粉煤灰酸浸提铝渣资源化利用研究进展

李世春, 池君洲, 许立军, 苗家兵. 粉煤灰酸浸提铝渣资源化利用研究进展[J]. 矿产综合利用, 2025, 46(2): 1-7. doi: 10.3969/j.issn.1000-6532.2025.02.001
引用本文: 李世春, 池君洲, 许立军, 苗家兵. 粉煤灰酸浸提铝渣资源化利用研究进展[J]. 矿产综合利用, 2025, 46(2): 1-7. doi: 10.3969/j.issn.1000-6532.2025.02.001
LI Shichun, CHI Junzhou, XU Lijun, MIAO Jiabing. Research Progress on Resource Utilization of Fly Ash Acid Leaching Residue after Aluminum Extraction[J]. Multipurpose Utilization of Mineral Resources, 2025, 46(2): 1-7. doi: 10.3969/j.issn.1000-6532.2025.02.001
Citation: LI Shichun, CHI Junzhou, XU Lijun, MIAO Jiabing. Research Progress on Resource Utilization of Fly Ash Acid Leaching Residue after Aluminum Extraction[J]. Multipurpose Utilization of Mineral Resources, 2025, 46(2): 1-7. doi: 10.3969/j.issn.1000-6532.2025.02.001

粉煤灰酸浸提铝渣资源化利用研究进展

  • 基金项目: 国家科技部“十二五”科技支撑计划项目(2011BAA04B05)
详细信息
    作者简介: 李世春(1987-),男,工学硕士,工程师,研究方向为粉煤灰资源化综合利用工艺技术
  • 中图分类号: TD989;X705

Research Progress on Resource Utilization of Fly Ash Acid Leaching Residue after Aluminum Extraction

  • 粉煤灰酸浸提铝渣的主要成分为二氧化硅,可作为许多硅基材料的生产原料。本文以粉煤灰酸浸提铝渣为原料,综述了制备白炭黑、沸石分子筛、介孔材料、陶瓷材料和橡胶填料等产品的研究进展,并对粉煤灰酸浸提铝渣资源化利用的未来发展进行了展望,提出了向高附加值化、低成本化和绿色环保化的发展方向。

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  • 图 1  传统化学沉淀法制备白炭黑的工艺流程

    Figure 1. 

    图 2  碳分法制备白炭黑的工艺流程

    Figure 2. 

  • [1]

    郭昭华. 粉煤灰“一步酸溶法”提取氧化铝工艺技术及工业化发展研究[J]. 煤炭工程, 2015, 47(7):5-8.GUO Z H. Study and industrialization development of one-step acid dissolution technology for alumina extraction from fly ash[J]. Coal Engineering, 2015, 47(7):5-8. doi: 10.11799/ce201507002

    GUO Z H. Study and industrialization development of one-step acid dissolution technology for alumina extraction from fly ash[J]. Coal Engineering, 2015, 47(7):5-8. doi: 10.11799/ce201507002

    [2]

    谢振山, 李军旗, 陈朝轶, 等. 粉煤灰盐酸浸出液酸分法结晶氯化铝的实验优化[J]. 湿法冶金, 2017, 36(4):316-319.XIE Z S, LI J Q, CHEN C Y, et al. Crystallization of aluminum chloride from hydrochloric acid leaching solution of fly ash[J]. Hydrometallurgy of China, 2017, 36(4):316-319.

    XIE Z S, LI J Q, CHEN C Y, et al. Crystallization of aluminum chloride from hydrochloric acid leaching solution of fly ash[J]. Hydrometallurgy of China, 2017, 36(4):316-319.

    [3]

    李来时, 翟玉春, 吴艳, 等. 硫酸浸取法提取粉煤灰中氧化铝[J]. 轻金属, 2006(12):9-12.LI LS, ZHAI Y C, WU Y, et al. Extracting alumina from fly ash by sulfuric acid[J]. Light Metals, 2006(12):9-12. doi: 10.3969/j.issn.1002-1752.2006.12.003

    LI LS, ZHAI Y C, WU Y, et al. Extracting alumina from fly ash by sulfuric acid[J]. Light Metals, 2006(12):9-12. doi: 10.3969/j.issn.1002-1752.2006.12.003

    [4]

    高桂梅. 粉煤灰中氧化铝硫酸直接浸取工艺优化[J]. 矿产综合利用, 2019(6):110-116.GAO G M. Optimization process of extraction of alumina by sulfuric acid direct leaching from the fly ash[J]. Multipurpose Utilization of Mineral Resources, 2019(6):110-116. doi: 10.3969/j.issn.1000-6532.2019.06.024

    GAO G M. Optimization process of extraction of alumina by sulfuric acid direct leaching from the fly ash[J]. Multipurpose Utilization of Mineral Resources, 2019(6):110-116. doi: 10.3969/j.issn.1000-6532.2019.06.024

    [5]

    杨权成, 马淑花, 谢华, 等. 高铝粉煤灰提取氧化铝的研究进展[J]. 矿产综合利用, 2012(3):3-7.YANG Q C, MA S H, XIE H, et al. Research progress of extracting alumina from high-aluminum fly ash[J]. Multipurpose Utilization of Mineral Resources, 2012(3):3-7. doi: 10.3969/j.issn.1000-6532.2012.03.001

    YANG Q C, MA S H, XIE H, et al. Research progress of extracting alumina from high-aluminum fly ash[J]. Multipurpose Utilization of Mineral Resources, 2012(3):3-7. doi: 10.3969/j.issn.1000-6532.2012.03.001

    [6]

    肖永丰. 粉煤灰提取氧化铝方法研究[J]. 矿产综合利用, 2020(4):156-162.XIAO Y F. Study on the methods of leaching alumina from fly ash[J]. Multipurpose Utilization of Mineral Resources, 2020(4):156-162. doi: 10.3969/j.issn.1000-6532.2020.04.027

    XIAO Y F. Study on the methods of leaching alumina from fly ash[J]. Multipurpose Utilization of Mineral Resources, 2020(4):156-162. doi: 10.3969/j.issn.1000-6532.2020.04.027

    [7]

    胡锐, 贺洋. 高铝粉煤灰酸法提铝尾渣制备超细白炭黑及应用研究[J]. 矿产综合利用, 2016(6):65-67.HU R, HE Y. Research on preparation and application of silica from aluminum tailings by acid leaching of alumina powder coal ash[J]. Multipurpose Utilization of Mineral Resources, 2016(6):65-67. doi: 10.3969/j.issn.1000-6532.2016.06.015

    HU R, HE Y. Research on preparation and application of silica from aluminum tailings by acid leaching of alumina powder coal ash[J]. Multipurpose Utilization of Mineral Resources, 2016(6):65-67. doi: 10.3969/j.issn.1000-6532.2016.06.015

    [8]

    LIU D D, FANG L, CHENG F Q. Bisurfactant‐assisted preparation of amorphous silica from fly ash[J]. Asia‐Pacific Journal of Chemical Engineering, 2016, 11(6):884-892.

    [9]

    田万军, 韩磊, 施正伦. 煤灰酸浸渣碳分法制备纳米白炭黑性能研究[J]. 化工进展, 2018, 37(3):984-991.TIAN W, HAN L, SHI Z L. Performance study of precipitated nano-silica from acid leaching residue of coal ash by carbonation method[J]. Chemical Industry and Engineering Progress, 2018, 37(3):984-991.

    TIAN W, HAN L, SHI Z L. Performance study of precipitated nano-silica from acid leaching residue of coal ash by carbonation method[J]. Chemical Industry and Engineering Progress, 2018, 37(3):984-991.

    [10]

    陆越. 高硅渣烧结法制备白炭黑工艺研究[D]. 沈阳: 沈阳工业大学, 2020.LU Y. Study on preparation of white carbon black by sintering the high silicon slag[D]. Shenyang: Shenyang University of Technology, 2020.

    LU Y. Study on preparation of white carbon black by sintering the high silicon slag[D]. Shenyang: Shenyang University of Technology, 2020.

    [11]

    王宏宾, 杜艳霞. 白泥硫酸法制取白炭黑的工艺研究[J]. 矿产综合利用, 2020(2):156-160.WANG H B, DU Y X. Technology study on preparation of white carbon black from white mud by sulfuric acid method[J]. Multipurpose Utilization of Mineral Resources, 2020(2):156-160. doi: 10.3969/j.issn.1000-6532.2020.02.028

    WANG H B, DU Y X. Technology study on preparation of white carbon black from white mud by sulfuric acid method[J]. Multipurpose Utilization of Mineral Resources, 2020(2):156-160. doi: 10.3969/j.issn.1000-6532.2020.02.028

    [12]

    李超, 王丽萍, 郭昭华, 等. 粉煤灰酸溶渣合成13X分子筛及其对铜离子吸附性能[J]. 无机盐工业, 2018, 50(9):63-66.LI C, WANG L P, GUO Z H, et al. Synthesis of 13X zeolite by fly ash acid residue and its adsorption performance to copper ions[J]. Inorganic Chemicals Industry, 2018, 50(9):63-66.

    LI C, WANG L P, GUO Z H, et al. Synthesis of 13X zeolite by fly ash acid residue and its adsorption performance to copper ions[J]. Inorganic Chemicals Industry, 2018, 50(9):63-66.

    [13]

    张中华, 王宝冬, 孙琦, 等. 工业固体废弃物粉煤灰制备沸石分子筛的研究[C]. 2015年中国环境科学学会学术年会论文集. 中国环境科学学会: 2015: 29-34.ZHANG Z H, WANG B D, SUN Q, et al. Study on the preparation of zeolite molecular sieves from industrial solid waste fly ash [C]. Proceedings of the 2015 Annual Conference of the Chinese Society for Environmental Sciences. Chinese Society for Environmental Sciences: 2015: 29- 34.

    ZHANG Z H, WANG B D, SUN Q, et al. Study on the preparation of zeolite molecular sieves from industrial solid waste fly ash [C]. Proceedings of the 2015 Annual Conference of the Chinese Society for Environmental Sciences. Chinese Society for Environmental Sciences: 2015: 29- 34.

    [14]

    竹涛, 韩一伟, 牛文风, 等. 粉煤灰制备13X分子筛及VOCs吸附性能研究[J]. 煤炭科学技术, 2021, 49(7):216-222.ZHU T, HAN Y W, NIU W F, et al. Preparation of 13X zeolite by coal fly ash for adsorption of volatile organic compounds[J]. Coal Science and Technology, 2021, 49(7):216-222.

    ZHU T, HAN Y W, NIU W F, et al. Preparation of 13X zeolite by coal fly ash for adsorption of volatile organic compounds[J]. Coal Science and Technology, 2021, 49(7):216-222.

    [15]

    陶春光, 田冬, 陈永红, 等. 粉煤灰尾渣碱融水热合成高性能13X分子筛[J]. 硅酸盐通报, 2019, 38(3):622-626+633.TAO C G, TIAN D, CHEN Y H, et al. Fly ash tailings alkali melting hydrothermal synthesis high performance 13X molecular sieves[J]. Bulletin of the Chinese Ceramic Society, 2019, 38(3):622-626+633.

    TAO C G, TIAN D, CHEN Y H, et al. Fly ash tailings alkali melting hydrothermal synthesis high performance 13X molecular sieves[J]. Bulletin of the Chinese Ceramic Society, 2019, 38(3):622-626+633.

    [16]

    贾敏, 杨磊, 王永旺. 体型化NaA分子筛的制备研究[J]. 无机盐工业, 2021, 53(10):98-103.JIA M, YANG L, WANG Y W. Study on preparation of body-shaped NaA aeolite[J]. Inorganic Chemicals Industry, 2021, 53(10):98-103.

    JIA M, YANG L, WANG Y W. Study on preparation of body-shaped NaA aeolite[J]. Inorganic Chemicals Industry, 2021, 53(10):98-103.

    [17]

    罗俊韬, 郭一帆, 张嘉琪, 等. 粉煤灰基NaA分子筛的合成及其吸附性能[J]. 化学研究, 2021, 32(2):160-164.LUO J T, GUO Y F, ZHANG J Q, et al. Preparation and performance of NaA zeolites derived from fly ash[J]. Chemical Research, 2021, 32(2):160-164.

    LUO J T, GUO Y F, ZHANG J Q, et al. Preparation and performance of NaA zeolites derived from fly ash[J]. Chemical Research, 2021, 32(2):160-164.

    [18]

    杨林, 李贺军, 曹建新. 酸溶粉煤灰残渣制备4A分子筛[J]. 武汉理工大学学报, 2012, 34(9):31-35.YANG L, LI H J, CAO J X. Preparation of 4A molecular sieve from acid insoluble ash residue[J]. Journal of Wuhan University of Technology, 2012, 34(9):31-35. doi: 10.3963/j.issn.1671-4431.2012.09.008

    YANG L, LI H J, CAO J X. Preparation of 4A molecular sieve from acid insoluble ash residue[J]. Journal of Wuhan University of Technology, 2012, 34(9):31-35. doi: 10.3963/j.issn.1671-4431.2012.09.008

    [19]

    贾敏, 池君洲, 王永旺, 等. 粉煤灰酸法提取氧化铝的残渣制备4A分子筛[J]. 矿产保护与利用, 2017(1):77-83.JIA M, CHI J Z, WANG Y W, et al. Prepartion 4A-zeolite with acid insoluble ash residue of alumina extraction from fly ash[J]. Mineral Conservation and Utilization, 2017(1):77-83.

    JIA M, CHI J Z, WANG Y W, et al. Prepartion 4A-zeolite with acid insoluble ash residue of alumina extraction from fly ash[J]. Mineral Conservation and Utilization, 2017(1):77-83.

    [20]

    柳丹丹. 粉煤灰酸法提铝过程SiO2强化分离及硅基材料制备研究[D]. 太原: 山西大学, 2019.LIU D D. Separation and utilization of silica from alumina extraction process of coal fly ash with acid leaching[D]. Taiyuan: Shanxi University, 2019.

    LIU D D. Separation and utilization of silica from alumina extraction process of coal fly ash with acid leaching[D]. Taiyuan: Shanxi University, 2019.

    [21]

    张梦露. 粉煤灰制备富铝浸出液及提铝酸渣制备吸附剂[D]. 大连: 大连理工大学, 2021.ZHANG M L. Aluminum extraction from coal fly ash and preparation of adsorbent with the acid leaching residue[D]. Dalian: Dalian University of Technology, 2021.

    ZHANG M L. Aluminum extraction from coal fly ash and preparation of adsorbent with the acid leaching residue[D]. Dalian: Dalian University of Technology, 2021.

    [22]

    姚聪. 粉煤灰提铝废渣制备介孔硅材料的研究[D]. 太原: 山西大学, 2018.YAO C. Synthesis of mesoporous silica using alumina-extracted residue derived from coal fly ash[D]. Taiyuan: Shanxi University, 2018.

    YAO C. Synthesis of mesoporous silica using alumina-extracted residue derived from coal fly ash[D]. Taiyuan: Shanxi University, 2018.

    [23]

    柳向阳. 粉煤灰酸法提铝渣制备层状硅酸钠和SBA-15及其性能研究[D]. 太原: 山西大学, 2019.LIU X Y. Synthesis, Characteri and performance of layered sodium silicate from acid-extraction residues of coal fly ash[D]. Taiyuan: Shanxi University, 2019.

    LIU X Y. Synthesis, Characteri and performance of layered sodium silicate from acid-extraction residues of coal fly ash[D]. Taiyuan: Shanxi University, 2019.

    [24]

    窦魁洲. 循环流化床(CFB)粉煤灰提铝酸溶渣制备赛隆复相材料[D]. 长春: 吉林大学, 2020.DOU K Z. Preparation of SiAlON multiphase materials from circulating fluidized bedrom (CFB) fly ash alumina extracted acid slag[D]. Changchun: Jilin University, 2020.

    DOU K Z. Preparation of SiAlON multiphase materials from circulating fluidized bedrom (CFB) fly ash alumina extracted acid slag[D]. Changchun: Jilin University, 2020.

    [25]

    FOO C T, SALLEH A, KOK K Y, et al. Characterization of high-temperature hierarchical porous mullite washcoat synthesized using aluminum dross and coal fly ash[J]. Crystals, 2020, 10(3):178. doi: 10.3390/cryst10030178

    [26]

    魏存弟, 雒锋, 蒋引珊, 等. 酸法提铝后的粉煤灰弃渣改性制备橡胶填料的方法[P]. 吉林省: CN102775816B, 2014-04-23.WEI C D, LUO F, JIANG Y S, et al. Method for preparing rubber filler by modification of fly ash spoil after acid extraction of aluminum [P]. Jilin Province: CN102775816B, 2014- 04-23.

    WEI C D, LUO F, JIANG Y S, et al. Method for preparing rubber filler by modification of fly ash spoil after acid extraction of aluminum [P]. Jilin Province: CN102775816B, 2014- 04-23.

    [27]

    于洪鉴, 杜高翔, 王丽娟, 等. 粉煤灰提铝残渣改性制备橡胶填料[J]. 中国粉体技术, 2016, 22(5):14-17.YU H J, DU G X, WANG L J, et al. Preparation of rubber filler by modified residue after extracting alumina from fly ash[J]. China Powder Science and Technology, 2016, 22(5):14-17.

    YU H J, DU G X, WANG L J, et al. Preparation of rubber filler by modified residue after extracting alumina from fly ash[J]. China Powder Science and Technology, 2016, 22(5):14-17.

    [28]

    池君洲. 粉煤灰提铝残渣粒度对天然橡胶性能的影响[J]. 非金属矿, 2017, 40(3):41-43.CHI J Z. Effects of the particle size of fly ash residue after extracting aluminum on properties of nature rubber[J]. Non-Metallic Mines, 2017, 40(3):41-43. doi: 10.3969/j.issn.1000-8098.2017.03.011

    CHI J Z. Effects of the particle size of fly ash residue after extracting aluminum on properties of nature rubber[J]. Non-Metallic Mines, 2017, 40(3):41-43. doi: 10.3969/j.issn.1000-8098.2017.03.011

    [29]

    池君洲. 改性粉煤灰提铝残渣填充橡胶复合材料的性能研究[J]. 露天采矿技术, 2017, 32(5):77-80.CHI J Z. Study on properties of modified ash residue after extracting aluminum filling rubber composites[J]. Opencast Mining Technology, 2017, 32(5):77-80.

    CHI J Z. Study on properties of modified ash residue after extracting aluminum filling rubber composites[J]. Opencast Mining Technology, 2017, 32(5):77-80.

    [30]

    胡婷婷. 白泥基水化硅酸钙的制备及其制品的性能研究[D]. 重庆: 重庆大学, 2020.HU T T. Study on preparation of calcium silicate hydrate from fly ash aluminum residue and study on the properties of calcium silicate hydrate test block[D]. Chongqing: Chongqing University, 2020.

    HU T T. Study on preparation of calcium silicate hydrate from fly ash aluminum residue and study on the properties of calcium silicate hydrate test block[D]. Chongqing: Chongqing University, 2020.

    [31]

    张丽宏, 柳向阳, 方莉, 等. 粉煤灰提铝渣制备δ-层状硅酸钠及其性能研究[J]. 无机盐工业, 2018, 50(12):54-59.ZHANG L H, LIU X Y, FANG L, et al. Synthesis, characterization and performance of δ-layered sodium silicate from alumina-extracted slag of coal fly ash[J]. Inorganic Chemicals Industry, 2018, 50(12):54-59.

    ZHANG L H, LIU X Y, FANG L, et al. Synthesis, characterization and performance of δ-layered sodium silicate from alumina-extracted slag of coal fly ash[J]. Inorganic Chemicals Industry, 2018, 50(12):54-59.

    [32]

    CHENG Y, LUO F, JIANG Y S, et al. The effect of calcination temperature on the structure and activity of TiO2/SiO2 composite catalysts derived from titanium sulfate and fly ash acid sludge[J]. Colloids & Surfaces A Physicochemical & Engineering Aspects, 2018, 554:81-85.

    [33]

    黄少文, 俞平胜. 粉煤灰酸法提铝渣制备硅酸盐水泥的研究[J]. 粉煤灰综合利用, 2002(2):40-41.HUANG S W, YU P S. Study on the preparation of portland cement by fly ashacid leaching residue[J]. Fly Ash Comprehensive Utilization, 2002(2):40-41. doi: 10.3969/j.issn.1005-8249.2002.02.015

    HUANG S W, YU P S. Study on the preparation of portland cement by fly ashacid leaching residue[J]. Fly Ash Comprehensive Utilization, 2002(2):40-41. doi: 10.3969/j.issn.1005-8249.2002.02.015

    [34]

    Zhao A C, Liu Y J, Zhang T A, et al. Preparation and characterization of Portland cement clinker from sulfuric acid leaching residue of coal fly ash[J]. Materials Research Express, 2022, 9(3).

    [35]

    Wang X K, Zhang N, Zhang Y H, et al. Composite plates utilizing dealkalized red mud, acid leaching slag and dealkalized red mud-fly ash: Preparation and performance comparison[J]. Construction and Building Materials, 2020, 261(261).

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出版历程
收稿日期:  2022-04-13
刊出日期:  2025-04-25

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