西藏甲玛铜钼矿浮选产品工艺矿物学

郭谨铭; 杨洪英; 孟晶; 佟琳琳; 金哲男; 陈国宝; 张勤

doi:10.3969/j.issn.1000-6532.2025.02.027

西藏甲玛铜钼矿浮选产品工艺矿物学

东北大学冶金学院，多金属共生矿生态化冶金教育部重点实验室，辽宁　沈阳　110819

基金项目: 国家重点研发项目（2018YFC1902002）；企业项目（2021021800150）

详细信息

作者简介: 郭谨铭（1996-），男，硕士研究生，主要从事重贵金属选矿技术研究

通讯作者: 杨洪英（1960-），女，教授，博士生导师，主要从事重贵金属选冶技术研究

中图分类号: TD952

收稿日期: 2022-04-14

刊出日期: 2025-04-25

Process Mineralogy of Flotation Products of a Copper-molybdenum Ore in Jiama, Xizang

Key Laboratory of Ecological Metallurgy of Polymetallic Symbiotic Ore, Ministry of Education, School of Metallurgy, Northeastern University, Shenyang 110819, Liaoning, China

More Information

Corresponding author: YANG Hongying, yanghy@smm.neu.edu.cn

Received Date: 14 April 2022

Publish Date: 25 April 2025

摘要

摘要:
对西藏甲玛角岩型和矽卡岩型铜钼矿石以及分离浮选得到的铜精矿和钼精矿进行了工艺矿物学研究。研究表明：角岩型铜钼矿含Cu 0.38%、 Mo 0.01%，矽卡岩型铜钼矿含Cu 0.85%、含Mo 0.03%，浮选得到的铜精矿中的Mo主要以与铜矿物连生的形式流失，钼精矿中杂质矿物主要以与辉钼矿连生或细小颗粒的形式进入到钼精矿中。研究结果为充分利用该矿石资源、选别工艺的优化提供理论指导。
- 铜钼矿石 /
- 角岩型 /
- 矽卡岩型 /
- 工艺矿物学 /
- 铜精矿 /
- 钼精矿
Abstract:
The process mineralogy was studied on hornstone and skarn copper-molybdenum ores and the copper and molybdenum concentrates was obtained by separating flotationin Jiama, Xizang. The research shows that the hornstone copper-molybdenum ore contains Cu 0.38% and Mo 0.01%, and the skarn copper-molybdenum ore contains Cu 0.85% and Mo 0.03%. Mo is mainly lost in the form of continuous growth with copper minerals in the copper concentrate. The impurity elements in the molybdenum concentrate mainly enter into the molybdenum concentrate in the form of continuous growth with molybdenite or fine particles. The research results provide theoretical guidance for making full use of the ore resources and optimizing the sorting process.
- Copper-molybdenum ore /
- Hornstone type /
- Skarn type /
- Process mineralogy /
- Copper concentrate /
- Molybdenum concentrate

HTML全文

图 1 黄铁矿颗粒

Figure 1.

下载: 全尺寸图片幻灯片

图 2 黄铜矿颗粒

Figure 2.

下载: 全尺寸图片幻灯片

图 3 斑铜矿颗粒

Figure 3.

下载: 全尺寸图片幻灯片

图 4 铜精矿中的辉钼矿

Figure 4.

下载: 全尺寸图片幻灯片

图 5 黄铁矿颗粒

Figure 5.

下载: 全尺寸图片幻灯片

图 6 黄铜矿颗粒

Figure 6.

下载: 全尺寸图片幻灯片

图 7 钼精矿中的杂质

Figure 7.

下载: 全尺寸图片幻灯片

表 1 角岩型铜钼矿石化学成分分析/%

Table 1. Analysis of chemical composition of hornstone copper-molybdenum ores

Cu	C	Mo	Fe	S	SiO₂	Al₂O₃	CaO	K₂O	MgO	其他
0.38	0.83	0.01	2.55	2.05	68.44	9.46	2.12	5.44	1.06	7.66

下载: 导出CSV

表 2 矽卡岩型铜钼矿石化学成分分析/%

Table 2. Chemical composition analysis of skarn copper-molybdenum ores

Cu	Mo	Fe	S	Bi	Pb	Zn	SiO₂	MgO	Al₂O₃	CaO	C	其他
0.85	0.03	7.13	5.45	0.01	0.12	0.05	35.42	1.39	4.41	26.52	2.22	16.40

下载: 导出CSV

表 3 铜钼分离浮选实验结果

Table 3. Results of copper and molybdenum separation flotation test

产品名称	产率/%	品位/%		回收率/%
产品名称	产率/%	Cu	Mo	Cu	Mo
混合精矿	100.00	19.00	0.38	100.00	100.00
钼精矿	0.66	0.94	46.50	0.03	80.76
铜精矿	99.34	19.12	0.07	99.97	19.24

下载: 导出CSV

表 4 矿物组成及相对含量

Table 4. Mineral composition and relative content

金属矿物	含量/%	非金属矿物	含量/%
黄铁矿	40.79	石英	2.64
黄铜矿	17.71	云母	1.15
斑铜矿	17.38	绿帘石	1.09
铜蓝	3.98	长石	0.98
辉铜矿	3.32	方解石	0.69
方铅矿	2.61	辉石	0.25
黑铜矿	1.65	硅灰石	0.03
闪锌矿	1.10	其他矿物	4.51
辉钼矿	0.12	合计	100.00

下载: 导出CSV

表 5 矿物组成及相对含量

Table 5. Mineral composition and relative content

金属矿物	含量/%	非金属矿物	含量/%
辉钼矿	78.67	石英	1.32
黄铁矿	9.37	方解石	0.89
黄铜矿	2.09	长石	0.46
斑铜矿	1.84	辉石	0.36
方铅矿	0.48	绿帘石	0.11
铜蓝	0.33	硅灰石	0.11
闪锌矿	0.26	其他矿物	3.71
		合计 100.00

下载: 导出CSV

参考文献(12)

[1]	陈良, 刘富权, 钱永超, 等. 四川会理红泥坡铜矿工艺矿物学[J]. 矿产综合利用, 2021(3):200-204.CHEN L, LIU F Q, QIAN Y C, et al. The process mineralogy of the Hongnipo copper deposit in Huili county, Sichuan[J]. Multipurpose Utilization of Mineral Resources, 2021(3):200-204. CHEN L, LIU F Q, QIAN Y C, et al. The process mineralogy of the Hongnipo copper deposit in Huili county, Sichuan[J]. Multipurpose Utilization of Mineral Resources, 2021(3):200-204.
[2]	王玲, 赵战锋. 工艺矿物学在地质冶金学中的应用及问题[J]. 矿产综合利用, 2020(2):37-43.WANG L, ZHAO Z F. Application and difficulties of process mineralogy in geometallurgy modeling[J]. Multipurpose Utilization of Mineral Resources, 2020(2):37-43. WANG L, ZHAO Z F. Application and difficulties of process mineralogy in geometallurgy modeling[J]. Multipurpose Utilization of Mineral Resources, 2020(2):37-43.
[3]	黄鹏亮, 杨丙桥, 胡杨甲, 等. 铜钼分离技术研究进展[J]. 有色金属(选矿部分), 2019(5):50-55+62.HUANG P L, YANG B Q, HU Y J, et al. Research progress of copper and molybdenum separation technology[J]. Nonferrous Metals (Mineral Processing Section), 2019(5):50-55+62. HUANG P L, YANG B Q, HU Y J, et al. Research progress of copper and molybdenum separation technology[J]. Nonferrous Metals (Mineral Processing Section), 2019(5):50-55+62.
[4]	赵刘阳, 吴臣星, 谢恩成, 等. 四川某伴生稀贵金属铜钼矿工艺矿物学研究[J]. 云南冶金, 2020, 49(5):14-23.ZHAO L Y, WU C X, XIE E C, et al. Process mineralogy of an associated rare and precious metal copper-molybdenum ore in Sichuan[J]. Yunnan Metallurgy, 2020, 49(5):14-23. doi: 10.3969/j.issn.1006-0308.2020.05.005 ZHAO L Y, WU C X, XIE E C, et al. Process mineralogy of an associated rare and precious metal copper-molybdenum ore in Sichuan[J]. Yunnan Metallurgy, 2020, 49(5):14-23. doi: 10.3969/j.issn.1006-0308.2020.05.005
[5]	王枫, 卢晶, 李磊, 等. 安徽池州大石门铅锌银硫多金属矿床物质组分赋存状态研究[J]. 矿产综合利用, 2019(4):98-102.WANG F, LU J, LI L, et al. Study on occurrence of Pb-Zn-Ag-S polymetallic deposit in Dashimen, Chizhou county, Anhui Province[J]. Multipurpose Utilization of Mineral Resources, 2019(4):98-102. doi: 10.3969/j.issn.1000-6532.2019.04.021 WANG F, LU J, LI L, et al. Study on occurrence of Pb-Zn-Ag-S polymetallic deposit in Dashimen, Chizhou county, Anhui Province[J]. Multipurpose Utilization of Mineral Resources, 2019(4):98-102. doi: 10.3969/j.issn.1000-6532.2019.04.021
[6]	陈典助. 西藏甲玛铜多金属矿选矿厂设计与生产实践[J]. 有色金属(选矿部分), 2011(2):30-34.CHEN D Z. Design and production practice of beneficiation plant of Jiama copper-polymetallic ore in Tibet[J]. Nonferrous Metals (Mineral Processing Section), 2011(2):30-34. CHEN D Z. Design and production practice of beneficiation plant of Jiama copper-polymetallic ore in Tibet[J]. Nonferrous Metals (Mineral Processing Section), 2011(2):30-34.
[7]	王艳, 巴正晨, 高歌, 等. 西藏甲玛矽卡岩型铜钼矿石工艺矿物学研究[J]. 黄金, 2019, 40(2):60-65.WANG Y, BA Z C, GAO G, et al. Process Mineralogy of Jiama skarn-type copper-molybdenum ore in Tibet[J]. Gold, 2019, 40(2):60-65. doi: 10.11792/hj20190213 WANG Y, BA Z C, GAO G, et al. Process Mineralogy of Jiama skarn-type copper-molybdenum ore in Tibet[J]. Gold, 2019, 40(2):60-65. doi: 10.11792/hj20190213
[8]	蒋先强, 毛益林, 曾令熙. 云南某矽卡岩型钼铜矿工艺矿物学研究[J]. 云南冶金, 2016, 45(4):15-20.JIANG X Q, MAO Y L, ZENG L X. Research on the process mineralogy of a skarn-type molybdenum-copper mine in Yunnan[J]. Yunnan Metallurgy, 2016, 45(4):15-20. doi: 10.3969/j.issn.1006-0308.2016.04.004 JIANG X Q, MAO Y L, ZENG L X. Research on the process mineralogy of a skarn-type molybdenum-copper mine in Yunnan[J]. Yunnan Metallurgy, 2016, 45(4):15-20. doi: 10.3969/j.issn.1006-0308.2016.04.004
[9]	陈健龙, 高歌, 王艳, 等. 西藏甲玛角岩型铜钼矿石工艺矿物学研究[J]. 黄金, 2021, 42(6):78-82.CHEN J L, GAO G, WANG Y, et al. Research on the process mineralogy of the Jiamajiao rock-type copper-molybdenum ore in Tibet[J]. Gold, 2021, 42(6):78-82. CHEN J L, GAO G, WANG Y, et al. Research on the process mineralogy of the Jiamajiao rock-type copper-molybdenum ore in Tibet[J]. Gold, 2021, 42(6):78-82.
[10]	和翠英, 王国强. 云南某铜钼多金属矿选矿工艺实验[J]. 现代矿业, 2018, 34(9):11-15.HE C Y, WANG G Q. Ore beneficiation process test of a copper-molybdenum polymetallic ore in Yunnan[J]. Modern Mining, 2018, 34(9):11-15. HE C Y, WANG G Q. Ore beneficiation process test of a copper-molybdenum polymetallic ore in Yunnan[J]. Modern Mining, 2018, 34(9):11-15.
[11]	陈志友, 苏小琼, 肖洪旭, 等. 云南某微细粒辉钼矿工艺矿物学与浮选回收技术研究[J]. 矿物学报, 2021, 41(3):287-293.CHEN Z Y, SU X Q, XIAO H X, et al. Research on process mineralogy and flotation recovery technology of a fine-grained molybdenite in Yunnan[J]. Acta Minera Sinica, 2021, 41(3):287-293. CHEN Z Y, SU X Q, XIAO H X, et al. Research on process mineralogy and flotation recovery technology of a fine-grained molybdenite in Yunnan[J]. Acta Minera Sinica, 2021, 41(3):287-293.
[12]	周雄, 曾令熙, 赵开乐. 云南香格里拉铜钼多金属矿工艺矿物学研究[J]. 矿物学报, 2019, 39(5):609-614.ZHOU X, ZENG L X, ZHAO K L. Study on process mineralogy of Shangri-La copper-molybdenum polymetallic ore in Yunnan[J]. Acta Minera Sinica, 2019, 39(5):609-614. ZHOU X, ZENG L X, ZHAO K L. Study on process mineralogy of Shangri-La copper-molybdenum polymetallic ore in Yunnan[J]. Acta Minera Sinica, 2019, 39(5):609-614.