Comprehensive Utilization and Development Strategy of Perlite Mineral Resources in China
-
摘要:
珍珠岩是无定形硅酸铝火山玻璃,主要成分为SiO2和Al2O3,因其含有结晶水而具有高膨胀性,主要用于制备膨胀珍珠岩,其应用领域广泛。本文介绍了珍珠岩的结构性质、资源现状及其在战略新兴产业领域的应用,总结了国内外珍珠岩行业发展差距,并展望了我国珍珠岩行业发展战略。
Abstract:Perlite is volcanic glass of amorphous aluminum silicate, mainly composed SiO2 and Al2O3, and has high expansibility due to its inclusion of crystalline water. Perlite is mainly used to prepare expanded perlite with a wide application field. The structural properties, resources status and application in strategic emerging industry of perlite were introduced, and the development gap of perlite industry at home and abroad was summarized. The development strategy of perlite industry in China was forecasted.
-
Key words:
- perlite /
- expanded perlite /
- comprehensive utilization
-
-
表 1 我国珍珠岩资源分布
Table 1. Distribution of perlite resource in China
省区 地点 河南 上天梯、罗山、浉河区(游河) 湖北 鄂州沼山乡 浙江 缙云、天台九里坪、宁海(松脂岩)、牛台、白水洋、金华、鄞县 安徽 宣州 山西 灵丘、库源、阳文 内蒙古 赤峰、固阳、多伦、太仆寺旗、正兰旗、中后旗、呼和浩特市榆林乡 吉林 九台 黑龙江 穆林木兰、嫩江县门鲁河 山东 潍坊、涌泉庄、莱西 江西 广丰、抚州市金溪县 河北 宽城、平泉以及张家口,围场,沽源 辽宁 凌源井杖子、建平金沟一双庙、法库、建平、锦州、锦西尖山子、义县、黑山 江苏 溧阳 福建 香炉山、霞浦、 广东 紫金、梅县、丰顺、和平(黑曜岩)、平远 广西 梧州 新疆 牙克石 表 2 信阳上天梯珍珠岩原矿化学组成
Table 2. Chemical composition of perlite mineral in Xinyang Shangtianti
Composition SiO2 Al2O3 K2O Na2O Fe2O3 CaO MgO MnO P2O5 TiO2 LOI Content/% 72.93 12.31 4.67 3.29 0.54 1.00 0.14 0.06 0.04 0.09 4.93 -
[1] 张富新, 谢海泉.珍珠岩尾砂资源化利用的技术条件分析[J].矿产综合利用, 2004(3):31-33. http://d.old.wanfangdata.com.cn/Periodical/kczhly200403008
[2] 李博威.珍珠岩的深加工技术方法及应用[J].矿产综合利用, 1992(2):33-40. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=QK000001939908
[3] 严育通, 贾宝剑, 周红升, 等.珍珠岩矿床地质背景研究进展[J].信阳师范学院学报, 2016, 29(4):645-649. http://d.old.wanfangdata.com.cn/Periodical/xysfxyxb-zrkx201604036
[4] 张宪圆, 林克辉, 谢红波.国内外珍珠岩概述及其在建筑领域的应用分析[J].广东建材, 2012(2):19-21. http://d.old.wanfangdata.com.cn/Periodical/gdjc201202022
[5] 耿谦.珍珠岩成矿及在陶瓷中的应用与成瓷机理[J].陶瓷, 2004(3):28-29, 47. http://d.old.wanfangdata.com.cn/Periodical/tc200403007
[6] 夏振洲.用珍珠岩水泥砂浆解救某"烂尾楼"工程[J].建筑工人, 2006(1):39. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=jzgr200601030
[7] 喻乐华, 段庆普.珍珠岩掺合料水泥浆体的微孔结构[J].硅酸盐学报, 2006, 34(7):894-898. http://d.old.wanfangdata.com.cn/Periodical/gsyxb200607028
[8] 喻乐华.混凝土集料界面与强度关系的界面理论分析[J].华东交通大学学报, 1999(4):14-19. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=hdjtdxxb199904004
[9] 赵韧.掺珍珠岩水泥水化机理研究与膨胀珍珠岩对水泥基材料的增强效应讨论[D].南京: 南京大学, 2004.
http://www.wanfangdata.com.cn/details/detail.do?_type=degree&id=Y802711 [10] 蒋元海, 许志云.预处理珍珠岩废料在水泥中的应用[J].矿产综合利用, 1994(2):40-43. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=QK199400668133
[11] 徐峰, 祁根德.珍珠岩尾砂在水泥和混凝土中的应用研究[J].混凝土, 1992(l):51-55. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=QK000001414728
[12] 佟继先.新型膨胀珍珠岩外墙外保温系统的应用与探讨[J].中国建材, 2005(12):38-40. http://d.old.wanfangdata.com.cn/Periodical/zgjc200512015
[13] 张家兵, 蔡维全.信阳市珍珠岩制品在建筑节能领域的应用现状与前景[J].建筑节能, 2010(3):39-41. http://www.cnki.com.cn/Article/CJFDTotal-QCGJ201003039.htm
[14] Tian Y S, Tang Y T, Li S Y, et al. Voigt-based swelling water model for super water absorbency of expanded perlite and sodium polyacrylate resin composite materials[J]. E-Polymers, 2019, 19(1):365-368. http://cn.bing.com/academic/profile?id=7cb4271a68169c3c25d3ca98af43c847&encoded=0&v=paper_preview&mkt=zh-cn
[15] 赵鹏.有机羧酸/多孔基体复合储能相变材料的制备与性能研究[D].西安: 西安建筑科技大学, 2008.
[16] 于永生.珍珠岩复合相变储能材料制备与应用研究[D].信阳: 信阳师范学院, 2011.
http://cdmd.cnki.com.cn/article/cdmd-10477-1011150608.htm [17] 许淘淘.基于膨胀珍珠岩相变建筑调温材料的制备及其传热特性研究[D].徐州: 中国矿业大学, 2019.
http://cdmd.cnki.com.cn/Article/CDMD-10290-1019855114.htm [18] LiuC Z, Luo C Y, Xu T T, et al. Experimental study on the thermal performance of capric acid-myristyl alcohol/expanded perlite composite phase change materials for thermal energy storage[J]. Solar Energy, 2019, 191:585-595. http://cn.bing.com/academic/profile?id=08d6cf0f66f979b0cac46db7cee9870c&encoded=0&v=paper_preview&mkt=zh-cn
[19] 王亮.气凝胶膨胀珍珠岩保温材料的研究及其建筑能耗分析[D].太原: 太原理工大学, 2019.
http://cdmd.cnki.com.cn/Article/CDMD-10112-1019871212.htm [20] 陈伟鹏, 郝万军, 何楠, 等.4G基站辐射防护板材设计及其电磁污染控制特性[J].材料科学与工程学报, 2019, 37(4):595-598. http://d.old.wanfangdata.com.cn/Periodical/clkxygc201904014
[21] Sari A, Sahinoglu G, Tuzen M. Antimony(Ⅲ) adsorption from aqueous solution using raw perlite and Mn-modified perlite:Equilibrium, thermodynamic, and kinetic studies[J]. Industrial & Engineering Chemistry Research, 2012, 51(19):6877-6886. https://pubs.acs.org/doi/10.1021/ie300243n
[22] Alihosseini A, Taghikhani V, Safekordi A A, et al. Equilibrium sorption of crude oil by expanded perlite using different adsorption isotherms at 298.15 K[J]. International Journal of Environmental Science and Technology, 2010, 7(3):591-598. http://d.old.wanfangdata.com.cn/OAPaper/oai_doaj-articles_a3dfca65d06431efa16096c5006cc707
[23] 林娜.膨胀珍珠岩的改性及应急处置溢油污染技术研究[D].哈尔滨: 哈尔滨工业大学, 2013.
http://cdmd.cnki.com.cn/Article/CDMD-10213-1014080695.htm [24] 徐春宏, 郑水林, 张广心, 等.均匀沉淀法制备纳米TiO2/膨胀珍珠岩复合材料[J].人工晶体学报, 2014, 43(8):1991-1997. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=rgjtxb98201408020
[25] Habibi M H, Zendehdel M. Synthesis and characterization of titaniananoparticles on the surface of microporous perlite using sol-gel method:Influence of titania precursor on characteristics[J]. Journal of Inorganic and Organometallic Polymers and Materials, 2011, 21(3):634-639. https://link.springer.com/10.1007/s10904-011-9500-z
[26] 方林霞, 张晓燕.膨胀珍珠岩负载Fe、Tb共掺杂TiO2光催化剂的制备及光催化性能研究[J].化工新型材料, 2015, 43(8):128-130. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=hgxxcl201508042
[27] Kasai M, Kobayashi Y, Togo M, et al. Synthesis of zeolite-surface-modified perlite and their heavy metal adsorption capability[J]. Materials Today:Proceedings, 2019, 16:232-238. http://cn.bing.com/academic/profile?id=59d4e1c3a928d8e6c6806b7a5d495a11&encoded=0&v=paper_preview&mkt=zh-cn
[28] 薛红波, 吴继阳, 刘姝彤, 等.Fe3+/TiO2负载膨胀珍珠岩降解水和土壤中苯酚的研究[J].环境工程, 2016(7):71-75, 81. http://www.cnki.com.cn/Article/CJFDTotal-HJGC201607017.htm
[29] Cámara-ZapataJ M, Brotons-MartínezJ M, Simón-GraoS, et al. Cost-benefit analysis of tomato in soilless culture systems with saline water under greenhouse conditions[J]. Journal of the Science of Food and Agriculture, 2019, 99(13):5842-5851. http://cn.bing.com/academic/profile?id=7ce07370284aa8d0047bad355492b163&encoded=0&v=paper_preview&mkt=zh-cn
[30] Mahkam M, Vakhshouri L. Colon-specific drug delivery behavior of pH-responsive PMAA/perlite composite[J]. International Journal of Molecular Sciences, 2010, 11:1546-1556. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=MDPI000000110734
[31] Erli H J, Ruger M, Ragoss C, et al. The effect of surface modification of a porous TiO2/perlite composite on the ingrowth of bone tissue in vivo[J]. Biomaterials, 2006, 27(8):1270-1276. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=95f03f5f6a76d686808acc5582a2d757
[32] 唐宗明.膨胀珍珠岩复合材料在矿井热害治理中的应用[J].煤炭技术, 2016, 35(10):214-216. http://d.old.wanfangdata.com.cn/Periodical/mtjs201610084
[33] 张伟, 王志刚, 余建.膨胀珍珠岩复合漂珠低密度水泥浆体系的应用研究[J].石油化工应用, 2019, 38(5):88-91. http://d.old.wanfangdata.com.cn/Periodical/syhgyy201905017
[34] Brindha K, Amutha P, Krishnakumar B, et al. BiCl3-modified perlite as an effective catalyst for selective organic transformations:a green protocol[J]. Research on Chemical Intermediates, 2019, 45(9):4367-4381. http://link.springer.com/article/10.1007/s11164-019-03836-x
[35] Oliveira A G, Jr C J, Rocha E B D, et al. Evaluation of expanded perlite behavior in PS/perlite composites[J]. Applied Clay Science, 2019, 181:105-223. http://cn.bing.com/academic/profile?id=3476e6034b6f34e615d5fb85c4322c53&encoded=0&v=paper_preview&mkt=zh-cn
[36] 刘新海, 沈上越, 李一波.珍珠岩尾矿综合利用深加工及其产业化[J].非金属矿, 2003(6):26-27. http://d.old.wanfangdata.com.cn/Periodical/fjsk200306011
[37] Yu Y S, HaoX F, Song L X, et al. Synthesis and characterization of single phase and low temperature co-fired cordierite glass-ceramics from perlite[J]. Journal of Non-Crystalline Solids, 2016, 448:36-42. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=748cd5b95341c42b33933faed89de3a4
[38] 王怀宇.珍珠岩生产消费与国际贸易[J].中国非金属矿工业导刊, 2011(2):58-59. http://d.old.wanfangdata.com.cn/Periodical/zgfjskgydk201102018
-