Genesis of Wuduoshan I-S type granite and the constraints on the Early Paleozoic tectonic evolution of the Northern Qinling: Evidence from zircon U-Pb age, geochemistry and Sr-Nd-Hf isotopes
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摘要:
秦岭造山带地处华北板块与扬子板块结合带,经历了复杂的构造演化过程,其板块拼合机制及碰撞时限一直备受争议。通过对北秦岭五朵山黑云母二长花岗岩进行年代学、地球化学和Sr-Nd-Hf同位素组成研究,以期对北秦岭早古生代构造演化进行约束。五朵山岩体至少存在2期侵入,分别为431 Ma和417 Ma。岩石具有高硅(SiO2=71.16%~74.22%),富碱富钾(K2O+Na2O=7.16%~8.88%,K2O/Na2O=0.69~2.34),过铝质(A/CNK=1.01~1.19))等特征。岩石稀土元素总量总体偏低,轻、重稀土元素分异较强,呈右倾配分模式,具轻微的负Eu异常。富集大离子亲石元素Rb、Th、U,亏损高场强元素(Nb、Ta、Zr)及Ba、Sr,在岩石类型上属于I-S过渡型花岗岩类。五朵山花岗岩具有相对低的(87Sr/86Sr)i值(0.70581~0.71093),εNd(t)值为-6.48~-3.18,对应的Nd的二阶段模式年龄为1.42~1.69 Ga; 绝大多数测点具负的εHf(t)值(-6.9~-0.1),tDM2=1.50~2.34 Ga。同位素特征指示这些花岗岩为古—中元古代地壳物质部分熔融的产物。五朵山花岗岩的形成与二郎坪岛弧与北秦岭微陆块碰撞作用关系密切,属同碰撞-后碰撞型花岗岩,岩浆源区为北秦岭微陆块古老的地壳物质。
Abstract:The Qinling orogenic belt, located at the junction zone of the North China plate and the Yangtze plate, has experienced a complex tectonic evolution process, and the mechanism of plate assembly and the collisional time are controversial.In this paper, the geochronology, geochemistry and Sr-Nd-Hf isotopic composition of the Wuduoshan biotite monzogranite in North Qinling studied to constrain the early Paleozoic tectonic evolution of the North Qinling.Two periods of intrusion were identified in Wudaoshan batholith, which is dating 431 Ma and 417 Ma respectively.The rocks are characterized by high silicon(SiO2 =71.16%~74.22%), alkali and potassium rich(K2O + Na2O =7.16%~8.88%, K2O / Na2O =0.69~2.34)and peraluminous(A / CNK =1.01~1.19).The total REE content is generally low, and LREE and HREE are strongly fractionated, showing a right dipping distribution pattern and slight negative Eu anomalies.They are characterized by enrichment in large ion lithophile elements(Rb, Th, U), relative depletion in high field strength elements(Nb, Ta, Zr)and Ba and Sr.They belong to "I-S" type granitoids.The Wuduoshan granite has relatively low(87Sr/ 86Sr)i values(0.70581~0.71093), and negative εNd(t)values(-6.48 to-3.18), with the corresponding two-stage Nd model age of 1.42 Ga ~1.69 Ga.Most of zircons have negative εHf(t)values(εHf(t)=-6.9~ -0.1), and tDM2 =1.50~2.34 Ga.The isotopic characteristics indicate that the Wuduoshan granite is the product of partial melting of Paleoproterozoic-Mesoproterozoic crustal material.Combined with the tectonic evolution of Qinling orogenic belt, we concluded that the formation of Wuduoshan granite was related to the collision between Erlangping island arc and North Qinling micro-continent and belongs to syn-collisional and post-conllisional type granite, and the magma source is the ancient crustal material of North Qinling micro-continent.
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图 1 东秦岭造山带构造简图及花岗岩分布(a) [13]和五朵山岩体地质简图(b)
Figure 1.
表 1 五朵山岩体锆石LA-ICP-MS U-Pb同位素分析结果
Table 1. Zircon LA-ICP-MS U-Pb dating results of Wuduoshan granite
测定点号 含量/10-6 同位素比值 年龄/Ma Pb U 207Pb/206Pb 1σ 207Pb/235U 1σ 206Pb/238U 1σ 207Pb/206Pb 1σ 207Pb/235U 1σ 206Pb/238U 1σ N1D603(中细粒黑云母二长花岗岩) 1 171 2426 0.0565 0.0008 0.5398 0.0077 0.0693 0.0007 473 31 438 6 432 4 2 116 1532 0.0564 0.0007 0.5446 0.0073 0.0701 0.0007 467 29 441 6 437 4 3 159 1941 0.0556 0.0009 0.5387 0.0097 0.0703 0.0007 436 37 438 8 438 4 4 153 2278 0.0576 0.0007 0.5507 0.0074 0.0694 0.0007 514 28 445 6 432 4 5 89 905 0.0781 0.0011 1.0146 0.0162 0.0942 0.0010 1150 27 711 11 580 6 6 124 1649 0.0571 0.0007 0.5519 0.0071 0.0701 0.0007 494 28 446 6 437 4 7 80 1087 0.0575 0.0008 0.5443 0.0074 0.0687 0.0007 510 30 441 6 428 4 8 111 1498 0.0580 0.0009 0.5530 0.0083 0.0691 0.0007 530 32 447 7 431 4 9 172 2431 0.0569 0.0008 0.5431 0.0075 0.0692 0.0007 488 29 440 6 431 4 10 50 694 0.0554 0.0008 0.5283 0.0085 0.0692 0.0007 428 33 431 7 431 4 11 78 928 0.0941 0.0015 0.9639 0.0163 0.0743 0.0007 1510 31 685 12 462 5 12 73 1165 0.0828 0.0013 0.6818 0.0106 0.0597 0.0006 1266 31 528 8 374 4 13 85 1173 0.0566 0.0010 0.5474 0.0102 0.0702 0.0007 475 39 443 8 437 4 14 144 1610 0.1046 0.0020 1.1471 0.0233 0.0795 0.0008 1707 35 776 16 493 5 15 77 1073 0.0559 0.0011 0.5368 0.0104 0.0696 0.0007 448 43 436 8 434 4 16 53 535 0.1169 0.0031 1.3274 0.0395 0.0824 0.0009 1909 47 858 26 510 5 N6D618(中粒黑云母二长花岗岩) 1 30 409 0.0558 0.0009 0.5114 0.0081 0.0665 0.0006 443 34 419 7 415 4 2 112 1693 0.0571 0.0007 0.5204 0.0069 0.0661 0.0006 496 29 425 6 413 4 3 78 1199 0.0562 0.0007 0.5166 0.0071 0.0667 0.0006 459 30 423 6 416 4 4 102 1477 0.0569 0.0008 0.5205 0.0071 0.0663 0.0006 489 30 426 6 414 4 5 193 2858 0.0567 0.0007 0.5192 0.0068 0.0664 0.0006 479 28 425 6 415 4 6 132 2087 0.0560 0.0007 0.5080 0.0068 0.0658 0.0006 451 29 417 6 411 4 7 142 2293 0.0555 0.0007 0.5015 0.0067 0.0655 0.0006 434 29 413 6 409 4 8 98 1314 0.0567 0.0008 0.5192 0.0075 0.0664 0.0007 481 31 425 6 414 4 9 257 3890 0.0554 0.0007 0.5124 0.0069 0.0671 0.0006 429 29 420 6 418 4 10 315 4906 0.0568 0.0007 0.5260 0.0070 0.0672 0.0007 482 29 429 6 419 4 11 165 5692 0.0488 0.0006 0.1970 0.0028 0.0293 0.0003 139 31 183 3 186 2 12 111 1466 0.0560 0.0007 0.5126 0.0069 0.0663 0.0006 454 29 420 6 414 4 13 70 983 0.0546 0.0009 0.5105 0.0087 0.0678 0.0007 395 37 419 7 423 4 14 231 3299 0.0555 0.0007 0.5186 0.0069 0.0677 0.0007 433 29 424 6 423 4 15 312 4906 0.0572 0.0007 0.5239 0.0069 0.0665 0.0006 498 28 428 6 415 4 16 244 3898 0.0561 0.0007 0.5078 0.0068 0.0657 0.0006 457 28 417 6 410 4 17 131 1785 0.0542 0.0007 0.5071 0.0069 0.0679 0.0007 377 30 416 6 424 4 18 51 688 0.0546 0.0009 0.5149 0.0097 0.0684 0.0007 394 38 422 8 427 4 19 31 394 0.0552 0.0012 0.5162 0.0113 0.0679 0.0007 419 47 423 9 423 4 20 41 565 0.0557 0.0010 0.5164 0.0106 0.0672 0.0007 441 42 423 9 419 4 21 64 806 0.0574 0.0008 0.5820 0.0085 0.0735 0.0007 508 30 466 7 457 4 22 168 2638 0.0586 0.0007 0.5388 0.0069 0.0667 0.0006 551 28 438 6 416 4 23 189 2655 0.0561 0.0007 0.5191 0.0067 0.0671 0.0007 456 28 425 5 419 4 24 132 2028 0.0577 0.0008 0.5379 0.0072 0.0676 0.0006 518 29 437 6 422 4 25 47 656 0.0550 0.0010 0.5135 0.0099 0.0677 0.0007 413 42 421 8 422 4 26 103 1409 0.0552 0.0009 0.5211 0.0095 0.0685 0.0007 419 37 426 8 427 4 27 280 3693 0.0587 0.0008 0.5414 0.0076 0.0669 0.0006 555 30 439 6 418 4 28 293 4266 0.0593 0.0009 0.5393 0.0082 0.0660 0.0006 577 32 438 7 412 4 29 85 1248 0.0543 0.0009 0.5178 0.0092 0.0691 0.0007 385 39 424 8 431 4 表 2 五朵山黑云母花岗岩主量、微量和稀土元素分析结果
Table 2. Major, trace and rare earth elements compositions for Wuduoshan biotite granite
送样号 Sr1/N1 XWG302/27-1 Sr1/N5 Sr2/N5 Sr3/N5 Sr1/N6 Sr2/N6 岩性区分 中细粒 中细粒 中粒 中粒 中粒 中粒 中粒 SiO2 71.55 72.11 74.22 72.52 71.62 72.56 71.16 TiO2 0.31 0.26 0.29 0.24 0.29 0.27 0.41 Al2O3 15.05 14.86 13.9 14.2 14.43 14.24 14.46 FeO 1.11 1.2 0.23 0.25 0.25 1.04 0.98 Fe2O3 0.69 0.46 0.71 1.52 1.67 0.72 1.28 MnO 0.038 0.04 0.012 0.027 0.029 0.032 0.038 MgO 0.61 0.62 0.19 0.45 0.46 0.44 0.63 CaO 2.29 1.95 0.32 1.28 1.34 1.79 1.69 Na2O 4.23 3.94 2.66 3.21 3.19 3.26 3.16 K2O 2.93 3.47 6.22 4.83 5.15 5.07 5.02 P2O5 0.093 0.08 0.05 0.073 0.092 0.075 0.12 烧失量 0.99 0.97 1.16 1.36 1.46 0.72 0.95 Rb 154 176.6 298 200 192 170 175 Ba 419 501 402 924 2170 1160 1900 Th 18.2 15.11 69.4 46.6 23.7 34.4 47.5 U 2.24 3.6 3.3 1.37 1.11 3.2 2.56 Nb 9.1 13.06 21 14.1 6.41 10.2 10.9 Ta 1.66 2.31 1.38 1.07 0.26 0.76 0.63 La 25.8 22.62 85.5 37.4 54.8 52.4 91.6 Ce 46.7 41.45 147 58.7 75.5 90.6 155 Pr 4.91 4.8 17.8 7.35 9.93 10.1 17.7 Sr 179 196 85.6 171 300 206 289 Nd 17.5 16.84 58.8 26.2 33 34.6 56.6 Zr 139 101.2 220 187 207 186 273 Hf 4.37 3.8 7.77 6.39 5.55 5.88 8.08 Sm 3.26 3.35 8.86 4.29 4.79 5.81 8.28 Eu 0.72 0.72 0.56 1.04 1.87 1.36 1.9 Gd 2.78 2.97 7.16 3.4 4.03 4.66 7.06 Tb 0.42 0.47 0.75 0.4 0.4 0.5 0.7 Dy 2.02 2.55 3.08 1.61 1.55 2.09 2.91 Y 9.7 11.61 13 8.25 7.63 9.34 12.7 Ho 0.33 0.43 0.52 0.29 0.27 0.35 0.48 Er 0.95 1.11 1.35 1 0.7 1.06 1.3 Tm 0.12 0.16 0.17 0.15 0.1 0.14 0.19 Yb 0.78 1 1.01 1.11 0.72 0.88 1.2 Lu 0.12 0.14 0.15 0.19 0.13 0.14 0.19 A/CNK 1.05 1.08 1.19 1.11 1.09 1.01 1.06 ΣREE 106.41 98.59 332.71 143.13 187.79 204.69 345.11 LREE 98.89 89.76 318.52 134.98 179.89 194.87 331.08 HREE 7.52 8.83 14.19 8.15 7.9 9.82 14.03 LREE/HREE 13.15 10.17 22.45 16.56 22.77 19.84 23.6 LaN/YbN 23.73 16.21 60.72 24.17 54.59 42.71 54.75 δEu 0.73 0.69 0.21 0.83 1.3 0.8 0.76 δCe 1.02 0.98 0.92 0.87 0.79 0.97 0.94 注:主量元素含量单位为%,微量和稀土元素含量单位为10-6 表 3 五朵山花岗岩全岩Sr-Nd同位素数据
Table 3. Sr-Nd isotopic data of the Wuduoshan granite
样品号 Rb/10-6 Sr/10-6 87Rb/86Sr 87Sr/86Sr (87Sr/86Sr)i Sm/10-6 Sr1/N1 154 179 2.4932 0.72389 0.70908 3.26 Sr1/N5 298 85.6 10.13515 0.77112 0.71093 8.86 Sr2/N5 200 171 3.39008 0.72594 0.70581 4.29 Sr3/N5 192 300 1.85343 0.71697 0.70596 4.79 Sr1/N6 170 206 2.39107 0.72205 0.70785 5.81 Sr2/N6 175 289 1.75358 0.71677 0.70635 8.28 样品号 Nd/10-6 147Sm/144Nd 143Nd/144Nd εNd(t) tDM1/Ga tDM2/Ga Sr1/N1 17.5 0.10469 0.51216 -4.37 1.38 1.52 Sr1/N5 58.8 0.10469 0.51206 -6.48 1.53 1.69 Sr2/N5 26.2 0.10469 0.51217 -4.19 1.37 1.5 Sr3/N5 33 0.10469 0.51222 -3.18 1.3 1.42 Sr1/N6 34.6 0.10469 0.51216 -4.53 1.39 1.53 Sr2/N6 56.6 0.10469 0.51217 -4.27 1.37 1.51 表 4 五朵山花岗岩锆石原位Hf同位素数据
Table 4. In-situ Hf isotopic data for zircons of the Wuduoshan granite
样品 年龄/Ma 176Yb/177Hf 176Lu/177Hf 176Hf/177Hf 2s εHf(t) fLu/Hf TDM /Ma TDMC /Ma N1D603(中细粒黑云母二长花岗岩) 603-1 433 0.0259 0.0009 0.282522 0.000017 0.4 -0.97 1032 1788 603-2 433 0.0310 0.0008 0.282410 0.000019 -3.5 -0.98 1185 2140 603-3 433 0.0334 0.0010 0.282558 0.000020 1.7 -0.97 984 1676 603-4 433 0.0236 0.0006 0.282413 0.000019 -3.4 -0.98 1175 2126 603-5 433 0.0175 0.0005 0.282451 0.000018 -2.0 -0.99 1117 2002 603-6 433 0.0225 0.0007 0.282483 0.000015 -0.9 -0.98 1079 1906 603-7 433 0.0293 0.0008 0.282507 0.000019 -0.1 -0.98 1048 1832 603-8 433 0.0189 0.0005 0.282430 0.000019 -2.7 -0.99 1147 2069 603-9 433 0.0326 0.0010 0.282537 0.000013 0.9 -0.97 1012 1742 603-10 433 0.0164 0.0004 0.282387 0.000020 -4.2 -0.99 1205 2205 603-11 433 0.0265 0.0008 0.282538 0.000016 1.0 -0.98 1006 1735 603-12 433 0.0262 0.0007 0.282446 0.000018 -2.2 -0.98 1132 2024 603-13 433 0.0448 0.0012 0.282477 0.000020 -1.3 -0.96 1104 1940 603-14 433 0.0228 0.0007 0.282610 0.000015 3.6 -0.98 903 1504 603-15 433 0.0292 0.0008 0.282453 0.000019 -2.0 -0.98 1123 2002 603-16 433 0.0221 0.0006 0.282388 0.000018 -4.2 -0.98 1208 2204 603-17 433 0.0171 0.0006 0.282568 0.000016 2.1 -0.98 958 1634 N6D618(中粒黑云母二长花岗岩) 618-1 417 0.0175 0.0005 0.282356 0.000016 -5.7 -0.99 1250 2328 618-2 417 0.0168 0.0005 0.282499 0.000017 -0.6 -0.98 1053 1872 618-3 417 0.0109 0.0003 0.282423 0.000017 -3.3 -0.99 1152 2109 618-4 417 0.0191 0.0005 0.282379 0.000015 -4.9 -0.99 1218 2252 618-5 417 0.0336 0.0009 0.282430 0.000017 -3.2 -0.97 1159 2099 618-6 417 0.0141 0.0004 0.282376 0.000021 -5.0 -0.99 1220 2260 618-7 417 0.0141 0.0003 0.282491 0.000016 -0.9 -0.99 1059 1894 618-8 417 0.0262 0.0007 0.282363 0.000019 -5.5 -0.98 1246 2307 618-10 417 0.0209 0.0006 0.282457 0.000016 -2.1 -0.98 1111 2005 618-11 417 0.0237 0.0006 0.282465 0.000016 -1.9 -0.98 1104 1984 618-12 417 0.0313 0.0008 0.282416 0.000019 -3.6 -0.98 1177 2142 618-13 417 0.0285 0.0008 0.282373 0.000018 -5.2 -0.98 1235 2278 618-14 417 0.0486 0.0014 0.282605 0.000021 2.9 -0.96 926 1555 618-15 417 0.0310 0.0008 0.282532 0.000016 0.5 -0.98 1014 1774 618-16 417 0.0294 0.0008 0.282480 0.000018 -1.4 -0.98 1088 1940 618-17 417 0.0257 0.0007 0.282441 0.000019 -2.7 -0.98 1137 2059 618-18 417 0.0207 0.0006 0.282462 0.000022 -2.0 -0.98 1106 1991 618-19 417 0.0154 0.0004 0.282520 0.000018 0.1 -0.99 1022 1804 618-20 417 0.0110 0.0003 0.282350 0.000017 -5.8 -0.99 1251 2337 -
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