Research progress in the geological characteristics and material sources of fluorite deposits in the Heyu-Checun area, western Henan Province
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摘要: 通过对豫西合峪—车村地区30余个萤石矿床的地质矿产、勘查地球化学资料进行归纳分析,总结区内萤石矿床类型、空间分布及地球化学特征,探究矿床成因和物质来源。合峪—车村地区萤石矿类型主要为单一型,矿床分布于燕山期花岗岩及其外接触带的断裂带上;合峪岩体形成年龄为124.7~148.2 Ma,太山庙岩体形成年龄为115~123.1 Ma,萤石成矿年龄为120~126.8 Ma,说明成矿作用发生在合峪岩体侵入末期、太山庙岩体侵入早期。成矿流体属中低温、低盐度、低密度的NaCl-H2O体系,指示区内矿床为中低温浅成热液型萤石矿床。区内萤石稀土元素配分模式可分为略微左倾型、平坦型及右倾型3类,以右倾型为主,且右倾型萤石稀土元素配分模式与燕山期花岗岩相似,二者均表现为强Eu负异常和弱Ce负异常,说明燕山期花岗岩对萤石的形成提供了一定的物质来源。成矿元素F可能主要来源于合峪岩体和太山庙岩体,成矿元素Ca部分来源于花岗岩围岩。Abstract: Based on the data on the geology, minerals, exploration, and geochemistry of more than 30 fluorite deposits in the Heyu-Checun area, western Henan Province, this study summarized the types, spatial distribution, and geochemical characteristics of fluorite deposits in the area and explored the genesis and material sources of the deposits. The fluorite deposits in this area have simple types and are distributed in Yanshanian granites and along the fault zone of the external contact zone of the granites. The formation ages of the Heyu and Taishanmiao plutons are 124.7~148.2 Ma and 115~123.1 Ma, respectively. The mineralized age of fluorites is 120~126.8 Ma, indicating that the mineralization occurred in the late stage of the intrusion of the Heyu pluton and the early stage of the intrusion of the Taishanmiao pluton. The ore-forming fluids belong to the NaCl-H2O system with a medium-low temperature, a low salinity, and a low density, indicating that the deposits in the area are medium-low-temperature supergene hydrothermal fluorite deposits. The chondrite-normalized REE patterns of fluorites in the area can be divided into slightly leftward, flat, and rightward types dominated by the rightward type. Moreover, the rightward chondrite-normalized REE patterns of fluorites are similar to those of the Yanshanian granites, both showing strongly negative Eu anomalies and weakly negative Ce anomalies. This finding indicates that the Yanshanian granites provide materials for the formation of fluorites. The metallogenic element F may mainly originate from the Heyu and Taishanmiao plutons, while the metallogenic element Ca partly comes from granites as surrounding rocks.
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Key words:
- geological characteristics /
- material sources /
- fluorite /
- Heyu-Checun
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[1] 赵鹏, 郑厚义, 张新, 等. 中国萤石产业资源现状及发展建议[J]. 化工矿产地质, 2020, 42(2):178-183.
[2] Zhao P, Zheng H Y, Zhang X, et al. Resource actualities and demand countermeasures of fluorite in China[J]. Geology of Chemical Minerals, 2020, 42(2):178-183.
[3] 王吉平, 商朋强, 熊先孝, 等. 中国萤石矿床分类[J]. 中国地质, 2014, 41(2):315-325.
[4] Wang J P, Shang P Q, Xiong X X, et al. The classification of fluorite deposits in China[J]. Geology in China, 2014, 41(2):315-325.
[5] 王吉平, 商朋强, 熊先孝, 等. 中国萤石矿床成矿规律[J]. 中国地质, 2015, 42(1):18-32.
[6] Wang J P, Shang P Q, Xiong X X, et al. Metallogenic regularities of fluorite deposits in China[J]. Geology in China, 2015, 42(1):18-32.
[7] 胡呈祥. 河南嵩县南坪地区萤石矿地质特征及成因[J]. 现代矿业, 2016, 32(6):165-168.
[8] Hu C X. Geological characteristics and genesis of fluorite deposits in Nanping area,Songxian,Henan province[J]. Modern Mining, 2016, 32(6):165-168.
[9] 邓红玲, 张苏坤, 汪江河, 等. 河南省栾川县杨山萤石矿床地质特征及成因研究[J]. 中国非金属矿工业导刊, 2017(3):37-40.
[10] Deng H L, Zhang S K, Wang J H, et al. Geological characteristics and genesis of the Yangshanfluorite deposit in Luanchuan,Henan province[J]. China Non-metallic Minerals Industry, 2017(3):37-40.
[11] 席晓凤, 吴林涛, 马珉艺. 杨山萤石矿矿床地质特征及围岩稀土元素地球化学特征[J]. 中国矿业, 2018, 27(S1):147-150.
[12] Xi X F, Wu L T, Ma M Y. Geological characteristics and rare earth element geochemistry of Yangshan fluorite ore[J]. China Mining Magazine, 2018, 27(S1):147-150.
[13] 冯绍平, 汪江河, 刘耀文, 等. 豫西杨山萤石矿稀土元素地球化学特征及其指示意义[J]. 稀土, 2020, 41(5):50-58.
[14] Feng S P, Wang J H, Liu Y W, et al. Geochemical characteristics and indicative significance of rare earth elements in Yangshan fluorite deposit in western Henan province[J]. Chinese Rare Earths, 2020, 41(5):50-58.
[15] 赵玉. 河南栾川马丢萤石矿地质地球化学特征及成因探讨[D]. 北京: 中国地质大学(北京), 2016.
[16] Zhao Y. Geochemistry characteristics and genesis of Madiu fluorite deposits in Luanchuan region,Henan[D]. Beijing: China University of Geosciences(Beijing), 2016.
[17] 赵玉, 张寿庭, 裴秋明, 等. 河南栾川马丢萤石矿床流体包裹体研究[J]. 矿物学报, 2015, 35(S1):649.
[18] Zhao Y, Zhang S T, Pei Q M, et al. Study on fluid inclusions of Madiu fluorite deposit in Luanchuan,Henan province[J]. Acta Mineralogica Sinica, 2015, 35(S1):649.
[19] 庞绪成, 司媛媛, 刘纪峰, 等. 河南嵩县康达萤石矿Sm-Nd同位素年龄及地质意义[J]. 矿物岩石地球化学通报, 2019, 38(3):534-538.
[20] Pang X C, Si Y Y, Liu J F, et al. Sm-Nd isotopic dating and geological significance of Kangda fluorite deposit in Songxian County of Henan Province[J]. Bulletin of Mineralogy,Petrology and Geochemistry, 2019, 38(3):534-538.
[21] 庞绪成, 董文超, 李文明, 等. 河南省嵩县萤石矿控矿因素及成矿机理研究报告[R]. 焦作: 河南理工大学, 2018.
[22] Pang X C, Dong W C, Li W M, et al. Research report on ore controlling factors and metallogenic mechanism of fluorite deposit in Songxian,Henan province[R]. Jiaozuo: Henan Polytechnic University, 2018.
[23] 杨东潮, 孟芳, 白德胜, 等. 河南省洛阳市合峪地区萤石矿整装勘查报告[R]. 郑州: 河南省地质矿产勘查开发局第二地质矿产调查院, 2021.
[24] Yang D C, Meng F, Bai D S, et al. Report on the whole loading exploration of fluorite ore in Heyu area,Luoyang City, Henan Province[R]. Zhengzhou: No.2 Institute of Geological & Mineral Resources Survey of Henan, 2021.
[25] 张宗清, 张国伟, 唐索寒. 南秦岭变质地层同位素年代学[M]. 北京: 地质出版社, 2002.
[26] Zhang Z Q, Zhang G W, Tang S H. Isotopic geochronology of metamorphic strata in South Qinling[M]. Beijing: Geological Publishing House, 2002.
[27] 李永峰. 豫西熊耳山地区中生代花岗岩类时空演化与钼(金)成矿作用[D]. 北京: 中国地质大学, 2005.
[28] Li Y F. The temporal-spital evolution of Mesozoid granitoids in the Xiong’ershan area and their relationships to molybdenum-gold mineralization[D]. Beijing: China University of Geosciences, 2005.
[29] Han Y G, Zhang S H, Franco P, et al. Evolution of the Mesozoic granites in the Xiong'ershan-Waifangshan Region,Western Henan Province,China,and its tectonic implications[J]. Acta Geologica Sinica, 2007, 81(2):253-265.
[30] 郭波, 朱赖民, 李犇, 等. 华北陆块南缘华山和合峪花岗岩岩体锆石U-Pb年龄、Hf同位素组成与成岩动力学背景[J]. 岩石学报, 2009, 25(2):265-281.
[31] Guo B, Zhu L M, Li B, et al. Zircon U-Pb age and Hf isotope composition of the Huashan and Heyu granite plutons at the southern margin of North China Craton:Implications for geodynamic setting[J]. Acta Petrologica Sinica, 2009, 25(2):265-281.
[32] 高昕宇, 赵太平, 原振雷, 等. 华北陆块南缘中生代合峪花岗岩的地球化学特征与成因[J]. 岩石学报, 2010, 26(12):3485-3506.
[33] Gao X Y, Zhao T P, Yuan Z L, et al. Geochemistry and petrogenesis of the Heyu batholith in the southern margin of the North China block[J]. Acta Petrologica Sinica, 2010, 26(12):3485-3506.
[34] 李春艳, 吕宪河, 李瑞强, 等. 河南1︰5万合峪(I49E013016) 、木植街(I49E013017)、栗树街(I49E014016)、车村(I49E014017)、二郎庙幅(I49E014018) 区域地质矿产调查报告[R].郑州: 河南省地质调查院, 2016.
[35] Li C Y, Lyu X H, Li R Q, et al. 1:50 000 regional geological and mineral survey report of Heyu(I49E013016),Muzhijie(I49E013017),Lishujie(I49E014016),Checun(I49E014017) and Erlaongmiao(I49E014018)in Henan Province[R].Zhegzhou:Henan Geological Survey Institute, 2016.
[36] Bao Z W, Xiong M F, Li Q. Mo-rich source and protracted crystallization of Late Mesozoic granites in the East Qinling porphyry Mo belt (central China):Constraints from zircon U/Pb ages and Hf-O isotopes[J]. Journal of Asian Earth Sciences, 2018, 160:322-333.
[37] 叶会寿, 毛景文, 徐林刚, 等. 豫西太山庙铝质A型花岗岩SHRIMP锆石U-Pb年龄及其地球化学特征[J]. 地质论评, 2008, 54(5):699-711.
[38] Ye H S, Mao J W, Xu L G, et al. SHRIMP zircon U-Pb dating and geochemistry of the Taishanmiao aluminous type granite in Western Henan Province[J]. Geological Review, 2008, 54(5):699-711.
[39] 高昕宇. 华北克拉通南缘外方山和伏牛山地区早白垩世花岗岩成因研究[D]. 广州: 中国科学院大学, 2012.
[40] Gao X Y. Geochemistry,geochronology and petrogenesis of early Cretaceous granites in the southern margin of the NorthChina Craton[D]. Guangzhou: University of Chinese Academy of Sciences, 2012.
[41] 齐玥. 东秦岭地区晚中生代老君山岩体和太山庙岩体成因[D]. 北京: 中国科学技术大学, 2014.
[42] Qi Y. Petrogenesis of Laojunshan and Taishanmiao granite plutons in eastern Qinling,central China[D]. Beijing: University of Science and Technology of China, 2014.
[43] 刘纪峰, 白德胜, 张凯涛, 等. 豫西陈楼萤石矿床地质特征及Sm-Nd同位素年龄[J]. 矿物岩石, 2020, 40(1):69-75.
[44] Liu J F, Bai D S, Zhang K T, et al. Geological characteristics and Sm-Nd isotopic age of Chenlou fluorite deposit,Western Henan Province[J]. Mineralogy and Petrology, 2020, 40(1):69-75.
[45] 李文明. 豫西南陈楼萤石矿地质地球化学特征及深部远景[D]. 焦作: 河南理工大学, 2018.
[46] Li W M. Geological-geochemical characteristics and deep metallogenic prospect of fluorite depositin Chenlou,southwest Henan Province[D]. Jiaozuo: Henan Polytechnic University, 2018.
[47] 庞绪成, 李文明, 刘纪峰, 等. 河南省嵩县陈楼萤石矿流体包裹体特征及其地质意义[J]. 河南理工大学学报:自然科学版, 2019, 38(1):45-53.
[48] Pang X C, Li W M, Liu J F, et al. Fluid inclusion and geological significance of Chenlou fluorite deposit in Songxian county,Henan province[J]. Journal of Henan Polytechnic University:Natural Science, 2019, 38(1) :45-53.
[49] 席晓凤, 吴林涛, 张林飞. 马丢萤石矿矿床地质特征及围岩稀土元素地球化学特征[J]. 中国矿业, 2019, 28(Z2):272-274.
[50] Xi X F, Wu L T, Zhang L F. Geological characteristics and REE geochemistry of Madiu fluorite deposit[J]. China Mining Magazine, 2019, 28(Z2):272-274.
[51] 董文超, 庞绪成, 司媛媛, 等. 河南嵩县车村萤石矿床稀土元素特征及地质意义[J]. 中国稀土学报, 2020, 38(5):706-714.
[52] Dong W C, Pang X C, Si Y Y, et al. REE geological characteristics of Checun fluorite deposit in Song county,Henanprovince[J]. Journal of the Chinese Society of Rare Earths, 2020, 38(5):706-714.
[53] 王建其, 朱赖民, 郭波, 等. 华北陆块南缘华山、老牛山及合峪花岗岩体Sr-Nd,Pb同位素组成特征及其地质意义[J]. 矿物岩石, 2015, 35(1):63-72.
[54] Wang J Q, Zhu L M, Guo B, et al. Characteristics of Sr-Nd and Pb isotopic composition and its geological significance of granitic plutons inthe Huashan,Laoniushan and Heyu area at the southern margin of north China Craton[J]. Mineralogy and Petrology, 2015, 35(1):63-72.
[55] 曹俊臣. 华南低温热液脉状萤石矿床稀土元素地球化学特征[J]. 地球化学, 1995, 24(3):225-234.
[56] Cao J C. REE geochemical characteristics of epithermal vein fluorite deposits in south China[J]. Geochimica, 1995, 24(3):225-234.
[57] 曹俊臣. 热液脉型萤石矿床萤石气液包裹体氢、氧同位素特征[J]. 地质与勘探, 1994, 30(4):28-29.
[58] Cao J C. Hydrogen and oxygen isotopic characteristics of fluorite gas liquid inclusions in hydrothermal vein fluorite deposits[J]. Geology and Exploration, 1994, 30(4):28-29.
[59] 周珂. 豫西鱼池岭斑岩型钼矿床的地质地球化学特征与成因研究[D]. 北京: 中国地质大学(北京), 2008.
[60] Zhou K. Geology,geochemisty and metallogenesis of theYuchiling porphyry Molybdenum deposit,westernHenan province[D]. Beijing: China University of Geosciences(Beijing), 2008.
[61] 史长义, 鄢明才, 刘崇民, 等. 中国不同岩石类型花岗岩类元素丰度及特征[J]. 物探化探计算技术, 2005, 27(3):256-262.
[62] Shi C Y, Yan M C, Liu C M, et al. Abundances of chemical elements indifeerent rock types of the granetoids of china and its characteristics[J]. Computing Techniques for Geophysical and Geochemical Exploration, 2005, 27(3):256-262.
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