三氯化铁-淀粉复合絮凝剂的制备及性能

张晋霞, 王聪磊, 牛福生, 郭建波, 王万擘. 三氯化铁-淀粉复合絮凝剂的制备及性能[J]. 矿产综合利用, 2025, 46(3): 44-50. doi: 10.12476/kczhly.202210090641
引用本文: 张晋霞, 王聪磊, 牛福生, 郭建波, 王万擘. 三氯化铁-淀粉复合絮凝剂的制备及性能[J]. 矿产综合利用, 2025, 46(3): 44-50. doi: 10.12476/kczhly.202210090641
ZHANG Jinxia, WANG Conglei, NIU Fusheng, GUO Jianbo, WANG Wanbo. Preparation and Properties of Ferric Chloride - starch Composite Flocculant[J]. Multipurpose Utilization of Mineral Resources, 2025, 46(3): 44-50. doi: 10.12476/kczhly.202210090641
Citation: ZHANG Jinxia, WANG Conglei, NIU Fusheng, GUO Jianbo, WANG Wanbo. Preparation and Properties of Ferric Chloride - starch Composite Flocculant[J]. Multipurpose Utilization of Mineral Resources, 2025, 46(3): 44-50. doi: 10.12476/kczhly.202210090641

三氯化铁-淀粉复合絮凝剂的制备及性能

  • 基金项目: 河北省自然科学基金(E2021209015)
详细信息
    作者简介: 张晋霞(1979-),女,博士,教授,硕士生导师,研究方向为复杂难选矿高效分选
    通讯作者: 王聪磊(1995-),男,硕士研究生,研究方向为固体废弃物资源化与综合利用。
  • 中图分类号: TD951

Preparation and Properties of Ferric Chloride - starch Composite Flocculant

More Information
  • 通过实验研究了三氯化铁-淀粉复合絮凝剂的适宜制备条件和絮凝性能。实验结果表明,制备体系的V(改性淀粉溶液):V(三氯化铁溶液)比例为0.5,制备温度为45 ℃,反应时间为3 h,熟化时间为18 h,制备的絮凝剂絮凝效果较好;利用该絮凝剂处理200 mL的尾矿水,尾矿水pH值为7.0,絮凝剂用量为21.18 kg/t,絮凝剂絮凝时间为60 s,浊度去除率可达98%。红外光谱分析结果表明,三氯化铁和淀粉并不是简单的混合,而是发生了络合反应,增强吸附架桥作用。

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  • 图 1  三氯化铁和改性淀粉不同体积比下复合絮凝剂的浊度

    Figure 1. 

    图 2  制备温度对复合絮凝剂絮凝效果的影响

    Figure 2. 

    图 3  反应时间对复合絮凝剂絮凝效果的影响

    Figure 3. 

    图 4  熟化时间对复合絮凝剂絮凝效果的影响

    Figure 4. 

    图 5  红外光谱

    Figure 5. 

    图 6  药剂用量对絮凝效果的影响

    Figure 6. 

    图 7  pH值对絮凝效果的影响

    Figure 7. 

    图 8  温度对絮凝效果的影响

    Figure 8. 

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收稿日期:  2022-10-09
刊出日期:  2025-06-25

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