石墨烯在防腐涂料中的应用进展

刘秋萍; 张凌燕; 邱杨率; 王靖; 周严洪

doi:10.13779/j.cnki.issn1001-0076.2020.03.024

石墨烯在防腐涂料中的应用进展

1.
武汉理工大学资源与环境工程学院，湖北武汉 430070

2.
矿物资源加工与环境湖北省重点试验室，湖北武汉 430070

详细信息

作者简介: 刘秋萍(1994-), 女, 湖北襄阳人, 硕士研究生, 主要从事非金属矿选矿理论与工艺研究, E-mail:2803985982@qq.com

通讯作者: 邱杨率(1987-), 男, 湖北武汉人, 博士, 讲师, 主要从事非金属矿选矿理论与工艺研究, E-mail:qiuyangshuai@whut.edu.cn

中图分类号: TQ637

收稿日期: 2020-01-22

刊出日期: 2020-06-25

Application Progress on Graphene Modified Anti-corrosion Coatings

1.
School of Resources and Environmental Engineering, Wuhan University of Technology, Wuhan 430070, Hubei, China

2.
Key Laboratory of Mineral Resources Processing and Environment, Wuhan 430070, Hubei, China

More Information

Corresponding author: QIU Yangshuai, qiuyangshuai@whut.edu.cn

Received Date: 22 January 2020

Publish Date: 25 June 2020

摘要

摘要:
对石墨烯的结构、性能以及常用的制备方法予以介绍，总结了石墨烯防腐涂料的制备方法和影响因素，同时对石墨烯防腐涂料的防腐机理加以概述，提出了石墨烯防腐涂料未来发展的瓶颈问题。
- 石墨烯 /
- 防腐涂料 /
- 表征测试 /
- 防腐机理
Abstract:
In this paper, structure, properties and common preparation methods of the graphene were briefly introduced. The preparation methods and influencing factors of graphene modified anti-corrosion coatings were summarized. Meanwhile, an overview of the anti-corrosion mechanism of graphene modified anti-corrosion coatings was provided. Finally, the bottleneck problem of the future development of graphene anticorrosive coatings was raised.
- graphene /
- anticorrosive coatings /
- characterization test /
- antiseptic mechanism

HTML全文

图 1 石墨烯的结构和形貌：(a)石墨烯的起伏；(b)锯齿型边缘GNR和扶手椅型边缘GNR ^[10]

Figure 1.

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图 2 石墨烯的电化学剥离过程示意图^[44]

Figure 2.

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图 3 铝合金(AA)的聚合物(PVB)-石墨烯(G)复合防腐涂层的制备过程图^[47]

Figure 3.

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图 4 不同样品的平均摩擦系数曲线图^[61]

Figure 4.

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图 5 样品磨损痕迹的显微照片^[61]：(a)纯环氧树脂，(b)P2BA0.5%，(c)P2BA0.5%-G0.5%和(d)P2BA0.5%-G0.5%

Figure 5.

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图 6 磁性石墨烯在均匀磁场中的取向^[65]

Figure 6.

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图 7 纯环氧树脂涂层、GO-a / EP复合涂层和GO-c / EP复合涂层的防腐机理对比^[72]

Figure 7.

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图 8 石墨烯的片层阻隔效应示意图^[74-75]

Figure 8.

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图 9 石墨烯的导电机理^[29]

Figure 9.

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图 10 取向(MG / Zn-MF)和未取向(MF / Zn)磁性石墨烯影响富锌涂层中锌类型的机理示意图^[79]

Figure 10.

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参考文献(79)

[1]	SHENG Q, SILVEIRA K C D, TIAN W, et al. Simultaneous hydrate and corrosion inhibition with modified poly (vinyl caprolactam) polymers[J]. Energy Fuels, 2017, 31:6724. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=5396b155148a7f78c3899923da563bca
[2]	赵洪涛, 陆卫中, 李京, 等.无溶剂环氧防腐涂层在模拟海水冲刷条件下的电化学行为[J].中国腐蚀与防护学报, 2016, 36(4):295-305. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=zgfsyfhxb201604002
[3]	彭欣, 李海晏, 孔祥峰, 等.纳米复合带锈涂装船用环氧防腐底涂料制备研究[J].新型建筑材料, 2016, 43(3):33-35. http://www.cnki.com.cn/Article/CJFDTotal-XXJZ201603012.htm
[4]	袁晓艳, 程原, 李婧.无溶剂环氧重防腐涂料的研究[J].现代涂料与涂装, 2014, 1(4):1-3. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=xdtlytz201404001
[5]	CHEN C, QIU S, CUI M. Achieving high performance corrosion and wear resistant epoxy coatings via incorporation of noncovalent functionalized graphene[J]. Carbon, 2016, 114:356-366. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=17727ccd920cbbbf18a601d6f18e1ace
[6]	LLI, S RYU, MR TOMASIK, et al. Graphenc oxidation:thickness dcpendent ctching and strong chemical doping[J]. Nano Letters, 2008, 8:1965-1970. https://pubs.acs.org/doi/10.1021/nl0808684
[7]	Y.S. DEDKOV, M. FONIN, CLAUBSCHAT, et al. A possible source of spin-polarized clectrons:the inert graphene/Ni(Ⅲ) system[J]. Applicd Physics Lctters, 2007, 92(5):166402-166405.
[8]	赵书华, 陈玉, 王树立, 等.石墨烯防腐涂料研究进展[J].常州大学学报(自然科学版), 2017, 29(2):23. http://www.cnki.com.cn/Article/CJFDTOTAL-JSSY201702005.htm
[9]	JIAN L, JI H W, SHAO G W, et al. Research Progress in Graphene for Anticorrosive Coatings[J]. Paint & Coatings Industry, 2017, 47(11):69. http://en.cnki.com.cn/Article_en/CJFDTOTAL-TLGY201711012.htm
[10]	钟雨嘉, 朱宏伟.石墨烯的结构、性能及潜在应用[J].物理, 2018, 47(11):704-714. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=wl201811003
[11]	朱科.丙烯酸酯-环氧树脂核壳乳液及石墨烯复合涂料的制备与防腐性能研究[D].西安: 陕西科技大学, 2018.https://www.ixueshu.com/document/91c3f56eaf3c7f54695554d56b9596da318947a18e7f9386.html
[12]	MEYER J C, GEIM A K, KATSNELSON M I, et al. The structure of suspended graphene sheets[J]. Nature, 2007, 446(7131):60-63. http://cn.bing.com/academic/profile?id=00bd47bd0092898532b7cfbe7dc9717f&encoded=0&v=paper_preview&mkt=zh-cn
[13]	XU K, CAO P, HEATH J R. Scanning tunneling microscopy characterization of the electrical propertics of wrinkles in exfoliated graphene monolayers[J]. Nano Lctters, 2012, 9(12):4446-4451. https://pubs.acs.org/doi/abs/10.1021/nl902729p%40proofing
[14]	LI X, WANG X, ZHANG L, et al. Chemically derived, ultrasmooth graphene nanoribbon semiconductors[J]. Science, 2008, 319(5867):1229-1232. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=af4dfdf6b6675dc1ccda0836a4bfad26
[15]	RAFIEE M A. Graphene-based composite materials[J]. Nature, 2011, 442(2):282-6. http://cn.bing.com/academic/profile?id=b20eb75f1a6d5a6f0a7693fe2fd6a8a0&encoded=0&v=paper_preview&mkt=zh-cn
[16]	MAGDA, GÁBOR ZSOLT, JIN X, et al. Room-temperature magnetic order on zigzag edges of narrow graphene nanoribbons[J]. Nature, 2014, 514(7524):608-611. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=ac24dff026e974f5256db1188d9356ae
[17]	WANG Y, HUANG Y, SONG Y, et al. Room temperature ferromagnetism of graphene[J]. Nano Letters, 2009, 9(1):220-224. http://cn.bing.com/academic/profile?id=a2efec9827628cb3ffc18b3f39f4fc0e&encoded=0&v=paper_preview&mkt=zh-cn
[18]	HUANG P Y, RUIZ-VARGAS C S, VAN D Z A M, et al. Grains and grain boundaries in single-layer graphene atomic patchwork quilts[J]. Nature, 2011, 469(7330):389-392. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=68f779a2558e02f280bac016fe813796
[19]	TSEN A W, BROWN L, LEVENDORF M P, et al. Tailoring Electrical Transport Across Grain Boundaries in Polycrystalline Graphene[J]. Science, 2012, 336(6085):1143. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=57cf76095ac776d6d8a8b2212ac19309
[20]	HASHIMOTO A, SUENAGA K, GLOTER A, et al. Direct evidence for atomic defects in graphene layers. Nature[J]. Nature, 2004, 430(7002):870-873. http://cn.bing.com/academic/profile?id=c908ffc34057b64616c25f12b2dcddb3&encoded=0&v=paper_preview&mkt=zh-cn
[21]	WARNER J H, MARGINE E R, MUKAI M, et al. Dislocation-driven deformations in graphene[J]. Science, 2012, 337(6091):209-212. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=d19f64120544fde68f2e61f1a42711af
[22]	BUTZ B, DOLLE C, NIEKIEL F, et al. Dislocations in bilayer graphene[J]. Nature, 2014, 505(7484):533-7. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=64df71008cab3831ef0ae31424eb6bd0
[23]	CAO Y, FATEMI V, FANG S, et al. Unconventional superconductivity in magic-angle graphene superlattices[J]. Nature, 2018, 556(7699):43-50. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=9a6a6e72127bc002431b74fc1c0dbdb7
[24]	CHEN J H, JANG C, XIAO S D, et al. Intrinsic and extrinsic performance limits of graphene devices on SiO₂[J]. Nature Nanotechnology, 2008, 3(3):206-209. https://www.nature.com/articles/nnano.2008.58
[25]	BALANDIN A A, GHOSH S, BAO W Z, et al. Superior thermal conductivity of single-layer graphene[J]. Nano Letters, 2008, 8(3):902-907. http://cn.bing.com/academic/profile?id=28a010c1f5bd5e256df3aa9d0b5b59bc&encoded=0&v=paper_preview&mkt=zh-cn
[26]	LEE C, WEI X, KYSAR J W, et al. Measurement of the elastic properties and intrinsic strength of monolayer graphene[J]. Science, 2008, 321(5887):385-388. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=11b9413d19ebf11f6fb62ec5e06397f3
[27]	NOVOSELOV KS, GEIM A K, MOROZOV S V, et al. Electric field effect in atomically thin carbon films[J]. Science, 2004, 306(5696):666-669. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=Arxiv000000425365
[28]	唐多昌, 李晓红, 袁春华, 等.机械剥离法制备高质量石墨烯的初步研究[J].西南科技大学学报, 2010, 25(3):16-18, 59. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=xngxyxb201003004
[29]	李爽, 张双红, 杨波, 等.石墨烯防腐涂料研究进展[J].腐蚀科学与防护技术, 2019, 31(4). http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=fskxyfhjs201904013
[30]	李强.石墨烯基防腐涂料的研究进展[J].上海化工, 2019(7):32-36. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=shhg201907011
[31]	DENG S, QI XD, ZHU Y L, et al. A facile way to large-scale production of few-layered graphene via, planetary ball mill[J]. Chinese Journal of Polymer Science, 2016, 34(10):1270-1280. http://cn.bing.com/academic/profile?id=d374bdd01a8eb067af118c447f2d3f3d&encoded=0&v=paper_preview&mkt=zh-cn
[32]	GUNASEKARAN R, KALIDOSS J, DAS S K, et al. Shear-force-dominated dual-drive planetary ball milling for scalable production of graphene and its electro-catalytic application with Pd nanostructures[J]. Rsc Advances, 2016, 6(24):20067-20073. https://pubs.rsc.org/en/content/articlelanding/2016/ra/c5ra24810h#!
[33]	HUMMERS WS, OFFEMAN R E. Preparation of graphite oxide[J]. Journal of the American Chemical Society, 1958, 80(6):1339-1339.
[34]	STANKOVICH S, DIKIN DA, PINER R D, et al. Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graph ite oxide[J]. Carbon, 2007, 45(7):1558-1565. http://utw10193.utweb.utexas.edu/Archive/RuoffsPDFs/160.pdf
[35]	MCALLISTER MJ, LI J L, ADAMSON D H, et al. Single sheet functionalized graphene by oxidation and thermal expansion of graphite[J]. Chemistry of Materials, 2007, 19(18):4396-4404. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=ef55516eefda9387ceaf3907379d4915
[36]	PAREDES J I, VILLAR-RODILS, MARTINEZALONSO A, et al. Graphene oxide dispersions in organic solvents[J]. Langmuir, 2008, 24(19):10560-10564. http://cn.bing.com/academic/profile?id=26c7aa9cc0540a062b055d12a6cad7f2&encoded=0&v=paper_preview&mkt=zh-cn
[37]	杨晓丽, 孟军华.化学气相沉积法可控制备石墨烯薄膜和单晶畴[J].微纳电子技术, 2018, 55(1):63-68. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=wndzjs201801011
[38]	LI X S, CAI W W, AN J H, et al. Large-area synthesis of high-quality and uniform graphene films on copper foils[J]. Science, 2009, 324(5932):1312-1314. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=0d2af75171b3aed7805b75ce2ec5880c
[39]	GAO L B, REN W C, XU H L, et al. Repeated growth and bub-bling transfer of graphene with millimetre-size single-erystal grains using platinum[J]. Nature Communications, 2012, 3(2):6991-6997. http://www.nature.com/doifinder/10.1038/ncomms1702
[40]	SIFT, ZHANG X W, LIU X, et al. Effects of ambient conditions on the quality of graphene synthesized by chemical vapor deposition[J]. Vacuum, 2012, 86(12):1867-1870. http://cn.bing.com/academic/profile?id=3726d441efae25e195147740ffc0a6e0&encoded=0&v=paper_preview&mkt=zh-cn
[41]	GENG D C, WU B, GUO Y L, et al. Uniform hexagonal graphene flakes and films grown on liquid copper surface[J]. Proceedings of the National Academy of Sciences, 2012, 109(21):7992-7996. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=b6a652876f9784aaa009baa5369d7269
[42]	HAO Y F, BHARATHI M S, WANG L, et al. The role of surface oxygen in the growth of large single-erystal graphene on copper[J]. Science, 2013, 342(6159):720-723. https://science.sciencemag.org/content/sci/342/6159/720.full.pdf
[43]	XU X Z, ZANG Z H, QIU L, et al. Ultrafast growth of singlecrystal graphene assisted by a continuous oxygen supply[J]. Nature Nanotechnology, 2016, 11(11):930-935. https://pubmed.ncbi.nlm.nih.gov/27501317/
[44]	SNEHA D, SUNNY R, BHATTACHARYYA A R, et al. Factors affecting barrier performance of composite anti-corrosion coatings prepared by using electrochemically exfoliated few-layer graphene as filler[J]. Composites Part B:Engineering, 2018, 155:1-10. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=3033cebea9e95035b5d51a085a73dcec
[45]	PARVEZ K, WU ZS, LI R, et al. Exfoliation of graphite into graphene in aqueous solutions of inorganic salts[J]. J Am Chem Soc, 2014, 136:6083-91. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=92d950ba6d0967c009291c7c413d428b
[46]	I WLASNY, P DABROWSKI, M ROGALA, et al. Role of graphene defects in corrosion of graphene-coated Cu(Ⅲ) surface[J]. Applied Physics Letters, 2013, 102(11):111601-111605. https://aip.scitation.org/doi/10.1063/1.4795861
[47]	FENG Y, CAMILLI L, WANG T, et al. Complete long-term corrosion protection with chemical vapor deposited graphene[J]. Carbon, 2018, 132:78-84. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=08eb4ab1b1565a12991a84769e739046
[48]	LIU S, PAN T J, WANG R F, et al. Anti-corrosion and conductivity of the electrodeposited graphene/polypyrrole composite coating for metallic bipolar plates[J]. Progress in Organic Coatings, 2019, 136:105237. http://cn.bing.com/academic/profile?id=84fd859e7aaa68645a0e4e2bcdd5d0c6&encoded=0&v=paper_preview&mkt=zh-cn
[49]	CHEN J, LI C, CAO W, et al. Conductive and high anticorrosive rGO-modified copper foil prepared by electrocoagulation and chemical reduction[J]. Ionics, 2019, 25(6):2935-2944. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=d86b4bef0187c6522332d97c7997a95b
[50]	QUEZADA-RENTERÍA, J.A, CHÁZARO-RUIZ, et al. Synthesis of reduced graphene oxide (rGO) films onto carbon steel by cathodic electrophoretic deposition:Anticorrosive coating[J]. Carbon, 2017, 122:266-275.
[51]	ZHOU M, WANG Y, ZHAI Y, et al. Controlled synthesis of large-area and patterned electrochemically reduced graphene oxide films[J], Chem.A Eur.J, 2009, 15:6116-6120. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=bb99a8a4836045f2e837ec75a85753e4
[52]	MOHSIN ALI RAZA, ASAD ALIA, FAIZAN ALI GHAURIA, et al. Electrochemical behavior of graphene coatings deposited on copper metal by electrophoretic deposition and chemical vapor deposition[J]. Surface & Coatings Technology, 2017, 332:112-119. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=ffa0e70952332fb89eac43341a75b4d3
[53]	LIU S, GU L, ZHAO H C, et al. Corrosion Resistance of Graphene-Reinforced Waterborne Epoxy Coatings[J]. Journal of Materials Science & Technology, 2016, 32(5):425-431. https://www.researchgate.net/publication/288039694_Corrosion_Resistance_of_Graphene-Reinforced_Waterborne_Epoxy_Coatings
[54]	POONEH HAGHDADEH, MEHDI GHAFFARI, BAHRAM RAMEZANZADEH, et al. Polyurethane coatings reinforced with 3-(triethoxysilyl)propyl isocyanate functionalized graphene oxide nanosheets:Mechanical and anti-corrosion properties[J]. Progress in Organic Coatings, 2019, 136:105, 243. https://www.researchgate.net/publication/334665021_Polyurethane_coatings_reinforced_with_3-triethoxysilylpropyl_isocyanate_functionalized_graphene_oxide_nanosheets_Mechanical_and_anti-corrosion_properties
[55]	DING R, ZHENG Y, YU H, et al. Study of water permeation dynamics and anti-corrosion mechanism of graphene/zinc coatings[J]. Journal of Alloys and Compounds, 2018, 748:481-495. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=b1909ee5b908780373c3512c776df337
[56]	CHANG K C, JI W F, LI C W, et al. The effect of varying carboxylic group content in reduced graphene oxides on the anticorrosive properties of PMMA/graphene composites[J], Express Polym. Lett, 2014, 8:908-919. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=Doaj000003694815
[57]	YANG H, SHAN C, LI F, et al. Convenient preparation of tunably loaded chemically converted graphene oxide/epoxy resin nanocomposites from graphene oxide sheets through two-phase extraction[J], 1. Mater. Chem, 2009, 19:8856-8860. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=e3f58fc05ea7abe79b3b05a09141ee7e
[58]	TANG X, ZHOU Y, PENG M. Green preparation of epoxy/graphene oxide nanocomposites using a glycidylamine epoxy resin as the surface modifier and phase transfer agent of graphene oxide[J]. ACS Appl. Mater. Interfaces, 2015, 8:1854-1866. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=787980374152b963434b0913ba5469da
[59]	XIA W, XUE H, WANG J, et al. Functionalized graphene serving as free radical scavenger and corrosion protection in gamma-irradiated epoxy composites[J]. Carbon, 2016, 101:315-323. https://www.sciencedirect.com/science/article/pii/S0008622316300975
[60]	LU H, ZHANG S, LI W, et al. Synthesis of graphene oxide-based sulfonated oligo anilines coatings for synergistically enhanced corrosion protection in 3.5% NaCl solution[J]. ACS Appl. Mater Interfaces, 4034-4043.https://www.researchgate.net/publication/312211944_Synthesis_of_Graphene_Oxide-Based_Sulfonated_Oligoanilines_Coatings_for_Synergistically_Enhanced_Corrosion_Protection_in_35_NaCl_Solution
[61]	CHENG C, QIU S, CUI M, et al. Achieving high performance corrosion and wear resistant epoxy coatings via incorporation of noncovalent functionalized graphene[J]. Carbon, 2017, 114:356-366. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=17727ccd920cbbbf18a601d6f18e1ace
[62]	WEI Y, WANG J, JIA X, et al. Polyaniline as corrosion protection coatings on cold rolled steel[J]. Polymer, 1995, 36(23):4535-4537. http://cn.bing.com/academic/profile?id=548175619c85ac6e6b38fee0b455cbe3&encoded=0&v=paper_preview&mkt=zh-cn
[63]	WEI Y, YANG C, DING T. ChemInform Abstract:A One-Step Method to Synthesize N, N'-Bis(4'-aminophenyl)-1, 4-quinonenediimine and Its Derivatives[J]. Cheminform, 2010, 27(22):731-734. https://www.researchgate.net/publication/250559798_ChemInform_Abstract_A_One-Step_Method_to_Synthesize_NN'Bis4'-aminophenyl-14-_quinonenediimine_and_Its_Derivatives
[64]	HSIU-YING HUANG, TSAO-CHENG HUANG, TZU-CHUN YEH, et al. Advanced anticorrosive materials prepared from amine-capped aniline trimer-based electroactive polyimide-clay nanocomposite materials with synergistic effects of redox catalytic capability and gas barrier properties[J]. Polymer, 2011, 52(11):2391-2400. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=ac6b554f03e8992862831a3b2ea779a7
[65]	DING R, CHEN S, LV J, et al. Study on graphene modified organic anti-corrosion coatings:A comprehensive review[J]. Journal of Alloys and Compounds, 2019, 806:611-635. http://cn.bing.com/academic/profile?id=c67f3d14a5ef98eeec8defda757e24f1&encoded=0&v=paper_preview&mkt=zh-cn
[66]	DONG R Y, CAO P, CAO G X, et al. DC electric field induced orientation of a graphene in water, Acta Phys. Sin, 2017, 66:218-225.
[67]	ZHOU J, WANG Q, SUN Q, et al. Ferromagnetism in semihydrogenated graphene sheet[J]. Nano Lett, 2009, 9:3867. http://cn.bing.com/academic/profile?id=47d558d234d3a7c065bd6ef641f60888&encoded=0&v=paper_preview&mkt=zh-cn
[68]	POURHASHEM S, VAEZI M R, RASHIDI A, et al. Exploring corrosion protection properties of solvent based epoxy-graphene oxide nanocomposite coatings on mild steel[J]. Corrosion Science, 2017, 115:78-92. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=45d739ad6b0396539337e93fab2210e7
[69]	POURHASHEM S, RASHIDI A, VAEZI M R, et al. Excellent corrosion protection performance of epoxy composite coatings filled with amino-silane functionalized graphene oxide[J]. Surface and Coatings Technology, 2017, 317:1-9. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=d4a8bc0ad2ea00bb92b990e52dec3ee4
[70]	GONG L X, PEI Y B, HAN Q Y, et al. Polymer grafted reduced graphene oxide sheets for improving stress transfer in polymer composites, Compos. Sci. Technol, 2016, 134:144-152. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=6c24b514a70ca5e627e1a44f2936c3e8
[71]	TANG L C, WAN Y J, YAN D, et al. The effect of graphene dispersion on the mechanical properties of graphene/epoxy composites, Carbon, 2013, 60:16-27. http://cn.bing.com/academic/profile?id=1a70bb50bfc1bfcc23b1002f7e79df75&encoded=0&v=paper_preview&mkt=zh-cn
[72]	JIANG F W, ZHAO W J, WU Y M, et al. Anti-corrosion behaviors of epoxy composite coatings enhanced via graphene oxide with different aspect ratios[J]. Progress in Organic Coatings, 2019, 127:70-79. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=604918560d423a4b952b9d1b05f06ee1
[73]	S. POURHASHEM, M.R. VAEZI, A. RASHIDI, et al. Exploring corrosion protection properties of solvent based epoxy-graphene oxide nanocomposite coatings on mild steel[J]. Corros. Sci, 2016, 115:78-92. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=45d739ad6b0396539337e93fab2210e7
[74]	CHEN S S, BROWN L, LEVENDORF M, et al. Oxidation resistance of graphene-coated Cu and Cu/Ni alloy[J]. ACS Nano, 2011, 5:1321. http://cn.bing.com/academic/profile?id=fd2034413c2e477e02d7e15fa7dc226e&encoded=0&v=paper_preview&mkt=zh-cn
[75]	CHI J H, CHEN S, CHEN X F, et al. Research progress and application of graphene anticorrosive coatings[J]. Equip Environ Eng, 2018, 15(5):56. http://en.cnki.com.cn/Article_en/CJFDTotal-JSCX201805012.htm
[76]	FAYYAD E M, SADASIVUNI K K, PONNAMMA D, et al. Oleic acid-grafted chitosan/graphene oxide composite coating for corrosion protection of carbon steel[J]. Carbohydrate Polymers, 2016, 151:871-878. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=eee54b0c96dcabe9790c42d1c1c08fe0
[77]	DING R, ZHENG Y, YU H, et al. Study of water permeation dynamics and anti-corrosion mechanism of graphene/zinc coatings, J. Alloy. Comp, 2018, 748:81-495. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=b1909ee5b908780373c3512c776df337
[78]	DING R, WANG X, JIANG J, et al. Study on evolution of coating state and role of graphene in graphene-modified low-zinc waterborne epoxy anticorrosion coating by electrochemical impedance spectroscopy[J]. Journal of Materials Engineering and Performance, 2017, 26:3319-3335. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=681bbafca38be55bbd03a97a0916bfc3
[79]	DING R, CHEN S, ZHOU N, et al. The diffusion-dynamical and electrochemical effect mechanism of magnetic graphene oriented arrangement on zinc-rich coatings and the electrody-namics and quantum mechanics mechanism of electron conduction in zinc-rich graphene coatings[J]. J. Alloy. Comp, 2019, 784:756-768.