C-CNF表面改性电气石及其分散稳定性

庞宝宝, 胡应模, 张震, 崔奎, 武莎莎, 郭素芳. C-CNF表面改性电气石及其分散稳定性[J]. 矿产综合利用, 2024, 45(2): 100-104, 117. doi: 10.3969/j.issn.1000-6532.2024.02.016
引用本文: 庞宝宝, 胡应模, 张震, 崔奎, 武莎莎, 郭素芳. C-CNF表面改性电气石及其分散稳定性[J]. 矿产综合利用, 2024, 45(2): 100-104, 117. doi: 10.3969/j.issn.1000-6532.2024.02.016
PANG Baobao, HU Yingmo, ZHANG Zhen, CUI Kui, WU Shasha, GUO Sufang. C-CNF Surface Modified Tourmaline and its Dispersion Stability[J]. Multipurpose Utilization of Mineral Resources, 2024, 45(2): 100-104, 117. doi: 10.3969/j.issn.1000-6532.2024.02.016
Citation: PANG Baobao, HU Yingmo, ZHANG Zhen, CUI Kui, WU Shasha, GUO Sufang. C-CNF Surface Modified Tourmaline and its Dispersion Stability[J]. Multipurpose Utilization of Mineral Resources, 2024, 45(2): 100-104, 117. doi: 10.3969/j.issn.1000-6532.2024.02.016

C-CNF表面改性电气石及其分散稳定性

详细信息
    作者简介: 庞宝宝(1996-),女,硕士,主要从事矿物表面改性及其复合应用的研究
    通讯作者: 胡应模(1964-),男,教授,博士生导师,主要从事矿物复合材料的研究。
  • 中图分类号: TD985

C-CNF Surface Modified Tourmaline and its Dispersion Stability

More Information
  • 这是一篇矿物加工工程领域的论文。电气石具有自发极化效应、热释电性、远红外辐射和负离子释放等效应被广泛应用。为了增加其在水性涂料中的分散稳定性,改善其在水性涂料中的使用性能,本实验采用羧基化纳米纤维素(C-CNF)对电气石进行表面接枝改性,并对实验条件进行了优化。实验结果表明,当C-CNF的添加量为2 g、反应温度为50 ℃、反应时间为2 h、固液比为1∶5时,改性电气石的性能达到较佳值,其浊度达到1361 ntu,接触角达到了53o。通过对改性电气石的结构进行表征,发现C-CNF成功接枝到了电气石表面,改性电气石在水性介质中的分散性得到较大的提升。

  • 加载中
  • 图 1  C-CNF用量对电气石改性效果的影响

    Figure 1. 

    图 2  反应温度对电气石改性效果的影响

    Figure 2. 

    图 3  反应时间对电气石改性效果的影响

    Figure 3. 

    图 4  改性前后电气石的红外光谱

    Figure 4. 

    图 5  电气石改性前后XRD (a)改性前;(b)改性后

    Figure 5. 

    图 6  电气石改性前后SEM(a)改性前;(b)改性后

    Figure 6. 

    图 7  静置3.5 h电气石改性前后沉降实验对比 (a)改性前;(b)改性后

    Figure 7. 

  • [1]

    Fuat Yavuz. TOURMAL: software package for tourmaline, tourmaline-rich rocks and related ore deposits[J]. Computers and Geosciences, 1997, 23(9):947-959. doi: 10.1016/S0098-3004(97)00080-0

    [2]

    杨进忠, 毛益林, 陈晓青, 等. 某尾矿资源化处置与综合利用[J]. 矿产综合利用, 2019(6):117-122.YANG J Z, MAO Y L, CHEN X Q, et al. Study on resource disposal and comprehensive utilization of tailings[J]. Multipurpose Utilization of Mineral Resources, 2019(6):117-122.

    YANG J Z, MAO Y L, CHEN X Q, et al. Study on resource disposal and comprehensive utilization of tailings[J]. Multipurpose Utilization of Mineral Resources, 2019(6):117-122.

    [3]

    邱明华, 李强, 念保义, 等. 白炭黑表面改性研究现状及进展[J]. 矿产综合利用, 2020(3):40-47.QIU M H, LI Q, NIAN B Y, et al. Research status and development of precipitated silica surface modification[J]. Multipurpose Utilization of Mineral Resources, 2020(3):40-47.

    QIU M H, LI Q, NIAN B Y, et al. Research status and development of precipitated silica surface modification[J]. Multipurpose Utilization of Mineral Resources, 2020(3):40-47.

    [4]

    Kairen Chen, Xinghui Gai, Guojun Zhou, et al. Study on a new type of pyroelectric materials with structure of tourmaline[J]. Ceramics International, 2019, 45(8):10684-10690. doi: 10.1016/j.ceramint.2019.02.139

    [5]

    Liang Yafeng, Tang Xuejiao, Zhu Qing, et al. A review: Application of tourmaline in environmental fields[J]. Chemosphere, 2021, 281(11):130780.

    [6]

    Xiaorui Zhang, Xingxing Zhou, Xinquan Xu, et al. Enhancing the functional and environmental properties of asphalt binders and asphalt mixtures using tourmaline anion powder modification[J]. Coatings, 2021, 11(5):550. doi: 10.3390/coatings11050550

    [7]

    Xiaoyu Han, Junping Meng, Jie Liu, et al. Enhanced far infrared radiation properties of functional ceramics derived from iron ore tailings incorporating tourmaline particles[J]. Ceramics International, 2020, 11:247.

    [8]

    胡应模, 安文峰, 张丹丹, 等. 含电气石的功能聚合物的合成及其功能纤维试制[J]. 功能材料, 2021, 52(2):2034-2038.HU Y M, AN W F, ZHANG D D, et al. Synthesis of functional polymers containing tourmaline and trial production of their functional fibers[J]. Functional Materials, 2021, 52(2):2034-2038.

    HU Y M, AN W F, ZHANG D D, et al. Synthesis of functional polymers containing tourmaline and trial production of their functional fibers[J]. Functional Materials, 2021, 52(2):2034-2038.

    [9]

    安文峰, 胡应模, 张丹丹, 等. 硅烷偶联剂KH570 对电气石表面改性条件优化与表征[J]. 矿产综合利用, 2021(1):193-198.AN W F, HU Y M, ZHANG D D, et al. Optimization and characterization of surface modification of tourmaline by silane coupling agent KH570[J]. Multipurpose Utilization of Mineral Resources, 2021(1):193-198.

    AN W F, HU Y M, ZHANG D D, et al. Optimization and characterization of surface modification of tourmaline by silane coupling agent KH570[J]. Multipurpose Utilization of Mineral Resources, 2021(1):193-198.

    [10]

    崔瑞, 王旭, 魏骞, 等. 湖北某重晶石-萤石型矿综合利用研究[J]. 矿产综合利用, 2019(2):70-74.CUI R, WANG X, WEI Q, et al. Study on comprehensive utilization of a barite-fluorite ore in Hubei province[J]. Multipurpose Utilization of Mineral Resources, 2019(2):70-74.

    CUI R, WANG X, WEI Q, et al. Study on comprehensive utilization of a barite-fluorite ore in Hubei province[J]. Multipurpose Utilization of Mineral Resources, 2019(2):70-74.

    [11]

    张峰, 王怀法. 乳化捕收剂稳定性的探索及应用[J]. 矿产综合利用, 2019(6):55-59.ZHANG F, WANG H F. Research and application of stability of emulsifying collector[J]. Multipurpose Utilization of Mineral Resources, 2019(6):55-59.

    ZHANG F, WANG H F. Research and application of stability of emulsifying collector[J]. Multipurpose Utilization of Mineral Resources, 2019(6):55-59.

    [12]

    纪莹蕾. 智能浊度传感器的研究与设计[D]. 合肥: 中国科学技术大学, 2014.JI Y L. Research and design of intelligent turbidity sensor [D]. Hefei: University of Science and Technology of China, 2014.

    JI Y L. Research and design of intelligent turbidity sensor [D]. Hefei: University of Science and Technology of China, 2014.

    [13]

    李贤勇. 接触角的测试方法及其在烟用接装纸原纸上的应用[J]. 中华纸业, 2019, 40(22):26-29.LI X Y. Test method for contact angle and its application to cigarette splicing paper base paper[J]. China Paper, 2019, 40(22):26-29.

    LI X Y. Test method for contact angle and its application to cigarette splicing paper base paper[J]. China Paper, 2019, 40(22):26-29.

    [14]

    李雯雯, 吴瑞华, 董颖. 电气石红外光谱和红外辐射特性的研究[J]. 高校地质学报, 2008(3):426-432.LI W W, WU R H, DONG Y. Study on infrared spectra and infrared radiation properties of tourmaline[J]. Journal of College Geology, 2008(3):426-432.

    LI W W, WU R H, DONG Y. Study on infrared spectra and infrared radiation properties of tourmaline[J]. Journal of College Geology, 2008(3):426-432.

  • 加载中

(7)

计量
  • 文章访问数:  939
  • PDF下载数:  246
  • 施引文献:  0
出版历程
收稿日期:  2022-08-01
刊出日期:  2024-04-25

目录