Environmental Assessment of Heavy Metal Contamination in the Northeast of Huize County, Yunnan Province
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摘要: 按照多目标地球化学填图计划, 云南省地质调查院开展了“云南省滇中-滇东北地区1:25万土地质量地球化学调查”工作, 获得了54项元素或氧化物的含量数据。本文基于此次调查中云南会泽东北部地区的182件表层土壤样品, 参照《土壤环境质量 农用地土壤污染风险管制标准(试行)》(GB15618—2018), 基于新标准本文提出农用地重金属单项污染指数和综合污染指数的计算及其定性赋值方法。对于标准中背景级、筛选级、管制级的定性分级, 在单项污染指数中分别赋值 0、1、10, 而综合污染指数取值为单项污染指数取值的累加。针对研究区5个重金属Pb、Cd、As、Cr、Hg进行了农用地环境质量评价。结果表明, 研究区土壤的pH值介于4.66~8.16, 土壤整体偏酸性; Pb和Cd含量局部高于GB15618—2018规定的污染风险管制值; Cr和As含量局部高于土壤污染风险筛选值, 但均低于管制值; Hg含量均低于污染风险筛选值。为便于重金属单项污染指数和综合污染指数的计算, 本文开发了EGAPI-GB15618软件供参考使用。
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关键词:
- 云南会泽 /
- 重金属 /
- 环境评价 /
- 污染指数 /
- EGAPI-GB15618
Abstract: According to the National Multi-Purpose Regional Geochemical Survey (NMPRGS) project, the geochemical survey project of land quality with a scale of 1: 250 000 in the center and northeast of Yunnan province has been completed. Fifty-four items (including pH, major oxides, and elements) were analyzed in each composite surface soil sample per 4 km2 in this project. Based on the 182 surface soil samples collected in the northeast of Huize county in Yunnan province and the Soil Environmental Quality (SEQ) risk control standard for soil contamination of agricultural land in China (GB15618-2018), the environmental quality of the study area was evaluated on 5 heavy metals (Pb, Cd, As, Cr and Hg) using a new single pollution index and integrated pollution index proposed in this paper with qualitative descriptions. For samples with no pollution, screening pollution or controlling pollution, the single pollution index is set to 0, 1 or 10 respectively, and the integrated pollution index is set to the sum of the single pollution index values. The soil in this area is generally acidic, and its pH varies from 4.66 to 8.16. Some contents of Pb and Cd are higher than the environmental pollution control values stipulated in GB15618-2018 for agricultural land. Both Cr and As contents are all lower than the control values although some contents are higher than the screening values of pollution risk. In addition, all contents of Hg were lower than the screening value for agricultural lands. Therefore, it is suggested to control the environmental pollution of Pb and Cd and to monitor the contents of Cr and As in the soil if the area is used for agriculture.Meanwhile, the pollution risk of Hg in the soil could be ignored according to the survey results. To calculate the single and integrated pollution indices proposed in this paper, software named EGAPI-GB15618 was developed non-commercially. -
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陈翠华, 倪师军, 何彬彬, 张成江. 2008. 江西德兴矿集区水系沉积物重金属污染的时空对比[J]. 地球学报, 29(5):639-646.
房辉, 曹敏. 2009. 云南会泽废弃铅锌矿重金属污染评价[J]. 生态学杂志, 28(7): 1277-1283.
高瑞英. 2012. 土壤重金属污染环境风险评价方法研究进展[J].科技管理研究, 32(8): 45-50.
国家环境保护局. 1995. 《土壤环境质量标准》(GB15618-1995)[S]. 北京: 中国标准出版社: 1-44.
国土资源部. 2014. 多目标区域地球化学调查规范(1:250000)( DZ/T 0258-2014)[S]. 北京: 中国标准出版社: 1-44.
韩润生, 胡煜昭, 王学琨, 黄智龙, 陈进, 王峰, 吴鹏, 李波, 王洪江, 董英, 雷丽. 2012. 滇东北富锗银铅锌多金属矿集区矿床模型[J]. 地质学报, 86(2): 280-294.
环境保护部, 国土资源部. 2014. 全国土壤污染状况调查公报[EB/OL]. [2014-04-17]. https://www.mee.gov.cn/gkml/sthjbgw/qt/201404/t20140417_270670_wh.htm.
黄智龙, 陈进, 韩润生, 李文博, 刘丛强, 张振亮, 马德云, 高德荣, 杨海林.2004. 云南会泽超大型铅锌矿床地球化学及成因--兼论峨眉山玄武岩与铅锌成矿的关系[M]. 北京:地质出版社: 1-187.
江小均, 王忠强, 李超, 郭忠林, 柴建华, 邱文龙, 王加昇. 2018.滇东北会泽超大型铅锌矿 Re-Os同位素特征及喜山期成矿作用动力学背景探讨[J]. 岩矿测试, 37(4): 448-461.
李金哲, 刘宁强, 龚庆杰, 李承柱. 2021. 广东汕头市内海湾沉积物重金属环境质量调查与评价[J]. 现代地质, 35(5):1441-1449.
李瑞萍, 王安建, 曹殿华, 耿诺, 高兰, 邹为雷, 赵以辛, 修群业. 2009. 云南兰坪金顶铅锌矿区土壤中 Pb分布特征[J].地球学报, 30(1): 72-78.
李志平, 余泽章, 罗大锋, 李永才, 魏江, 李惠. 2018. 云南会泽县麒麟厂铅锌矿床构造叠加晕特征及找矿意义[J]. 地质科技情报, 37(2): 109-117.
刘青枰, 邓时强, 赵元艺, 李小赛. 2018. 西藏尕尔勤矿床区域性土壤重金属元素地球化学特征及来源解析[J]. 地球学报, 39(4): 481-490.
陆泗进, 王业耀, 何立环. 2014. 会泽某铅锌矿周边农田土壤重金属生态风险评价[J]. 生态环境学报, 23(11): 1832-1838.
陆泗进, 王业耀, 何立环. 2015. 会泽某铅锌矿周边农田土壤重金属风险评价研究[J]. 中国环境监测, 31(6): 77-82.
骆永明, 滕应. 2018. 我国土壤污染的区域差异与分区治理修复策略[J]. 中国科学院院刊, 33(2): 145-152.
山成栋. 2020. 会泽铅锌矿富锗闪锌矿的沉淀机制研究[D]. 北京: 中国地质大学: 1-97.
生态环境部, 国家市场监督管理总局. 2018. 土壤环境质量农用地土壤污染风险管控标准(试行)(GB15618-2018)[S]. 北京:中国环境出版社.
王英辉, 陈学军, 赵艳林, 祁士华. 2007. 铅锌矿区土壤重金属污染与优势植物累积特征[J]. 中国矿业大学学报, 36(4):487-493.
吴劲楠, 龙健, 刘灵飞, 李娟, 廖洪凯, 彭四清, 万洪富. 2018.某铅锌矿区农田重金属分布特征及其风险评价[J]. 中国环境科学, 38(3): 1054-1063.
杨斌, 金灿海, 张玙, 冀盘龙, 郭阳, 王子正. 2018. 云南乌蒙山区毛坪铅锌矿矿床特征及成矿模式研究[J]. 地球学报, 39(5): 592-605.
叶金利, 田路萍, 吴文卫, 黄小凤. 2019. 云南会泽者海镇典型矿区场地重金属污染特征及健康风险评价[J]. 环境监测管理与技术, 31(3): 36-40.
云南省地质调查院. 2019. 云南省滇中-滇东北地区1:25万土地质量地球化学调查成果报告[R]. 昆明: 云南省地质调查院.
张艳, 韩润生, 魏平堂, 邱文龙. 2017. 云南会泽矿山厂铅锌矿床流体包裹体特征及成矿物理化学条件[J]. 吉林大学学报(地球科学版), 47(3): 719-733.
张长青. 2008. 中国川滇黔交界地区密西西比型(MVT)铅锌矿床成矿模型[D]. 北京: 中国地质科学院: 1-167.
左群超, 叶天竺, 冯艳芳, 葛佐, 王英超. 2018. 中国陆域1: 25万分幅建造构造图空间数据库[J]. 中国地质, 45(S1): 1-26, 163.
AN Yong-long, YAN Tao-tao, GONG Qing-jie, WANG Xue-qiu, HUANG Yong, ZHANG Bi-min, YIN Zhi-qiang, ZHAO Xiu-fang, LIU Ning-qiang. 2022. Chromium(Cr) geochemical mapping based on fixed-values' method: Case studies in China[J]. Applied Geochemistry, 136: 105168.
CHEN Cui-hua, NI Shi-jun, HE Bin-bin, ZHANG Cheng-jiang.2008. Spatial-temporal variation of heavy metals contamination in sediments of the Dexing Mine, Jiangxi Province[J].Acta Geoscientica Sinica, 29(5): 639-646(in Chinese with English abstract).
CHENG Jie-liang, SHI Zhou, ZHU You-wei. 2007. Assessment and mapping of environmental quality in agricultural soils of Zhejiang Province, China[J]. Journal of Environmental Sciences, 19: 50-54.
FANG Hui, CAO Min. 2009. Assessment of heavy metals pollution in abandoned lead-zinc mine tailings in Huize of Yunnan Province[J]. Chinese Journal of Ecology, 28(7): 1277-1283(in Chinese with English abstract).
GAO Rui-ying. 2012. Progress of environmental risk assessment methods on heavy metal contamination in soil[J]. Science and Technology Management Research, 32(8): 45-50(in Chinese with English abstract).
GONG Qing-jie, DENG Jun, XIANG Yun-chuan, WANG Qingfei, YANG Li-qiang. 2008. Calculating pollution indices by heavy metals in ecological geochemistry assessment and a case study in parks of Beijing[J]. Journal of China University of Geosciences, 19(3): 230-241.
HAKANSON L. 1980. An ecological risk index for aquatic pollution control.a sedimentological approach[J]. Water Research, 14(8): 975-1001.
HAN Run-sheng, HU Yu-zhao, WANG Xue-kun, HUANG Zhi-long, CHEN Jin, WANG Feng, WU Peng, LI Bo, WANG Hong-jiang, DONG Ying, LEI Li. 2012. Mineralization model of rich Ge-Ag-Bearing Zn-Pb polymetallic deposit concentrated district in northeastern Yunnan, China[J]. Acta Geologica Sinica, 86(2):280-294(in Chinese with English abstract).
HUANG Zhi-long, CHEN Jin, HAN Run-sheng, LI Wen-bo, LIU Cong-qiang, ZHANG Zhen-liang, MA De-yun, GAO De-rong, YANG Hai-lin.2004. Geochemistry and genesis of the Huize super large lead-zinc deposit in Yunnan province: in addition to a discussion of relationship between Emeishan Basalt and lead-zinc mineralization[M]. Beijing: Geological Publishing House: 1-187(in Chinese).
JIANG Xiao-jun, WANG Zhong-qiang, LI Chao, GUO Zhong-lin, CHAI Jian-hua, QIU Wen-long, WANG Jia-sheng. 2018.Re-Os isotope characteristics of the Huize ultra-large lead-zinc deposit, northeastern Yunnan Province: Constraints on the Himalayan metallogenic dynamic background[J]. Rock and Mineral Analysis, 37(4): 448-461(in Chinese with English abstract).
LI Rui-ping, WANG An-jian, CAO Dian-hua, GENG Nuo, GAO Lan, ZOU Wei-lei, ZHAO Yi-xin, XIU Qun-ye. 2009. Distribution of Pb in soils of the Jinding Pb-Zn Deposit, Lanping, Yunnan Province[J]. Acta Geoscientica Sinica, 30(1):72-78(in Chinese with English abstract).
LI Zhi-ping, YU Ze-zhang, LUO Da-feng, LI Yong-cai, WEI Jiang, LI Hui. 2018. Characteristics of structural superimposed halos and exploration significance of the Qilinchang Pb-Zn Deposit, Huize, Yunnan[J]. Geological Science and Technology Information, 37(2): 109-117(in Chinese with English abstract).
LI Jin-zhe, LIU Ning-qiang, GONG Qing-jie, LI Cheng-zhu. 2021.Investigation and evaluation on environmental quality of heavy metals in sediments of the inland bay of Shantou City, Guangdong Province[J]. Geoscience, 35(5): 1441-1449(in Chinese with English abstract).
LIU Guan-nan, WANG Juan, LIU Xuan, LIU Xin-hui, LI Xiao-sai, REN Ya-qiong, WANG Jing, DONG Li-ming. 2018. Partitioning and geochemical fractions of heavy metals from geogenic and anthropogenic sources in various soil particle size fractions[J]. Geoderma, 312: 104-113.
LIU Qing-ping, DENG Shi-qiang, ZHAO Yuan-yi, LI Xiao-sai.2018. Sources analysis and element geochemical characteristics of regional soil heavy metals from the Ga’erqin Ore Deposit, Xizang[J]. Acta Geoscientica Sinica, 39(4): 481-490(in Chinese with English abstract).
LU Si-jin, WANG Ye-yao, HE Li-huan. 2014. Heavy metal pollution and ecological risk assessment of the paddy soils around a Pb-Zn mine in Huize Country[J]. Ecology and Environmental Sciences, 23(11): 1832-1838(in Chinese with English abstract).
LU Si-jin, WANG Ye-yao, HE Li-huan. 2015. Ecological and health risk of heavy metals in soils near a Pb-Zn mine in Huize Country[J]. Environmental Monitoring in China, 31(6):77-82(in Chinese with English abstract).
LUO Yong-ming, TENG Ying. 2018. Regional difference in soil pollution and strategy of soil zonal governance and remediation in China[J]. Bulletin of Chinese Academy of Sciences, 33(2): 145-152(in Chinese with English abstract).
Ministry of Ecology And Environment, State Administration for Market Regulation. 2018. Soil environmental quality-Risk control standard for soil contamination of agricultural land(GB15618-2018)[S]. Beijing: China Environmental Press(in Chinese).
Ministry of Environmental Protection, Ministry of Land And Resources. Report on the national general survey of soil contamination[EB/OL]. [2014-04-17]. https://www.mee.gov.cn/gkml/sthjbgw/qt/201404/t20140417_270670_wh.htm(in Chinese).
Ministry of Land and Resources. 2014. Specification of multi-purpose regional geochemistry survey(1:250000):(DZ/T 0258-2014)[S]. Beijing: China Quality and Standards Publishing & Media Co., Ltd: 1-44(in Chinese).
National Environmental Protection Bureau. 1995. GB15618-1995 the National Soil Environmental Quality Standard[S]. Beijing:Standards Press of China (in Chinese).
SHAN Cheng-dong. 2020. Study on the precipitation mechanism of germanium-rich sphalerite in Huize lead-zinc mine[D].Beijing: China University of Geosciences: 1-97(in Chinese with English abstract).
WANG Ying-hui, CHEN Xue-jun, ZHAO Yan-lin, QI Shi-hua.2007. Heavy metal pollution in soils and plant accumulation in a restored lead-zinc mineland in Guangxi, South China[J].Journal of China University of Mining & Technology, 36(4):487-493(in Chinese with English abstract).
WU Jin-nan, LONG Jian, LIU Ling-fei, LI Juan, LIAO Hong-kai, PENG Si-qing, WAN Hong-fu. 2018. Spatial distribution and risk assessment of heavy metal pollution in farmland soil of a lead-zinc mining area[J]. China Environmental Science, 38(3):1054-1063(in Chinese with English abstract).
XU Lei, DAI Hui-ping, SKUZA Lidia, WEI Shu-he. 2021. Comprehensive exploration of heavy metal contamination and risk assessment at two common smelter sites[J]. Chemosphere, 285: 131350.
YANG Bin, JIN Can-hai, ZHANG Yu, JI Pan-long, GUO Yang, WANG Zi-zheng. 2018. Ore deposit characteristics and metallogenic model of the Maoping Pb-Zn Deposit in Wumengshan Mountainous area, Yunnan Province[J]. Acta Geoscientica Sinica, 39(5): 592-605(in Chinese with English abstract).
YE Jin-li, TIAN Lu-ping, WU Wen-wei, HUANG Xiao-feng. 2019.Characteristics and health risk assessment of heavy metal pollution in typical mining area in Zhehai, Huize County, Yunnan Province[J]. The Administration and Technique of Environmental Monitoring, 31(3): 36-40(in Chinese with English abstract).
Yunnan Geological Survey Institute. 2019. Geochemical Survey Report of Land Quality in northeastern and central Yunnan province(1: 250, 000)[R]. Kunming: Yunnan Geological Survey Institute(in Chinese).
ZHANG Chang-qing. 2008. The genetic model of Mississippi Valley-type deposits in the boundary area of Sichuan, Yunnan and Guizhou provinces, China[D]. Beijing: Chinese Academy of Geological Sciences: 1-167(in Chinese with English abstract).
ZHANG Yan, HAN Run-sheng, WEI Ping-tang, QIU Wen-long.2017. Fluid inclusion features and physicochemical conditions of the Kuangshanchang Pb-Zn Deposit, Huize, Yunnan Province[J]. Journal of Jilin University(Earth Science Edition), 47(3): 719-733(in Chinese with English abstract).
ZOLLER W H, GLADNEY E S, DUCE R A. 1974. Atmospheric concentrations and sources of trace metals at the South Pole[J].Science, 183(4121): 198-200.
ZUO Qun-chao, YE Tian-zhu, FENG Yan-fang, GE Zuo, WANG Ying-chao. 2018. Spatial database of serial suite-tectonic map-sheets of mainland China(1: 250, 000)[J]. Geology in China, 45(S1): 1-26, 163(in Chinese with English edition).
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