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静电场轨道阱质谱在水中溶解性有机质表征中的应用进展

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王书越, 何洪源, 饶竹, 石喆元, 孟建卫, 王立平, 李开开. 2022. 静电场轨道阱质谱在水中溶解性有机质表征中的应用进展[J]. 地球学报, 43(1): 101-109. doi: 10.3975/cagsb.2021.121301
引用本文: 王书越, 何洪源, 饶竹, 石喆元, 孟建卫, 王立平, 李开开. 2022. 静电场轨道阱质谱在水中溶解性有机质表征中的应用进展[J]. 地球学报, 43(1): 101-109. doi: 10.3975/cagsb.2021.121301
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WANG Shu-yue, HE Hong-yuan, RAO Zhu, SHI Zhe-yuan, MENG Jian-wei, WANG Li-ping, LI Kai-kai. 2022. Progress in the Application of Orbitrap Mass Spectrometry in the Characterization of Dissolved Organic Matter in Water. Acta Geoscientica Sinica, 43(1): 101-109. doi: 10.3975/cagsb.2021.121301
Citation: WANG Shu-yue, HE Hong-yuan, RAO Zhu, SHI Zhe-yuan, MENG Jian-wei, WANG Li-ping, LI Kai-kai. 2022. Progress in the Application of Orbitrap Mass Spectrometry in the Characterization of Dissolved Organic Matter in Water. Acta Geoscientica Sinica, 43(1): 101-109. doi: 10.3975/cagsb.2021.121301
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静电场轨道阱质谱在水中溶解性有机质表征中的应用进展

  • 1. 中国人民公安大学侦查学院, 北京 100038;

  • 2. 自然资源部生态地球化学重点实验室, 国家地质实验测试中心, 北京 100037;

  • 3. 河北省矿产资源与生态环境监测重点实验室, 河北保定 071000

  • 基金项目:

    本文由中国地质调查局地质调查项目“重点地区健康地质调查试点”(编号: DD20211414)、“水样测试分析质量控制”(编号:DD20190323)、中央高校基本科研业务费项目(编号: 2021JKF201)和上海市现场物证重点实验室开放课题(编号: 2021XCWZK05)联合资助

详细信息
    作者简介: 王书越, 女, 1996年生。硕士研究生。刑事科学技术专业, 主要从事地下水溶解性有机质研究。通讯地址: 100038, 北京市西城区中国人民公安大学木樨地校区。E-mail: 835769986@qq.com
    通讯作者: 何洪源, 女, 1965年生。博士, 教授。主要从事法庭毒物分析。通讯地址: 100038, 北京西城区木樨地南里甲1号中国人民公安大学。E-mail: 13311296819@189.cn

  • 中图分类号: X1; O657.6

Progress in the Application of Orbitrap Mass Spectrometry in the Characterization of Dissolved Organic Matter in Water

  • 1. School of Investigation, People’s Public Security University of China, Beijing 100038;

  • 2. Key Laboratory of Eco-geochemistry, Ministry of Natural Resources, National Research Center for Geoanalysis, Beijing 100037;

  • 3. Hebei Key Laboratory of Mineral Resources and Ecological Environment Monitoring, Baoding, Hebei 071000

More Information
    Corresponding author: HE Hong-yuan

    摘要
  • 溶解性有机质(Dissolved Organic Matter, DOM)在水生生态环境中广泛存在, 影响着水环境中多种物质的生物地球化学性质。分析其组成与含量具有重要的生态环境意义, 是生态环境科学领域研究的热点。溶解性有机质组成非常复杂, 其分子组成的解析一直是难题。近年来, 具有高分辨率、高灵敏度、高通量、高扫描速率等特性的静电场轨道阱质谱技术, 结合计算机编程技术、可视化技术对 DOM 分子组成分布特征进行表征, 可大幅提升对DOM的解析能力。本文总结了DOM的高分辨质谱数据表达方法, 综述了静电场轨道阱质谱技术的发展及其表征水体中DOM的应用现状, 并对未来研究进行展望。
    Dissolved organic matter (DOM) exists widely in the aquatic ecological environment and has a significant influence on the biogeochemical properties of many substances. Its composition and content have important ecological and environmental significance and has been a hot spot in ecological and environmental science research. The composition of DOM is complex, and its molecular composition analysis has always been a challenge. In recent years, Orbitrap mass spectrometry (Orbitrap MS), capable of high resolution, high sensitivity, high throughput, and high scanning rate, combined with computer programming technology and visualization technology could be used to characterize the molecular composition and distribution of DOM, greatly improving the capabilities of DOM. In this paper, the explanation methods of DOM high-resolution MS data are summarized, the Orbitrap MS technology and its application status in characterization of DOM in water are reviewed, and the prospects for future developments are analyzed.
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