轻质多孔结构制备及响应面优化

何凯, 裴向军, 张晓超, 李强, 候谦儒, 王萌琪, 黄山松, 蒙明辉. 轻质多孔结构制备及响应面优化[J]. 水文地质工程地质, 2024, 51(6): 208-218. doi: 10.16030/j.cnki.issn.1000-3665.202309012
引用本文: 何凯, 裴向军, 张晓超, 李强, 候谦儒, 王萌琪, 黄山松, 蒙明辉. 轻质多孔结构制备及响应面优化[J]. 水文地质工程地质, 2024, 51(6): 208-218. doi: 10.16030/j.cnki.issn.1000-3665.202309012
HE Kai, PEI Xiangjun, ZHANG Xiaochao, LI Qiang, HOU QianRu, WANG Mengqi, HUANG Shansong, MENG Minghui. Preparation and response surface optimization of lightweight porous structures[J]. Hydrogeology & Engineering Geology, 2024, 51(6): 208-218. doi: 10.16030/j.cnki.issn.1000-3665.202309012
Citation: HE Kai, PEI Xiangjun, ZHANG Xiaochao, LI Qiang, HOU QianRu, WANG Mengqi, HUANG Shansong, MENG Minghui. Preparation and response surface optimization of lightweight porous structures[J]. Hydrogeology & Engineering Geology, 2024, 51(6): 208-218. doi: 10.16030/j.cnki.issn.1000-3665.202309012

轻质多孔结构制备及响应面优化

  • 基金项目: 四川省自然科学基金项目(2023NSFSC0378);地质灾害防治与地质环境保护国家重点实验室自主课题(SKLGP2021Z018);新疆维吾尔自治区地质矿产勘查开发局地质勘查项目(XGMB202358)
详细信息
    作者简介: 何凯(1999—),男,硕士研究生,主要从事生态修复方向的研究工作。E-mail:hekai_1999@163.com
    通讯作者: 张晓超(1978—),女,博士,教授,主要从事地质灾害调查及岩土工程试验研究。E-mail:31685032@qq.com
  • 中图分类号: TU528

Preparation and response surface optimization of lightweight porous structures

More Information
  • 多孔结构作为新型建筑材料结构,目前依然存在制备材料最佳配比不准确、结构材料与植物相容性差等问题影响其应用。为确定制备多孔结构最佳材料配比,提高其力学强度的同时具有良好植生空间,文章采用轻质多孔火山石作为粗骨料,水泥、粉煤灰、拌合水搅拌而成的胶凝浆体作为胶结剂,制作轻质多孔材料,开展相关的多孔结构制备试验并探究其不同单因素水平下的物理力学性能,得到合理的配合比范围,并采用响应面进行优化,得到满足一定抗压强度、具有良好植生空间及透水性能的最佳材料配合比。结果如下:(1)抗压强度随着水灰比增大呈现先增大后减小的变化趋势,最佳水灰比约0.35,骨料粒径越小,多孔结构抗压强度越高,但为了满足多孔性和透水性,选取2 cm左右的骨料较为适宜;(2)胶凝浆体中胶凝材料由质量占比75%的水泥与25%的粉煤灰组成,并含有0.1%的减水剂,应控制浆体含量为15%~25%,且不应超过30%;(3)根据响应面优化分析,制备多孔结构最优化配合比为:骨料粒径约2 cm,水灰比0.377,胶凝材料体积含量20.7%,在该配比下孔隙率、有效孔隙率和透水系数分别为:38.3%、33.5%、2.98 cm/s。最佳配比下的多孔结构既满足其力学要求,同时具有良好的植物相容性,研究成果可为多孔结构的制备与应用提供科学依据。

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  • 图 1  试件制备

    Figure 1. 

    图 2  抗压强度测试

    Figure 2. 

    图 4  不同因素下的孔隙率变化

    Figure 4. 

    图 3  不同因素下的抗压强度变化

    Figure 3. 

    图 5  不同因素下的透水系数变化

    Figure 5. 

    图 6  有效孔隙率与全孔隙率的关系

    Figure 6. 

    图 7  有效孔隙率与透水系数的关系

    Figure 7. 

    图 8  骨料粒径与水灰比对抗压强度的交互影响

    Figure 8. 

    图 9  骨料粒径与胶凝材料体积含量对抗压强度的交互影响

    Figure 9. 

    图 10  水灰比与胶凝浆体体积对抗压强度的交互影响

    Figure 10. 

    图 11  预测抗压强度值与试验值对比

    Figure 11. 

    表 1  水灰比单因素试验设计

    Table 1.  Single factor test design of water cement ratio

    序号 水灰比 胶凝材料
    体积占比/%
    骨料
    /(kg·m−3
    水泥
    /( kg·m−3
    粉煤灰
    /( kg·m−3
    拌合水
    /( kg·m−3
    减水剂质
    量分数/%
    1 0.25 20 720 274.8 68.7 85.9 0.1
    2 0.30 20 720 253.9 63.5 95.2 0.1
    3 0.35 20 720 234.5 58.6 102.6 0.1
    4 0.40 20 720 218.6 54.7 109.3 0.1
    下载: 导出CSV

    表 2  胶凝材料体积含量单因素试验设计

    Table 2.  Single factor test design of volume content of cementitious material

    序号 水灰比 胶凝材料
    体积占比/%
    骨料/
    (kg·m−3
    水泥/
    (kg·m−3
    粉煤灰/
    (kg·m−3
    拌合水/
    (kg·m−3
    减水剂质
    量分数/%
    1 0.35 15 720 190.8 47.7 83.5 0.1
    2 0.35 20 720 244.5 61.1 107.0 0.1
    3 0.35 25 720 293.2 73.3 128.3 0.1
    4 0.35 30 720 340.1 85.0 148.8 0.1
    下载: 导出CSV

    表 3  骨料粒径区间单因素试验设计

    Table 3.  Single factor test design of aggregate particle size interval

    序号 水灰比 胶凝材料
    体积占比%
    骨料
    /(kg·m−3
    骨料粒径
    /mm
    水泥
    /(kg·m−3
    粉煤灰
    /(kg·m−3
    拌合水
    /(kg·m−3
    减水剂质
    量分数/%
    1 0.35 20% 796 9.5~16.0 254.5 63.6 111.3 0.1
    2 0.35 20% 762 16.0~19.0 244.5 61.1 107.0 0.1
    3 0.35 20% 720 19.0~26.5 234.5 58.6 102.6 0.1
    4 0.35 20% 683 26.5~31.5 226.7 56.7 99.2 0.1
    下载: 导出CSV

    表 4  水灰比单因素试验结果

    Table 4.  Results of single factor test of water cement ratio

    序号 水灰比 抗压强度/MPa 孔隙率/% 透水系数
    /(cm·s−1
    7 d 28 d 全孔隙率 有效孔隙率
    1 0.25 0.28 0.32 40 36 2.90
    2 0.30 0.58 0.62 42 37 3.03
    3 0.35 0.95 1.10 43 37 3.19
    4 0.40 0.74 0.82 44 39 3.23
    下载: 导出CSV

    表 5  胶凝材料体积含量单因素试验结果

    Table 5.  Results of single factor test of volume content of cementitious materials

    序号 胶凝材料
    体积含量/%
    抗压强度/MPa 孔隙率/% 透水系数
    /(cm·s−1
    7 d 28 d 全孔隙率 有效孔隙率
    1 15 0.69 0.79 45 41 3.52
    2 20 1.02 1.12 40 36 3.11
    3 25 1.78 1.90 38 32 2.15
    4 30 2.20 2.37 34 27 0.06
    下载: 导出CSV

    表 6  骨料粒径区间单因素试验结果

    Table 6.  Results of single factor test of aggregate particle size range

    序号 骨料粒径
    /mm
    抗压强度/MPa 孔隙率/% 透水系数
    /(cm·s−1
    7 d 28 d 全孔隙率 有效孔隙率
    1 9.5~16.0 1.55 1.81 42 35 2.83
    2 16.0~19.0 1.22 1.24 41 37 2.98
    3 19.0~26.5 1.02 1.15 40 38 3.22
    4 26.5~31.5 0.64 0.72 45 39 3.24
    下载: 导出CSV

    表 7  自变量因素水平表

    Table 7.  Independent variable factor level

    自变量 代号 自变量水平
    −1 0 1
    骨料粒径/mm X1 16.0~19.0 19.0~26.5 26.5~35.0
    水灰比 X2 0.30 0.35 0.40
    胶凝材料体积含量/% X3 15 20 25
    下载: 导出CSV

    表 8  响应面试验结果

    Table 8.  Results of response surface test

    编号 X1 X2 X3 Y1/MPa
    1 −1 −1 0 1.24
    2 1 −1 0 0.90
    3 −1 1 0 1.24
    4 1 1 0 0.90
    5 −1 0 −1 0.83
    6 1 0 −1 0.69
    7 −1 0 1 1.35
    8 1 0 1 0.92
    9 0 −1 −1 0.75
    10 0 1 −1 0.85
    11 0 −1 1 1.27
    12 0 1 1 1.28
    13 0 0 0 1.27
    14 0 0 0 1.33
    15 0 0 0 1.21
    16 0 0 0 1.26
    17 0 0 0 1.36
    下载: 导出CSV

    表 9  回归模型方差分析

    Table 9.  Regression model analysis of variance

    方差来源 平方和 自由度 均方 F P 显著性
    模型 0.8560 9 0.0952 31.3500 <0.0001 **
    X1 0.1907 1 0.1907 50.0400 <0.0001 **
    X2 0.0014 1 0.0014 0.3215 0.5221
    X3 0.3604 1 0.3604 77.0000 <0.0001 **
    X1X2 0.0001 1 0.0001 0.0126 0.9137
    X1X3 0.0204 1 0.0204 8.3700 0.0232 *
    X2X3 0.0019 1 0.0019 0.4153 0.5398
    X12 0.0960 1 0.0960 27.5700 0.0012 *
    X22 0.0154 1 0.0154 1.5700 0.2506
    X32 0.1460 1 0.1460 34.6700 0.0006 *
    残差 0.0212 7 0.0030
    失拟项 0.0072 3 0.0024 0.6820 0.6078
    纯误差 0.0141 4 0.0035
    总变异 0.8779 16
    R2 0.9670
    $R^2_{{\mathrm{Adj}}} $ 0.9247
    $R^2_{{\mathrm{pred}}} $ 0.8439
      注:表中**表示极显著差异;*表示显著差异;$R^2_{{\mathrm{Adj}}} $为修正决定系数;$R^2_{{\mathrm{pred}}}$为预测决定系数;空白表示该项不存在此类数据。
    下载: 导出CSV
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出版历程
收稿日期:  2023-09-05
修回日期:  2023-12-22
刊出日期:  2024-11-15

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