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摘要:
铝电解槽内衬及废旧阴极等材料的无害化处理及回收利用,不仅能解决其堆存导致的严重环境污染,还可实现资源再用,同时可满足生态文明建设与保障资源安全供给的国家重大战略需求。本文总结了废旧铝电解槽材料回收利用的研究现状,分析了这些废旧材料的应用前景,为之后废旧铝电解槽材料处理提供思路。
Abstract:The innocuous treatment and recycling of materials such as spent aluminum electrolytic cell lining and waste cathode can not only solve the serious environmental pollution caused by its stacking, but also realize the reuse of resources, and at the same time meet the national strategic needs of ecological civilization construction and resource security supply. This paper summarizes the research status of the recycling of waste materials in the spent aluminum electrolytic cell, analyzes the application prospects of these waste materials, and provides ideas for the future research of waste materials in spent aluminum electrolytic cells.
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Key words:
- Aluminum electrolytic cel /
- Lining /
- Waste cathode /
- Innocuous treatment
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表 1 我国铝电解槽内衬组成/%
Table 1. Composition of aluminum electrolytic cell lining in China
耐火保温材料 炭质材料 氟化物 氰化物 其他 30 37 30 0.20 2 表 2 废旧铝电解槽内衬物相分析结果/%
Table 2. Phase analysis results of waste cell liner
碳 氧化铝 冰晶石 氟化钠 碳酸钠 石英 氟化钙 其他 30 26 13 8 6 3 3 11 表 3 废旧阴极炭块中电解质的主要成分和含量/%
Table 3. Main composition and content of electrolyte in waste cathode carbon block
NaF Na3AlF6 Al2O3 NaAl11O17 CaF2 LiF 12.7 65.7 5.6 4.6 2.9 2.7 -
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