有机膦化合物选冶领域的应用研究现状

陶均, 葛英勇, 刘顺兵, 高钦, 方纪. 有机膦化合物选冶领域的应用研究现状[J]. 矿产综合利用, 2023, 44(1): 127-132. doi: 10.3969/j.issn.1000-6532.2023.01.017
引用本文: 陶均, 葛英勇, 刘顺兵, 高钦, 方纪. 有机膦化合物选冶领域的应用研究现状[J]. 矿产综合利用, 2023, 44(1): 127-132. doi: 10.3969/j.issn.1000-6532.2023.01.017
Tao Jun, Ge Yingyong, Liu Shunbing, Gao Qin, Fang Ji. Application and Research Status of Organophosphine Compounds in Beneficiation and Metallurgy[J]. Multipurpose Utilization of Mineral Resources, 2023, 44(1): 127-132. doi: 10.3969/j.issn.1000-6532.2023.01.017
Citation: Tao Jun, Ge Yingyong, Liu Shunbing, Gao Qin, Fang Ji. Application and Research Status of Organophosphine Compounds in Beneficiation and Metallurgy[J]. Multipurpose Utilization of Mineral Resources, 2023, 44(1): 127-132. doi: 10.3969/j.issn.1000-6532.2023.01.017

有机膦化合物选冶领域的应用研究现状

详细信息
    作者简介: 陶均(1994-),男,硕士研究生。研究方向为矿物加工工程
    通讯作者: 葛英勇(1961-),男,教授,博士研究生导师。研究方向为矿物加工工程
  • 中图分类号: TD982

Application and Research Status of Organophosphine Compounds in Beneficiation and Metallurgy

More Information
  • 有机膦化合物在工业生产,日常生活中有着广阔的应用前景,其灵活多变的极性基,非极性基,使之具备了可调控的性能。有机膦化合物及其衍生物的种类繁多,物化性能也不尽相同,使得有机膦化合物在生产生活中特别是在选冶药剂方面的用途越来越广泛,文章通过列举一些在实验室实验过程中取得良好数据或在工业应用上表现优异的有机膦药剂,以及一些极具代表性的磷化合物选冶药剂,参考目前的一些研究成果,结合生产实践,对其进行具体的分类研究,对其今后的发展和应用趋势进行了展望。

  • 加载中
  • 图 1  苯乙烯膦酸

    Figure 1. 

    图 2  烷胺双甲基膦酸

    Figure 2. 

    图 3  单硫代膦酸四种配位形式

    Figure 3. 

  • [1]

    王帅, 王明月, 杨佳, 等. 有机磷选冶药剂的合成与应用[J]. 矿产保护与利用, 2020, 40(2):1-9. WANG S, WANG M Y, YANG J, et al. Synthesis and application of organophosphorous dressing agents[J]. Conservation and Utilization of Mineral Resources, 2020, 40(2):1-9. doi: 10.13779/j.cnki.issn1001-0076.2020.02.001

    [2]

    林强, 王淀佐. 有机磷浮选剂[J]. 湖南有色金属, 1989, 5(1):16-20. LIN Q, WANG D Z. Organophosphorus flotation agents[J]. Hunan Nonferrous Metals, 1989, 5(1):16-20.

    [3]

    谭鑫. 钨锡矿物螯合捕收剂靶向性分子设计及其作用机理研究[D]. 沈阳: 东北大学, 2017.

    TAN X. Molecular design and mechanism of targeting of tungsten and tin mineral chelating collectors[D]. Shenyang: Northeastern University, 2017.

    [4]

    许宜蔚, 阙煊兰. 锡石的新捕收剂——1-羟基-1、3-二甲基丁基膦酸浮选锡石试验[J]. 矿冶工程, 1983(1):24-27. XU Y W, JUE X L. Flotation of stannate by a new collector, 1-hydroxy-1, 3-dimethyl-butylphosphonic acid[J]. Mining and Metallurgical Engineering, 1983(1):24-27.

    [5]

    王孝愈. 苯乙烯膦酸浮选锡细泥工业试验[J]. 有色金属(选矿部分), 1980(3):42-44. WANG X Y. Industrial test of styrene phosphonic acid flotation tin fine sludge[J]. Nonferrous Metals (Mineral Processing Section), 1980(3):42-44.

    [6]

    东乃良. 2-苯乙烯膦酸浮选黑钨矿和锡石的行为[J]. 国外金属矿选矿, 1989(7):1-4. DONG N L. Flotation of wolfram and cassiterite with 2-styrenephosphonic acid[J]. Foreign Mineral Processing, 1989(7):1-4.

    [7]

    钟宏, 朱建光. 浮锡灵对锡石的捕收性能和作用机理[J]. 有色金属, 1985(4):37-45. ZHONG H, ZHU J G. Collection performance and mechanism of the FXL[J]. Nonferrous Metals, 1985(4):37-45.

    [8]

    王钊军, 劳晓峰. 一种含羟基烷叉双膦酸钛铁矿捕收剂的合成及浮选性能研究[J]. 矿产综合利用, 2010(4):24-26. WANG Z J, LAO X F. Study on synthesis and flotation performance of a collector containing hydroxy alkane forkbisphosphonate ilmenite[J]. Multipurpose Utilization of Mineral Resources, 2010(4):24-26. doi: 10.3969/j.issn.1000-6532.2010.04.006

    [9]

    王勇泉, 刘广义, 任恒, 等. 有机单(双)硫代磷(膦)酸类化合物的研究进展[J]化工进展, 2013(2): 433-440.

    WANG Y Q, LIU G Y, REN H, et al. Progress in studies on organic single (double) phosphorous acid compounds[J]. Chemical Industry Progress, 2013(2): 433-440.

    [10]

    杨晓玲, 林强. 浮选剂二烃基二硫代磷酸盐类化合物的研制及应用[J]. 广西化工, 1996, 25(4):17-25. YANG X L, LIN Q. Preparation and application of flotation agent dihydroalkyl dithiophosphates[J]. Guangxi Chemical Industry, 1996, 25(4):17-25.

    [11]

    杨晓玲, 林强, 王淀佐. 二烷基硫代磷酸铵的捕收性能[J]. 山东冶金, 1997, 19(4):32-34. YANG X L, LIN Q, WANG D Z. Collection performance of ammonium dialkyl thiophosphate[J]. Shandong Metallurgy, 1997, 19(4):32-34.

    [12]

    朱玉霜, 朱建光. 浮选药剂的化学原理(修订版)[M]. 长沙: 中南工业大学出版社, 1996: 50-51.

    ZHU Y S, ZHU J G. Chemical principles of flotation reagents (revised edition)[M]. Changsha: Central South University of Technology Press, 1996: 50-51.

    [13]

    杨晓玲, 林强. 新型捕收剂二烃基硫代次膦酸的合成及起泡性能[J]. 广西化工, 1997, 26(2):27-31. YANG X L, LIN Q. Synthesis and foaming properties of a new collector, dihydroalkyl thiophosphonic acid[J]. Guangxi Chemical Industry, 1997, 26(2):27-31.

    [14]

    朱建光. 2005年浮选药剂的进展[J]. 国外金属矿选矿, 2006(3):8-9. ZHU J G. Progress of flotation reagents in 2004[J]. Foreign Metal Ore dressing, 2006(3):8-9.

    [15]

    杨晓玲, 林强, 王淀佐. 新型捕收剂二烃基硫代次膦酸的结构设计及浮选非硫化矿物性能[J]. 有色金属, 1999(3):30-35. YANG X L, LIN Q, WANG D Z. Structural design and flotation performance of a new collector, dihydroalkyl thiophosphonic acid[J]. Nonferrous Metals, 1999(3):30-35.

    [16]

    朱建光. 2003年浮选药剂的进展[J]. 国外金属矿选矿, 2004(2):4-11. ZHU J G. Progress of flotation reagents in 2003[J]. Foreign Metal Ore Beneficiation, 2004(2):4-11.

    [17]

    朱建光. 2004年浮选药剂的进展[J]. 国外金属矿选矿, 2005(2):5-12. ZHU J G. Progress of flotation reagents in 2004[J]. Foreign Metal Ore Beneficiation, 2005(2):5-12.

    [18]

    Tan X, He F Y, Shang Y B, et al. Flotation behavior and adsorption mechanism of(1-hydroxy-2-methyl-2-octenyl) phosphonic acid to cassiterite[J]. Transactions of Nonferrous Metals Society of China, 2016, 26(9):2469-2478. doi: 10.1016/S1003-6326(16)64368-6

    [19]

    Huang K, Cao Z, Wang S, et al. Flotation performance and adsorption mechanism of styryl phosphonate mono-iso-octyl ester to malachite[J]. Colloids and Surfaces A:Physicochemical and Engineering As-pects, 2019(579):1-8.

    [20]

    马田, 魏添昱. 重金属离子萃取剂的研究进展[J]. 江西化工, 2015(5):25-30. MA T, WEI T Y. Research progress of heavy metal ion extractants[J]. Jiangxi Chemical Industry, 2015(5):25-30. doi: 10.3969/j.issn.1008-3103.2015.05.008

    [21]

    马荣骏. 萃取冶金[M]. 北京: 冶金工业出版社, 2009.131.

    MA R J. Extractive metallurgy[M]. Beijing: Metallurgical Industry Press, 2009. 131.

    [22]

    李红喜, 杨卉, 温慧霞, 等. 有机含磷及含氮萃取剂萃取分离锆铪的研究进展[J]稀有金属, 2014, 28(6): 283-291.

    LI H X, YANG H, WEN H X, et al. Progress in the separation of zirconium and hafnium with organic phosphorus and nitrogen extractors[J]. Rare Metals, 2014, 28(6): 283-291.

    [23]

    吕天然, 王凌云, 周海涛, 等. 酸性有机磷萃取剂对镓的萃取研究[J]. 山东化工, 2019, 48(12):9-12. LU T R, WANG L Y, ZHOU H T, et al. Study on extraction of gallium by acid organophosphorus extraction agent[J]. Shandong Chemical Industry, 2019, 48(12):9-12. doi: 10.3969/j.issn.1008-021X.2019.12.006

    [24]

    Chen W, Feng Q M, Zhang G F, et al. Investigations on flotation separation of scheelite from calcite by using a novel depressant: Sodium phytate[J]. Minerals Engineering, 2018, 126:116-122. doi: 10.1016/j.mineng.2018.06.008

    [25]

    Ramachandran V S, Lowery M S, Wise T, et al. Materials and Structures, 1993, 26(7), 431.

    [26]

    林炎坤, 张德琛, 许建钊. 磷酸盐/膦及其盐缓凝剂的作用机理及性能[J]. 商品混凝土, 2018(8):25-28. LIN Y K, ZHANG D S, XU J Z. Mechanism and Properties of Phosphate/phosphine and its salt retarders[J]. Commercial Concrete, 2018(8):25-28.

    [27]

    李学静, Olga Gey, Christian Quellet, 等. 工艺参数对层状液晶乳液结构的影响[J]. 日用化学工业, 2006, 36(3):143-147. LI X J, Olga Gey, Christian Quellet, et al. Effect of process parameters on the structure of layered liquid crystal emulsion[J]. Journal of Daily-use Chemical Industry, 2006, 36(3):143-147. doi: 10.3969/j.issn.1001-1803.2006.03.003

    [28]

    张婉萍, 陈雪清. 含液晶结构固体脂质微粒的制备技术研究[J]. 日用化学工业, 2012, 42(6):436-439. ZHANG W P, CHEN X Q. Research on preparation technology of solid lipid particles with liquid crystal structure[J]. Daily Chemical Industry, 2012, 42(6):436-439. doi: 10.13218/j.cnki.csdc.2012.06.014

    [29]

    Carnali J O. Personal care compositions comprising alkyl phosphate surfactants and selected auxiliary surfactants[Z]. US, 2007.

    [30]

    Miller D, Vollmer A, Feustel M, et al. Synergistic mixtures of phosphoric esters with carboxylic acids or carboxylic acid derivatives as asphaltene dispersants[Z]. US, 2001.

    [31]

    王学川, 张铭让. 磷酸酯的合成及其在皮革加脂剂中的应用[J]. 皮革科学与工程, 2002, 12(1):26-29. WANG X C, ZHANG M R. Synthesis of phosphate ester and its application in leather fatliquors[J]. Leather Science and Engineering, 2002, 12(1):26-29. doi: 10.3969/j.issn.1004-7964.2002.01.008

    [32]

    曹向禹, 兰云军. 磷酸酯加脂剂合成过程中若干问题的探讨[J]. 皮革科学与工程, 2004, 14(2):49-52. CAO X Y, LAN Y J. Discussion on some problems in the synthesis of phosphate ester fatliquor[J]. Leather Science and Engineering, 2004, 14(2):49-52. doi: 10.3969/j.issn.1004-7964.2004.02.013

  • 加载中

(3)

计量
  • 文章访问数:  1371
  • PDF下载数:  388
  • 施引文献:  0
出版历程
收稿日期:  2020-12-23
刊出日期:  2023-02-25

目录