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电解锰渣无害化处理与资源化利用技术研究进展

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文章导航 > 矿产保护与利用 > 2019 > 39(3): 111-118

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张超, 王帅, 钟宏, 秦林. 电解锰渣无害化处理与资源化利用技术研究进展[J]. 矿产保护与利用, 2019, 39(3): 111-118. doi: 10.13779/j.cnki.issn1001-0076.2019.03.018
引用本文: 张超, 王帅, 钟宏, 秦林. 电解锰渣无害化处理与资源化利用技术研究进展[J]. 矿产保护与利用, 2019, 39(3): 111-118. doi: 10.13779/j.cnki.issn1001-0076.2019.03.018
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ZHANG Chao, WANG Shuai, ZHONG Hong, QIN Lin. Review on Decontamination and Resource Utilization of Electrolytic Manganese Residue Technology[J]. Conservation and Utilization of Mineral Resources, 2019, 39(3): 111-118. doi: 10.13779/j.cnki.issn1001-0076.2019.03.018
Citation: ZHANG Chao, WANG Shuai, ZHONG Hong, QIN Lin. Review on Decontamination and Resource Utilization of Electrolytic Manganese Residue Technology[J]. Conservation and Utilization of Mineral Resources, 2019, 39(3): 111-118. doi: 10.13779/j.cnki.issn1001-0076.2019.03.018
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电解锰渣无害化处理与资源化利用技术研究进展

  • 1.

    贵州武陵锰业有限公司，贵州 松桃 554115

  • 2.

    重庆武陵锰业有限公司，重庆 秀山 409912

  • 3.

    中南大学 化学化工学院 锰资源高效清洁利用湖南省重点实验室，湖南 长沙 410083

  • 基金项目:
    国家科技支撑计划课题（2015BAB17B01）；湖南省科技计划项目（2016TP1007）
详细信息
    作者简介: 张超(1987-), 男, 辽宁丹东人, 博士, 研究方向:锰资源选冶技术, E-mail:116078138@qq.com
    通讯作者: 钟宏(1961-), 男, 浙江龙泉人, 教授, 博士, 主要研究方向为资源化工, E-mail:zhongh@csu.edu.cn

  • 中图分类号: X753

Review on Decontamination and Resource Utilization of Electrolytic Manganese Residue Technology

  • 1.

    Guizhou Wuling Manganese Industry Co., Ltd., Songtao 554115, Guizhou, China

  • 2.

    Chongqing Wuling Manganese Industry Co., Ltd., Xiushan 409912, Chongqing, China

  • 3.

    College of Chemistry and Chemical Engineering, Hunan Provincial Key Laboratory of Efficient and Clean Utilization of Manganese Resources, Central South University, Changsha 410083, Hunan, China

More Information

    摘要

  • 电解锰渣属第Ⅱ类一般工业固废。随着电解锰渣产量的增加和国家对环保要求的提高，电解锰渣的合理处置问题受到了越来越多的关注。根据电解锰渣的利用级别，可将电解锰渣的处理方式分为安全堆存、无害化处理和资源化利用三个层次。根据技术特征，可以将电解锰渣处理技术分为安全堆存技术、干法处理技术、火法处理技术及湿法处理技术四大类。本文按照电解锰渣的处理技术特征，对近年来的相关研究进展进行探讨，以期寻找到在技术、经济、市场容量或消纳能力及标准要求等方面同时可行的方案。

    Electrolytic manganese slag belongs to the class Ⅱ general industrial solid waste. With the increase of the output of electrolytic manganese residue and the improvement of environmental requirements, reasonable treatment methods for the electrolytic manganese residue are catching more and more attention. Based on the utilization level of electrolytic manganese slag, the treatment methods of electrolytic manganese slag can be divided into three aspects which are safe storage, harmless treatment and resource utilization, respectively. According to the technical characteristics, the treatment technology of electrolytic manganese slag can be divided into four categories which are safe storage technology, dry treatment technology, fire treatment technology and wet treatment technology, respectively. According to the characteristics of electrolytic manganese slag treatment technology, the paper discussed the related research progress in recent years in order to find feasible solutions in technology, economy, market capacity or absorptive capacity and standard requirements.

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  • 表 1  电解锰渣中硫酸盐分解反应方程式及所需温度

    Table 1.  Sulfate decomposition equation and temperature in the electrolytic manganese residue

    直接高温煅烧
    2(NH4)2SO4=
    4NH3(g)+2SO2(g) + 2H2O(g) + O2(g)    		 T≥600 ℃
    4MnSO4=2Mn2O3+4SO2(g)+O2(g) T≥970 ℃
    3MnSO4=Mn3O4+3SO2(g)+O2(g) T≥980 ℃
    MnSO4=MnO2+SO2(g) T≥1 120 ℃
    2MgSO4=2MgO+2SO2(g)+O2(g) T≥1 040 ℃
    2CaSO4=2CaO+2SO2(g)+O2(g) T≥1 670 ℃
    加还原碳粉焙烧
    2(NH4)2SO4+C=
    4NH3(g)+2SO2(g)+2H2O(g)+CO2(g)    		 T≥240 ℃
    4MnSO4+C=2Mn2O3+4SO2(g)+CO2(g) T≥420 ℃
    3MnSO4+C= Mn3O4+3SO2(g)+CO2(g) T≥530 ℃
    2MgSO4+C=2MgO+2SO2(g)+CO2(g) T≥310 ℃
    2CaSO4 +C=2CaO+2SO2(g)+CO2(g) T≥850 ℃
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收稿日期:  2019-03-03
刊出日期:  2019-06-25

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