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山东省滕州城市边缘区土壤潜在有毒元素来源解析和健康风险评价

Source analysis and health risk assessment of potential toxic elements in soil of Tengzhou City Marginal Area

  • 摘要:
    研究目的 为探究城市边缘区周边土壤潜在有毒元素(PTEs)污染特征、来源及生态风险状况。
    研究方法 采集了滕州市边缘区周边456个表层(0~20 cm)土壤样本,测定了As、Cd、Cr、Cu、Hg、Ni、Pb和Zn含量。采用地累积指数法和潜在生态风险指数法评估城市PTEs污染特征,利用绝对主成分得分多元线性回归模型(APCS-MLR)和正矩阵因式分解(PMF)定量解析PTEs污染物来源,并采用健康风险指数模型评估人体健康的风险。
    研究结果 PTEs含量特征等结果表明,表层表土壤的生态风险相对较低,Hg污染最为严重,Hg污染存在空间差异大、污染聚集和受人类活动影响严重的特点。源解析表明,滕州市边缘区土壤PTEs源于自然源、工业源、交通源和农业源,在APCS-MLR模型中占比分别为39.59%、29.48%、25.17% 和 5.77%,在PMF模型中占比分别为29.64%、15.38%、28.03% 和 26.93%。人类健康风险评价表明,成人非致癌风险极低,儿童的非致癌风险及总人群的总致癌风险较大,As和Cr有一定致癌危害。
    结论 表层土壤PTEs主要来源地质背景,要注意Hg、As和Cr监测和治理。建议加强饮用水资源的监测,并且减少交通污染排放,强化工厂废物排放监管。

     

    Abstract:
    This paper is the result of environmental geological survey engineering.
    Objective To investigate the contamination characteristics, sources, and ecological risk status of potentially toxic elements (PTEs) in soils around urban fringe areas.
    Methods Soil samples were collected from 456 surface layers (0-20 cm) around the fringe area of Tengzhou City, and As, Cd, Cr, Cu, Hg, Ni, Pb and Zn contents were determined. The geo-accumulation index method and potential ecological risk index method were used to assess the pollution characteristics of urban PTEs, the Absolute Principal Component Score-Multiple Linear Regression (APCS-MLR) model and Positive Matrix Factorization (PMF) were used to quantitatively resolve the sources of PTEs pollutants, and the health risk index model was used to assess the risk to human health.
    Results The ecological risk of surface topsoil is relatively low, Hg pollution is the most serious, and Hg pollution is characterized by large spatial variations, aggregation of pollution, and serious influence by human activities. Source analysis showed that soil PTEs in the edge area of Tengzhou originated from natural, industrial, transportation and agricultural sources, which accounted for 39.59%, 29.48%, 25.17% and 5.77% in the APCS-MLR model, and 29.64%, 15.38%, 28.03% and 26.93% in the PMF model. The human health risk evaluation showed that non-carcinogenic risk for adults was low, the non-carcinogenic risk for children and the total carcinogenic risk for population were high, and As and Cr had some carcinogenic hazards.
    Conclusions The main source of surface soil PTEs is the geological background, and attention should be paid to Hg, As and Cr monitoring and treatment. It is recommended that the monitoring of drinking water resources be strengthened, and that traffic pollution emissions be reduced and the regulation of factory waste emissions be strengthened.

     

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