DISTRIBUTION PATTERN OF HEAVY METALS IN SURFACE SEDIMENTS OF THE YANGTZE ESTUARY AND ADJACENT AREAS AND ITS ECOLOGICAL RISK
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摘要: 对长江口及其邻近海域表层沉积物中重金属Cu、Mn、Pb、Zn、Cr、Fe、Hg、Cd的含量分布以及富集状况进行分析,并采用Hakanson潜在生态危害指数法评价该海域中Cu、Pb、Zn、Cr、Hg、Cd污染的程度及其潜在的生态危害,结果表明:长江口及其邻近海域表层沉积物中Cu、Mn、Pb、Zn、Cr、Fe的分布特征表现为由近岸向远岸递减的趋势,整体上象山县和舟山群岛近岸海域的含量高于研究区北部含量;Hg在长江口南端含量较高,呈由西向东递减的趋势;Cd在长江口南端以及象山县东含量较高,在研究区中部含量较低。潜在生态危害评价结果表明,长江口及其邻近海域表层沉积物只有部分站点处于生态危害的中等级别,大多站点生态危害轻微,污染程度顺序为Cd > Hg > Cu > Pb > Cr > Zn;对长江口及其邻近海域生态环境具有潜在影响的重金属元素首先是Cd,其次是Hg。对底质环境质量进行系统聚类分析结果显示,象山县和长江口外以及济州岛西南近海海域的底质环境较差,应予以重视。Abstract: The concentration and distribution pattern of heavy metals of Cu,Mn,Pb,Zn,Cr,Fe,Hg,Cd in the surface sediments of the Yangtze estuary and its adjacent areas were studied.Hakanson index method was used to evaluate the pollution level of the heavy metals of Cu,Pb,Zn,Cr,Hg,Cd and their ecological vulnerability. It is found that the elements of Cu、Mn、Pb、Zn、Cr、Fe are distributed in a declined pattern from the coast to the offshore within the estuary and its adjacent areas.The contents of these heavy metals are, in general, higher in the Xiangshan County and Zhoushan Islands rather than in the northern part.Hg is higher in the southern estuary and declines from the west to the east, while Cd is high in the south but lower in the middle estuary.Ecological assessment proves that the major part of the surface sediment in the Yangtze estuary and its adjacent areas is slightly vulnerable except some sites which are in the rank of moderate ecological risk.The risk index of these heavy metals are in an order of Cd > Hg > Cu > Pb > Cr > Zn.The heavy metals which might bring ecological danger to the environment within the estuary and its adjacent areas are firstly Cd and then Hg.According to the results of cluster analysis,we conclude that Xiangshan County and the offshore area out of the Yangtze Estuary up to the southwest of the Cheju Island are more vulnerable, and, therefore, more attention is required.
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Key words:
- sediments /
- heavy metal /
- potential ecological risk /
- Yangtze estuary
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[1] Chapman P M, Wang P Y, et al. Appropriate applications of sediment quality values for metals and metalloids[J]. Environmental Science & Technology,1999, 33(22):3937-3941.
[2] Emmerson R H C, O'reilly-Wiese S B, Macleod C L, et al. A multivariate assessment of metal distribution in intertidal sediments of the Blackwater estuary,UK[J]. Marine Pollution Bulletin,1997,34(11):960-968.
[3] Schubel R J. The estuary as a filter for fine grained suspended sediments in the estuarine environment[J]. Technical Report Reld,1983(14):310-313.
[4] 孟紫强. 环境毒理学基础[M]. 北京:高等教育出版社,2003:183-246.[MENG Ziqiang. Basis of Environmental Toxicology[M]. Beijing:Higher Education Press, 2003:183
-246.]
[5] Lawrence A L, Mason R P. Factors controlling the bioaccumulation of mercury and methylmercury by the estuarine amphipod Leptocheirus plumulosus[J]. Environmental Pollution,2001,111:217-231.
[6] 张丽洁, 王贵, 姚德, 等. 近海沉积物重金属研究及环境意义[J]. 海洋地质动态,2003,19(3):6-9.
[ZHANG Lijie,WANG Gui,YAO De, et al. Environment significance and research of heavy metals in offshore sediments[J].Marine Geology Letters,2003,19(3):6-9.]
[7] 李玉, 冯志华, 李谷祺,等. 连云港近岸海域沉积物中重金属污染来源及生态评价[J]. 海洋与湖沼,2010,41(6):829-833.
[LI Yu,FENG Zhihua,LI Guqi. The estimation of source of heavy metal contamination and assessment in marine sediments in Lianyungang area[J].Oceanologia et Limnologia Sinica,2010,41(6):829-833.]
[8] Tretey J H. History of heavy metal input to Mississippi Delta sediments[J]. Estuaries,1985,12(2):231-239.
[9] 国家海洋局. 2003年中国海洋环境质量公报[R]. 北京:国家海洋局,2004.[National Bureau of Oceanography. Report on the State of the Marine Environment in China, P.R.C in 2003[R].Beijing:National Bureau of Oceanography,2004.]
[10] 国家海洋局. 2004年中国海洋环境质量公报[R]. 北京:国家海洋局,2005.[National Bureau of Oceanography. Report on the State of the Marine Environment in China, P.R.C in 2004[R].Beijing:National Bureau of Oceanography,2005.]
[11] 国家海洋局. 2005年中国海洋环境质量公报[R]. 北京:国家海洋局,2006.[National Bureau of Oceanography. Report on the State of the Marine Environment in China, P R C in 2005[R].Beijing:National Bureau of Oceanography,2006.]
[12] 陈敏, 陈邦林, 夏福兴, 等. 长江口最大浑浊带悬移质、底质微量金属形态分布[J]. 华东师范大学学报:自然科学版,1996(1):38-44.[CHEN Min,CHEN Banglin,XIA Fuxing, et al. Speciation of Trace Metals in Suspended Particles and Surface Benthic Sediment in the Maximum Turbidity Zones of the Changjiang Estuary[J].Journal of East China Normal University(Natural Science), 1996
(1):38-44.]
[13] 孟翊, 刘苍字, 程江. 长江口沉积物重金属元素地球化学特征及其底质环境评价[J]. 海洋地质与第四纪地质,2003,23(3):37-43.
[MENG Yi,LIU Cangzi,CHENG Jiang. Geochemical characteristics of heavy metal elements in the surface sediments in the Yangtze River Estuarine area and evaluations of the bed materials[J].Marine Geology and Quaternary Geology, 2003,23(3):37-43.]
[14] 李莲芳, 曾希柏, 李国学, 等. 北京市温榆河沉积物的重金属污染风险评价[J]. 环境科学学报,2007,27(2):289-297.
[LI Lianfang,ZEN Xibai,LI Guoxue, et al. Heavy metal pollution of Wenyu River sediment and its risk assessment[J].Acta Scientiae Circum Stantiae,27(2):289-297.]
[15] 刘哲民.宝鸡土壤重金属污染及其防治[J].干旱区资源与环境,2005,19(2):101-104.
[LIU Zhemin. Heavy metals pollution in vegetable fields and its prevention[J]. Journal of Arid Land Resources and Environment, 2005,19(2):101-104.]
[16] Forstner U. Lecture Notes in Earth Sciences (Contaminated Sediments)[M]. Berlin:Springer Verleg,1989:107-109.
[17] 丁喜桂,叶思源,高宗军,等. 近海沉积物重金属污染评价方法[J]. 海洋地质动态,2005,21(8):31-36.
[DING Xigui,YE Siyuan,GAO Zongjun, et al. Methods of heavy metal pollution evaluation for offshore sediments[J]. Marine Geology Letters, 2005,21(8):31-36.]
[18] Hakanson L. An ecological risk index for aquatic pollution control:a sediment toxicological approach[J]. Water Research,1980,14(8):975-1001.
[19] 赵一阳, 鄢明才. 黄河、长江、中国浅海沉积物化学元素丰度比较[J]. 科学通报,1992,13:1202-1204.[ZHAO Yiyang, YAN Mingcai. The comparison of abundance of chemical elements in sediment of The Yellow River,the Yangtze River and China shallow sea[J]. Chinese Science Bulletin, 1992
,13:1202-1204.]
[20] 徐争启, 倪师军, 庹先国, 等. 潜在生态危害指数法评价中重金属毒性系数计算[J]. 环境科学与技术,2008,31(2):112-115.
[XUE Zhengqi, NI Junshi, TUO Xianguo, et al. Calculation of heavy metals'toxicity coefficient in the evaluation of potential ecological risk index[J]. Environmental Science&Technology, 2008,31(2):112-115.]
[21] 孙元敏, 陈彬, 黄海萍, 等. 中国南亚热带海岛海域沉积物重金属污染及潜在生态危害[J]. 中国环境科学,2011,31(1):123-130.
[SUN Yuanmin,CHEN Lin,HUANG Haiping, et al. Heavy metals contamination and potential ecological risk in the sediment of the sea areas around south subtropical islands, China[J]. China Environmental Science, 2011,31(1):123-130.]
[22] 董爱国,翟世奎,Zabel Matthias,等. 长江口及邻近海域表层沉积物中重金属元素含量分布及其影响因素[J].海洋学报,2009,31(6):54-68.
[DONG Aiguo,ZHAI Shikui, Zabel Matthias, et al. The distribution of heavy metal contents in surface sediments of the Changjiang Estuary in China and surrounding coastal areas[J].ACTA Oceanological Sinica, 2009,31(6):54-68.]
[23] 张怀静,翟世奎,范德江,等. 三峡工程一期蓄水后长江口及其邻近海域悬浮物浓度分布特征[J].环境科学,2007,28(8):1655-1661.
[ZHANG Huaijing,ZHAI Shikui,FAN Dejiang, et al. Distribution of suspended matter concentration in the Changjiang estuary and adjacent area after the first-stage storage of the Three Gorges project[J]. Environmental Science, 2007,28(8):1655-1661.]
[24] 孙毅,母清林,佘运勇,等. 长江口及邻近海域沉积物重金属分布特征及生态风险评价[J]. 浙江海洋学院学报:自然科学版,2011,30(2):107-111.
[SUN Yi,MU Qingliu, SHE Yunyong,et al. Distribution Patterns of Heavy Metals in Sediments of the Yangtze Estuary and its Adjacent Areas and Ecological Risk Assessment[J]. Journal of Zhejiang Ocean University(Natural Science), 2011,30(2):107-111.]
[25] 董爱国,翟世奎,于增慧,等. 长江口海域表层沉积物重金属元素的潜在生态风险评价[J].海洋科学,2010,34(3):69-75.
[DONG Aiguo,ZHAI Shikui,YU Zenghui, et al. Evaluation on potential ecological risk of the heavy metals in the surface sediments of the Changjiang(Yangtze)estuary and its adjacent coastal area[J]. Marine Sciences, 2010,34(3):69-75.]
[26] 张丽旭,蒋晓山,赵敏,等. 长江口洋山海域表层沉积物重金属的富积及其潜在生态风险评价[J]. 长江流域资源与环境,2007,16(3):351-356.
[ZHANG Lixu,JIANG Xioshan,ZHAO Min,et al. Accumulation of heavy metals in surface sediments from the sea region of Yangshan in the Yangtize Estuary with assessment of their potential ecological risk[J]. Resources and Environment in the Yangtze Basin, 2007,16(3):351-356.]
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