包括营养元素、有机物、重金属、新污染物、氟化物、硫酸盐和氯化物等,其中生活污水相关研究文献占比高达64.45%,污染物主要集中于氮、磷和有机物。重点阐述了人工湿地各功能单元的净化机制:①微生物通过降解和转化过程去除氮与有机物;②填料基质依靠过滤、吸附、沉淀和离子交换等方式去除磷、重金属和氟化物;③植物则在为微生物提供生存环境的同时,参与污染物吸收与转化;④对于石油类和新污染物,则依赖于驯化微生物的生物降解与植物辅助吸收,硫酸盐的去除亦依赖于硫酸盐还原菌、硫氧化菌等硫代谢微生物的协同作用。实际污水中常存在氮、磷、有机物、重金属等多种污染物共存的复合污染问题,传统人工湿地系统对多污染物的协同去除机制仍缺乏系统认识,未来可构建适用于复合污染情境的人工湿地系统,提升其协同净化能力和抗冲击性能;部分污染物如石油烃和新污染物在湿地中虽能被有效去除,但其在处理过程中的转化路径及最终产物尚不明确,需加强对这类污染物处理后转化产物的定量检测与毒理评估;人工湿地中,微生物、植物与填料在污染物去除过程中发挥着协同作用,但目前对其各自贡献及其在多介质、多过程中的耦合机制缺乏量化与机制性认知,未来研究应致力于多组分作用过程的解析与优化调控,为人工湿地结构设计与功能提升提供理论支撑。

     

    Abstract: Constructed wetlands are complex ecological treatment systems, and their pollutant purification process is the combined effect of physical, chemical and biological processes. However, the types and concentrations of pollutants in wastewater from different sources vary significantly, resulting in complexity and differences in the pollutant removal effect and mechanism of constructed wetlands, which restricts the promotion and application of constructed wetland technology. This review summarizes the research results on the treatment of industrial, agricultural and domestic wastewater from different sources by constructed wetlands. It concludes that the pollutants that can be treated include nutrients, organic matter, heavy metals, emerging pollutants, fluorides, sulfates and chlorides, among which the proportion of research literature related to domestic wastewater is as high as 64.45%. Pollutants are mainly concentrated in nitrogen, phosphorus and organic matter. The purification mechanisms of each functional unit of constructed wetlands are mainly summarized as follows: (1) Microorganisms remove nitrogen and organic matter through degradation and transformation processes. (2) The filler matrix removes phosphorus, heavy metals and fluorides through filtration, adsorption, sedimentation and ion exchange, etc. (3) Plants, while providing a living environment for microorganisms, also participate in the absorption and transformation of pollutants. (4) For petroleum and new pollutants, it relies on the biodegradation of domesticated microorganisms and the assistance of plants in absorption. The removal of sulfates also depends on the synergistic action of sulfur-metabolizing microorganisms such as sulfate-reducing bacteria and sulfur-oxidizing bacteria. In actual wastewater, there often exists complex pollution problems where multiple pollutants such as nitrogen, phosphorus, organic matter, and heavy metals coexist. Traditional constructed wetland systems still lack a systematic understanding of the collaborative removal mechanism of multiple pollutants. In the future, constructed wetland systems suitable for complex pollution scenarios can be constructed to enhance their collaborative purification capacity and anti-shock performance. Although some pollutants such as petroleum hydrocarbons and new pollutants can be effectively removed in wetlands, their transformation pathways and final products during the treatment process are still unclear. It is necessary to strengthen the quantitative detection and toxicological assessment of the transformation products of such pollutants after treatment. In constructed wetlands, microorganisms, plants and fillers play a synergistic role in the process of pollutant removal. However, at present, there is a lack of quantitative and mechanistic understanding of their respective contributions and the coupling mechanisms in multiple media and processes. Future research should focus on the analysis and optimal regulation of multi-component interaction processes to provide theoretical support for the structural design and functional improvement of constructed wetlands. The BRIEF REPORT is available for this paper at http://www.ykcs.ac.cn/en/article/doi/10.15898/j.ykcs.202504290110.

     

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