Research Status of the Effect of Typical Impurity Minerals and Ions on Chalcopyrite Leaching
-
摘要:
黄铜矿常与黄铁矿、石英、碳酸盐类及硅酸盐类等杂质矿物共生，而这些矿物的存在会对黄铜矿的浸出产生一定影响。此外，黄铜矿浸出时常需加入一些氧化剂来促进其溶解，而额外加入的氧化剂产生的离子以及杂质矿物自身溶解产生的离子也会影响其浸出效率。因此，本文综述了近年来典型杂质矿物及溶液中离子对黄铜矿浸出影响的相关研究，旨在为实现高效完全黄铜矿浸出提供理论支撑和科学依据。
Abstract:Chalcopyrite is often associated with some impurity minerals such as pyrite, quartz, carbonateand silicate minerals, and the presence of these minerals will affect the leaching of chalcopyrite. Additionally, to promote the dissolution of chalcopyrite, some oxidants often need to be added in its leaching process, which generates manyunavoidable ions. Therefore, involving the ions produced from the dissolution of impurity minerals will affect the leaching efficiency of chalcopyrite.In this paper, the effect of the typical impurity minerals and ions on chalcopyrite dissolution was reviewed for providinga theoretical foundation for the high-efficiency and complete CuFeS2 leaching.
-
Key words:
- Leaching /
- Chalcopyrite /
- Impurity mineral /
- Ions
-
-
[1] 孙若凡, 刘丹, 杜钰, 等. 黄铜矿、方铅矿分离研究现状及进展[J]. 矿产综合利用, 2021(4):80-86. doi: 10.3969/j.issn.1000-6532.2021.04.012
SUN R F, LIU D, DU Y, et al. Research status and development of separation of chalcopyrite and galena[J]. Multipurpose Utilization of Mineral Resources, 2021(4):80-86. doi: 10.3969/j.issn.1000-6532.2021.04.012
[2] 卢晶, 王枫, 李磊, 等. 安徽省铜陵马山金硫矿床北段金矿物特征研究[J]. 矿产综合利用, 2020(5):115-119. doi: 10.3969/j.issn.1000-6532.2020.05.017
LU J, WANG F, LI L, et al. Study on the characteristics of gold minerals in the northern segment of the Mashan gold-sulfur deposit in Tongling, Anhui province[J]. Multipurpose Utilization of Mineral Resources, 2020(5):115-119. doi: 10.3969/j.issn.1000-6532.2020.05.017
[3] 肖炜, 田小松. 云南迪庆铜铅锌硫化矿浮选分离研究[J]. 矿产综合利用, 2020(1):65-70. doi: 10.3969/j.issn.1000-6532.2020.01.014
XIAO W, TIN X S. Study on flotation separation of copper-lead-zinc sulfide ore in Diqing Yunnan[J]. Multipurpose Utilization of Mineral Resources, 2020(1):65-70. doi: 10.3969/j.issn.1000-6532.2020.01.014
[4] 张兴勋. 某低品位次生硫化铜矿生物柱浸试验[J]. 矿产综合利用, 2020(3):111-116. doi: 10.3969/j.issn.1000-6532.2020.03.018
ZHANG X X. Experiment of biological column leaching of a low-grade secondary copper sulfide ore[J]. Multipurpose Utilization of Mineral Resources, 2020(3):111-116. doi: 10.3969/j.issn.1000-6532.2020.03.018
[5] 张水龙, 刘金艳, 杨林恒, 等. 吉林铜钴镍多金属硫化矿的生物浸出试验研究[J]. 矿产综合利用, 2020(1):50-53. doi: 10.3969/j.issn.1000-6532.2020.01.010
ZHANG S L, LIU J Y, YANG L H, et al. Bioleaching of copper-cobalt-nickel polymetallic sulfide ores in Jilin[J]. Multipurpose Utilization of Mineral Resources, 2020(1):50-53. doi: 10.3969/j.issn.1000-6532.2020.01.010
[6] 王新宇, 李育彪. 黄铜矿的浸出及其动力学研究[J]. 金属矿山, 2017(1):82-85. doi: 10.3969/j.issn.1001-1250.2017.01.018
WANG X Y, LI Y B. Study on the chalcopyrite leaching and its kinetics[J]. Metal Mine, 2017(1):82-85. doi: 10.3969/j.issn.1001-1250.2017.01.018
[7] Hiroshi Majima, Yasuhiro Awakura, Tetsuji Hirato, et al. The leaching of chalcopyrite in ferric chloride and ferric sulfate solutions[J]. Canadian Metallurgical Quarterly, 2013, 24(4).
[8] 白云龙, 王伟, 谢锋, 等. 黄铁矿对黄铜矿浸出的影响[J]. 有色金属(冶炼部分), 2020(7):5-10+40.
BAI Y L, WANG W, XIE F, et al. Effect of Pyrite on Leaching Behavior of Chalcopyrite[J]. Nonferrous Metals(Extractive Metallurgy), 2020(7):5-10+40.
[9] Yubiao Li, Gujie Qian, Jun Li, Andrea Gerson. Chalcopyrite Dissolution at 650 mV and 750 mV in the Presence of Pyrite[J]. Metals, 2015, 5(3).
[10] 李宏煦, 邱冠周, 胡岳华, 等. 原电池效应对混合硫化矿细菌浸出的影响[J]. 中国有色金属学报, 2003(5):1283-1287. doi: 10.3321/j.issn:1004-0609.2003.05.045
LI H X, QIU G Z, HU Y H, et al. Galvanic effect on mixed sulfide bioleaching[J]. The Chinese Journal of Nonferrous Metals, 2003(5):1283-1287. doi: 10.3321/j.issn:1004-0609.2003.05.045
[11] Baisui Han, Batnasan Altansukh, Kazutoshi Haga, et al. Leaching and kinetic study on pressure oxidation of chalcopyrite in H2SO4 solution and the effect of pyrite on chalcopyrite leaching[J]. Journal of Sustainable Metallurgy, 2017, 3(3).
[12] 王廷健, 周仲魁, 孙占学, 等. 黄铁矿添加量对微生物浸出的影响[J]. 有色金属(冶炼部分), 2020(7):53-58.
WANG T J, ZHOU Z K, SUN Z X, et al. Effect of pyrite addition on microbiological leaching[J]. Nonferrous Metals(Extractive Metallurgy), 2020(7):53-58.
[13] 潘灵, 孔迎辰. 黄铁矿在微生物浸矿技术中的应用[J]. 科技资讯, 2011(36):61+63.
PAN L, KONG Y C. Application of pyrite in microbiological leaching technology[J]. Science & Technology Information, 2011(36):61+63.
[14] 莫晓兰, 林海, 傅开彬, 等. 黄铁矿促进黄铜矿微生物浸出影响因素[J]. 北京科技大学学报, 2012, 34(7):761-768.
MO X L, LIN H, FU K B, et al. Influence factors of pyrite promotion on the bioleaching of chalcopyrite[J]. Journal of University of Science and Technology Beijing, 2012, 34(7):761-768.
[15] Z Sadowski, E Jazdzyk, H Karas. Bioleaching of copper ore flotation concentrates[J]. Minerals Engineering, 2003, 16(1).
[16] 张冬艳, 张通. 细菌浸出黄铜矿过程中黄铁矿的影响行为[J]. 湿法冶金, 1997(2):4-7.
ZHANG D Y, ZHANG T. Influence behavior of pyrite on the bioleaching of chalcopyrite[J]. Hydrometallurgy of China, 1997(2):4-7.
[17] 周闪闪. 脉石矿物在微生物浸出黄铜矿体系的溶出特性及机理研究[D]. 北京: 北京科技大学, 2016.
ZHOU S S. Study on mechanism and dissolution characteristics of gangue minerals in bioleaching of chalcopyrite[D]. Beijing: University of Science and Technology Beijing, 2016.
[18] 莫晓兰, 林海, 董颖博, 等. 石英对微生物浸出黄铜矿的作用[J]. 北京科技大学学报, 2011, 33(6):682-687.
MO X L, LIN H, DONG Y B, et al. Effect of quartz on bioleaching of chalcopyrite[J]. Journal of University of Science and Technology Beijing, 2011, 33(6):682-687.
[19] Yingbo Dong, Hai Lin, Shanshan Zhou, et al. Effects of quartz addition on chalcopyrite bioleaching in shaking flasks[J]. Minerals Engineering, 2013:46-47.
[20] 莫晓兰, 林海, 温建康, 等. 脉石矿物对细菌浸出黄铜矿的影响研究[J]. 稀有金属, 2013, 37(3):437-445. doi: 10.3969/j.issn.0258-7076.2013.03.017
MO X L, LIN H, WEN J K, et al. Effect of gangue minerals on chalcopyrite bioleaching[J]. Chinese Journal of Rare Metals, 2013, 37(3):437-445. doi: 10.3969/j.issn.0258-7076.2013.03.017
[21] 莫晓兰, 林海, 傅开彬, 等. 绢云母对黄铜矿微生物浸出的影响[J]. 中国有色金属学报, 2012, 22(5):1475-1481.
MO X L, LIN H, FU K B, et al. Effect of sericite on bioleaching of chalcopyrite[J]. The Chinese Journal of Nonferrous Metals, 2012, 22(5):1475-1481.
[22] 杨聪仁, 焦芬, 覃文庆. 黄铜矿浸出: 强调铜离子和铁离子的作用(英文)[J]. Journal of Central South University, 2018, 25(10):2380-2386. doi: 10.1007/s11771-018-3922-5
YANG C R, JIAO F, QIN W Q. Leaching of chalcopyrite: An emphasis on effect of copper and iron ions[J]. Journal of Central South University, 2018, 25(10):2380-2386. doi: 10.1007/s11771-018-3922-5
[23] 甘晓文, 王军, 赵红波, 等. Fe3+对黄铜矿与铁闪锌矿分步浸出的影响机制[J]. 矿冶工程, 2017, 37(1):77-80. doi: 10.3969/j.issn.0253-6099.2017.01.021
GAN X W, WANG J, ZHAO H B, et al. Effect of Fe3+ on stepwise bioleaching of chalcopyrite and marmatite[J]. Mining and Metallurgy Engineering, 2017, 37(1):77-80. doi: 10.3969/j.issn.0253-6099.2017.01.021
[24] 许晓芳. 不同离子胁迫对微生物浸出黄铜矿的影响和机理[D]. 北京: 北京科技大学, 2016.
XU X F. Effect and mechanism of different ions stress on bioleaching of chalcopyrite[D]. Beijing: University of Science and Technology Beijing, 2016.
[25] HAVLIK T, SKROBIAN M, BALAZP, KAMMELR. Leaching of chalcopyrite concentrate with ferric chloride[J]. International Journal of Mineral Processing, 1995, 43(1/2):61-72.
[26] 毛天舒. 氯化银对生物浸出黄铜矿精矿的影响[J]. 湿法冶金, 2000, 19(4):63. doi: 10.3969/j.issn.1009-2617.2000.04.024
MAO T S. Effect of silver chloride on bioleaching of chalcopyrite concentrate[J]. Hydrometallurgy of China, 2000, 19(4):63. doi: 10.3969/j.issn.1009-2617.2000.04.024
[27] Ahmad Ghahremaninezhad, Rebecca Radzinski, Tudor Gheorghiu, et al. A model for silver ion catalysis of chalcopyrite (CuFeS2) dissolution[J]. Hydrometallurgy, 2015:155.
[28] 童雄, 孙永贵. 微生物浸出难浸黄铜矿的研究[J]. 矿产综合利用, 1999(4):7-11.
TONG X, SUN Y G. Study on microbiological leaching of refractory chalcopyrite[J]. Multipurpose Utilization of Mineral Resources, 1999(4):7-11.
[29] 王康林, 韩效钊, 汪模辉, 等. 银离子在细菌浸出黄铜矿中的催化行为研究[J]. 矿冶工程, 2003(5):60-62. doi: 10.3969/j.issn.0253-6099.2003.05.020
WANG K L, HAN X Z, WANG M H, et al. The study of catalyzing behavior of silver ions in bacterial leaching of chalcopyrite[J]. Mining and Metallurgy Engineering, 2003(5):60-62. doi: 10.3969/j.issn.0253-6099.2003.05.020
[30] 徐伟昌. 生物技术在核工业中的应用[M]. 长沙: 国防科技大学出版社, 2002.
XU W C. Application of Biotechnology in the Nuclear Industry[M]. Changsha: National University ofDefense Technology Press, 2002.
[31] Saleh Rasouli, Behrad Mojtahedi, Hossein Yoozbashizadeh. Oxidative Leaching of Chalcopyrite by Cupric Ion in Chloride Media[J]. Transactions of the Indian Institute of Metals, 2020.
[32] 崔亚铨, 冯守帅, 黄兴, 等. 铜耐受定向驯化强化嗜酸喜温硫杆菌浸出贫黄铜矿[J]. 生物技术通报, 2019, 35(8):95-102.
CUI Y Q, FENG S, HUANG X, et al. Directed domestication of copper tolerance for enhancing low- grade chalcopyrite bioleaching by ccidithiobacilluscaldus[J]. Biotechnology Bulletin, 2019, 35(8):95-102.
[33] 李洪枚, 柯家骏. Mg2+对氧化亚铁硫杆菌生长活性的影响[J]. 中国有色金属学报, 2000(4):576-578. doi: 10.3321/j.issn:1004-0609.2000.04.026
LI H M, KE J J. Effect of Mg2+ on growth and activity of thiobacillus ferrooxidans[J]. The Chinese Journal of Nonferrous Metals, 2000(4):576-578. doi: 10.3321/j.issn:1004-0609.2000.04.026
[34] 蒋金龙, 汪模辉, 王康林. 金属离子对细菌浸出复杂金属硫化矿的影响[J]. 成都理工学院学报, 2001(2):209-213.
JIANG J L, WANG M H, WANG K L. The Influence of various metallic ions on the bioleaching of complex metal sulphides[J]. Journal of Chengdu Institute of Technology, 2001(2):209-213.
[35] G·J·奥尔松, 汪镜亮, 李长根. 金属硫化矿物的生物氧化基本原理[J]. 国外金属矿选矿, 2004(12):21,34-38.
G J OHLSSON, WANG J L, LI C G. Fundamental principles of biological oxidation of metallic sulfide minerals[J]. Metallic Ore Dressing Abroad, 2004(12):21,34-38.
[36] 田国才, 胡均贤, 字富庭. 氧化剂在黄铜矿氧化浸出中应用的研究进展[J]. 过程工程学报, 2017, 17(4):664-676. doi: 10.12034/j.issn.1009-606X.216368
TIAN G C, HU J X, ZI F T. Research advances in applications of oxidants in oxidation leaching of chalcopyrite[J]. The Chinese Journal of Process Engineering, 2017, 17(4):664-676. doi: 10.12034/j.issn.1009-606X.216368
[37] M F C Carneiro, V A Leão. The role of sodium chloride on surface properties of chalcopyrite leached with ferric sulphate[J]. Hydrometallurgy, 2007, 87(3).
[38] Hiroyoshi N, Miki H, Hirajima T, et al. Model for ferrous-promoted chalcopyrite leaching[J]. Hydrometallurgy, 2000, 57(1):31-38. doi: 10.1016/S0304-386X(00)00089-X
[39] 李治明, 钟珊, 李育彪, 等. 亚氯酸钠氧化浸出黄铜矿研究[J]. 金属矿山, 2019(1):74-77.
LI Z M, ZHONG S, LI Y B, et al. Research of chalcopyrite oxidative leaching mechanism by sodium chlorite[J]. Metal Mine, 2019(1):74-77.
[40] P C Hernández, Taboada M E, Herreros O O , et al. Leaching of Chalcopyrite in Acidified Nitrate Using Seawater-Based Media[J]. Minerals, 2018, 8(6).
-
计量
- 文章访问数: 1848
- PDF下载数: 111
- 施引文献: 0
下载: