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摘要:
为了解国内外冶金球团用膨润土粘结剂的研究进展，本文通过查阅大量国内外文献，首先介绍了膨润土资源背景、晶体结构、矿物组成和物化特性以及冶金球团用膨润土的性能指标和测评方法，着重对冶金球团用膨润土的性效关系、膨润土各性能指标与球团指标间的相关关系、膨润土粘结剂的制备现状以及膨润土粘结剂的作用机理等方面的国内外研究进展进行概述，以期为相关研究提供参考。
Abstract:In order to understand the research progress of bentonite binder used in metallurgical pellets in China and abroad, basing on a large number of literature, the resource background, crystal structure, mineral composition, physical and chemical properties of bentonite as well as the performance index and evaluation method of bentonite used in metallurgical pellets were introduced firstly. And then the relationship between bentonite properties and pellet properties, the preparation status of bentonite binder and the action mechanism of its when used in metallurgical pellets were summarized to provide reference for related researches.
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Key words:
- Bentonite /
- Metallurgical pellets /
- Binder /
- Research progress
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[1] 汪镜亮. 膨润土的某些加工和应用[J]. 矿产综合利用, 1991(2):18-23. WANG J L. Some processing and application of bentonite[J]. Multipurpose Utilization of Mineral Resources, 1991(2):18-23.
[2] 池永沁. 酒钢粉煤灰替代膨润土探索性试验研究[J]. 酒钢科技, 2019(2):18-22. CHI Y Q. Exploratory test study on replacing bentonite with fly ash of Jiuquan Iron and Steel Co[J]. Jiuquan Iron and Steel Science and Technology, 2019(2):18-22.
[3] 李国青, 邱俊, 刘栋梁, 等. 蒙脱石分子模拟研究进展[J]. 矿产综合利用, 2019(4):26-32. LI G Q, QIU J, LIU D L, et al. Research progress of montmorillonite molecular simulation[J]. Multipurpose Utilization of Mineral Resources, 2019(4):26-32. doi: 10.3969/j.issn.1000-6532.2019.04.005
[4] Mohamed O A. The role of normal and activated bentonite on the pelletization of barite iron ore concentrate and the quality of pellets[J]. Powder Technology, 2003, 130(3):277-282.
[5] Ahmed Y M Z, Mohamed F M. Variation in physico-chemical properties of iron oxide pellets using bentonite with calcium hydroxide as binder[J]. Metallurgia Italiana. 2005, 11-12(97): 31-37.
[6] 葛方红. 国内外膨润土指标对铁矿球团性能影响的探讨[J]. 烧结球团, 1996(5):17-23. GE F H. Discussion on the influence of bentonite indexes at home and abroad on the properties of iron ore pellets[J]. Sintered Pellets, 1996(5):17-23. doi: 10.13403/j.sjqt.1996.05.004
[7] 刘新兵. 冶金球团用膨润土性能指标的探讨[J]. 烧结球团, 2010, 35(4):12-16. LIU X B. Discussion on the performance index of bentonite for metallurgical pellets[J]. Sintered Pellets, 2010, 35(4):12-16. doi: 10.13403/j.sjqt.2010.04.003
[8] 侯恩俭, 翁兴洋, 范晓慧. 纤维化复合膨润土强化氧化球团制备研究[J]. 烧结球团, 2019, 44(4):40-44. HOU E J, WENG X Y, FAN X H. Preparation of fiberized composite bentonite reinforced oxidized pellets[J]. Sintered Pellets, 2019, 44(4):40-44. doi: 10.13403/j.sjqt.2019.04.059
[9] 蒙飞宇. 铁矿球团用膨润土性效关系及作用机理研究[D]. 长沙: 中南大学, 2010.
MENG F Y. Study on the property-effect relationship and mechanism of bentonite for iron ore pellets[D]. Changsha: Central South University, 2010.
[10] 蒋娜娜. 铁球团配加不同膨胀容膨润土试验研究[J]. 福建冶金, 2020, 49(1):11-13. JIANG N N. Experimental study on iron pellets with different expansion capacity of bentonite[J]. Fujian Metallurgy, 2020, 49(1):11-13. doi: 10.3969/j.issn.1672-7665.2020.01.003
[11] 韩卫涛. 不同种类膨润土对生球强度的影响规律[J]. 矿业工程, 2015, 13(4):41-44. HAN W T. The influence of different types of bentonite on the green strength[J]. Mining Engineering, 2015, 13(4):41-44. doi: 10.3969/j.issn.1671-8550.2015.04.014
[12] 郑长文, 管俊芳, 郑佳敏, 等. 矿业领域膨润土应用的研究进展[J]. 矿产综合利用, 2020(3):22-27. ZHENG C W, GUAN J F, ZHENG J M, et al. Progress in the application of bentonite in mining industry[J]. Multipurpose Utilization of Mineral Resources, 2020(3):22-27. doi: 10.3969/j.issn.1000-6532.2020.03.004
[13] 孙健宁, 刘小杰, 严照照, 等. 不同含量SiO2对球团质量的影响[J]. 矿产综合利用, 2020(5):63-70. SUN J N, LIU X J, YAN Z Z, et al. Effect of different contents of SiO2 on the quality of pellets of Hanstell[J]. Multipurpose Utilization of Mineral Resources, 2020(5):63-70. doi: 10.3969/j.issn.1000-6532.2020.05.008
[14] 何秋芝, 秦研, 莫伟, 等. 利用水力旋流器对广西典型钙基膨润土的湿法提纯研究[J]. 矿产综合利用, 2017(208):(06)-63. HE Q Z, QIN Y, MO W, et al. Study on the wet purification of Guangxi typical calcium-based bentonite using hydrocyclones[J]. Multipurpose Utilization of Mineral Resources, 2017(208):(06)-63. doi: 10.3969/j.issn.1000-6532.2017.06.012
[15] 殷志祥, 李秀晨, 白阳, 等. 提纯膨润土制备复合粘结剂用于生产球团试验[J]. 金属矿山, 2018(4):126-130. YIN Z X, LI X C, BAI Y, et al. Experiments on the preparation of composite binder from purified bentonite for pellet production[J]. Metal Mine, 2018(4):126-130.
[16] 李彩霞, 白阳, 赵靖雨, 等. 建平膨润土提纯及制备球团粘结剂实验研究[J]. 非金属矿, 2017, 40(3):54-56. LI C X, BAI Y, ZHAO J Y, et al. Experimental study on purification of Jianping bentonite and preparation of pellet binder[J]. Non-metallic Minerals, 2017, 40(3):54-56. doi: 10.3969/j.issn.1000-8098.2017.03.015
[17] 刘鹏君, 张玉柱, 曹朝真, 等. 球团用钙基膨润土钠化改性试验研究[J]. 矿产综合利用, 2006(4):3-7. LIU P J, ZHANG Y Z, CAO C Z, et al. Experimental study on sodium modification of calcium-based bentonite for pellets[J]. Multipurpose Utilization of Mineral Resources, 2006(4):3-7. doi: 10.3969/j.issn.1000-6532.2006.04.001
[18] 胡攀, 莫朝文, 闫应娇, 等. 济钢球团配加钠基膨润土试验研究[J]. 矿产综合利用, 2010(1):15-19. HU P, MO C W, YAN Y J, et al. Experimental study on the addition of sodium bentonite in Jinan Iron and Steel Group[J]. Multipurpose Utilization of Mineral Resources, 2010(1):15-19. doi: 10.3969/j.issn.1000-6532.2010.01.004
[19] 袁继铁, 朱及天. 用皖东膨润土开发冶金球团粘结剂[J]. 矿产综合利用, 2002(6):42-44. YUAN J T, ZHU J T. Using Bentonite in East Anhui to develop metallurgical pellet binder[J]. Multipurpose Utilization of Mineral Resources, 2002(6):42-44. doi: 10.3969/j.issn.1000-6532.2002.06.012
[20] 任瑞晨, 张孝松, 白阳, 等. 冶金球团用膨润土半干法钠化改性试验[J]. 金属矿山, 2016(6):90-92. REN R C, ZHANG X S, BAI Y, et al. Semi-dry sodium modification test of bentonite for metallurgical pellets[J]. Metal Mine, 2016(6):90-92. doi: 10.3969/j.issn.1001-1250.2016.06.018
[21] 李彩霞, 王飞飞, 白阳, 等. 钙基膨润土提纯制备球团粘结剂试验[J]. 硅酸盐通报, 2018, 37(2):672-676. LI C X, WANG F F, BAI Y, et al. Experiment on preparation of pellet binder by purification of calcium-based bentonite[J]. Bulletin of the Chinese Ceramic Society, 2018, 37(2):672-676.
[22] 谢小林, 段婷, 郑富强, 等. 改性复合粘结剂制备磁铁矿氧化球团研究[J]. 金属矿山, 2018(1):79-83. XIE X L, DUAN T, ZHENG F Q, et al. Preparation of magnetite oxidized pellets by modified composite binder[J]. Metal Mine, 2018(1):79-83.
[23] 黄柱成, 江源, 韩志国, 等. 球团矿中膨润土的作用机理研究[J]. 化工矿物与加工, 2005(8):13-15,34. HUANG Z C, JIANG Y, HAN Z G, et al. Study on the mechanism of bentonite in pellets[J]. Industrial Minerals and Processing, 2005(8):13-15,34. doi: 10.3969/j.issn.1008-7524.2005.08.005
[24] 魏福申. 澳精粉配比对氧化球团质量的影响规律[J]. 矿产综合利用, 2019(3):61-64. WEI F S. Influence of Australian ore powder ratio on oxidation pellets[J]. Multipurpose Utilization of Mineral Resources, 2019(3):61-64. doi: 10.3969/j.issn.1000-6532.2019.03.014
[25] 陈许玲, 甘敏, 范晓慧, 等. 有机粘结剂氧化球团固结特性及强化措施[J]. 中南大学学报(自然科学版), 2009, 40(3):550-555. CHEN X L, GAN M, FAN X H, et al. Consolidation characteristics and strengthening measures of organic binder oxidized pellets[J]. Journal of Central South University (Natural Science Edition), 2009, 40(3):550-555.
[26] 李金莲, 朱建伟, 宫作岩, 等. 铁矿球团复合粘结剂技术经济评价[J]. 鞍钢技术, 2020(2):18-24. LI J L, ZHU J W, GONG Z Y, et al. Technical and economic evaluation of composite binder for iron ore pellets[J]. Anshan Iron and Steel Technology, 2020(2):18-24. doi: 10.3969/j.issn.1006-4613.2020.02.004
[27] 李彩霞, 赵家林, 王飞飞, 等. 膨润土球团粘结剂中有机物的选择试验研究[J]. 非金属矿, 2017, 40(5):36-37. LI C X, ZHAO J L, WANG F F, et al. Experimental study on the selection of organic matter in bentonite pellet binders[J]. Nonmetallic Minerals, 2017, 40(5):36-37. doi: 10.3969/j.issn.1000-8098.2017.05.011
[28] 张元波, 欧阳学臻, 路漫漫, 等. 腐植酸改性膨润土在铁矿球团中的应用效果[J]. 烧结球团, 2018(4):27-32. ZHANG Y B, OUYANG X Z, LU M M, et al. Application effect of humic acid modified bentonite in iron ore pellets[J]. Sintered Pellets, 2018(4):27-32. doi: 10.13403/j.sjqt.2018.04.053
[29] Zhou Y, ZhangY, Li P, etal. Comparative study on theadsorption interactions of humic acid onto natural magnetite, hematite and quartz: Effect of initial HA concentration[J]. Powder Technology, 2014, 251(1):1-8.
[30] 田赋, 马先峰, 王一, 等. 铁矿球团膨润土添加剂替代资源的开发研究[J]. 矿产综合利用, 2009(3):7-11. TIAN F, MA X F, WANG Y, et al. Development of alternative resources for bentonite additives in iron ore pellets[J]. Multipurpose Utilization of Mineral Resources, 2009(3):7-11. doi: 10.3969/j.issn.1000-6532.2009.03.002
[31] 张伟, 王丽丽, 邢宏伟, 等. 球团矿配加两种赤铁矿取代膨润土的可行性研究[J]. 矿产综合利用, 2008(5):16-19. ZHANG W, WANG L L, XING H W, et al. Feasibility study of adding two kinds of hematite to replace bentonite in pellet ore[J]. Multipurpose Utilization of Mineral Resources, 2008(5):16-19. doi: 10.3969/j.issn.1000-6532.2008.05.005
[32] 郑银珠, 彭志坚. 铁矿球团复合粘结剂的试验研究[J]. 烧结球团, 2009(5):28-33. ZHENG Y Z, PENG Z J. Experimental study on composite binder of iron ore pellets[J]. Sintered Pellets, 2009(5):28-33. doi: 10.13403/j.sjqt.2009.05.006
[33] 周明顺, 尚策, 赵东明, 等. 鞍钢炼铁原料准备新技术与新工艺自主创新与展望[J]. 鞍钢技术, 2019(6):1-9. ZHOU M S, SHANG C, ZHAO D M, et al. Independent innovation and prospects of new technologies and new processes for the preparation of iron-making raw materials in Anshan Iron and Steel[J]. Anshan Iron and Steel Technology, 2019(6):1-9. doi: 10.3969/j.issn.1006-4613.2019.06.001
[34] 范晓慧, 田志远, 甘敏, 等. 细粒磁铁精矿球团孔隙结构的优化研究[J]. 矿冶工程, 2018, 38(1):71-75. FAN X H, TIAN Z Y, GAN M, et al. Optimization of the pore structure of fine-grained magnetite concentrate pellets[J]. Mining and Metallurgical Engineering, 2018, 38(1):71-75. doi: 10.3969/j.issn.0253-6099.2018.01.016
[35] 刘国根, 邱冠周, 王淀佐. 直接还原炼铁中的粘结剂[J]. 矿产综合利用, 2001(4):27-30. LIU G G, QIU G Z, WANG D Z. Binder in direct reduction ironmaking[J]. Multipurpose Utilization of Mineral Resources, 2001(4):27-30. doi: 10.3969/j.issn.1000-6532.2001.04.007
[36] S. Jayson Ripke, S. KomarKawatra. Can fly-ash extend bentonite binder for ironoreag glomeration Int. J. Miner. Process, 2000, (60): 181~198
[37] S. KomarKawatra, S. JaysonRipke. Laboratory studies forimproving green ball strength in bentonite-bonded magnetite concentrate pellets[J]. Internatinal Journal of Mineral Processing, 2003, (72): 429-441
[38] S. KomarKawatra, S. Jayson Ripke. Effects of bentonite fiber formation in ironore palletization[J]. Int. J. Miner. Process, 2002 (65): 141-149
[39] 王慕荣, 秦洪来, 姚文龙. 钠膨润土—铁矿球团抗爆机理探讨[J]. 烧结球团, 1982(3):7-17. WANG M R, QIN H L, YAO W L. Discussion on the anti-explosion mechanism of sodium bentonite-iron ore pellets[J]. Sintered Pellets, 1982(3):7-17. doi: 10.13403/j.sjqt.1982.03.003
[40] 薛正良, 周国凡, 阳洪. 粘结剂在生球抗爆方面的作用机理[J]. 烧结球团, 1995(5):7-13. XUE Z L, ZHOU G F, YANG H. The mechanism of binder in anti-knock of green ball[J]. Sintered pellets, 1995(5):7-13. doi: 10.13403/j.sjqt.1995.05.003
[41] K. 梅耶尔. 铁矿球团法[M]. 北京: 冶金工业出版社, 1986.
K. Meyer. Iron ore pelletization method [M]. Beijing: Metallurgical Industry Press, 1986.
[42] 姜涛, 铁矿造块学[M]. 长沙: 中南大学出版社, 2016.
JIANG T, Iron Ore Agglomeration[M]. Changsha: Central South University Press, 2016.
[43] D. W. Fuerstenau, S. W. Clark, 肖琪. 蒙脱石在铁精矿造球中的作用[J]. 烧结球团, 1983(1):97-106. D. W. Fuerstenau, S. W. Clark, XIAO Q. The role of montmorillonite in the pelletizing of iron ore concentrate[J]. Sintered Pellets, 1983(1):97-106.
[44] 李彩霞, 白阳, 赵靖雨, 等. 复合球团黏结剂提高生球性能的模拟试验研究[J]. 非金属矿, 2018, 41(6):59-62. LI C X, BAI Y, ZHAO J Y, et al. Simulation test study on improving green ball performance with composite pellet binder[J]. Non-metallic Minerals, 2018, 41(6):59-62. doi: 10.3969/j.issn.1000-8098.2018.06.019
[45] 李宏煦, 姜涛, 邱冠周, 等. 铁矿球团有机粘结剂的分子构型及选择判据[J]. 中南工业大学学报 (自然科学版), 2000(1):17-20. LI H X, JIANG T, QIU G Z, et al. Molecular configuration and selection criterion of organic binder for iron ore pellets[J]. Journal of Central South University of Technology (Natural Science Edition), 2000(1):17-20.
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