ZIRCON U-Pb DATING OF MONZOGRANITE DIKES IN WENGQUANGOU BORON OREFIELD, EASTERN LIAONING: Constraints on Metallogenic Age
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摘要:
辽东地区翁泉沟硼矿区露天采场产出一条切穿硼矿体的二长花岗岩脉.本研究采集了该二长花岗岩脉的薄片、化学分析样品,并进行锆石LA-ICP-MSU-Pb年代学测试分析.该二长花岗岩脉具有高SiO2含量,为71.82%~75.68%,较高的Na2O+K2O含量,为8.41%~10.57%,属钙碱性-高钾钙碱性系列花岗岩.岩脉中锆石颗粒呈自形柱状,CL图中较黑,因铀含量较高引起.U-Pb上交点年龄为1842±29Ma,其中9个测点得出1842±30Ma的加权平均年龄,反映了该花岗岩脉侵位于古元古代晚期,同时翁泉沟硼镁铁矿成矿应早于该时代.此年龄与前人研究古元古代胶辽吉造山过程中变质作用峰后时间相吻合,反映了古元古代造山作用过程中伴随了硼矿成矿事件.
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关键词:
- 锆石LA-ICP-MS /
- U-Pb年龄 /
- 胶辽吉造山带 /
- 翁泉沟硼镁铁矿 /
- 辽宁省
Abstract:A monzogranite dike cuts through the ludwigite orebody in the open pit of Wengquangou boron deposit, Liaodong Peninsula. Samples of the dike are collected for thin section and zircon LA-ICP-MS U-Pb geochronology analysis. The monzogranite dike is characterized by high SiO2 content(71.82%-75.68%) and high Na2O+K2O content (8.41%-10.57%), belonging to calc alkali-high K calc alkaline series granite. The zircon grains in the dikes are euhedral column in shape and dark in the CL image due to the high uranium content. The U-Pb upper intercept age is 1842±29 Ma, among which 9 testing points yield the weighted average age of 1842±30 Ma, indicating that the emplacement age of dike was Late Paleoproterozoic and the Wengquangou ludwigite deposit should be formed earlier. The age is consistent with the post-peak time of metamorphism in the Paleoproterozoic Jiao-Liao-Ji orogeny, reflecting the boron mineralization occurred during the process.
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Key words:
- zircon LA-ICP-MS /
- U-Pb age /
- Jiao-Liao-Ji orogenic belt /
- Wengquangou ludwigite /
- Liaoning Province
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图 1 辽东半岛翁泉沟硼矿床地质简图(据文献[6]修改)
Figure 1.
图 4 翁泉沟硼矿二长花岗岩岩性系列判别图解(据文献[39]修改)
Figure 4.
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[1] 林秋婷, 陈晨, 刘海洋. 硼的地球化学性质及其在俯冲带的循环与成矿初探[J]. 岩石学报, 2020, 36(1): 5-12. https://www.cnki.com.cn/Article/CJFDTOTAL-YSXB202001002.htm
Lin C T, Chen C, Liu H Y. Boron prospecting based on boron cycling in subduction zone[J]. Acta Petrologica Sinica, 2020, 36(1): 5-12. https://www.cnki.com.cn/Article/CJFDTOTAL-YSXB202001002.htm
[2] 焦森, 郑厚义, 屈云燕, 等. 全球硼矿资源供需形势分析[J]. 国土资源情报, 2020, 27(10): 85-89. doi: 10.3969/j.issn.1674-3709.2020.10.015
Jiao S, Zheng H Y, Qu Y Y, et al. Supply and demand situation of global boron resources[J]. Land and Resources Information, 2020, 27(10): 85-89. doi: 10.3969/j.issn.1674-3709.2020.10.015
[3] 张艳飞, 刘敬党, 肖荣阁, 等. 辽宁后仙峪硼矿区古元古代电气石岩: 锆石特征及SHRIMP定年[J]. 地球科学——中国地质大学学报, 2010, 35(6): 985-999. https://www.cnki.com.cn/Article/CJFDTOTAL-DQKX201006010.htm
Zhang Y F, Liu J D, Xiao R G, et al. The hyalotourmalites of Houxianyu borate deposit in eastern Liaoning: Zircon features and SHRIMP dating[J]. Earth Sciences-Journal of China University of Geosciences, 2010, 35(6): 985-999. https://www.cnki.com.cn/Article/CJFDTOTAL-DQKX201006010.htm
[4] Liu J D, Xiao R G, Zhang Y F, et al. Zircon SHRIMP U-Pb dating of the tourmalinites from boron-bearing series of borate deposits in eastern Liaoning and its geological implications[J]. Acta Geologica Sinica (English Edition), 2012, 86(1): 118-130. doi: 10.1111/j.1755-6724.2012.00616.x
[5] Hu G Y, Li Y H, Fan C F, et al. In situ LA-MC-ICP-MS boron isotope and zircon U-Pb age determinations of Paleoproterozoic borate deposits in Liaoning Province, Northeastern China[J]. Ore Geology Reviews, 2015, 65: 1127-1141. doi: 10.1016/j.oregeorev.2014.09.005
[6] 赵宇霆. 辽宁凤城翁泉沟地区含铀硼铁矿床成岩成矿年代学研究[D]. 北京: 中国地质大学, 2018: 1-85.
Zhao Y T. Diagenetic and metallogenic geochronology of uranium-bearing boron iron deposit in Wengquangou area, Fengcheng, Liaoning Province[D]. Beijing: China University of Geosciences, 2018: 1-85.
[7] 翟明国, 彭澎. 华北克拉通古元古代构造事件[J]. 岩石学报, 2007, 23(11): 2665-2682. doi: 10.3969/j.issn.1000-0569.2007.11.001
Zhai M G, Peng P. Paleoproterozoic events in the North China Craton[J]. Acta Petrologica Sinica, 2007, 23(11): 2665-2682. doi: 10.3969/j.issn.1000-0569.2007.11.001
[8] 李三忠, 韩宗珠, 刘永江, 等. 辽河群区域变质特征及其大陆动力学意义[J]. 地质论评, 2001, 47(1): 9-18. https://www.cnki.com.cn/Article/CJFDTOTAL-DZLP200101001.htm
Li S Z, Han Z Z, Liu Y J, et al. Continental dynamics and regional metamorphism of the Liaohe Group[J]. Geological Review, 2001, 47(1): 9-18. https://www.cnki.com.cn/Article/CJFDTOTAL-DZLP200101001.htm
[9] 孙中任, 赵雪娟, 段会升, 等. 华北板块与西伯利亚板块缝合带之重磁证据[J]. 地质与资源, 2020, 29(5): 461-466. http://manu25.magtech.com.cn/Jweb_dzyzy/CN/abstract/abstract10232.shtml
Sun Z R, Zhao X J, Duan H S, et al. Gravity and magnetic evidences for the suture zone between North China plate and Siberian plate[J]. Geology and Resources, 2020, 29(5): 461-466. http://manu25.magtech.com.cn/Jweb_dzyzy/CN/abstract/abstract10232.shtml
[10] 张允平, 那福超, 宋维民, 等. 对东北地区古生代几个重要时段地层古生物信息的区域构造学思考[J]. 地质与资源, 2021, 30(1): 1-13. http://manu25.magtech.com.cn/Jweb_dzyzy/CN/abstract/abstract10259.shtml
Zhang Y P, Na F C, Song W M, et al. Regional tectonic implication of the Paleozoic stratigraphic paleontology information in Northeast China[J]. Geology and Resources, 2021, 30(1): 1-13. http://manu25.magtech.com.cn/Jweb_dzyzy/CN/abstract/abstract10259.shtml
[11] Yan X L, Chen B. Chemical and boron isotopic compositions of tourmaline from the Paleoproterozoic Houxianyu borate deposit, NE China: Implications for the origin of borate deposit[J]. Journal of Asian Earth Sciences, 2014, 94: 252-266. doi: 10.1016/j.jseaes.2014.05.021
[12] Dong A G, Zhu X K, Li Z H, et al. A multi-isotope approach towards constraining the origin of large-scale Paleoproterozoic B-(Fe) mineralization in NE China[J]. Precambrian Research, 2017, 292: 115-129. doi: 10.1016/j.precamres.2017.01.030
[13] Wang Z Q, Chen B, Yan X L. Geochemistry and boron isotopic compositions of tourmaline from the Paleoproterozoic amphibolites, NE China: Implications for the origin of borate deposit[J]. Precambrian Research, 2019, 326: 258-271. doi: 10.1016/j.precamres.2018.01.006
[14] 白瑾. 华北陆台北缘前寒武纪地质及铅锌成矿作用[M]. 北京: 地质出版社, 1993: 47-89.
Bai J. The Precambrian geology and Pb-Zn mineralization in the northern margin of North China platform[M]. Beijing: Geology Press, 1993: 47-89. (in Chinese)
[15] 张秋生, 杨振升, 刘连登. 辽东半岛早期地壳与矿床[M]. 北京: 地质出版社, 1988: 1-574.
Zhang Q S, Yang Z S, Liu L D. Early crust and mineral deposits of Liaodong Peninsula, China[M]. Beijing: Geological Publishing House, 1988: 1-574.
[16] 赵岩, 寇林林, 张朋, 等. 辽东半岛隆昌地区~2113 Ma变辉长岩地球化学与Hf同位素研究: 对胶辽吉造山带构造演化的制约[J]. 地球科学, 2019, 44(10): 3333-3345. https://www.cnki.com.cn/Article/CJFDTOTAL-DQKX201910012.htm
Zhao Y, Kou L L, Zhang P, et al. Characteristics of geochemistry and Hf isotope from meta-gabbro in Longchang area, Liaodong Peninsula: Implications on evolution of the Jiao-Liao-Ji Paleoproterozoic orogenic belt[J]. Earth Science, 2019, 44(10): 3333-3345. https://www.cnki.com.cn/Article/CJFDTOTAL-DQKX201910012.htm
[17] Li Z, Chen B, Wei C J, et al. Provenance and tectonic setting of the Paleoproterozoic metasedimentary rocks from the Liaohe Group, Jiao-Liao-Ji belt, North China Craton: Insights from detrital zircon U-Pb geochronology, whole-rock Sm-Nd isotopes, and geochemistry[J]. Journal of Asian Earth Sciences, 2015, 111: 711-732. doi: 10.1016/j.jseaes.2015.06.003
[18] Li Z, Chen B, Wang J L. Geochronological framework and geodynamic implications of mafic magmatism in the Liaodong Peninsula and adjacent regions, North China Craton[J]. Acta Geologica Sinica (English Edition), 2016, 90(1): 138-153. doi: 10.1111/1755-6724.12647
[19] Zhao Y, Lin S F, Zhang P, et al. Geochronology and geochemical characteristics of Paleoproterozoic syn-orogenic granitoids and constraints on the geological evolution of the Jiao-Liao-Ji orogenic belt, North China Craton[J]. Precambrian Research, 2021, 365: 106386. doi: 10.1016/j.precamres.2021.106386
[20] 卢良兆, 徐学纯, 刘福来. 中国北方早前寒武纪孔兹岩系[M]. 长春: 长春出版社, 1996: 219-230.
Lu L Z, Xu X C, Liu F L. Early Precambrian khondalite series in Northern China[M]. Changchun: Changchun Publishing House, 1996: 219-230. (in Chinese)
[21] 刘福来, 刘平华, 王舫, 等. 胶-辽-吉古元古代造山/活动带巨量变沉积岩系的研究进展[J]. 岩石学报, 2015, 31(10): 2816-2846. https://www.cnki.com.cn/Article/CJFDTOTAL-YSXB201510002.htm
Liu F L, Liu P H, Wang F, et al. Progresses and overviews of voluminous meta-sedimentary series within the Paleoproterozoic Jiao-Liao-Ji orogenic/mobile belt, North China Craton[J]. Acta Petrologica Sinica, 2015, 31(10): 2816-2846. https://www.cnki.com.cn/Article/CJFDTOTAL-YSXB201510002.htm
[22] 刘平华, 蔡佳, 邹雷. 辽东半岛北部三家子石榴斜长角闪岩变质演化P-T-t轨迹及其地质意义: 来自相平衡模拟与锆石U-Pb定年的约束[J]. 岩石学报, 2017, 33(9): 2649-2674. https://www.cnki.com.cn/Article/CJFDTOTAL-YSXB201709001.htm
Liu P H, Cai J, Zou L. Metamorphic P-T-t path and its geological implication of the Sanjiazi garnet amphibolites from the northern Liaodong Penisula, Jiao-Liao-Ji belt: Constraints on phase equilibria and zircon U-Pb dating[J]. Acta Petrologica Sinica, 2017, 33(9): 2649-2674. https://www.cnki.com.cn/Article/CJFDTOTAL-YSXB201709001.htm
[23] 文飞, 田忠华. 辽东半岛辽河群变泥质岩变质变形研究: 对古元古代造山作用及折返过程的启示[J]. 岩石学报, 2021, 37(2): 619-635. https://www.cnki.com.cn/Article/CJFDTOTAL-YSXB202102018.htm
Wen F, Tian Z H. A metamorphic and deformational study of meta-pelites in the Liaohe Group located at Liaodong Peninsula: Significance to process of Paleoproterozoic orogenesis and exhumation[J]. Acta Petrologica Sinica, 2021, 37(2): 619-635. https://www.cnki.com.cn/Article/CJFDTOTAL-YSXB202102018.htm
[24] 赵岩, 杨宏智, 杨凤超, 等. 辽东半岛青城子矿田典型金矿成因: 来自硫、氢、氧同位素的证据[J]. 地质与资源, 2020, 29(1): 21-28. doi: 10.3969/j.issn.1671-1947.2020.01.003 http://manu25.magtech.com.cn/Jweb_dzyzy/CN/abstract/abstract10145.shtml
Zhao Y, Yang H Z, Yang F C, et al. Genesis of typical gold deposits in Qingchengzi orefield, Liaodong Peninsula: Evidences from S-D-O isotopes[J]. Geology and Resources, 2020, 29(1): 21-28. doi: 10.3969/j.issn.1671-1947.2020.01.003 http://manu25.magtech.com.cn/Jweb_dzyzy/CN/abstract/abstract10145.shtml
[25] 赵岩, 张朋, 毕中伟, 等. 沉积建造在辽东半岛古元古代杨木杆硼矿富集成矿过程中的重要作用[J]. 地球科学与环境学报, 2022, 44(2): 207-219. https://www.cnki.com.cn/Article/CJFDTOTAL-XAGX202202005.htm
Zhao Y, Zhang P, Bi Z W, et al. Key role of sedimentary formation played in the mineralization process of the Paleoproterozoic Yangmugan boron deposit in Liaodong Peninsula, NE China[J]. Journal of Earth Sciences and Environment, 2022, 44(2): 207-219. https://www.cnki.com.cn/Article/CJFDTOTAL-XAGX202202005.htm
[26] 王林世, 彭虎, 郭亚波, 等. 辽宁东平金矿床地质特征及找矿方向[J]. 地质与资源, 2020, 29(3): 246-251. doi: 10.3969/j.issn.1671-1947.2020.03.006 http://manu25.magtech.com.cn/Jweb_dzyzy/CN/abstract/abstract10199.shtml
Wang L S, Peng H, Guo Y B, et al. Geological characteristics and prospecting directions of Dongping gold deposit in Liaoning Province[J]. Geology and Resources, 2020, 29(3): 246-251. doi: 10.3969/j.issn.1671-1947.2020.03.006 http://manu25.magtech.com.cn/Jweb_dzyzy/CN/abstract/abstract10199.shtml
[27] 隋真龙, 张琦, 冯啸宇, 等. 辽宁宽甸县爱林铁矿地质特征及控矿因素分析[J]. 地质与资源, 2020, 29(2): 120-125. doi: 10.3969/j.issn.1671-1947.2020.02.002 http://manu25.magtech.com.cn/Jweb_dzyzy/CN/abstract/abstract10182.shtml
Sui Z L, Zhang Q, Feng X Y, et al. Analysis on the geology and ore-controlling factors of Ailin iron deposit in Liaoning Province[J]. Geology and Resources, 2020, 29(2): 120-125. doi: 10.3969/j.issn.1671-1947.2020.02.002 http://manu25.magtech.com.cn/Jweb_dzyzy/CN/abstract/abstract10182.shtml
[28] Ma Y B, Bagas L, Xing S W, et al. Genesis of the stratiform Zhenzigou Pb-Zn deposit in the North China Craton: Rb-Sr and C-O-S-Pb isotope constraints[J]. Ore Geology Reviews, 2016, 79: 88-104. doi: 10.1016/j.oregeorev.2016.05.009
[29] Li L X, Zi J W, Li H M, et al. High-grade magnetite mineralization at 1.86 Ga in Neoarchean banded iron formations, Gongchangling, China: In situ U-Pb geochronology of metamorphic-hydrothermal zircon and monazite[J]. Economic Geology, 2019, 114(6): 1159-1175. doi: 10.5382/econgeo.4678
[30] 胡古月, 李延河, 范昌福, 等. 辽东翁泉沟硼镁铁矿矿床海相蒸发成因: 来自稳定同位素地球化学证据[J]. 矿床地质, 2014, 33(4): 821-832. doi: 10.3969/j.issn.0258-7106.2014.04.012
Hu G Y, Li Y H, Fan C F, et al. Marine evaporative genesis of Wengquangou ludwigite deposit in eastern Liaoning Province: Evidences from stable isotopic compositions[J]. Mineral Deposits, 2014, 33(4): 821-832. doi: 10.3969/j.issn.0258-7106.2014.04.012
[31] 赵岩, 张朋, 毕中伟, 等. 辽东岫岩地区两类古元古代花岗岩年代学、地球化学及地质意义[J]. 地球科学, 2020, 45(11): 4072-4090. https://www.cnki.com.cn/Article/CJFDTOTAL-DQKX202011014.htm
Zhao Y, Zhang P, Bi Z W, et al. Geochronology and geochemistry of two types of Paleoproterozoic granites and their geological implications in the Xiuyan area, Liaodong Peninsula[J]. Earth Science, 2020, 45(11): 4072-4090. https://www.cnki.com.cn/Article/CJFDTOTAL-DQKX202011014.htm
[32] Liu J, Zhang J, Liu Z H, et al. Geochemical and geochronological study on the Paleoproterozoic rock assemblage of the Xiuyan region: New constraints on an integrated rift-and-collision tectonic process involving the evolution of the Jiao-Liao-Ji belt, North China Craton[J]. Precambrian Research, 2018, 310: 179-197. doi: 10.1016/j.precamres.2018.03.005
[33] Zhao Y, Zhang P, Li Y, et al. Geochemistry of two types of Palaeoproterozoic granites, and zircon U-Pb dating, and Lu-Hf isotopic characteristics in the Kuandian area within the Jiao-Liao-Ji belt: Implications for regional tectonic setting[J]. Geological Journal, 2020, 55(11): 7564-7580. doi: 10.1002/gj.3869
[34] Zong K Q, Klemd R, Yuan Y, et al. The assembly of Rodinia: The correlation of early Neoproterozoic (ca. 900 Ma) high-grade metamorphism and continental arc formation in the southern Beishan orogen, southern Central Asian orogenic belt (CAOB)[J]. Precambrian Research, 2017, 290: 32-48. doi: 10.1016/j.precamres.2016.12.010
[35] Liu Y S, Gao S, Hu Z C, et al. Continental and oceanic crust recycling-induced melt-peridotite interactions in the trans-North China Orogen: U-Pb dating, Hf isotopes and trace elements in zircons from mantle xenoliths[J]. Journal of Petrology, 2010, 51(1/2): 537-571.
[36] Ludwig K R. Isoplot 3.00: A geochronological toolkit for Microsoft Excel[M]. Berkeley: Berkeley Geochronology Center, 2003.
[37] Irvine T N, Baragar W R A. A guide to the chemical classification of the common volcanic rocks[J]. Canadian Journal of Earth Sciences, 1971, 8(5): 523-548. doi: 10.1139/e71-055
[38] Rickwood P C. Boundary lines within petrologic diagrams which use oxides of major and minor elements[J]. Lithos, 1989, 22(4): 247-263. doi: 10.1016/0024-4937(89)90028-5
[39] Whalen J B, Currie K L, Chappell B W. A-type granites: Geochemical characteristics, discrimination and petrogenesis[J]. Contributions to Mineralogy and Petrology, 1987, 95(4): 407-419. doi: 10.1007/BF00402202
[40] Li S Z, Zhao G C, Sun M, et al. Are the south and north Liaohe Groups of North China Craton different exotic terranes?Nd isotope constraints[J]. Gondwana Research, 2006, 9(1/2): 198-208.
[41] Li S Z, Zhao G C. SHRIMP U-Pb zircon geochronology of the Liaoji granitoids: Constraints on the evolution of the Paleoproterozoic Jiao-Liao-Ji belt in the eastern block of the North China Craton[J]. Precambrian Research, 2007, 158(1/2): 1-16.
[42] Li Z, Chen B, Wei C J. Is the Paleoproterozoic Jiao-Liao-Ji belt (North China Craton) a rift?[J]. International Journal of Earth Sciences, 2017, 106(1): 355-375. doi: 10.1007/s00531-016-1323-2
[43] Li Z, Chen B, Yan X L. The Liaohe Group: An insight into the Paleoproterozoic tectonic evolution of the Jiao-Liao-Ji belt, North China Craton[J]. Precambrian Research, 2019, 326: 174-195. doi: 10.1016/j.precamres.2018.01.009
[44] Liu F L, Liu L S, Cai J, et al. A widespread Paleoproterozoic partial melting event within the Jiao-Liao-Ji belt, North China Craton: Zircon U-Pb dating of granitic leucosomes within pelitic granulites and its tectonic implications[J]. Precambrian Research, 2019, 326: 155-173. doi: 10.1016/j.precamres.2017.10.017
[45] 喻钢, 杨刚, 陈江峰, 等. 辽东猫岭金矿中含金毒砂的Re-Os年龄及地质意义[J]. 科学通报, 2005, 50(12): 1248-1252. https://www.cnki.com.cn/Article/CJFDTOTAL-KXTB200512015.htm
Yu G, Yang G, Chen J F, et al. Re-Os dating of gold-bearing arsenopyrite of the Maoling gold deposit, Liaoning Province, Northeast China and its geological significance[J]. Chinese Science Bulletin, 2005, 50(14): 1509-1514. https://www.cnki.com.cn/Article/CJFDTOTAL-KXTB200512015.htm
[46] 刘军, 李铁刚, 段超. 辽宁猫岭大型金矿床成岩成矿年龄及同位素地球化学特征[J]. 地质通报, 2018, 37(7): 1325-1337. https://www.cnki.com.cn/Article/CJFDTOTAL-ZQYD201807016.htm
Liu J, Li T G, Duan C. Geochronology and isotopic geochemistry characteristics of the Maoling large gold deposit, Liaoning Province, China[J]. Geological Bulletin of China, 2018, 37(7): 1325-1337. https://www.cnki.com.cn/Article/CJFDTOTAL-ZQYD201807016.htm
-