Research Progress and Development Suggestion on Resource Utilization of Titanium Gypsum
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摘要:
这是一篇冶金工程领域的论文。钛石膏是采用硫酸法生产钛白粉时产生的以二水硫酸钙为主要成分的工业废渣。钛石膏因其杂质含量高、脱水困难、后续产品力学性能差等因素目前资源化利用率较低。大量露天堆存的钛石膏给钛白粉企业造成了极大的环保与经济压力,也是对土地资源的严重浪费。本文总结了目前国内外钛石膏在建材、化工、农业及应对气候变化等方面的利用现状和研究进展,并从产品结构调整、技术革新与绿色发展、标准制定与政策扶持等方面对钛石膏的有效减量及高质量资源化提出了建议与展望。
Abstract:This is an article in the field of metallurgical engineering. Titanium gypsum is an industrial waste residue mainly composed of calcium sulfate dehydrate when the titanium dioxide is produced by the sulfuric acid method. At present, the utilization rate of titanium gypsum is relatively low due to its high impurity content , difficulty in dehydration and poor mechanical properties of the subsequent products. A large amount of titanium gypsum stored in the open air has caused great environmental and economic stress on the titanium dioxide enterprises, which is a serious waste of land resources. In this article, the current situation and research progress of global titanium gypsum in building materials, chemical industry, agriculture and climate change were summarized. The suggestions and prospects for the effective reduction and high-quality resource utilization of titanium gypsum from the aspects of structure adjustment, technological innovation, green development, standard formulation and policy support were provided.
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表 1 德阳和攀枝花地区化工厂的钛石膏化学成分/%
Table 1. Chemical composition of titanium gypsum in chemical factories of Deyang and Panzhihua
原料名称 CaO SO3 Fe2O3 TiO2 SiO2 MgO Al2O3 V2O5 德阳某化工厂压滤新鲜钛石膏 30.95 40.50 17.22 1.65 1.60 1.09 0.59 0.04 德阳某化工厂堆场堆存钛石膏 31.15 36.69 11.18 1.02 3.98 2.60 1.45 0.03 攀枝花某化工厂压滤新鲜钛石膏 30.21 38.96 12.55 3.12 1.89 2.28 0.85 0.05 攀枝花某化工厂堆场堆存钛石膏 29.23 35.92 10.59 2.79 2.96 2.56 1.09 0.05 -
[1] 许惠, 傅敏. 钛白废液的治理与综合利用研究进展[J]. 矿产综合利用, 2006(4):34-7.XU H, FU M. Research progress in comprehensive utilization of spent acid and waste water in titanium dioxide production[J]. Multipurpose Utilization of Mineral Resources, 2006(4):34-7. doi: 10.3969/j.issn.1000-6532.2006.04.010
XU H, FU M. Research progress in comprehensive utilization of spent acid and waste water in titanium dioxide production[J]. Multipurpose Utilization of Mineral Resources, 2006(4):34-7. doi: 10.3969/j.issn.1000-6532.2006.04.010
[2] QCA B, WDA B, HSA B, et al. Synthesis of anhydrite from red gypsum and acidic wastewater treatment [J]. Journal of Cleaner Production, 2020, 278.
[3] 靳必强, 张婷婷, 朱静平, 等. 钛石膏的开发利用研究进展[J]. 矿产综合利用, 2020(3):28-32.JIN B Q, ZHANG T T, ZHU J P, et al. The development and research progress of titanium gypsum exploitation and utilization[J]. Multipurpose Utilization of Mineral Resources, 2020(3):28-32. doi: 10.3969/j.issn.1000-6532.2020.03.005
JIN B Q, ZHANG T T, ZHU J P, et al. The development and research progress of titanium gypsum exploitation and utilization[J]. Multipurpose Utilization of Mineral Resources, 2020(3):28-32. doi: 10.3969/j.issn.1000-6532.2020.03.005
[4] 魏长河, 孙玉壮, 高兴保, 等. 钛石膏中重金属元素的浸出特性研究[J]. 环境工程, 2015, 33(5):131-5.WEI C H, SUN Y Z, GAO X B, et al. Study on leaching characteristics of heavy metals in titanium gypsum[J]. Environmental Engineering, 2015, 33(5):131-5.
WEI C H, SUN Y Z, GAO X B, et al. Study on leaching characteristics of heavy metals in titanium gypsum[J]. Environmental Engineering, 2015, 33(5):131-5.
[5] 杨贺, 陈伟, 梁贺之. 脱硫石膏—钛矿渣粉复合胶凝材料力学性能研究[J]. 钢铁钒钛, 2019, 40(6):67-72.YANG H, CHEN W, LIANG H Z. Study on mechanical properties of flue gas desulphurization gypsum-titanium slag powder composite cementitious material[J]. Iron Steel Vanadium Titauium, 2019, 40(6):67-72.
YANG H, CHEN W, LIANG H Z. Study on mechanical properties of flue gas desulphurization gypsum-titanium slag powder composite cementitious material[J]. Iron Steel Vanadium Titauium, 2019, 40(6):67-72.
[6] 冯智广, 于峰泉, 耿健. 钛石膏基复合胶凝材料抗碳化性能的研究[J]. 低温建筑技术, 2021, 43(9):1-4.FENG Z G, YU F Q, GENG J. Research on anti-carbonation performance of titanium gypsum-based composite cementitious material[J]. Low Temperature Architecture Technology, 2021, 43(9):1-4.
FENG Z G, YU F Q, GENG J. Research on anti-carbonation performance of titanium gypsum-based composite cementitious material[J]. Low Temperature Architecture Technology, 2021, 43(9):1-4.
[7] 陈夕全, 杨姝, 王伟, 等. 钛石膏净化工艺研究[J]. 山东化工, 2020, 49(6):44-5+7.CHEN X Q, YANG S, WANG W, et al. Study on purification process of titanium gypsum[J]. Shandong Chemical Industry, 2020, 49(6):44-5+7. doi: 10.3969/j.issn.1008-021X.2020.06.016
CHEN X Q, YANG S, WANG W, et al. Study on purification process of titanium gypsum[J]. Shandong Chemical Industry, 2020, 49(6):44-5+7. doi: 10.3969/j.issn.1008-021X.2020.06.016
[8] 龚家竹. 钛石膏与磷石膏固废耦合资源化利用技术进展[J]. 无机盐工业, 2019, 51(1):1-6+11.GONG J Z. Progress in coupling utilization technology of titanium gypsum and phosphogypsum solid waste[J]. Inorganic Chemicals Industry, 2019, 51(1):1-6+11.
GONG J Z. Progress in coupling utilization technology of titanium gypsum and phosphogypsum solid waste[J]. Inorganic Chemicals Industry, 2019, 51(1):1-6+11.
[9] 石鑫, 杨绍利, 马兰. “三石膏”综合利用现状及其新工艺[J]. 现代化工, 2020, 40(9):8-13+9.SHI X, YANG S L, MA L. Present situation of comprehensive utilization of“three-gypsum”and new technologies[J]. Modern Chemical Industry, 2020, 40(9):8-13+9.
SHI X, YANG S L, MA L. Present situation of comprehensive utilization of“three-gypsum”and new technologies[J]. Modern Chemical Industry, 2020, 40(9):8-13+9.
[10] 付一江. 工业副产石膏—钛石膏的现状及综合利用前景[J]. 钢铁钒钛, 2019, 40(6):63-6+100.FU Y J. Situation and comprehensive utilization prospect of titanium gypsum[J]. Iron Steel Vanadium Titauium, 2019, 40(6):63-6+100.
FU Y J. Situation and comprehensive utilization prospect of titanium gypsum[J]. Iron Steel Vanadium Titauium, 2019, 40(6):63-6+100.
[11] 谭纪林. 钛石膏作缓凝剂在水泥生产中的应用[J]. 水泥, 2017(2):20-23.TAN J L. Application of titanium gypsum as retarder in cement production.[J]. Cement, 2017(2):20-23.
TAN J L. Application of titanium gypsum as retarder in cement production.[J]. Cement, 2017(2):20-23.
[12] 黄绪泉, 严龙, 徐胜, 等. 钛石膏改性胶结材干化湖泊污泥效果及机理[J]. 环境工程学报, 2015, 9(4):1977-83.HUANG X Q, YAN L, XU S, et al. Drying effect and mechanism of lake sludge with titanium gypsum modified cementitious materials[J]. Chinese Journal of Environmental Engineering, 2015, 9(4):1977-83. doi: 10.12030/j.cjee.20150474
HUANG X Q, YAN L, XU S, et al. Drying effect and mechanism of lake sludge with titanium gypsum modified cementitious materials[J]. Chinese Journal of Environmental Engineering, 2015, 9(4):1977-83. doi: 10.12030/j.cjee.20150474
[13] 蔡宽, 阮长城, 李瑞萍, 等. 改性钛白石膏对阳离子染料罗丹明B的吸附性能[J]. 环境工程学报, 2015, 9(7):3184-90.CAI K, RUAN C C, LI R P, et al. Adsorption characteristics of cationic dye RhB on modified titanium gypsum[J]. Chinese Journal of Environmental Engineering, 2015, 9(7):3184-90. doi: 10.12030/j.cjee.20150718
CAI K, RUAN C C, LI R P, et al. Adsorption characteristics of cationic dye RhB on modified titanium gypsum[J]. Chinese Journal of Environmental Engineering, 2015, 9(7):3184-90. doi: 10.12030/j.cjee.20150718
[14] 王晓琪, 姚媛媛, 陈宝成, 等. 硫酸法钛石膏作为土壤调理剂在油菜上的施用效果研究 [J]. 水土保持学报, 2018, 32(4): 333-8+45.WANG X Q, YAO Y Y , CHEN B C , et al. Effects of titanium gypsum produced by sulfuric acid method as sold conditioner on rape seedings[J]. Journal of Soil And Water Conservation, 2018, 32(4): 333-338+345.
WANG X Q, YAO Y Y , CHEN B C , et al. Effects of titanium gypsum produced by sulfuric acid method as sold conditioner on rape seedings[J]. Journal of Soil And Water Conservation, 2018, 32(4): 333-338+345.
[15] AZDARPOUR A, ASADULLAH M, JUNIN R, et al. Direct carbonation of red gypsum to produce solid carbonates[J]. Fuel Processing Technology, 2014, 126:429-34. doi: 10.1016/j.fuproc.2014.05.028
[16] 李亮. 钛石膏在烧结砖中的应用研究[J]. 钢铁钒钛, 2015, 36(4):53-7.LI L. Study on the application of titanium gypsum in sintered brick[J]. Iron Steel Vanadium Titauium, 2015, 36(4):53-7. doi: 10.7513/j.issn.1004-7638.2015.04.010
LI L. Study on the application of titanium gypsum in sintered brick[J]. Iron Steel Vanadium Titauium, 2015, 36(4):53-7. doi: 10.7513/j.issn.1004-7638.2015.04.010
[17] ROSLI N, AZIZ H A, SELAMAT M R, et al. Physical, mechanical and chemical properties of dewatered sewage sludge and red gypsum mix as a potential recycling product[J]. Solid State Phenomena, 2019, 294:24-9. doi: 10.4028/www.scientific.net/SSP.294.24
[18] 彭志辉, 刘巧玲, 彭家惠, 等. 钛石膏作水泥缓凝剂研究[J]. 重庆建筑大学学报, 2004(1):93-6.PENG Z H, LIU Q L, PENG J H, et al. Study on titanium gypsum as set retarder for cement[J]. Journal of Chongqing Jianzhu University, 2004(1):93-6.
PENG Z H, LIU Q L, PENG J H, et al. Study on titanium gypsum as set retarder for cement[J]. Journal of Chongqing Jianzhu University, 2004(1):93-6.
[19] 张宾, 张玉玲, 陈博文. 钛石膏作缓凝剂对水泥净浆流动度影响的研究[J]. 水泥, 2020(8):1-5.ZHANG B, ZHANG Y L, CHEN B W. Effect of titanium as retarder on fluidity of cement paste[J]. Cement, 2020(8):1-5.
ZHANG B, ZHANG Y L, CHEN B W. Effect of titanium as retarder on fluidity of cement paste[J]. Cement, 2020(8):1-5.
[20] GAZQUEZ M J, BOLIVAR J P, VACA F, et al. Evaluation of the use of TiO2 industry red gypsum waste in cement production[J]. Cement & Concrete Composites, 2013, 37:76-81.
[21] 杨贺, 陈伟, 梁贺之, 等 钛工业固废钛石膏胶凝性与强度机理分析 [J]. 非金属矿, 2021, 44(1): 100-3.YANG H, CHEN W, LIANG H Z, et al. Analysis on the cementation and strength mechanism of titanium industry solid waste titanium gypsum[J]. Non-Metallic Mines, 2021, 44(1): 100-3.
YANG H, CHEN W, LIANG H Z, et al. Analysis on the cementation and strength mechanism of titanium industry solid waste titanium gypsum[J]. Non-Metallic Mines, 2021, 44(1): 100-3.
[22] 刘振东. 用黄石膏、水泥和FAC-1配制混凝土的研究 [J]. 矿产综合利用, 2013 (3): 75-8.LIU Z D. Hydration mechanism of cementitious composite based on yellow gypsum & cement[J]. Non-Metallic Mines, 2007 (5): 26-8+39.
LIU Z D. Hydration mechanism of cementitious composite based on yellow gypsum & cement[J]. Non-Metallic Mines, 2007 (5): 26-8+39.
[23] 杨贺. 石灰碱激发钛石膏复合胶凝材料强度机理分析[J]. 钢铁钒钛, 2021, 42(3):111-8.YANG H. Analysis of the strength mechanism of lime-base activated titanium gypsum composite cementitious material[J]. Iron Steel Vanadium Titauium, 2021, 42(3):111-8. doi: 10.7513/j.issn.1004-7638.2021.03.017
YANG H. Analysis of the strength mechanism of lime-base activated titanium gypsum composite cementitious material[J]. Iron Steel Vanadium Titauium, 2021, 42(3):111-8. doi: 10.7513/j.issn.1004-7638.2021.03.017
[24] 刘代俊. 中国无机固体废弃物处理技术进展[J]. 无机盐工业, 2020, 52(3):1-10.LIU D J. Advance in inorganic solid waste treatment technology in China[J]. Inorganic Chemicals Industry, 2020, 52(3):1-10. doi: 10.11962/1006-4990.2019-0640
LIU D J. Advance in inorganic solid waste treatment technology in China[J]. Inorganic Chemicals Industry, 2020, 52(3):1-10. doi: 10.11962/1006-4990.2019-0640
[25] 孟维正, 刘伟杰, 曹新文. 改良钛石膏无侧限抗压强度研究[J]. 新型建筑材料, 2019, 46(7):28-31.MENG W Z, LIU W J, CAO X W. Research on the unconfined compressive strength of modified titanium gypsum[J]. New Building Materials, 2019, 46(7):28-31. doi: 10.3969/j.issn.1001-702X.2019.07.007
MENG W Z, LIU W J, CAO X W. Research on the unconfined compressive strength of modified titanium gypsum[J]. New Building Materials, 2019, 46(7):28-31. doi: 10.3969/j.issn.1001-702X.2019.07.007
[26] 赵玉静, 施惠生. 粉煤灰-钛白石膏路基材料的研究[J]. 建筑材料学报, 2000(4):328-34.ZHAO Y J, SHI H S. Study on composite for base pavement made of waste gypsum from TiO2 production and fly ash[J]. Journal Of Building Materials, 2000(4):328-34. doi: 10.3969/j.issn.1007-9629.2000.04.006
ZHAO Y J, SHI H S. Study on composite for base pavement made of waste gypsum from TiO2 production and fly ash[J]. Journal Of Building Materials, 2000(4):328-34. doi: 10.3969/j.issn.1007-9629.2000.04.006
[27] 朱浩泽, 于峰泉, 耿健, 等. 钛石膏基可控低强度材料强度及体积稳定性研究 [J]. 硅酸盐通报: 1-11.ZHU H Z, YU F Q, GENG J, et al. Compressive strength and volume stability of controlled low strength material based on red gypsum[J]. Bulletin of the Chinese Ceramic Society: 1-11.
ZHU H Z, YU F Q, GENG J, et al. Compressive strength and volume stability of controlled low strength material based on red gypsum[J]. Bulletin of the Chinese Ceramic Society: 1-11.
[28] 隋肃, 高子栋, 李国忠. 钛石膏的改性处理和力学性能研究[J]. 硅酸盐通报, 2010, 29(1):89-93.SUI S, GAO Z D, LI G Z. Study on modification and mechanical property of titanium gypsum[J]. Bulletin of the Chinese Ceramic Society, 2010, 29(1):89-93.
SUI S, GAO Z D, LI G Z. Study on modification and mechanical property of titanium gypsum[J]. Bulletin of the Chinese Ceramic Society, 2010, 29(1):89-93.
[29] CHEN H, WANG Z, PEI L, et al. Fabrication of baking-free bricks from iron ore tailings [J]. Current Materials Science: Formerly: Recent Patents on Materials Science, 2020.
[30] ZHANG J, YAN Y, HU Z, et al. Properties and hydration behavior of Ti-extracted residues-red gypsum based cementitious materials[J]. Construction and Building Materials, 2019, 218(SEP.10):610-7.
[31] B A A A, B M A, A R J, et al. Extraction of calcium from red gypsum for calcium carbonate production - science direct[J]. Fuel Processing Technology, 2015, 130(130):12-9.
[32] 蒋美雪. 钛石膏除杂制备硫酸钙晶须与酸浸液处理研究[D]. 绵阳: 西南科技大学, 2019.JIANG M X. Study on impurity removal from titanium gypsum and preparation calcium sulfate whisker and the treatment of acid leaching solution[D]. Mianyang: Southwest University of Science and technology, 2019.
JIANG M X. Study on impurity removal from titanium gypsum and preparation calcium sulfate whisker and the treatment of acid leaching solution[D]. Mianyang: Southwest University of Science and technology, 2019.
[33] PENG X, ZHENG J, LIU Q, et al. Efficient removal of iron from red gypsum via synergistic regulation of gypsum phase transformation and iron speciation [J]. Science of The Total Environment, 2021: 148319.
[34] 蔡宽, 阮长城, 李瑞萍, 等. 钛白石膏对重金属Pb(Ⅱ)的吸附特性研究[J]. 非金属矿, 2014, 37(6):74-7.CAI K, RUAN C C, LI R P, et al. Adsorption characteristics of heavy metal Pb(II) on titanium gypsum[J]. Non-Metallic Mines, 2014, 37(6):74-7. doi: 10.3969/j.issn.1000-8098.2014.06.023
CAI K, RUAN C C, LI R P, et al. Adsorption characteristics of heavy metal Pb(II) on titanium gypsum[J]. Non-Metallic Mines, 2014, 37(6):74-7. doi: 10.3969/j.issn.1000-8098.2014.06.023
[35] PETRUZZELLI G, SCATENA M, ROSELLINI I, et al. The use of compost – red gypsum mixture as a low cost alternative adsorbent for lead [J]. 2015.
[36] 朱静平, 张婷婷, 刘洪, 等. 钛石膏制备片状钙白粉的生产工艺研究[J]. 非金属矿, 2019, 42(4):51-2+76.ZHU J P, ZHANG T T, LIU H, et al. Technical study on the preparation of flaky calcium white powder from titanium gypsum[J]. Non-Metallic Mines, 2019, 42(4):51-2+76. doi: 10.3969/j.issn.1000-8098.2019.04.015
ZHU J P, ZHANG T T, LIU H, et al. Technical study on the preparation of flaky calcium white powder from titanium gypsum[J]. Non-Metallic Mines, 2019, 42(4):51-2+76. doi: 10.3969/j.issn.1000-8098.2019.04.015
[37] 黄佳乐, 武斌, 陈葵, 等. 钛石膏作土壤镉污染改良剂的可行性分析[J]. 无机盐工业, 2016, 48(10):68-72.HUANG J L, WU B, CHEN K, et al. Red gypsum as a feasible additive for remediation of cadmium in soil[J]. Inorganic Chemicals Industry, 2016, 48(10):68-72.
HUANG J L, WU B, CHEN K, et al. Red gypsum as a feasible additive for remediation of cadmium in soil[J]. Inorganic Chemicals Industry, 2016, 48(10):68-72.
[38] FAUZIAH I, ZAUYAH S, JAMAL T. Characterization and land application of red gypsum: a waste product from the titanium dioxide industry[J]. Science of The Total Environment, 1996, 188(2-3):243-51. doi: 10.1016/0048-9697(96)05179-0
[39] 黄佳乐. 钛石膏改良土壤镉污染的机理及镉的生物有效性研究 [D]. 上海: 华东理工大学, 2016.HUANG J L. Mechanism for remediation of cadmium contaminated soils with red gypsum and bioavailability study of immobilized cadmium[D]. Shanghai: East China University of Science and Technology, 2016.
HUANG J L. Mechanism for remediation of cadmium contaminated soils with red gypsum and bioavailability study of immobilized cadmium[D]. Shanghai: East China University of Science and Technology, 2016.
[40] 邹丽娜, 徐婧婧, 陈铮铮, 等. 水旱轮作下钛石膏对土壤砷铅有效性的影响研究[J]. 农业环境科学学报, 2021, 40(4):774-81.ZOU L N, XU J J, CHEN Z Z, et al. Effect of titanium gypsum on the availability of arsenic and lead in agricultural soil under paddy-dryland rotation conditions[J]. Journal of Agro Environment Science, 2021, 40(4):774-81. doi: 10.11654/jaes.2020-1290
ZOU L N, XU J J, CHEN Z Z, et al. Effect of titanium gypsum on the availability of arsenic and lead in agricultural soil under paddy-dryland rotation conditions[J]. Journal of Agro Environment Science, 2021, 40(4):774-81. doi: 10.11654/jaes.2020-1290
[41] RODRIGUEZ-JORDA M P, GARRIDO F, GARCIA-GONZALEZ M T. Potential use of gypsum and lime rich industrial by-products for induced reduction of Pb, Zn and Ni leachability in an acid soil[J]. Journal of Hazardous Materials, 2010, 175(1-3):762-9. doi: 10.1016/j.jhazmat.2009.10.074
[42] 陈琨, 上官宇先, 杨乾龙, 等. 钛石膏对镉污染土壤水稻生长及镉有效性的影响[J]. 亚热带农业研究, 2020, 16(4):217-23.CHEN K, SHANGGUAN Y X, YANG Q L, et al. Effect of titanium gypsum application on rice growth and cadmium availability in cadmium-contaminated soil[J]. Subtropical Agriculture Research, 2020, 16(4):217-23.
CHEN K, SHANGGUAN Y X, YANG Q L, et al. Effect of titanium gypsum application on rice growth and cadmium availability in cadmium-contaminated soil[J]. Subtropical Agriculture Research, 2020, 16(4):217-23.
[43] 张华军, 李化全. 一种利用固体废弃物钛石膏制备硫酸钙复合肥的方法研究[J]. 山东化工, 2016, 45(13):41-2+5.ZHANG H J, LI H Q. Method for preparing calcium sulfate compound fertilizer by utilizing solid waste titanium gypsum[J]. Shandong Chemical Industry, 2016, 45(13):41-2+5. doi: 10.3969/j.issn.1008-021X.2016.13.014
ZHANG H J, LI H Q. Method for preparing calcium sulfate compound fertilizer by utilizing solid waste titanium gypsum[J]. Shandong Chemical Industry, 2016, 45(13):41-2+5. doi: 10.3969/j.issn.1008-021X.2016.13.014
[44] 王深, 吕连宏, 张保留, 等. 基于多目标模型的中国低成本碳达峰碳中和路径研究 [J]. 环境科学研究: 1-15.WANG S, LYU L H, ZHANG B L, et al. Multi objective programming model of low-cost path for China’s peaking carbon dioxide emissions and carbon neutrality[J]. Research of Environmental Sciences: 1-15.
WANG S, LYU L H, ZHANG B L, et al. Multi objective programming model of low-cost path for China’s peaking carbon dioxide emissions and carbon neutrality[J]. Research of Environmental Sciences: 1-15.
[45] 包炜军, 李会泉, 张懿. 温室气体CO2矿物碳酸化固定研究进展[J]. 化工学报, 2007(1):1-9.BAO W J, LI H Q, ZHANG Y. Progress in carbon dioxide sequestration by mineral carbonation[J]. Journal of Chemical Industry and Engineering (China), 2007(1):1-9. doi: 10.3321/j.issn:0438-1157.2007.01.001
BAO W J, LI H Q, ZHANG Y. Progress in carbon dioxide sequestration by mineral carbonation[J]. Journal of Chemical Industry and Engineering (China), 2007(1):1-9. doi: 10.3321/j.issn:0438-1157.2007.01.001
[46] RAHMANI O, JUNIN R, TYRER M, et al. Mineral Carbonation of Red Gypsum for CO2 Sequestration[J]. Energy & Fuels, 2014, 28(9):5953.
[47] PéREZ-MORENO S, GáZQUEZ M, BOLíVAR J. CO2 sequestration by indirect carbonation of artificial gypsum generated in the manufacture of titanium dioxide pigments[J]. Chemical Engineering Journal, 2015, 262:737-46. doi: 10.1016/j.cej.2014.10.023
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