Research on Rubidium and Cesium Resources, Extraction Technology, Development, and Utilization in China
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摘要: 铷、铯具有优异的物理化学性能, 不仅在电子器件、催化剂、特种玻璃等传统领域中, 在高科技新兴应用领域也有广泛的用途。我国铷、铯资源相对丰富, 类型多样, 不仅有固体矿, 而且还有液体矿。本文介绍了国内铷铯资源、提取技术及特点、资源开发利用现状。国内铷铯资源以固体矿为主, 铷、铯的储量分别为116 万t(Rb2O)和14 万t(Cs2O)。利用酸法从固体矿提取铷铯已实现工业化, 萃取法和离子交换法在液体矿上更具有应用前途。广东天堂山铷矿开发项目在近年来备受关注。指出盐湖及地下卤水中的铷铯资源更具发展潜力, 建议加强国内铷铯资源调查、勘查和低品位固体矿、液体矿资源综合提取技术攻关, 拓宽铷铯产品新性能和应用领域。Abstract: Rubidium and cesium have excellent physicochemical properties and are widely used in traditional applications, including electronic devices, catalysts, and special glass, and emerging high-tech applications.Cesium and rubidium resources in China are relatively abundant and of various types, including solid and liquid minerals.This study focused on domestic rubidium and cesium resources, extraction technology and characteristics, and the current situation of resource development and utilization.Domestic rubidium-cesium resources are primarily solid ores, with reserves of rubidium and cesium in the forms of Rb2O and Cs2O amounting to 1.16 million and 140 000 tons, respectively.The extraction of rubidium-cesium from solid ores using the acid method has been industrialized, and the extraction and ion-exchange methods hold promise for liquid ore application.Recently, the rubidium mine, in Tiantangshan, Guangdong Province, a development project has attracted increasing attention.Rubidium and cesium resources in salt lakes and underground brines have more development potential, indicating the need to strengthen domestic rubidium-cesium resource investigation, surveys, comprehensive extraction technology research and development for low-grade solid and liquid ore resources, and broadening the rubidium-cesium products regarding new performance and application areas.
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Key words:
- rubidium and cesium /
- resource /
- extraction technology /
- development and utilization /
- suggestion
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宝阿敏, 钱志强, 郑红, 等, 2017.铷、铯的分离提取方法及其研究进展[J].应用化工, 46(7): 1377-1382.
高丹丹, 李东东, 樊燕飞, 等, 2022.察尔汗盐湖铷资源利用-从基础认知到技术创新[J].盐湖研究, 30(3): 1-11, 41.
高芯蕊, 贾宏翔, 李天骄, 等, 2023.中国铷铯资源需求展望[J].地球学报, 44(2): 279-285.
葛飞, 李雷明, 姜莹莹, 等, 2023.专利视角下铷铯分离技术研究现状分析和评述[J].应用化工, 52(2): 639-645.
郭春平, 周健, 文小强, 等, 2015.锂云母硫酸盐法提取锂铷铯的研究[J].有色金属(冶炼部分), (12): 31-33.
郭秀红, 郑绵平, 刘喜方, 等, 2008.西藏盐湖卤水铯资源及其开发利用前景[J].盐业与化工, 37(3): 8-13.
胡方泱, 刘小驰, 何少雄, 等, 2023.喜马拉雅淡色花岗岩铷铯成矿作用[J].中国科学: 地球科学, 53(12): 2868-2895.
简鹏, 周义朋, 柯平超, 等, 2024.氯化焙烧-水浸法从富铷锂云母矿中提取Li、Rb[J].中国有色冶金, 53(2): 69-78.
李建森, 李廷伟, 马云麒, 等, 2022.柴达木盆地卤水型Li、Rb关键金属矿产元素分布特征及富集机制[J].中国科学(地球科学), 52(3): 474-485.
李庆宽, 王建萍, 樊启顺, 等, 2023.西藏盐湖沉积物: 一种潜在的铷、铯资源[J].地质学报, 97(10): 3410-3420.
李颖, 陈侠, 苗淑兰, 等, 2019.磷钨酸铵复合材料对铷铯吸附性能的研究[J].无机盐工业, 51(6): 34-37.
刘磊, 马保中, 王成彦, 等, 2022.铷的应用及提取工艺研究进展[J].有色金属科学与工程, 13(5): 8-15.
刘力, 2013.中国铷铯资源、技术现状[J].新疆有色金属, 36(S1):158-165.
卢智, 2011.平落坝构造海相深层卤水中铷分离提取技术研究[D].成都: 成都理工大学.
毛景文, 杨宗喜, 谢桂青, 等, 2019a.关键矿产--国际动向与思考[J].矿床地质, 38(4): 689-698.
毛景文, 袁顺达, 谢桂青, 等, 2019b.21 世纪以来中国关键金属矿产找矿勘查与研究新进展[J].矿床地质, 38(5):935-969.
梅燕雄, 裴荣富, 魏然, 等, 2022.关键矿产与能源资源安全[J].中国矿业, 31(11): 1-8.
潘彤, 陈建洲, 丁成旺, 等, 2023.柴达木盆地盐湖黏土中锂, 铷, 铯超常富集及其开发潜力[J].中国地质, 50(6): 1925-1927.
庞登科, 2020.拉果错盐湖卤水中铷、铯萃取分离工艺研究[D].西宁: 中国科学院青海盐湖研究所.
孙艳, 王登红, 王成辉, 等, 2019.我国铷矿成矿规律、新进展和找矿方向[J].地质学报, 93(6): 1231-1244.
王超, 孙小虹, 丁晓姜, 等, 2023.察尔汗盐湖晒卤过程中铷和铯元素富集规律研究[J].岩石矿物学杂志, 42(5): 701-710.
王春连, 黄华, 王九一, 等, 2018.江陵凹陷富钾锂卤水矿田地质特征及成藏模式研究[J].地质学报, 92(8): 1630-1646.
王核, 徐义刚, 闫庆贺, 等, 2021.新疆白龙山伟晶岩型锂矿床研究进展[J].地质学报, 95(10): 3085-3098.
王雪静, 高世扬, 周建国, 等, 2002.用天然斜发沸石从西藏地热水中分离提取K+, Rb+, Cs+的研究[J].盐湖研究, 10(3):31-37.
吴昌志, 贾力, 雷如雄, 等, 2021.中亚造山带天河石花岗岩及相关铷矿床的主要特征与研究进展[J].岩石学报, 37(9):2604-2628.
吴建江, 2023.国内铷铯分离提纯技术的研究进展[J].新疆有色金属, 46(4): 23-24.
谢绍雷, 时东, 张禹泽, 等, 2023.无机吸附材料分离提取铷铯的研究现状[J].稀有金属, 47(7): 1020-1042.
叶秀深, 2009.氯化物型卤水中铷、铯的分析与吸附分离研究[D].西宁: 中国科学院青海盐湖研究所.
张生辉, 王振涛, 李永胜, 等, 2022.中国关键矿产清单、应用与全球格局[J].矿产保护与利用, 42(5): 138-168.
张晓伟, 辛天宇, 刘佳兴, 等, 2021.全球铯矿资源现状及其综合利用技术分析[J].矿产保护与利用, 41(5): 7-11.
张秀峰, 伊跃军, 谭秀民, 等, 2021.硫酸熟化锂云母提取锂铷铯的机理及动力学特征[J].中南大学学报(自然科学版), 52(9): 3093-3102.
赵元艺, 韩景仪, 郭立鹤, 等, 2008.西藏搭格架热泉型铯矿床矿物学与矿石组构特征及地质意义[J].岩石学报, 24(3):519-530.
郑绵平, 王秋霞, 多吉, 等, 1995.水热成矿新类型-西藏铯硅矿床[M].北京: 地质出版社.
周潇, 赵元艺, 陈文西, 2024.青藏高原盐湖铷铯资源现状、富集规律与提取技术[J].地质论评, 70(2): 705-716.
朱军, 徐翌童, 郭梅, 等, 2022.锂云母复合盐焙烧-水浸提取锂铷铯[J].矿冶工程, 42(2): 80-84.
自然资源部, 2023.2022 年全国矿产资源储量统计表[R].北京:自然资源部: 1-24.
BAO Amin, QIAN Zhiqiang, ZHENG Hong, et al., 2017.Progress of separation and extraction methods for rare alkali metals rubidium and cesium[J].Applied Chemical Industry, 46(7):1377-1382(in Chinese with English abstract).
GAO Dandan, LI Dongdong, FAN Yanfei, et al., 2022.Economically utilization of the rubidium resources in Qarhan Salt Lake:From fundamental study to technology innovation[J].Journal of Salt Lake Research, 30(3): 1-11, 41(in Chinese with English abstract).
GAO Xinrui, JIA Hongxiang, LI Tianjiao, et al., 2023.Perspective of Rubidium and Caesium Resource Demand in China[J].Acta Geoscientica Sinica, 44(2): 279-285(in Chinese with English abstract).
GE Fei, LI Leiming, JIANG Yingying, et al., 2023.Analysis and comments on separation for rubidium and cesium from perspective of patents[J].Applied Chemical Industry, 52(2):639-645(in Chinese with English abstract).
GUO Chunping, ZHOU Jian, WEN Xiaoqiang, et al., 2015.Extraction of Lithium, Rubidium and Cesium from Lepidolite by Sulfate Process[J].Nonferrous Metals (Extractive Metallurgy), (12): 31-33(in Chinese with English abstract).
GUO Xiuhong, ZHENG Mianping, LIU Xifang, et al., 2008.Saline Cesium Resource and Prospect of its Exploitation and Utilization in Tibet[J].Journal of Salt and Chemical Industry, 37(3): 8-13(in Chinese with English abstract).
HU Fangyang, LIU Xiaochi, HE Shaoxiong, et al., 2023.Cesium-rubidium mineralization in Himalayan leucogranites[J].Science China Earth Sciences, 66(12): 2827-2852(in Chinese with English abstract).
JIAN Peng, ZHOU Yipeng, KE Pingchao, et al., 2024.Extraction of lithium and rubidium from rubidium-rich lithium mica ore by chlorination roasting-water leaching process[J].China Nonferrous Metallurgy, 53(2): 69-78(in Chinese with English abstract).
LI Jianshen, LI Tingwei, MA Yunlin, et al., 2022.Distribution and origin of brine-type Li-Rb mineralization in the Qaidam Basin, NW China[J].Science China Earth Sciences, 65(3):477-489(in Chinese with English abstract).
LI Qingkuan, WANG Jianping, FAN Qishun, et al., 2023.Rubidium and cesium enrichment in lacustrine sediments from Tibetan salt lakes: A potential resource[J].Acta Geologica Sinica, 97(10): 3410-3420(in Chinese with English abstract).
LI Ying, CHEN Xia, MIAO Shulan, et al., 2019.Study on adsorption properties of ammonium phosphate tungsten composites on rubidium and cesium[J].Inorganic Chemicals Industry, 51(6): 34-37(in Chinese with English abstract).
LIU Lei, MA Baozhong, WANG Chengyan, et al., 2022.Research progress in the application and extraction process of Rubidium[J].Nonferrous Metals Science and Engineering, 13(5):8-15(in Chinese with English abstract).
LIU Li, 2013.Development and consideration of rubidium and cesium[J].Xinjiang Nonferrous Metals, 36(S1): 158-165(in Chinese).
LIU Shiming, LIU Hehui, HUANG Yunjing, et al., 2015.Solvent extraction of rubidium and cesium from salt lake brine with t-BAMBP-kerosene solution[J].Transactions of Nonferrous Metals Society of China, 25(1): 329-334.
LU Zhi, 2011.Separation and Extraction of rubidium from deep brine of structure marine of Ping Luo Ba[D].Chengdu:Chengdu University of Technology(in Chinese with English abstract).
MAO Jingwen, YANG Zhongxi, XIE Giuqing, et al., 2019a.Critical minerals: International trends and thinking[J].Mineral Deposits, 38(4): 689-698(in Chinese with English abstract).
MAO Jingwen, YUAN Shunda, XIE Giuqing, et al., 2019b.New advances on metallogenic studies and exploration on critical minerals of China in 21st century[J].Mineral Deposits, 38(5):935-969(in Chinese with English abstract).
MEI Yanxiong, PEI Rongfu, WEI Ran, et al., 2022.Critical minerals and energy resources security[J].China Mining Magazine, 31(11): 1-8(in Chinese with English abstract).
Ministry of Natural Resources, 2023.National Mineral Reserves Statistical Table 2022[R].Beijing: Ministry of Natural Resources: 1-24(in Chinese).
PAN Tong, CHEN Jianzhou, DING Chengwang, et al., 2023.Supernormal enrichment of lithium, rubidium and cesium and its development potential in the clay of Salt Lake of Qaidam Basin[J].Geology in China, 50(6): 1925-1927(in Chinese with English abstract).
PANG Dengke, 2020.Extraction and separation technology of rubidium and cesium in the Brine of La Guocuo Salt Lake brine[D].Xining: Qinghai Institute of Salt Lake Chinese Academy of Sciences(in Chinese with English abstract).
SUN Yan, WANG Denghong, WANG Chenghui, et al., 2019.Metallogenic regularity, new prospecting and guide direction of rubidium deposits in China[J].Acta Geologica Sinica, 93(6): 1231-1244(in Chinese with English abstract).
USGS, 2024.Mineral Commodity Summaries January[R].Reston VA: U.S.Geological Survey.
WANG Chao, SUN Xiaohong, DING Xiaojiang, et al., 2023.Research on the enrichment regularity of rubidium and cesium in Qarhan[J].Acta Petrologica et Mineralogica, 42(5):701-710(in Chinese with English abstract).
WANG Chunlian, HUANG Hua, WANG Jiuyi, et al., 2018.Geological features and metallogenic model of K-and Li-rich brine ore field in the Jiangling Depression[J].Acta Geologica Sinica, 92(8): 1630-1646(in Chinese with English abstract).
WANG He, XU Yigan, YAN Qinghe, et al., 2021.Research progress On Bailongshan pegmatite type lithium deposit, Xinjiang[J].Acta Geologica Sinica, 95(10): 3085-3098(in Chinese with English abstract).
WANG Xuejing, GAO Shiyang, ZHOU Jianguo, et al., 2002.Study on the extraction and separation of K+, Rb+, Cs+ with natural clinoptilolite from geothermal water in Tibet[J].Journal of Salt Lake Research, 10(3): 31-37(in Chinese with English abstract).
WU Changzhi, JIA Li, LEI Ruxiong, et al., 2021.Advances and general characteristics of the amazonite granite and related rubidium deposits in Central Asian orogenic belt[J].Acta Petrologica Sinica, 37(9): 2604-2628(in Chinese with English abstract).
WU Jianjiang, 2023.Research progress of rubidium cesium separation and purification technology in China[J].Xinjiang Nonferrous Metals, 46(4): 23-24(in Chinese).
XIE Shaolei, SHI Dong, ZHANG Yuze, et al., 2023.Research Status of Separation and Extraction of Rubidium and Cesium by Inorganic Adsorbents[J].Chinese Journal of Rare Metals, 47(7): 1020-1042(in Chinese with English abstract).
YE Xiushen, 2009.Analysis and Adsorption Separation of Rubidi-um and Cesium in Chloride Type Brine[D].Xining:Qinghai Institute of Salt Lake Chinese Academy of Sciences(in Chinese with English abstract).
ZHANG Shenghui, WANG Zhentao, LI Yongsheng, et al., 2022.List, application and global pattern of critical minerals of China[J].Conservation and Utilization of Mineral Resources, 42(5): 138-168(in Chinese with English abstract).
ZHANG Xiaowei, XIN Tianyu, LIU Jiaxing, et al., 2021.Analysis on the current situation of global cesium resources and its comprehensive utilization technology[J].Conservation and Utilization of Mineral Resources, 41(5): 7-11(in Chinese with English abstract).
ZHANG Xiufeng, TAN Xiumin, LI Chun, et al., 2019.Energyefficient and simultaneous extraction of lithium, rubidium and cesium from lepidolite concentrate via sulfuric acid baking and water cheek tor leaching[J].Hydrometallurgy, 185:244-249.
ZHANG Xiufeng, YI Yuejun, TAN Xiumin, et al., 2021.Mechanism and kinetics characteristics of sulfuric acid baking process for extracting lithium, rubidium and cesium from lepidolite[J].Journal of Central South University (Science and Technology), 52(9): 3093-3102(in Chinese with English abstract).
ZHAO Yuanyi, HAN Jingyi, GUO Lihe, et al., 2008.Characteristics and geological significance of mineralogy and fabrics for the hot spring cesium deposit occurring within the Targejia district, Tibet[J].Acta Petrologica Sinica, 24(3): 519-530(in Chinese with English abstract).
ZHENG Mianping, WANG Qiuxia, DUO Ji, et al., 1995.A New Type of Hydrothermal Deposit: Cesium-bearing Geyserite in Tibet[M].Beijing: Geologica Publishing House(in Chinese).
ZHOU Xiao, ZHAO Yuanyi, CHEN Wenxi, 2024.Rubidium and cesium resources current status, enrichment pattern and extraction technology in salt lakes of Qinghai-Xizang(Tibet)Plateau, China[J].Geological Review, 70(2): 705-716(in Chinese with English abstract).
ZHU Jun, XU Yitong, GUO Mei, et al., 2022.Extraction of Lithium, Rubidium and Cesium from Lepidolite Using Composite Salt Roasting and Aqueous Leach Process[J].Mining and metallurgical engineering, 42(2): 80-84(in Chinese with English abstract).
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