Research Progress in the Application of Red Mud in Water, Soil and Air Environmental Treatment
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摘要:
中国作为世界上最大的氧化铝生产国,产生的大量赤泥对环境造成严重影响。我国多年来一直重视赤泥的安全处置问题,以环境资源的可持续发展为主,以赤泥的资源化利用及无害化处理为手段,以实现赤泥二次资源化利用为最终目的,展开了多领域、多学科的赤泥综合利用技术研究。本文系统地阐述了赤泥的物理、化学性质以及赤泥在污水处理、土壤修复、废气处理等环境治理中的综合应用情况,展望了赤泥在今后环境治理中的应用前景。
Abstract:As the largest alumina producer in the world, China produces a large amount of red mud that has a serious impact on the environment. For many years, China has attached great importance to the treatment of red mud, focusing on the sustainable development of resources and the environment, taking the use of red mud as a means to achieve the secondary purpose of red mud utilization. Researches on the comprehensive utilization technology of red mud in multiple fields and disciplines were carried out. This paper systematically elaborated the physical and chemical properties of red mud and its comprehensive application in environmental management such as sewage treatment, soil remediation, and waste gas treatment, and prospected the future application of red mud in environmental treatment.
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表 1 国内不同地区赤泥的理化特性
Table 1. Physicochemical properties of red mud in different regions of China
样品(一水硬铝石) 河南 广西 山西 山东 Al2O3/% 25.48 18.87 10.50 8.32 SiO2/% 20.58 8.87 22.20 32.50 Fe2O3/% 11.77 34.25 6.75 5.70 TiO2/% 4.14 6.05 2.55 / K2O/% 2.07 0.08 0.85 / Na2O% 6.55 4.35 3.00 2.33 CaO/% 13.97 13.59 45.25 41.62 MgO/% 1.54 0.41 2.46 / 比表面积/(m2·g-1) 11.65 7.37 5.31 / 孔隙体积/(10-3cm3·g-1) 11.15 7.05 4.75 / 平均孔径/nm 3.83 3.82 3.58 / 分形维数 2.75 2.75 2.78 / 注:“/”表示基准未经过试 表 2 2009年我国赤泥利用现状
Table 2. Status of utilization of red mud in China in 2009
赤泥 利用方法 体积用量 注 烧结/复合法 建筑及建筑材料 200~250 ktpa 直接使用赤泥 玻璃、陶瓷 100 ktpa 来自三水铝石和一水硬铝石的高铁赤泥 钢铁生产 800~1000 ktpa 从赤泥中分离出铁矿石 水泥 800~1000 ktpa 建筑材料(砖) 1000~1300 ktp 从赤泥中分离出沙子 来自中国一水硬铝矿的拜耳法赤泥 稀土元素 N/A 研究中 其余的赤泥 聚合物填料 10 ktpa 环境保护 10 kt 试点研究中 总计 3000~3600 ktp -
[1] Power G, Gräfe M, Klauber C. Bauxite residue issues: I. Current management, disposal and storage practices[J]. Hydrometallurgy, 2011, 108(1-2):33-45. doi: 10.1016/j.hydromet.2011.02.006
[2] 顾汉念, 王宁, 刘世荣, 等. 烧结法赤泥的物质组成与颗粒特征研究[J]. 岩矿测试, 2012, 31(2):312-7. doi: 10.3969/j.issn.0254-5357.2012.02.022
GU H N, WANG N, LIU S R, et al. Study on the material composition and particle characteristics of sintering red mud[J]. Rock and Mineral Analysis, 2012, 31(2):312-7. doi: 10.3969/j.issn.0254-5357.2012.02.022
[3] 刘大钧. 浅谈氧化铝工业污染防治对策[J]. 轻金属, 2011(2):3-7+10.
LIU D J. Talking about the Pollution Prevention and Control Countermeasures of Alumina Industry[J]. Light Metals, 2011(2):3-7+10.
[4] Liu W, Chen X, Li W, et al. Environmental assessment, management and utilization of red mud in China[J]. Journal of Cleaner Production, 2014, 84(dec.1):606-10.
[5] 景英仁, 景英勤, 杨奇. 赤泥的基本性质及其工程特性[J]. 轻金属, 2001(4):20-3. doi: 10.3969/j.issn.1002-1752.2001.04.006
JING Y R, JING Y Q, YANG Q. The basic properties of red mud and its engineering characteristics[J]. Light Metals, 2001(4):20-3. doi: 10.3969/j.issn.1002-1752.2001.04.006
[6] 朱德庆, 翟勇, 潘建, 等. 煤基直接还原—磁选超微细贫赤铁矿新工艺[J]. 中南大学学报(自然科学版), 2008, 39(06):1132-8.
ZHU D Q, ZHAI Y, PAN J, et al. Coal-based direct reduction-a new process for magnetic separation of ultra-fine lean hematite[J]. Journal of Central South University(Science and Technology), 2008, 39(06):1132-8.
[7] 蒋文艳, 张琳叶, 龙建沿, 等. 赤泥基环境修复材料的制备及应用进展[J]. 现代化工, 2018, 38(5):29-33.
JIANG W Y, ZHANG L Y, LONG J Y, et al. Progress in the preparation and application of red mud-based environmental remediation materials[J]. Modern Chemical Industry, 2018, 38(5):29-33.
[8] 包惠明, 傅涛. 赤泥的综合利用现状分析[J]. 矿产综合利用, 2018(5):6-12. doi: 10.3969/j.issn.1000-6532.2018.05.002
BAO H M, FU T. Analysis on the current situation of comprehensive utilization of red mud[J]. Mineral Resources, 2018(5):6-12. doi: 10.3969/j.issn.1000-6532.2018.05.002
[9] 孙栀子, 孙振平. 赤泥基本性能及其在水泥和混凝土中的应用研究进展[J]. 粉煤灰, 2014, 26(2):15-9.
SUN Z Z, SUN Z P. The basic properties of red mud and its application in cement and concrete[J]. Fly Ash Comprehensive Utilization, 2014, 26(2):15-9.
[10] 吴波, 张德成, 张昭忠, 等. 利用赤泥生产加气混凝土砌块的研究[J]. 中国资源综合利用, 2005(6):29-31. doi: 10.3969/j.issn.1008-9500.2005.06.009
WU B, ZHANG D C, ZHANG S Z, et al. Research on using red mud to produce aerated concrete blocks[J]. China Resources Comprehensive Utilization, 2005(6):29-31. doi: 10.3969/j.issn.1008-9500.2005.06.009
[11] 李小雷, 翟二安, 陶丰, 等. 低温熔融法制备拜耳法赤泥质微晶石的研究[J]. 新型建筑材料, 2011, 38(3):61-3. doi: 10.3969/j.issn.1001-702X.2011.03.017
LI X L, ZHAI E A, TAO F, et al. Study on preparation of Bayer Process red mud microcrystallite by low temperature melting method[J]. New Building Material, 2011, 38(3):61-3. doi: 10.3969/j.issn.1001-702X.2011.03.017
[12] 南相莉, 张廷安, 刘燕, 等. 我国主要赤泥种类及其对环境的影响[J]. 过程工程学报, 2009, 9(S1):459-64.
NAN X L, ZHANG T A, LIU Y, et al. The main types of red mud in my country and their impact on the environment[J]. Chinese Journal of Process Engineering, 2009, 9(S1):459-64.
[13] 王腾飞, 张金山, 李侠, 等. 碱法提取高铝粉煤灰中氧化铝的研究进展[J]. 矿产综合利用, 2019(1):16-21. doi: 10.3969/j.issn.1000-6532.2019.01.004
WANG T F, ZHANG J S, LI X, et al. Research progress of extracting alumina in alkali method from high- alumina coal fly ash[J]. Multipurpose Utilization of Mineral Resources, 2019(1):16-21. doi: 10.3969/j.issn.1000-6532.2019.01.004
[14] 章庆和, 庄剑鸣, 王隆千. 赤泥综合利用的现状及在塑料生产中的应用[J]. 矿产综合利用, 1994(01):37-40.
ZHANG Q H, ZHUANG J M, WANG L Q. The current situation of comprehensive utilization of red mud and its application in plastic production[J]. Mineral Resources, 1994(01):37-40.
[15] 刘述仁, 谢刚, 李荣兴, 等. 氧化铝厂废渣赤泥的综合利用[J]. 矿冶, 2015, 24(3):72-5. doi: 10.3969/j.issn.1005-7854.2015.03.018
LIU S R, XIE G, LI R X, et al. Comprehensive utilization of waste residue and red mud in alumina plant[J]. Mining and Metallurgy, 2015, 24(3):72-5. doi: 10.3969/j.issn.1005-7854.2015.03.018
[16] Liu Y, Naidu R, Ming H. Red mud as an amendment for pollutants in solid and liquid phases[J]. Geoderma, 2011, 163(1-2):0-12.
[17] 史力争, 陈惠康, 吴川, 等. 赤泥及其复合钝化剂对土壤铅、镉和砷的稳定效应[J]. 中国科学院大学学报, 2018, 35(05):617-626.
SHI L Z, CHEN H K, WU C, et al. Stabilizing effect of red mud and its compound passivation agent on soil lead, cadmium and arsenic[J]. Journal of University of Chinese Academy of Sciences, 2018, 35(05):617-626.
[18] Hua Y, Heal KV, Friesl-Hanl W. The use of red mud as an immobiliser for metal/metalloid-contaminated soil: A review[J]. Journal of Hazardous Materials, 2016:325.
[19] 王斌, 朱文凤, 王林江, 等. 广西拜尔法赤泥烧胀陶粒制备及对水体中Pb~(2+)的吸附[J]. 武汉理工大学学报, 2014, 36(4):30-34.
WANG B, ZHU W F, WANG L J, et al. Preparation of Guangxi Bayer Process red mud swelling ceramsite and adsorption of Pb2+ in water[J]. Journal of Wuhan University of Technology, 2014, 36(4):30-34.
[20] 马巧珊, 范方方. 赤泥基聚合硫酸铝铁絮凝剂的制备与应用研究[J]. 山东化工, 2018, 47(24):201-3. doi: 10.3969/j.issn.1008-021X.2018.24.088
MA Q S, FAN F F. Study on the preparation and application of red mud-based polyaluminum iron sulfate flocculant[J]. Shandong Chemical Industry, 2018, 47(24):201-3. doi: 10.3969/j.issn.1008-021X.2018.24.088
[21] 李尉卿, 李舒, 郑作杰, 等. 氧化铝厂赤泥在垃圾渗滤液处理中的吸附和脱氮研究[J]. 现代科学仪器, 2008(5):96-9.
LI W Q, LI S, ZHENG Z J, et al. Study on the adsorption and denitrification of red mud from alumina plant in the treatment of landfill leachate[J]. Modern Scientific Instruments, 2008(5):96-9.
[22] 张书武, 韩宾, 安文超. 改性赤泥负载瓷砂滤料吸附剂的制备与表征[J]. 应用化工, 2018, 47(12):2568-71+76. doi: 10.3969/j.issn.1671-3206.2018.12.004
ZHANG S W, HAN B, AN W C. Preparation and Characterization of Modified Red Mud Loaded Porcelain Sand Filter Adsorbent[J]. Applied Chemical Industry, 2018, 47(12):2568-71+76. doi: 10.3969/j.issn.1671-3206.2018.12.004
[23] Lombi E, Zhao F J, Wieshammer G, et al. In situ fixation of metals in soils using bauxite residue: biological effects[J]. Environmental Pollution, 2002, 118(3):445-52. doi: 10.1016/S0269-7491(01)00295-0
[24] Zhou R, Liu X, Luo L, et al. Remediation of Cu, Pb, Zn and Cd-contaminated agricultural soil using a combined red mud and compost amendment[J]. International Biodeterioration & Biodegradation, 2017, 118:73-81.
[25] 李东洁, 刘树庆, 李鹏, 等. 高肥料投入条件下不同污泥用量对油菜生长及品质的影响[J]. 农业环境科学学报, 2013, 32(09):1752-7.
LI D J, LIU S Q, L P, et al. Effects of different amounts of sludge on the growth and quality of rape under the condition of high fertilizer input[J]. Journal of Agro-Environment Science, 2013, 32(09):1752-7.
[26] 蔡德龙, 钱发军, 陈常友, 等. 赤泥硅肥在玉米上试验研究[J]. 地域研究与开发, 1997(3):83-4.
CAI D L, QIAN F J, CHEN C Y, et al. Experimental research on red mud silicon fertilizer on corn[J]. Areal Research and Development, 1997(3):83-4.
[27] 金永铎. 国内外矿产资源综合利用现状及发展方向[J]. 矿产综合利用, 1996(2):35-9.
JIN Y D. The current situation and development direction of comprehensive utilization of mineral resources at home and abroad[J]. Mineral Resources, 1996(2):35-9.
[28] 何伯泉, 周国华, 薛玉兰. 赤泥在环境保护中的应用[J]. 轻金属, 2001(2):24-6. doi: 10.3969/j.issn.1002-1752.2001.02.007
HE B Q, ZHOU G H, XIE Y L. Application of Red Mud in Environmental Protection[J]. Light Metals, 2001(2):24-6. doi: 10.3969/j.issn.1002-1752.2001.02.007
[29] 舒月红, 陈杰, 方瑜, 等. 赤泥处理铅酸蓄电池厂硫酸雾研究[J]. 华南师范大学学报(自然科学版), 2015, 47(1):55-9.
SHU Y H, CHEN J, FANG Y, et al. Study on Red Mud Treatment of Sulfuric Acid Fog in Lead-acid Battery Plant[J]. Journal of South China Normal University(Natural Science Edition), 2015, 47(1):55-9.
[30] 杨凌云. 拜耳法氧化铝赤泥无害化处理探讨[J]. 化工管理, 2019(23):55-6. doi: 10.3969/j.issn.1008-4800.2019.23.039
YANG L Y. Discussion on the Harmless Treatment of Alumina Red Mud by Bayer Process[J]. Chemical Enterprise Management, 2019(23):55-6. doi: 10.3969/j.issn.1008-4800.2019.23.039
[31] 竹涛, 王若男, 金鑫睿, 等. 以废治废——铝厂固废赤泥治理工业废气二氧化硫的应用研究[J]. 有色金属工程, 2019, 9(7):109-14. doi: 10.3969/j.issn.2095-1744.2019.07.017
ZHU T, WANG R N, JIN X R, et al. Treating Waste with Waste——Application Research on Treatment of Industrial Waste Gas Sulfur Dioxide with Solid Waste Red Mud in Aluminum Plant[J]. Nonferrous Metals Engineering, 2019, 9(7):109-14. doi: 10.3969/j.issn.2095-1744.2019.07.017
[32] 陈义, 李军旗, 黄芳, 等. 拜耳赤泥吸收SO2废气的性能研究[J]. 贵州工业大学学报(自然科学版), 2007(4):30-2+6.
CHEN Y, LI J Q, HUANG F, et al. Study onperformance of bayer red mud absorbing SO2 waste gas[J]. Journal of Guizhou University of Technology(Natural Science Edition), 2007(4):30-2+6.
[33] 李彬, 吴恒, 王枝平, 等. 碱性固废赤泥脱硫脱硝研究进展[J]. 硅酸盐通报, 2019, 38(5):1401-7+19.
LI B, WU H, WANG Z P, et al. Research progress on desulfurization and denitrification of alkaline solid waste red mud[J]. Bulletin of the Chinese Ceramic Society, 2019, 38(5):1401-7+19.
[34] 林建飞, 李忆冬, 韩敏芳, 等. 用赤泥捕集二氧化碳[J]. 化工环保, 2013, 33(6):549-52. doi: 10.3969/j.issn.1006-1878.2013.06.017
LIN J F, LI Y D, HAN M F, et al. Use red mud to capture carbon dioxide[J]. Environmental Protection of Chemical Industry, 2013, 33(6):549-52. doi: 10.3969/j.issn.1006-1878.2013.06.017
[35] 南相莉, 李凤华, 胡恩柱. 基于超声波机械搅拌耦合作用下赤泥对二氧化碳的固化封存[J]. 环境工程学报, 2018, 12(10):2973-9. doi: 10.12030/j.cjee.201805010
NAN X L, LI F H, HU E Z. Solidification and storage of carbon dioxide by red mud based on the coupling of ultrasonic mechanical agitation[J]. Chinese Journal of Environmental Engineering, 2018, 12(10):2973-9. doi: 10.12030/j.cjee.201805010
[36] Nath H, Sahoo A. Red mud and its applicability in fluoride abatement[J]. 2018.
[37] 肖晓阳, 徐学鸥. 赤泥的理化性质及综合利用[J]. 四川水泥, 2016(5):338. doi: 10.3969/j.issn.1007-6344.2016.05.325
XIAO X Y, XU X O. The physical and chemical properties of red mud and its comprehensive utilization[J]. Sichuan Cement, 2016(5):338. doi: 10.3969/j.issn.1007-6344.2016.05.325
[38] 马爱元, 郑雪梅, 李松, 等. 含锌钢铁冶金渣尘处理技术现状[J]. 矿产综合利用, 2020(4):1-7. doi: 10.3969/j.issn.1000-6532.2020.04.001
MA A Y, ZHENG X M, LI S, et al. Present situation of zinc metallurgical slags and dusts treatment technology[J]. Multipurpose Utilization of Mineral Resources, 2020(4):1-7. doi: 10.3969/j.issn.1000-6532.2020.04.001
[39] 侯淼, 刘然, 赵俊, 等. 烟煤烟气吸附剂脱汞技术的现状及展望[J]. 矿产综合利用, 2020(1):25-8. doi: 10.3969/j.issn.1000-6532.2020.01.004
HOU M, LIU R, ZHAO J, et al. Current status and prospects of mercury removal technology for bituminous coal flue gas adsorbent[J]. Mineral Resources, 2020(1):25-8. doi: 10.3969/j.issn.1000-6532.2020.01.004
-