新疆阿尔金喀腊大湾地区拉配泉组流纹岩年龄和地球化学特征及其对阿尔金北缘构造演化的启示

武彬; 王爱国; 彭博; 王继龙; 张艺武; 鲍晓明; 叶现韬; 于俊杰

doi:10.12097/j.issn.1671-2552.2023.11.008

新疆阿尔金喀腊大湾地区拉配泉组流纹岩年龄和地球化学特征及其对阿尔金北缘构造演化的启示

1.
中国地质调查局南京地质调查中心, 江苏南京 210016

2.
河海大学海洋学院, 江苏南京 210098

基金项目:
国家科技支撑计划项目《甜水海-塔什库尔干地块基底演化与成矿》（编号：2015BAB05B01-02）

详细信息

作者简介: 武彬(1982-), 男, 硕士, 高级工程师, 从事矿产地质调查与研究。E-mail: 119825061@qq.com

通讯作者: 于俊杰(1983-), 男, 正高级工程师, 从事基础地质调查研究。E-mail: 25320701@qq.com

中图分类号: P588.14⁺1;P597⁺.3

收稿日期: 2021-07-30

修回日期: 2021-12-27

刊出日期: 2023-11-15

Chronology and geochemical characteristics of the Lapeiquan Formation rhyolite in the Altun Kaladawan area, Xinjiang, and implications for tectonic evolution of the northern margin of Altun

1.
Nanjing Center, China Geological Survey, Nanjing 210016, Jiangsu, China

2.
College of Oceanography, Hohai University, Nanjing 210098, Jiangsu, China

More Information

Corresponding author: YU Junjie, 25320701@qq.com

Received Date: 30 July 2021

Revised Date: 27 December 2021

Publish Date: 15 November 2023

摘要

摘要:
由于新疆阿尔金拉配泉组研究程度较低，其沉积时代及构造成因仍存在疑问。以拉配泉组流纹岩为研究对象，开展年代学、地球化学等方面的研究。LA-ICP-MS锆石U-Pb测年结果显示，拉配泉组二段流纹岩年龄为497±2.0 Ma、三段流纹岩年龄为483.4±1.9 Ma。岩石地球化学研究显示，样品具有富硅（70.07%~78.55%）、低镁（0.32%~0.58%）、低Mg^#（24~30）等特征。稀土元素分析结果显示，样品呈现富集轻稀土元素，相对亏损重稀土元素的特征，（La/Yb）_N=10.23~12.73，负Eu异常明显（δEu=0.10~0.19）；微量元素分析结果显示，样品明显富集La、Nd、Zr、Ce、Sm、U、Th、Hf等，相对亏损Sr、Nb、Ti等。结合前人研究成果，厘定拉配泉组沉积时代为晚寒武世—早奥陶世。二段流纹岩具有A型花岗岩特征，可能主要来源于地壳物质的部分熔融，构造环境为北阿尔金洋回转引起的弧后伸展环境。
- 拉配泉组 /
- 流纹岩 /
- U-Pb年龄 /
- 地球化学 /
- 阿尔金
Abstract:
Due to the low level studies on the Altun Lapeiquan Formation in Xinjiang, its depositional age and tectonic genesis are still in doubt.Chronological and geochemical studies were carried out on the rhyolites of the Lapeiquan Formation.The results of zircon LA-ICP-MS U-Pb dating show that the ages of the second and third member rhyolites of the Lapaiquan Formation are 497±2.0 Ma and 483.4±1.9 Ma, respectively.The petrogeochemical studies show that the samples are Si-rich(70.07%~78.55%), Mg-poor(0.32%~0.58%), and Mg^#-low(24~30).The rare earth elements exhibit the characteristics of enrichment of light rare earth elements and relatively deficient in heavy rare earth elements((La/Yb)_N=10.23~12.73), and the negative Eu is abnormally obvious(δEu=0.10~0.19);the analysis of trace elements shows that the samples are obviously enriched in La, Nd, Zr, Ce, Sm, U, Th, Hf, etc., and relatively deficient in Sr, Nb, Ti, etc.Combined with the previous researches, the depositional age of the Lapeiquan Formation is determined to be Late Cambrian-Early Ordovician.The second member of rhyolite has the characteristics of A-type granite, and it most likely came from partial melting of crustal materials, and the tectonic environment is a post-arc extensional environment caused by the reversal of the North Altun Ocean.
- Lapeiquan Formation /
- rhyolite /
- U-Pb dating /
- geochemistry /
- Altun

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图 1 区域构造单元划分(a)和新疆喀腊大湾地质简图(b)(据陈宣华等，2009)

Figure 1.

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图 2 拉配泉组二段流纹岩原位及镜下(正交)照片(a、b)和三段流纹岩原位及镜下(正交)照片(c、d)

Figure 2.

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图 3 拉配泉组二段(a、b)、三段(c、d)流纹岩锆石阴极发光(CL)图像及锆石U-Pb谐和图

Figure 3.

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图 4 拉配泉组流纹岩TAS(a)和SiO₂-K₂O图解(b)(底图据Le，1984)

Figure 4.

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图 5 拉配泉组流纹岩A/CNK-A/NK(a)和AR-SiO₂(b)图解

Figure 5.

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图 6 拉配泉组流纹岩稀土元素配分图(a)和微量元素蛛网图(b)(标准化值据Sun et al., 1989)

Figure 6.

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图 7 拉配泉组流纹岩Zr+Nb+Ce+Y-(Na₂O+K₂O)/CaO(a)和10000 Ga/Al-Zr(b)图解(据Whalen et al., 1987)

Figure 7.

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图 8 拉配泉组流纹岩Zr-Zr/Sm(a，据Schiano et al., 2010)和C/MF-A/MF(b，据Altherr et al., 2000)图解

Figure 8.

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图 9 拉配泉组流纹岩A₁、A₂类型判别图(据Eby，1992)

Figure 9.

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图 10 拉配泉组流纹岩(Y+Nb)-Rb(a)与Y-Nb(b)图解(据Pearce et al., 1984)

Figure 10.

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表 1 拉配泉组二段、三段流纹岩LA-ICP-MS锆石U-Th-Pb测试结果

Table 1. Zircon LA-ICP-MS U-Th-Pb dating result of the second and third members of rhyolite of the Lapeiquan Formation

编号	含量/10^-6			Th/U	同位素比值						年龄/Ma
编号	Pb	U	Th	Th/U	²⁰⁶Pb/²³⁸U	1σ	²⁰⁷Pb/²³⁵U	1σ	²⁰⁷Pb/²⁰⁶Pb	1σ	²⁰⁷Pb/²⁰⁶Pb	1σ	²⁰⁶Pb/²³⁸U	1σ
2-1	80	925	771	0.8339	0.0801	0.0009	0.6158	0.0122	0.0557	0.0010	442	40	497	6
2-2	243	2620	3006	1.1472	0.0809	0.0009	0.6341	0.0116	0.0568	0.0009	484	36	502	6
2-3	92	1058	897	0.8472	0.0800	0.0009	0.6296	0.0116	0.0571	0.0010	495	37	496	6
2-4	128	1443	1418	0.9823	0.0808	0.0009	0.6363	0.0118	0.0571	0.0009	496	37	501	6
2-5	149	1663	1869	1.1239	0.0802	0.0009	0.6202	0.0116	0.0561	0.0009	455	37	498	6
2-6	53	623	443	0.7105	0.0814	0.0010	0.6350	0.0171	0.0566	0.0012	476	48	504	6
2-7	122	1320	1750	1.3258	0.0813	0.0009	0.6249	0.0118	0.0558	0.0010	443	38	504	6
2-8	93	1122	721	0.6422	0.0813	0.0009	0.6309	0.0118	0.0563	0.0010	463	38	504	6
2-9	55	670	432	0.6452	0.0801	0.0010	0.6334	0.0126	0.0574	0.0010	505	40	497	6
2-10	87	1054	806	0.7645	0.0797	0.0009	0.6195	0.0115	0.0564	0.0010	466	38	495	5
2-11	78	907	844	0.9299	0.0802	0.0009	0.6245	0.0121	0.0565	0.0010	472	39	497	6
2-12	99	1154	1013	0.8776	0.0808	0.0010	0.6177	0.0118	0.0555	0.0009	430	38	501	6
2-13	524	6685	3836	0.5738	0.0820	0.0009	0.6457	0.0114	0.0571	0.0009	496	36	508	5
2-14	102	1174	1053	0.8970	0.0811	0.0009	0.6502	0.0121	0.0582	0.0010	536	37	503	6
2-15	131	1470	1511	1.0278	0.0812	0.0009	0.6754	0.0123	0.0603	0.0010	615	36	503	5
2-16	55	663	452	0.6816	0.0809	0.0009	0.6205	0.0120	0.0556	0.0010	438	40	501	6
2-17	179	1996	2128	1.0662	0.0805	0.0009	0.6685	0.0123	0.0603	0.0010	613	36	499	6
2-18	107	1226	1223	0.9975	0.0817	0.0010	0.6883	0.0126	0.0611	0.0010	642	37	506	6
2-19	124	1415	1540	1.0882	0.0798	0.0009	0.6031	0.0110	0.0548	0.0009	405	37	495	5
2-20	142	1695	1593	0.9402	0.0782	0.0009	0.6063	0.0109	0.0562	0.0009	461	37	486	5
2-21	81	978	719	0.7354	0.0797	0.0009	0.6105	0.0117	0.0556	0.0010	435	39	494	6
2-22	50	603	391	0.6479	0.0802	0.0009	0.6104	0.0124	0.0552	0.0010	420	42	497	6
2-23	76	924	780	0.8441	0.0782	0.0008	0.6054	0.0116	0.0562	0.0010	460	40	485	5
2-24	142	1622	1721	1.0609	0.0798	0.0009	0.6289	0.0115	0.0571	0.0010	497	37	495	6
2-25	141	2072	3997	1.9291	0.0666	0.0007	0.5835	0.0105	0.0636	0.0011	727	37	415	4
2-26	64	779	494	0.6346	0.0798	0.0008	0.7140	0.0149	0.0649	0.0013	770	41	495	5
2-27	84	1050	552	0.5257	0.0798	0.0009	0.6214	0.0117	0.0565	0.0010	471	38	495	6
2-28	187	2098	2777	1.3238	0.0791	0.0008	0.6113	0.0109	0.0560	0.0009	454	37	491	5
2-29	127	1486	1399	0.9414	0.0801	0.0009	0.6255	0.0113	0.0566	0.0009	477	37	497	5
2-30	101	1136	1298	1.1429	0.0805	0.0009	0.6899	0.0135	0.0622	0.0011	681	36	499	6
2-31	127	1480	1573	1.0625	0.0789	0.0009	0.6184	0.0114	0.0568	0.0010	486	37	489	5
3-1	42	541	313	0.5783	0.0769	0.0008	0.6256	0.0108	0.0590	0.0009	567	34	478	5
3-2	61	552	338	0.6127	0.0905	0.0011	1.7886	0.0377	0.1433	0.0023	2267	28	559	7
3-3	56	698	444	0.6366	0.0776	0.0009	0.6587	0.0160	0.0616	0.0012	659	42	482	5
3-4	54	669	420	0.6277	0.0783	0.0009	0.6266	0.0105	0.0580	0.0009	531	32	486	5
3-5	62	763	520	0.6823	0.0778	0.0008	0.6297	0.0105	0.0587	0.0009	556	32	483	5
3-6	44	545	339	0.6215	0.0773	0.0009	0.6865	0.0133	0.0644	0.0010	755	34	480	6
3-7	49	603	359	0.5956	0.0784	0.0009	0.6569	0.0113	0.0608	0.0009	631	32	487	5
3-8	49	623	341	0.5477	0.0769	0.0008	0.6063	0.0103	0.0572	0.0009	499	33	478	5
3-9	42	543	282	0.5192	0.0766	0.0008	0.6186	0.0103	0.0585	0.0009	550	33	476	5
3-10	35	434	243	0.5603	0.0783	0.0009	0.6126	0.0108	0.0568	0.0009	483	35	486	5
3-11	59	707	457	0.6468	0.0785	0.0009	0.7416	0.0200	0.0685	0.0015	884	45	487	6
3-12	58	701	404	0.5764	0.0791	0.0008	0.7493	0.0121	0.0687	0.0011	891	32	490	5
3-13	41	509	275	0.5398	0.0788	0.0009	0.6216	0.0107	0.0572	0.0009	499	34	489	5
3-14	44	541	319	0.5883	0.0783	0.0008	0.6272	0.0106	0.0581	0.0009	533	35	486	5
3-15	59	743	451	0.6075	0.0779	0.0008	0.6172	0.0106	0.0575	0.0009	509	33	484	5
3-16	55	683	417	0.6095	0.0784	0.0009	0.6246	0.0105	0.0578	0.0009	521	34	487	5
3-17	62	774	497	0.6424	0.0774	0.0008	0.6642	0.0119	0.0623	0.0010	683	33	480	5
3-18	37	467	223	0.4783	0.0780	0.0009	0.6285	0.0112	0.0584	0.0010	546	36	484	5
3-19	47	596	322	0.5402	0.0779	0.0009	0.6289	0.0105	0.0585	0.0009	550	34	484	5
3-20	39	487	252	0.5185	0.0785	0.0009	0.6325	0.0111	0.0584	0.0009	546	35	487	5
3-21	55	686	406	0.5914	0.0776	0.0009	0.6311	0.0104	0.0590	0.0009	567	34	482	5
3-22	38	487	236	0.4847	0.0781	0.0008	0.6337	0.0111	0.0589	0.0010	562	36	485	5
3-23	67	833	550	0.6595	0.0775	0.0009	0.6287	0.0104	0.0588	0.0009	560	33	481	5
3-24	52	657	356	0.5421	0.0780	0.0009	0.6278	0.0112	0.0584	0.0009	544	34	484	5
3-25	51	655	379	0.5788	0.0765	0.0008	0.6296	0.0111	0.0597	0.0010	592	35	475	5
3-26	57	719	392	0.5451	0.0787	0.0009	0.6240	0.0105	0.0575	0.0009	512	33	488	5
3-27	49	621	404	0.6506	0.0770	0.0008	0.6002	0.0102	0.0565	0.0009	474	34	478	5
3-28	36	461	243	0.5263	0.0787	0.0009	0.6383	0.0109	0.0588	0.0009	560	34	488	5
3-29	32	421	177	0.4208	0.0781	0.0008	0.6038	0.0111	0.0560	0.0010	454	38	485	5
3-30	58	737	473	0.6415	0.0775	0.0008	0.6697	0.0112	0.0627	0.0009	697	32	481	5
3-31	40	514	247	0.4809	0.0782	0.0008	0.6328	0.0115	0.0587	0.0010	557	35	485	5

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表 2 拉配泉组二段流纹岩主量、微量和稀土元素分析结果

Table 2. Major, trace and rare earth element analytical data of the rhyolite in the second member of the Lapeiquan Formation

元素	D1101H1	D1101H2	D1101H3	D1101H4	D1101H5	D1101H6	D1101H7	D1101H8
SiO₂	75.83	72.25	74.17	78.55	74.70	71.16	70.07	74.44
Al₂O₃	11.75	14.17	12.26	10.25	12.38	13.86	14.38	12.59
CaO	0.98	1.46	1.87	0.75	1.10	2.60	2.54	1.70
MgO	0.36	0.46	0.43	0.32	0.58	0.51	0.53	0.48
K₂O	4.05	1.91	4.22	4.72	2.79	1.85	1.57	1.69
Na₂O	3.45	5.86	2.97	2.27	4.25	5.29	5.97	5.06
TiO₂	0.16	0.17	0.16	0.15	0.17	0.18	0.17	0.19
P₂O₅	0.021	0.019	0.024	0.020	0.021	0.022	0.024	0.022
MnO	0.037	0.050	0.053	0.034	0.053	0.069	0.064	0.053
烧失量	0.66	0.65	0.93	0.54	0.74	0.89	1.18	0.85
TFe₂O₃	2.10	2.47	2.54	1.94	2.72	3.25	3.07	2.58
BaO	0.15	0.07	0.18	0.19	0.12	0.07	0.06	0.06
总量	99.55	99.54	99.81	99.73	99.62	99.75	99.63	99.72
K₂O/Na₂O	0.85	3.07	0.70	0.48	1.52	2.86	3.80	2.99
FeO/MgO	5.25	4.83	5.32	5.46	4.22	5.74	5.21	4.84
A/NK	1.17	1.21	1.30	1.16	1.24	1.30	1.25	1.24
A/CNK	0.99	0.99	0.95	1.00	1.03	0.90	0.89	0.95
分异指数DI	91.68	88.80	87.23	92.92	89.28	84.18	84.91	88.12
Mg^#	25.35	26.95	25.11	24.62	29.69	23.71	25.48	26.93
Li	1.58	1.55	1.92	1.22	1.89	1.27	1.62	1.48
Be	2.73	3.70	1.83	2.38	2.76	4.21	4.06	2.71
Sc	4.57	5.3	4.88	3.97	4.97	4.91	5.32	5.15
V	1.64	2.94	2.54	1.53	2.66	2.99	2.72	2.36
Cr	2.03	5	4.4	6.23	6.73	4.83	6.16	5.25
Co	164	126	174	181	152	124	99.5	134
Ni	7.59	5.68	7.26	10.6	11.3	6.51	5.35	5.29
Cu	1.14	1.14	1.95	1.28	1.93	1.35	1.61	1.07
Zn	60.7	80.5	61.9	61.2	85.6	76.2	79.3	59.4
Ga	14.9	19.4	21.3	12.2	17.2	25.3	22.3	18.7
Ge	1.14	1.37	1.66	0.886	1.24	2.06	1.68	1.59
As	0.99	1.14	1.39	1.14	1.12	1.60	1.53	1.33
Rb	92.9	46.4	96.1	89.2	67.5	47.1	44.5	44.1
Sr	92	182	181	74.4	124	286	249	172
Y	47.10	53.89	61.01	41.95	58.38	62.87	60.68	57.83
Zr	304	332	306	279	343	325	321	349
Nb	19.62	20.99	19.85	18.86	22.90	22.21	21.53	23.28
Sb	0.66	0.60	0.92	0.57	0.55	1.39	1.14	0.83
Ba	1470	679	1720	1830	1100	683	484	554
Nb/Ta	11.43	12.36	11.71	11.62	12.57	13.02	13.44	13.04
Rb/Nb	4.74	2.21	4.84	4.73	2.95	2.12	2.07	1.89
Rb/Sr	1.01	0.25	0.53	1.20	0.54	0.16	0.18	0.26
Sr/Y	1.95	3.38	2.97	1.77	2.12	4.55	4.10	2.97
La	62.1	71.4	62.5	57.3	72.2	66	62.3	70.5
Ce	107	113	111	103	122	120	111	124
Pr	12.5	13.5	12.5	11.2	14.3	13.4	12.3	14
Nd	45.3	49.3	46.7	42.1	52.5	50.2	45.2	51.4
Sm	8.29	9.28	9.31	8.08	9.56	9.56	8.52	9.99
Eu	0.96	1.22	1.74	0.79	1.14	1.44	1.32	1.14
Gd	8.18	8.66	9.23	8.26	9.29	9.52	8.75	9.37
Tb	1.28	1.44	1.48	1.16	1.52	1.56	1.42	1.54
Dy	7.7	8.82	9.29	7.26	9.37	9.94	9.39	9.18
Ho	1.53	1.79	1.85	1.4	1.98	2.11	1.94	1.96
Er	4.88	5.64	5.88	4.38	6	6.53	6.04	6
Tm	0.71	0.81	0.78	0.66	0.90	0.91	0.84	0.90
Yb	4.88	5.76	5.9	4.64	6.27	6.39	6.09	6.32
Lu	0.73	0.85	0.84	0.66	0.93	0.88	0.91	0.90
Hf	7.88	8.62	8.16	7.48	8.7	8.48	8.75	9.03
Ta	1.72	1.70	1.70	1.62	1.82	1.71	1.60	1.79
W	958	737	1080	1130	936	835	611	843
Pb	6.81	5.62	8.47	6.04	5.57	8.62	6.96	5.72
Th	23.5	24.8	23.3	21.4	26	24.8	23.9	26.7
U	5.87	7.25	8.19	4.82	7.01	7.83	7.6	6.92
LREE	283.25	311.59	304.77	264.42	330.08	323.48	301.32	328.87
HREE	29.88	33.76	35.25	28.42	36.27	37.84	35.38	36.17
∑REE	313.14	345.36	340.02	292.84	366.34	361.31	336.70	365.04
LREE/HREE	9.48	9.23	8.65	9.30	9.10	8.55	8.52	9.09
(La/Yb)_N	12.73	12.40	10.59	12.35	11.52	10.33	10.23	11.16
δEu	0.12	0.14	0.19	0.10	0.12	0.15	0.15	0.12
T_Zr/℃	847	847	842	845	862	833	828	862
注：主量元素含量单位为%，微量、稀土元素含量单位为10^-6；A/NK= Al₂O₃ /(Na₂O+ K₂O); A/CNK= Al₂O₃ /(GaO+ Na₂O+ K₂O); DI=Qz+Qr+Ab+Ne+Lc+Kp；Mg^#=100*(MgO/40.3044)/(MgO/40.3044+ TFeO/71.844)；δEu=2Eu/(Sm+Gd); T_Zr/℃计算据Watson et al.(1983)温度计算公式

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