中国地质科学院矿产综合利用研究所主办
高级检索

Z-200体系下Pb2+，Zn2+对黄铜矿可浮性的影响及其机理

,  ,  ,  , 

文章导航 > 矿产综合利用 > 2024 > 45(1): 155-159, 166

上一篇

下一篇

鱼博, 何廷树, 王鑫, 贺寒冰, 王宇斌. Z-200体系下Pb2+，Zn2+对黄铜矿可浮性的影响及其机理[J]. 矿产综合利用, 2024, 45(1): 155-159, 166. doi: 10.3969/j.issn.1000-6532.2024.01.020
引用本文: 鱼博, 何廷树, 王鑫, 贺寒冰, 王宇斌. Z-200体系下Pb2+，Zn2+对黄铜矿可浮性的影响及其机理[J]. 矿产综合利用, 2024, 45(1): 155-159, 166. doi: 10.3969/j.issn.1000-6532.2024.01.020
shu
YU Bo, HE Tingshu, WANG Xin, HE Hanbing, WANG Yubin. Effect of Pb2+, Zn2+ on Floatability of Chalcopyrite in Z-200 System and Its Mechanism[J]. Multipurpose Utilization of Mineral Resources, 2024, 45(1): 155-159, 166. doi: 10.3969/j.issn.1000-6532.2024.01.020
Citation: YU Bo, HE Tingshu, WANG Xin, HE Hanbing, WANG Yubin. Effect of Pb2+, Zn2+ on Floatability of Chalcopyrite in Z-200 System and Its Mechanism[J]. Multipurpose Utilization of Mineral Resources, 2024, 45(1): 155-159, 166. doi: 10.3969/j.issn.1000-6532.2024.01.020
shu

Z-200体系下Pb2+，Zn2+对黄铜矿可浮性的影响及其机理

  • 1.

    西安建筑科技大学　资源工程学院，陕西　西安　710055

  • 2.

    铜川润鑫新材料有限公司，陕西 铜川 727018

  • 基金项目: 陕西省科技厅重点研发项目（2018GY-088）
详细信息
    作者简介: 鱼博（1996-），男，硕士研究生，主要从事矿物综合利用研究
    通讯作者: 王宇斌（1972-），男，博士，副教授，主要从事矿物综合利用研究

  • 中图分类号: TD912

Effect of Pb2+, Zn2+ on Floatability of Chalcopyrite in Z-200 System and Its Mechanism

  • 1.

    School of Resources Engineering, Xi’an University of Architecture and Technology , Xi’an 710055, Shaanxi, China

  • 2.

    Tongchuan Runxin New Material Co., Ltd., Tongchuan 727018, Shaanxi, China

More Information

    摘要

  • 这是一篇矿物加工工程领域的论文。黄铜矿、方铅矿和闪锌矿通常会相互伴(共)生，为了探究Pb2+和Zn2+对黄铜矿浮选行为和表面性质的影响，本研究对黄铜矿进行了单矿物浮选实验，并利用溶液化学计算、Zeta电位和XPS检测等方法，对比研究了Pb2+和Zn2+对黄铜矿浮选行为和表面性质的影响。黄铜上的 Zn2+。矿石可浮性影响的差异。测试结果表明，Pb2+和Zn2+都会吸附在黄铜矿表面，改变黄铜矿表面的Zeta电位，抑制黄铜矿的可浮性，并且随着pH值的升高，抑制作用增强；结合浮选实验结果可知，浮选所处的矿浆pH值范围内，锌主要以Zn(OH)2沉淀的形式吸附在黄铜矿表面从而对黄铜矿的浮选产生抑制效果，所以Zn2+对黄铜矿浮选的抑制效果要比Pb2+显著；且XPS分析结果表明，Pb2+和Zn2+都能在黄铜矿表面形成沉淀物，并以化学吸附的形式出现在黄铜矿表面，从而抑制黄铜矿的可浮性。

    This is an article in the field of mineral processing engineering. Chalcopyrite, galena and sphalerite are usually associated with each other. In order to find out the influence of Pb2+ and Zn2+ on the flotation behavior and surface characteristics of chalcopyrite, the difference of the influence of Pb2+ and Zn2+ on the floatability of chalcopyrite was studied by single mineral flotation test, solution chemical calculation, Zeta potential and XPS detection. The results show that Pb2+ and Zn2+ are adsorbed on the surface of chalcopyrite, which changes the Zeta potential of chalcopyrite surface and inhibits the floatability of chalcopyrite, and the inhibition increases with the increase of pH value. According to the flotation test results, zinc is mainly adsorbed on the surface of chalcopyrite in the form of Zn(OH)2 precipitation in the range of pulp pH, which has an inhibitory effect on the flotation of chalcopyrite. Therefore, the inhibitory effect of Zn2+ on the flotation of chalcopyrite is more significant than that of Pb2+ and XPS results show that Pb2+ and Zn2+ can precipitate on the surface of chalcopyrite and exist on the surface of chalcopyrite in the form of chemical adsorption, thus inhibiting the floatability of chalcopyrite.

    • HTML全文
  • 加载中

  • 图 1  单矿物浮选流程

    Figure 1. 

    下载: 全尺寸图片 幻灯片

    图 2  pH 值对黄铜矿浮选效果的影响

    Figure 2. 

    下载: 全尺寸图片 幻灯片

    图 3  Pb2+, Zn2+浓度对黄铜矿浮选效果的影响

    Figure 3. 

    下载: 全尺寸图片 幻灯片

    图 4  Pb2+溶液各组分lgC-pH

    Figure 4. 

    下载: 全尺寸图片 幻灯片

    图 5  Zn2+溶液各组分lgC-pH

    Figure 5. 

    下载: 全尺寸图片 幻灯片

    图 6  不同条件下黄铜矿表面 Zeta 电位

    Figure 6. 

    下载: 全尺寸图片 幻灯片

    图 7  黄铜矿的XPS

    Figure 7. 

    下载: 全尺寸图片 幻灯片

    图 8  CuFeS2的高分辨扫描XPS及分峰拟合

    Figure 8. 

    下载: 全尺寸图片 幻灯片

    表 1  黄铜矿表面原子相对百分含量及元素电子结合能

    Table 1.  Relative content and electron binding energy of atoms on chalcopyrite surface

    序号 浓度/ (mg/L)
    		 相对含量/% 电子结合能/eV
    Pb2+ Zn2+ Cu O S C Pb Zn Cu S Pb Zn
    1 0 0 2.03 16.95 7.74 71.52 - - 932.49 162.35 - -
    2 50 0 1.65 23.34 7.79 66.42 0.80 - 932.62 162.01 138.77 -
    3 0 50 0.72 30.66 0.48 65.37 - 1.67 932.53 163.18 - 1022.09
    下载: 导出CSV

    表 2  Cu的价键形态及分峰拟合分布比例

    Table 2.  Distribution ratio of each sub-peak fitting form of Cu

    序号浓度/ (mg/L)
    		结合能/eV相对含量/%
    Pb2+Zn2+CuFeS2CuSCu(Ⅱ)CuFeS2CuSCu(Ⅱ)
    100932.98932.26935.8937.5554.168.29
    2500932.13933.33936.6720.8369.349.83
    3050931.85932.84933.9662.6822.3814.94
    下载: 导出CSV
    • 参考文献(12)
  • [1]

    王威, 李以科, 封宁. 全球铜矿资源格局分析[J]. 资源与产业, 2013, 15(5):27-32.WANG W, LI Y K, FENG N. Global cooper resource pettern[J]. Resources and Industry, 2013, 15(5):27-32.

    WANG W, LI Y K, FENG N. Global cooper resource pettern[J]. Resources and Industry, 2013, 15(5):27-32.

    [2]

    张汉彪, 薛伟. 刚果(金)某复杂难选氧化铜矿选矿试验研究[J]. 矿产综合利用, 2020(3):117-120.ZHANG H B, XUE W. Experimental study on beneficiation of a complex refractory copper oxide ore in Congo (DRC)[J]. Multipurpose Utilization of Mineral Resources, 2020(3):117-120.

    ZHANG H B, XUE W. Experimental study on beneficiation of a complex refractory copper oxide ore in Congo (DRC)[J]. Multipurpose Utilization of Mineral Resources, 2020(3):117-120.

    [3]

    黄真瑞, 钟宏, 王帅, 等. 黄铜矿浮选工艺及捕收剂研究进展[J]. 应用化工, 2013, 42(11): 2048-2051+2055.HUANG Z R, ZHONG H, WANG S , et al. Progress of flotation technology and collectors for chalcopyrite [J]. Applied Chemical Industry, 2013, 42 (11): 2048-2051 + 2055.

    HUANG Z R, ZHONG H, WANG S , et al. Progress of flotation technology and collectors for chalcopyrite [J]. Applied Chemical Industry, 2013, 42 (11): 2048-2051 + 2055.

    [4]

    肖炜, 田小松. 云南迪庆铜铅锌硫化矿浮选分离研究[J]. 矿产综合利用, 2020(1):65-70.XIAO W, TIAN X S. Study on flotation separation of copper-lead-zinc sulfide ore in Diqing Yunnan[J]. Multipurpose Utilization of Mineral Resources, 2020(1):65-70. doi: 10.3969/j.issn.1000-6532.2020.01.014

    XIAO W, TIAN X S. Study on flotation separation of copper-lead-zinc sulfide ore in Diqing Yunnan[J]. Multipurpose Utilization of Mineral Resources, 2020(1):65-70. doi: 10.3969/j.issn.1000-6532.2020.01.014

    [5]

    王亮, 李育彪, 李万青. 不同价态杂质离子对黄铜矿浮选的影响机理研究[J]. 金属矿山, 2018(12):84-88.WANG L, LI Y B, LI W Q. Influencing mechanism of ions with different valences on chalcopyrite flotation[J]. Metal Mineses, 2018(12):84-88. doi: 10.19614/j.cnki.jsks.201812015

    WANG L, LI Y B, LI W Q. Influencing mechanism of ions with different valences on chalcopyrite flotation[J]. Metal Mineses, 2018(12):84-88. doi: 10.19614/j.cnki.jsks.201812015

    [6]

    雷大士, 王宇斌, 郭月琴, 等. 陕西某含铋白钨矿选矿试验研究[J]. 中国钨业, 2017, 32(3):31-35.LEI D S, WANG Y B, GUO Y Q, et al. Beneficiation of a bismuth-containing scheelite in Shaanxi[J]. China Tungsten Industry, 2017, 32(3):31-35.

    LEI D S, WANG Y B, GUO Y Q, et al. Beneficiation of a bismuth-containing scheelite in Shaanxi[J]. China Tungsten Industry, 2017, 32(3):31-35.

    [7]

    温 凯, 陈建华. 某含银复杂铜铅锌多金属硫化矿浮选试验[J]. 矿产综合利用, 2019(6):28-32.WEN K, CHEN J H. Experimental study on flotation of copper, lead and zinc polymetallic sulfide ore containing silver[J]. Multipurpose Utilization of Mineral Resources, 2019(6):28-32.

    WEN K, CHEN J H. Experimental study on flotation of copper, lead and zinc polymetallic sulfide ore containing silver[J]. Multipurpose Utilization of Mineral Resources, 2019(6):28-32.

    [8]

    鱼博, 王宇斌, 王妍, 等. 某铜铅锌多金属硫化矿工艺矿物学研究[J]. 中国钼业, 2021, 45(1):34-38.YU B, WANG Y B, WANG Y, et al. Research on process mineralogy of a copper-lead-zinc polymetallic sulphide ore[J]. China Molybdenum Industry, 2021, 45(1):34-38.

    YU B, WANG Y B, WANG Y, et al. Research on process mineralogy of a copper-lead-zinc polymetallic sulphide ore[J]. China Molybdenum Industry, 2021, 45(1):34-38.

    [9]

    魏明安, 孙传尧. 矿浆中的难免离子对黄铜矿和黄铜矿浮选的影响[J]. 有色金属, 2008(2):92-95.WEI M A, SUN C Y. Influence of metal cations in pulp to chalcopyrite and galena floatability[J]. Nonferrous Metals(Mineral Processing Section), 2008(2):92-95.

    WEI M A, SUN C Y. Influence of metal cations in pulp to chalcopyrite and galena floatability[J]. Nonferrous Metals(Mineral Processing Section), 2008(2):92-95.

    [10]

    施帅, 何廷树, 李慧. Ca2+和Mg2+对辉钼矿可浮性的影响对比[J]. 过程工程学报, 2021, 21(2):153-159.SHI S, HE T S, LI H. Comparison of the effects of Ca2+and Mg2+ on the floatability of molybdenite[J]. Journal of Process Engineering, 2021, 21(2):153-159.

    SHI S, HE T S, LI H. Comparison of the effects of Ca2+and Mg2+ on the floatability of molybdenite[J]. Journal of Process Engineering, 2021, 21(2):153-159.

    [11]

    刘微, 刘广义, 肖静晶, 等. N-异丁氧羰基硫脲浮选黄铜矿的机理[J]. 中国有色金属学报, 2017, 27(1):128-137.LIU W, LIU G Y, XIAO J J, et al. Mechanism of N-isobutoxycarbonyl thiourea (iBCTU) for chalcopyrite flotation[J]. The Chinese Journal of Nonferrous Metals, 2017, 27(1):128-137.

    LIU W, LIU G Y, XIAO J J, et al. Mechanism of N-isobutoxycarbonyl thiourea (iBCTU) for chalcopyrite flotation[J]. The Chinese Journal of Nonferrous Metals, 2017, 27(1):128-137.

    [12]

    马鑫, 王帅, 钟宏. 苄基三硫代碳酸钠的合成及其对黄铜矿的浮选性能[J]. 中国有色金属学报, 2018, 28(5):1067-1075.MA X, WANG S, ZHONG H. Sodium benzyl trithiocarbonate synthesis and flotation performance to chalcopyrite[J]. Chinese Journal of Nonferrous metals, 2018, 28(5):1067-1075. doi: 10.19476/j.ysxb.1004.0609.2018.05.24

    MA X, WANG S, ZHONG H. Sodium benzyl trithiocarbonate synthesis and flotation performance to chalcopyrite[J]. Chinese Journal of Nonferrous metals, 2018, 28(5):1067-1075. doi: 10.19476/j.ysxb.1004.0609.2018.05.24

    • 相关文章
  • 施引文献
  • 资源附件(0)
  • 加载中

图(8)

表(2)

计量
  • 文章访问数:  647
  • PDF下载数:  95
  • 施引文献:  0
出版历程
收稿日期:  2021-05-10
刊出日期:  2024-02-25

目录

    版权所有：中国地质调查局发展研究中心 copyright @2020
    返回