赤泥中钪和钛的回收研究进展

雷清源, 周康根, 何德文, 张雪凯. 赤泥中钪和钛的回收研究进展[J]. 矿产保护与利用, 2019, 39(3): 15-20. doi: 10.13779/j.cnki.issn1001-0076.2019.03.003
引用本文: 雷清源, 周康根, 何德文, 张雪凯. 赤泥中钪和钛的回收研究进展[J]. 矿产保护与利用, 2019, 39(3): 15-20. doi: 10.13779/j.cnki.issn1001-0076.2019.03.003
LEI Qingyuan, ZHOU Kanggen, HE Dewen, ZHANG Xuekai. Research Progress on the Recovery of Scandium and Titanium from Red Mud[J]. Conservation and Utilization of Mineral Resources, 2019, 39(3): 15-20. doi: 10.13779/j.cnki.issn1001-0076.2019.03.003
Citation: LEI Qingyuan, ZHOU Kanggen, HE Dewen, ZHANG Xuekai. Research Progress on the Recovery of Scandium and Titanium from Red Mud[J]. Conservation and Utilization of Mineral Resources, 2019, 39(3): 15-20. doi: 10.13779/j.cnki.issn1001-0076.2019.03.003

赤泥中钪和钛的回收研究进展

详细信息
    通讯作者: 周康根(1963-), 男, 博士, 教授, 博士生导师, 主要从事赤泥资源综合利用研究, E-mail:zhoukg63@163.com
  • 中图分类号: X758

Research Progress on the Recovery of Scandium and Titanium from Red Mud

More Information
  • 赤泥中富含铝、铁、钛等多种有价金属,以及钪、钇、铈、镧等稀土元素,是一种极具回收价值的二次资源。目前,国内外钛被广泛应用于各个领域,钪由于稀缺导致价格昂贵。赤泥作为碱性固体废弃物,具有较高的钪钛含量,可以加以回收利用,缓解资源匮乏的同时又能改善环境。本文综述了目前国内外赤泥中钪和钛的回收研究现状,并指出了各工艺存在的问题,同时对赤泥中钪和钛的选择性回收提出了展望。

  • 加载中
  • 图 1  溶剂萃取回收钪的工艺流程图

    Figure 1. 

    图 2  联合法回收钪的工艺流程图

    Figure 2. 

    图 3  回收钛的工艺流程图

    Figure 3. 

    表 1  从赤泥中回收钪和钛的工艺总结

    Table 1.  The process summary of scandium and titanium recovery from red mud

    Valuable element Method Recovery rate Lack of technology Reference
    Sc Hydrometallurgy 99% Other elementsare extracted at the same time, such as titanium [15]
    98% Complex process and high cost of solvent [16]
    Combined method >80% Recovery rate is low [33]
    >90% High energy consumption and low comprehensive utilization [34]
    Ti Acid leaching - High energy consumption and waste gas pollution [25]
    64.5% The metal ion selectivity is poor by acid leaching [26]
    73% Long process and low recovery [31]
    54.3% Recovery rate is low [27]
    >80% High acid concentration and harsh treatment environment [28]
    下载: 导出CSV
  • [1]

    ZhouK G, Teng C Y, Zhang X K, et al. Enhanced selective leaching of scandium from red mud[J]. Hydrometallurgy, 2018, 182:57-63. doi: 10.1016/j.hydromet.2018.10.011

    [2]

    Li G H, Ye Q, Deng B N, et al. Extraction of scandium from scandium-richmaterial derived from bauxite ore residues[J]. Hydrometallurgy, 2018, 176:62-68. doi: 10.1016/j.hydromet.2018.01.007

    [3]

    练佳佳, 唐庆杰, 吴文荣, 等.赤泥在环境修复领域的应用综述[J].硅酸盐通报, 2015(11):3236-3242. http://d.old.wanfangdata.com.cn/Periodical/gsytb201511030

    [4]

    Zhang X K, Zhou K G, Chen W, et al. Recovery of iron and rare earth elements from red mud through an acid leaching-stepwise extraction approach[J]. Journal of central couth university, 2019, 26(2):458-466. doi: 10.1007/s11771-019-4018-6

    [5]

    滕春英, 周康根, 宁凌峰, 等.盐酸分级浸出赤泥中有价金属元素[J].环境工程学报, 2018, 12(1):310-315. http://d.old.wanfangdata.com.cn/Periodical/hjwrzljsysb201801040

    [6]

    林亮.赤泥建设材料衍生产品的安全性分析[J].中国安全生产科学技术, 2014, 10(1):165-169. http://d.old.wanfangdata.com.cn/Periodical/zgzyaqwsgltxrz201401036

    [7]

    杨艳娟, 李建伟, 张茂亮, 等.改性赤泥免烧砖的制备与放射性屏蔽机理分析[J].矿产保护与利用, 2019, 39(1):95-99. http://kcbh.cbpt.cnki.net/WKD/WebPublication/paperDigest.aspx?paperID=bb1a8e22-bfe3-4bf9-a0b8-adb983687ed2

    [8]

    刘中凯, 刘万超, 王洋洋, 等.赤泥土壤修复扩大实验及微生物修复技术[C]//2018中国环境科学学会科学技术年会论文集(第三卷).合肥, 2018.

    [9]

    刘奋照, 王中慧, 薛玟, 等.赤泥利用及提炼钪综述[J].广东化工, 2015, 42(5):56-58. doi: 10.3969/j.issn.1007-1865.2015.05.030

    [10]

    司秀芬, 邓佐国, 徐廷华.赤泥提钪综述[J].江西有色金属, 2003, 17(2):28-31. doi: 10.3969/j.issn.1674-9669.2003.02.010

    [11]

    徐璐, 罗宇智, 史光大.从赤泥硫酸熟化浸出液中预富集钪[J].有色金属(冶炼部分), 2018(11):39-41. doi: 10.3969/j.issn.1007-7545.2018.11.009

    [12]

    杨绪平, 邵志超, 张晨.赤泥的资源化综合利用[J].现代冶金, 2018, 46(1):42-44. doi: 10.3969/j.issn.1005-6068.2018.01.013

    [13]

    杨涛, 王志坚, 肖劲, 等.赤泥和钛白废液中提钪的浸出工艺研究[J].矿冶, 2015, 24(5):37-40. doi: 10.3969/j.issn.1005-7854.2015.05.010

    [14]

    Bonomi C, Alexandri A, Vind J, et al. Scandium and titanium recovery from bauxite residue by direct leaching with a bronsted acidic ionic liquid[J]. Metals, 2018, 8(10):834. doi: 10.3390/met8100834

    [15]

    Wang W W, Pranolo Y, Cheng C Y. Recovery of scandium from synthetic red mud leach solutions by solvent extraction with D2EHPA[J]. Separation and purification technology, 2013, 108:96-102. doi: 10.1016/j.seppur.2013.02.001

    [16]

    Onghena B, Borra C R, Van G T, et al. Recovery of scandium from sulfation-roasted leachates of bauxite residue by solvent extraction with the ionic liquid betainium bis(trifluoromethylsulfonyl)imide[J]. Separation and purification technology, 2017, 176:208-219. doi: 10.1016/j.seppur.2016.12.009

    [17]

    罗宇智, 徐璐, 史光大.硫酸熟化浸出赤泥中钪的研究[J].有色金属(冶炼部分), 2017(4):45-47. doi: 10.3969/j.issn.1007-7545.2017.04.011

    [18]

    Nghiem V N, Lizuka A, Shibata E, et al. Study of adsorption behavior of a new synthesized resin containing glycol amic acid group for separation of scandium from aqueous solutions[J]. Hydrometallurgy, 2016, 165:51-56. doi: 10.1016/j.hydromet.2015.11.016

    [19]

    赵恒, 李望, 朱晓波, 等.赤泥提钛研究现状与展望[J].河南化工, 2018, 35(6):3-12. http://d.old.wanfangdata.com.cn/Periodical/hnhg201806001

    [20]

    刘卫, 尹志芳, 李国高, 等.钛白废酸提钪工艺中除钛的研究[J].稀土, 2016, 37(6):86-89. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=xitu201606015

    [21]

    韩东战, 尹中林.赤泥提钛的研究现状[J].矿产综合利用, 2017(3):33-37. doi: 10.3969/j.issn.1000-6532.2017.03.005

    [22]

    朱晓波, 李望, 管学茂.赤泥循环酸浸提钛实验及动力学研究[J].稀有金属与硬质合金, 2015(3):9-12. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=xyjsyyzhj201503003

    [23]

    李冬, 潘利祥, 赵良庆, 等.赤泥综合利用的研究进展[J].环境工程, 2014(S1):616-618. http://d.old.wanfangdata.com.cn/Periodical/sxhg201510036

    [24]

    李亮星, 黄茜琳.从赤泥中提取钛的试验研究[J].湿法冶金, 2011, 30(4):323-325. doi: 10.3969/j.issn.1009-2617.2011.04.016

    [25]

    Kasliwal P, Sai P S T. Enrichment of titanium dioxide in red mud:a kinetic study[J]. Hydrometallurgy, 1999, 53(1):73-87. doi: 10.1016/S0304-386X(99)00034-1

    [26]

    Agatzini-Leonardou S, Oustadakis P, Tsakiridis P E, et al. Titanium leaching from red mud by diluted sulfuric acid at atmospheric pressure[J]. Journal of hazardous materials, 2008, 157(2-3):579-586. doi: 10.1016/j.jhazmat.2008.01.054

    [27]

    王琪, 姜林.硫酸浸出赤泥中铁、铝、钛的工艺研究[J].矿冶工程, 2011, 31(4):90-94. doi: 10.3969/j.issn.0253-6099.2011.04.024

    [28]

    廖春发, 姜平国, 焦芸芬, 等.赤泥中钛硫酸浸出的工艺条件及动力学研究[J].矿业研究与开发, 2008(2):45-47. doi: 10.3969/j.issn.1005-2763.2008.02.015

    [29]

    徐璐, 史光大, 李元坤, 等.盐酸浸出拜耳法赤泥预富集钪的研究[J].有色金属(冶炼部分), 2015(1):54-56. doi: 10.3969/j.issn.1007-7545.2015.01.014

    [30]

    Zhou G, Li Q, Sun P, et al. Removal of impurities from scandium chloride solution using 732-type resin[J]. Journal of rare earths, 2017, 36(3):311-316. http://d.old.wanfangdata.com.cn/Periodical/zgxtxb-e201803014

    [31]

    Piga L, Pochetti F, Stoppa L. Recovering metals from red mud generated during alumina production[J]. Journal of the minerals, metals and materials society, 1993, 45(11):54-59. doi: 10.1007/BF03222490

    [32]

    王璐, 郝彦忠, 郝增发.赤泥中有价金属提取与综合利用进展[J].中国有色金属学报, 2018, 28(8):213-226. http://d.old.wanfangdata.com.cn/Periodical/zgysjsxb201808025

    [33]

    Borra C R, Blanpain B, Pontikes Y, et al. Recovery of rare earths and major metals from bauxite residue (red mud) by alkali roasting, smelting, and leaching[J]. Journal of sustainable metallurgy, 2017, 3(2):393-404. doi: 10.1007/s40831-016-0103-3

    [34]

    Palant A, Petrova V A. Scandium extraction from hydrochloric acid solutions poly(2-ethylhexyl) phosphonitrllic acid[J]. Russian journal of inorganic chemistry, 1997, 42(6):943-946.

    [35]

    Shinde V M, Bhilare N G. Extraction and separation of Sc salicylate with tripheny/phosphine oxide[J]. Fresenius journal of analytical chemistry, 1997, 357(4):402-407.

    [36]

    肖金凯.工业废渣赤泥中钪的分布特征[J].地质地球化学, 1996(2):82-86. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=QK199600061719

  • 加载中

(3)

(1)

计量
  • 文章访问数:  1907
  • PDF下载数:  103
  • 施引文献:  0
出版历程
收稿日期:  2019-04-11
刊出日期:  2019-06-25

目录