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基于土地利用的广西田东县土壤重金属污染风险评价与来源解析

Pollution risk assessment and source analysis of soil heavy metals in Tiandong County, Guangxi based on land use

  • 摘要:
    研究目的 查明广西田东县土壤重金属含量特征,评价土壤重金属污染风险,揭示土壤重金属来源,为当地绿色农业开发、土壤重金属污染防控及土地资源管理提供科学依据。
    研究方法 系统采集2779件表层土样和704件深层土样,组合形成表层分析样704件、深层分析样176件,分析测试了As、Cd、Cr、Cu、Hg、Ni、Pb和Zn共8种重金属元素含量,运用统计分析方法对重金属含量特征进行分析;对于水田、旱地、果园和建制镇等人类活动影响强烈区,依据《土壤环境质量 农用地土壤污染风险管控标准(试行)》(GB15618-2018)和《土壤环境质量 建设用地土壤污染风险管控标准(试行)》(GB36600-2018)对表层土壤重金属污染风险进行评价;对于有林地、灌木林地、其他林地、其他草地、其他园地和裸地等人类活动影响较弱区,以深层土壤重金属元素含量作为背景值,利用单因子污染指数法和内梅罗综合污染指数法对表层土壤重金属污染风险进行评价;采用相关分析、插值分析、因子分析和绝对主成分−多元线性回归模型(APCS−MLR)对表层土壤重金属来源进行解析。
    研究结果 表层土壤中重金属平均含量明显高于全国表层土壤背景值,深层土壤中重金属平均含量明显高于全国深层土壤背景值,岩溶区土壤重金属元素平均含量明显高于非岩溶区土壤;水田、旱地、果园和建制镇重金属污染风险评价结果显示,旱地污染风险较高,旱地中Cd含量超过土壤污染风险筛选值的样品比例为33.59%;有林地、灌木林地、其他林地、其他草地、其他园地和裸地重金属污染风险评价结果显示,除Cd外,其他重金属污染程度以无和轻度为主,Cd轻度、中度和重度污染样品占比分别为43.52%、15.09%和10.64%;研究区表层土壤重金属来源于成土母质和人类活动,成土母质源和人类活动源对重金属的平均贡献率分别为78.58%和21.42%。
    结论 研究区土壤重金属具有高含量特征,Cd为研究区首要防控污染元素,重金属含量总体受地质背景控制,人类活动带来了重金属的进一步累积。

     

    Abstract:
    This paper is the result of environmental geological survey engineering.
    Objective This study aims to characterize the heavy metal content in soil, assess topsoil pollution risk and apportion the sources of topsoil heavy metals, thereby providing a scientific basis for green agriculture development, soil heavy metal pollution prevention and land resource management in Tiandong County, Guangxi.
    Methods A total of 2779 topsoil and 704 subsoil samples were collected systematically, which were formed into 704 topsoil and 176 subsoil analysis samples. The content of As, Cd, Cr, Cu, Hg, Ni, Pb and Zn was determined. Statistical analysis methods were applied to analyze the characteristics of heavy metal content. For paddy fields, drylands, orchards, and towns with strong human activity impacts, topsoil heavy metal pollution risk was assessed against the “Soil Environmental Quality Risk Control Standard for Soil Contamination of Agricultural Land (Trial)” (GB15618—2018) and “Soil Environmental Quality Risk Control Standard for Soil Contamination of Construction Land (Trial)” (GB36600—2018). For forest land, shrub land, other woodlands, other grasslands, other orchards, and bare land with weak human activity impacts, topsoil heavy metal pollution risk was assessed by using the single−factor pollution index and the Nemerow comprehensive pollution index, with subsoil metal content as the background. The heavy metal sources were analyzed using correlation analysis, factor analysis, and the Absolute Principal Component−Multiple Linear Regression (APCS−MLR) model.
    Results The average content of heavy metals in topsoil and subsoil was both significantly higher than the corresponding national background values. The average content of heavy metal elements in karst soil were significantly higher than that in non-karst soil. The risk assessment for paddy fields, dry land, orchards, and towns showed that the dry land posed the highest pollution risk. In dry land, 33.59% of soil samples exceeded Cd pollution risk screening value. The risk assessment for forest land, shrub land, other woodlands, other grasslands, other orchards, and bare land showed that pollution by heavy metals other than Cd was largely absent or mild. The proportions of samples with mild, moderate and severe Cd pollution were 15.06%, 19.20% and 10.74%, respectively. Topsoil heavy metals in the study area originated from soil parent material and anthropogenic sources, contributing 78.58% and 21.42%, respectively.
    Conclusion Soil heavy metals in the study area exhibited high content. Cd was the primary pollution prevention and control element in the study area. The heavy metal content was primarily controlled by the geological background, with human activities contributing to their further accumulation.

     

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