General Situation of Gold Resources and Research Progress of Mineral Processing and Hydrometallurgy Technology in China
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摘要:
我国金矿资源主要集中在山东、甘肃、新疆、内蒙古、河南和云南等6省区,主要为砂金、岩金和伴生金3种类型。我国金矿资源丰富,是世界上最大的黄金生产国、消费国和进口国,但对外依存度较高,金消费大量依赖进口。加强国内金矿资源选冶技术攻关,实现其高效、合理开发,是保障金矿资源安全的重要举措。本文介绍了国内外金矿资源分布及概况,综述了金矿选矿工艺及选矿药剂研究现状、难处理金矿预处理工艺研究现状及湿法浸出工艺研究现状,阐述了金矿选冶技术的显著特点,以及其优点和局限性,展望了无氰浸出工艺和绿色高效的无氰浸出药剂将是难处理金矿石绿色提金的发展方向,为提金技术的进一步研究及应用提供参考借鉴。
Abstract:Gold resources in China are mainly concentrated in Shandong, Gansu, Xinjiang, Inner Mongolia, Henan and Yunnan Provinces, which are mainly composed of placer gold, rock gold and associated gold. China has rich gold resources and is the largest gold producing, consuming and importing country in the world, but it has a high degree of foreign dependence and a large amount of gold consumption depends on imports. It is an important measure to ensure the safety of gold resources to strengthen the research of domestic gold mining technology and realize its efficient and rational development. This paper introduces the distribution and general situation of gold ore resources in China and abroad, summarizes the research status of gold ore beneficiation technology and beneficiation reagents, pretreatment technology of refractory gold ore and wet leaching technology, expounds the salient characteristics of gold ore beneficiation technology, as well as its advantages and limitations. It is expected that cyanide-free leaching process and green and efficient cyanide-free leaching agents will be the development direction of green gold extraction from refractory gold ores, which will provide reference for further research and application of gold extraction technology.
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Key words:
- Gold /
- Beneficiation process /
- Pretreatment process /
- Wet leaching /
- Non-cyanide process
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[1] 王成龙, 王士强, 洪涛, 等. 我国金矿资源现状及其可持续发展研究[J]. 中国矿山工程, 2017, 12(6):42-45. WANG C L, WANG S Q, HONG T, et al. Situation and sustainable development research of gold resources in China[J]. China Mine Engineering, 2017, 12(6):42-45. doi: 10.3969/j.issn.1672-609X.2017.06.010
[2] 倪曦, 白海铃. 中国金矿资源特征及成矿规律概要[J]. 找矿技术, 2021(10):60-61. NI X, BAI H L. Characteristics of gold resources and metallogenic regularity in China[J]. Prospecting Technology, 2021(10):60-61.
[3] 自然资源部. 中国矿产资源报告2021 [M]. 北京: 地质出版社.
Ministry of Natural Resources. China Mineral Resources 2021[M]. Beijing: Geological Publishing House.
[4] 冯丹丹. 2017年度全球黄金资源供需形势分析[J]. 矿产保护与利用, 2019(1):150-154. FENG D D. Analysis of supply and demand situation of gold resources in 2017[J]. Conservation and Utilization of Mineral Resources, 2019(1):150-154. doi: 10.13779/j.cnki.issn1001-0076.2019.01.027
[5] 许文力. 浅谈我国金矿资源现状[J]. 世界有色金属, 2017(9):134-135. XU W L. Brief discussion on present situation of gold resources in China[J]. World Nonferrous Metals, 2017(9):134-135.
[6] 中国地质调查局. 中国地质调查百项成果 [M]. 北京: 地质出版社.
China Geological Survey. 100 results of China Geological Survey [M]. Beijing: World Nonferrous Metals, 2017(9): 134-135.
[7] 卢杰, 王建国, 严松涛, 等. 我国西部金矿资源现状及发展对策[J]. 中国矿业, 2015(10):10-14. LU J, WANG J G, YAN S T, et al. Analysis of the current situation and developmental counter measures of gold resources in West China[J]. China Mining Magazine, 2015(10):10-14. doi: 10.3969/j.issn.1004-4051.2015.10.003
[8] 魏春霞. 中国金矿资源的现状及前景分析[J]. 中国金属通报, 2018(1):19-20. WEI C X. Analysis of present situation and prospect of gold resources in China[J]. China Metal Bulletin, 2018(1):19-20. doi: 10.3969/j.issn.1672-1667.2018.01.005
[9] 寸圭, 鞠毓绂. 我国金矿资源的概况[J]. 黄金科学技术, 1999(6):1-7. CUN G, JU Y F. The general situation of gold resources in China[J]. Gold Science and Technology, 1999(6):1-7.
[10] 张龙坤. 我国金矿资源前景与分析[J]. 世界有色金属, 2017(20):151-152. ZHANG L K. The gold mine resource prospects and analysis in our country[J]. World Nonferrous Metals, 2017(20):151-152.
[11] 国土资源部中国地质调查局, 新疆维吾尔自治区人民政府. 新疆金矿资源调查报告[R]. 北京: 国土资源部中国地质调查局, 2016: 1-9.
China Geological Survey Bureau, Ministry of land and resources, People's Government of Xinjiang Uygur Autonomous Region. Xinjiang gold resources survey report [J]. Beijing: China Geological Survey Bureau, 2016: 1-9.
[12] 黄庆. 新疆金矿资源特点及开发[J]. 地球, 2014(7):73-73. HUANG Q. Characteristics and exploitation of gold resources in Xinjiang[J]. Earth, 2014(7):73-73.
[13] 杜亚龙, 李智明, 姜寒冰, 等. 新疆地区金矿分布特征及找矿潜力分析[J]. 西北地质, 2016, 49(1):121-134. DU Y L, LI Z M, JIANG H B, et al. Analysis on the distribution and ore potentials of gold deposits in Xinjiang[J]. Northwestern Geology, 2016, 49(1):121-134. doi: 10.3969/j.issn.1009-6248.2016.01.013
[14] 杨思军, 徐宏斌, 曹锋, 等. 尼尔森选矿机在四方金矿重选工艺中的应用[J]. 现代矿业, 2015(5):187-189. YANG S J, XU H B, CAO F, et al. Application of Nelson concentrator in gravity separation of Sifang gold mine[J]. Modern Mining, 2015(5):187-189. doi: 10.3969/j.issn.1674-6082.2015.05.069
[15] 刘静宇. 某金矿重选尾矿回收金、铜的工艺研究[J]. 矿产综合利用, 2020(1):112-115. LIU J Y. Recovery of gold and copper from tailings of gravity separation in a gold ore[J]. Multipurpose Utilization of Mineral Resources, 2020(1):112-115. doi: 10.3969/j.issn.1000-6532.2020.01.023
[16] 崔学奇, 张耀军, 吕宪俊, 等. 重选法回收某高碳质金矿石中金的试验研究[J]. 黄金, 2007(1):40-42. CUI X Q, ZHANG Y J, LV X J, et al. Experimental research on gold recovery from high-carbon gold ore with gravity concentration[J]. Gold, 2007(1):40-42. doi: 10.3969/j.issn.1001-1277.2007.01.010
[17] 朱一民, 葛文成, 张淑敏, 等. 内蒙古某金矿尼尔森重选—低氰浸出试验研究[J]. 金属矿山, 2021(7):119-123. ZHU Y M, GE W C, ZHANG S M, et al. Nielsen gravity concentration combined with low cyanide leaching test research for a gold mine in Inner Mongolia[J]. Metal Mine, 2021(7):119-123. doi: 10.19614/j.cnki.jsks.202107016
[18] 吕良, 岳铁兵, 王威, 等. 非洲某氧化型金矿重选—浸出工艺研究[J]. 黄金, 2021(3):56-59. LV L, YUE T B, WANG W, et al. Research of gravity-leaching process of an oxidized gold ore in Africa[J]. Gold, 2021(3):56-59.
[19] 杜飞飞, 杨志军, 郭存丰. 某金矿浮选试验研究[J]. 现代矿业, 2012(1):30-34. DU F F, YANG Z J, GUO C F. Flotation test research of a gold mine[J]. Modern Mining, 2012(1):30-34. doi: 10.3969/j.issn.1674-6082.2012.01.008
[20] 余世磊, 王毓华, 王进明, 等. 新疆某黄铁矿型低品位金矿石浮选试验[J]. 金属矿山, 2013(5):78-81. YU S L, WANG Y H, WANG J M, et al. Flotation experimental research on a low-grade pyritic gold in Xinjiang[J]. Metal Mine, 2013(5):78-81. doi: 10.3969/j.issn.1001-1250.2013.05.021
[21] 汤亦婧, 罗思岗, 陆红羽. 辽宁某金矿选矿试验研究[J]. 有色金属:选矿部分, 2022(4):105-110. TANG Y J, LUO S G, LU H Y. Experimental study on mineral processing of a gold ore in Liaoning[J]. Nonferrous Metals(Mineral Processing Section), 2022(4):105-110.
[22] 陈广, 羊坤, 陈思竹, 等. 浮-重选联合流程选别金尾矿实验研究[J]. 矿产综合利用, 2022(2):131-134. CHEN G, YANG K, CHEN S Z, et al. Study on separation of gold from tailings by combined floatation-gravity beneficiation flowsheet[J]. Multipurpose Utilization of Mineral Resources, 2022(2):131-134. doi: 10.3969/j.issn.1000-6532.2022.02.024
[23] 毛益林, 陈晓青, 杨进忠, 等. 四川某石英脉型金矿联合选矿工艺[J]. 有色金属工程, 2015(3):68-70. MAO Y L, CHEN X Q, YANG J Z, et al. Combined beneficiation on a quartz vein type gold ore in Sichuan[J]. Nonferrous Metals Engineering, 2015(3):68-70. doi: 10.3969/j.issn.2095-1744.2015.03.015
[24] 王振, 邹 旦, 赵开乐, 等. 硫化型金矿浮选技术研究现状及进展[J]. 化 工 矿 物 与 加 工, 2022(6):54-60. WANG Z, ZOU D, ZHAO K L, et al. Research status and progress of the flotation technology for gold sulfide ore[J]. Industrial Minerals & Processing, 2022(6):54-60.
[25] 康建雄, 周 跃, 吕中海, 等. 含砷金矿浮选研究现状与展望[J]. 四川有色金属, 2022(6):54-60. KANG J X, ZHOU Y, LV Z H, et al. The research situation and prospects of floatation of arsenic containing gold ores[J]. Sichuan Nonferrous Metals, 2022(6):54-60.
[26] 张文杰, 朱辉, 谢贤, 等. 某含硫高碳难处理金矿选矿工艺研究[J]. 有色金属:选矿部分, 2022(6):54-60. ZHANG W J, ZHU H, XIE X, et al. The research situation and prospects of floatation of arseniccontaining gold dres[J]. Sichuan Nonferrous Metals, 2022(6):54-60.
[27] 邱显扬, 梁冬云, 洪秋阳, 等. 难处理金矿石的工艺矿物学及可选冶特性分析[J]. 贵金属, 2020, 41(2):36-44. QIU X Y, LIANG D Y, HONG Q Y, et al. Process mineralogy and process improvement analysis of a refractory gold ore[J]. PreciousMetals, 2020, 41(2):36-44. doi: 10.3969/j.issn.1004-0676.2020.02.008
[28] 印万忠, 洪正秀, 马英强, 等. 国内外含砷硫金矿预处理技术的研究进展[J]. 现代矿业, 2011(2):1-8. YIN W Z, HONG Z X, MA Y Q, et al. Research progress of pretreatment technology for As, S-bearing gold ore concentrate at home and abroad[J]. Modern Mining, 2011(2):1-8. doi: 10.3969/j.issn.1674-6082.2011.02.001
[29] 周源, 田树国, 刘亮. 高砷金矿脱砷预处理技术进展[J]. 金属矿山, 2009(2):98-101. ZHOU Y, TIAN S G, LIU L. Progress in the pretreatment technology for arsenic removal from high arsenic gold ore[J]. Metal Mine, 2009(2):98-101. doi: 10.3321/j.issn:1001-1250.2009.02.026
[30] 邱廷省, 聂光华, 张强, 等. 难处理含铜金矿石预处理与浸出技术现状及进展[J]. 黄金, 2005(8):30-34. QIU T S, NIE G H, ZHANG Q, et al. Present situation and developmental trend of pretreatment and leaching technology for refractory copper-bearing gold ores[J]. Gold, 2005(8):30-34. doi: 10.3969/j.issn.1001-1277.2005.08.010
[31] 杨洪英, 范金, 崔 日成, 等. 难处理 高砷金矿的细菌 氧化 一提金研究[J]. 贵金属, 2009(3):1-3. YANG H Y, FAN J, CUI R C, et al. Study on bacterial oxidation-extraction gold of refractory gold ore[J]. Precious Metals, 2009(3):1-3. doi: 10.3969/j.issn.1004-0676.2009.03.001
[32] 宋言, 杨洪英, 佟琳琳, 等. 甘肃某复杂难处理金矿细菌氧化一氰化实验研究[J]. 黄金科学技术, 2018(2):241-247. SONG Y, YANG H Y, TONG L L, et al. Experimental study on bacterial oxidation-cyanidation of a complex refractory gold mine in Gansu Province[J]. Gold Science and Technology, 2018(2):241-247. doi: 10.11872/j.issn.1005-2518.2018.02.241
[33] 李骞, 董斯宇, 许瑞, 等. 金矿提金技术及其研究进展[J]. 黄金, 2020(9):86-101. LI Q, DONG S Y, XU R, et al. Gold extraction technology for gold ores and its research progress[J]. Gold, 2020(9):86-101. doi: 10.11792/hj20200914
[34] 谷晋川, 刘亚川, 张允湘. 山东某金矿氰化浸出过程中影响因素的研究[J]. 矿产综合利用, 2002(3):3-6. GU J C, LIU Y C, ZHANG Y X. Research on the influencing factors of cyanide leaching of a gold ore in Shandong Province[J]. Multipurpose Utilization of Mineral Resources, 2002(3):3-6. doi: 10.3969/j.issn.1000-6532.2002.03.001
[35] 储春利, 蒋中刚, 唐道文. 难浸金矿硫脲浸出试验研究[J]. 有色金属:冶炼部分, 2014(3):37-39. CHU C L, JIANG Z G, TANG D W. Experimental study on leaching of refractory gold ore with thiourea[J]. Nonferrous Metals(Extractive Metallurgy), 2014(3):37-39.
[36] 邱洋, 黄成戈, 唐道文, 等. 硫代硫酸钠浸出贵州卡林型金矿[J]. 有色金属科学与工程, 2021(1):22-27. QIU Y, HUANG C G, TANG D W, et al. Leaching of Guizhou Carlin-type gold mine with sodium thiosulfate at room temperature[J]. Nonferrous Metals Science and Engineering, 2021(1):22-27. doi: 10.13264/j.cnki.ysjskx.2021.01.004
[37] 王虎, 秦贞军, 石宝兴, 等. 甘氨酸在含铜金矿石氰化浸出工艺中的应用及研究[J]. 现代矿业, 2022(5):140-141. WANG H, QIN Z J, SHI B X, et al. Application and research of glycine in cyanide leaching process of copper-bearing gold ore[J]. Modern Mining, 2022(5):140-141. doi: 10.3969/j.issn.1674-6082.2022.05.034
[38] 彭科波, 高利坤, 饶兵, 等. 金矿非氰化浸金研究进展[J]. 工程科学学报, 2021(7):871-882. PENG K B, GAO L K, RAO B, et al. Research progress of non-cyanide gold leaching in gold mines[J]. Chinese Journal of Engineering, 2021(7):871-882.
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